[Objective] The aim was to explore the application of terahertz （THz） technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides （butachlor and ...[Objective] The aim was to explore the application of terahertz （THz） technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides （butachlor and metolachlor） were measured by THz time-domain spectroscopy （THz-TDS） under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.展开更多
Transmission spectroscopy of two Nb double superconducting split-ring samples with different thicknesses on MgO substrates was measured by a continuous Tera-Hertz spectrometer.The transmission curves of two different ...Transmission spectroscopy of two Nb double superconducting split-ring samples with different thicknesses on MgO substrates was measured by a continuous Tera-Hertz spectrometer.The transmission curves of two different samples with the thicknesses of 50 and 150 nm at 7.5 K show dips at 480,545 GHz,respectively,which origin from the different capacities and inductances of the samples.For the sample of 50 nm,the dip shifts to lower frequency,also decreases in depth and increases in width with temperature or field increasing below T c of Nb film,while the sample of 150 nm does not show such a phenomenon.This thickness-dependent transmission behavior is due to the kinetic inductance and conductivity change of superfluid electrons in Nb film and may suggest a practical tunable THz filter based on the thinner samples.展开更多
基金Supported by Special Fund for Scientific Research on Public Welfare by China Quality Monitoring Bureau (200910181)National Natural Science Foundation of China (60902095)~~
文摘[Objective] The aim was to explore the application of terahertz （THz） technique in pesticide recognition and residue determination. [Method] THz far-infrared spectral characteristics of 2 herbicides （butachlor and metolachlor） were measured by THz time-domain spectroscopy （THz-TDS） under conditions of room temperature and nitrogen,meanwhile their refractive index and absorption coefficient between 0.2 and 2.2 THz were calculated by using models based on Fresenl equations. [Result] The 2 pesticides both had a series of different characteristic absorption peaks between 0.2 and 2.2 THz,respectively. Their molecular structures were similar,but there were great difference in absorption and refractive index spectrum between them. [Conclusion] THz-TDS technique is feasible to detect pesticide residues,especially there is a greater advantage in identifying the structure of similar substances.
基金supported by the Science Foundation of the Chinese Academy of Sciences (Grant No.KJCX2-SW-W20)the National Basic Research Program of China (Grant No.2011CB921702)
文摘Transmission spectroscopy of two Nb double superconducting split-ring samples with different thicknesses on MgO substrates was measured by a continuous Tera-Hertz spectrometer.The transmission curves of two different samples with the thicknesses of 50 and 150 nm at 7.5 K show dips at 480,545 GHz,respectively,which origin from the different capacities and inductances of the samples.For the sample of 50 nm,the dip shifts to lower frequency,also decreases in depth and increases in width with temperature or field increasing below T c of Nb film,while the sample of 150 nm does not show such a phenomenon.This thickness-dependent transmission behavior is due to the kinetic inductance and conductivity change of superfluid electrons in Nb film and may suggest a practical tunable THz filter based on the thinner samples.
