The burst error of wireless channels and the two-state Markov wireless model are analyzed. Based on this model and the coding modes of the video encoder,the channel distortion of inter-coding and intra-coding due to b...The burst error of wireless channels and the two-state Markov wireless model are analyzed. Based on this model and the coding modes of the video encoder,the channel distortion of inter-coding and intra-coding due to burst error is deduced. Then we propose a novel intra refresh scheme in rate-distortion (R-D) framework. This scheme optimizes the error resilience and coding efficiency of wireless video transmission system. It can also stop error propagation and reduce channel distortion effectively. Simulations under different channel conditions verify the improvements of the proposed scheme with respect to error resilience for wireless video communication.展开更多
A new insight into the constant current-constant voltage (CC-CV) charge protocol based on the spherical diffusion model was presented. From the model, the CV-charge process compensates, to a large extent, the capaci...A new insight into the constant current-constant voltage (CC-CV) charge protocol based on the spherical diffusion model was presented. From the model, the CV-charge process compensates, to a large extent, the capacity loss in the CC process, and the capacity loss increases with increasing the charging rate and decreases with increasing the lithium-ion diffusion coefficient and using a smaller r value (smaller particle-size and larger diffusion coefficient) and a lower charge rate will be helpful to decreasing the capacity loss. The results show that the CC and the CV charging processes, in some way, are complementary and the capacity loss during the CC charging process due to the large electrochemical polarization can be effectively compensated from the CV charging process.展开更多
A novel single-phase Buck converter for power factor correction is proposed. It features simple control due to the constant duty ratio PWM used. It can obtain unity power factor by selecting a suitable LC filter at it...A novel single-phase Buck converter for power factor correction is proposed. It features simple control due to the constant duty ratio PWM used. It can obtain unity power factor by selecting a suitable LC filter at its input to force the voltage of capacitor to operate in discontinuous capacitor voltage mode. And by using another resonant LC filter at its output, it can not only eliminate the input current distortion at the vicinity of the zero crossing of the supply but also drastically reduce the 100 Hz output voltage ripple. The validity of analysis is confirmed by simulation results and experimental results.展开更多
Delay Tolerant Network (DTN) is a class of networks that experience frequent and long-duration partitions due to sparse distribution of nodes. It has a broad prospect to new network applications for a better seal...Delay Tolerant Network (DTN) is a class of networks that experience frequent and long-duration partitions due to sparse distribution of nodes. It has a broad prospect to new network applications for a better sealability, fault-tolerant, and high performance. In DTNs, path failure occurs frequently, so message transfer is not reliable. Sometimes it is required to change routing even in a very short period, resulting in transmission delay and reception delay. However, some well-known assumptions of traditional networks are no longer true in DTNs. In this paper, we study the problem of path failures in DTNs. The path failure process in DTNs is described when the path appears completely normal, completely failed and partially failed. Traditional approaches based on using precisely known network dynamics have not accounted for message losses. A new fault tolerant scheme to generate redundancy is to use erasure coding and full replication. This can greatly decrease the path failure rate. At last, a traffic DTN model is analyzed. Results reveal the superiority of our scheme in comparison to other present schemes.展开更多
In bandpass sigma delta modulator, resonator is the key block, This papcr proposed a new resonator which can simplify the circuit implementation when designing bandpass modulator with Iowpass prototype. The effect of ...In bandpass sigma delta modulator, resonator is the key block, This papcr proposed a new resonator which can simplify the circuit implementation when designing bandpass modulator with Iowpass prototype. The effect of finite gain, finite bandwidth, and path mismatch on the resonator is analyzed. The function of the proposed resonator and the devired equations about path mismatch have been verified by switched capacitor software SWITCAR.展开更多
In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high temp...In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high tempera- ture. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy (EDS), and differential scanning calorimetry (DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1 : 0.4, and the calcination and expansion temperature is in the range of 650--750 ~C. Under such conditions, the expansion volume of composites could reach 98 mE/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.展开更多
An adaptive joint source channel bit allocation method for video communications over error-prone channel is proposed.To protect the bit-streams from the channel bit errors,the rate compatible punctured convolution(RCP...An adaptive joint source channel bit allocation method for video communications over error-prone channel is proposed.To protect the bit-streams from the channel bit errors,the rate compatible punctured convolution(RCPC)code is used to produce coding rates varying from 4/5 to 1/2 using the same encoder and the Viterbi decoder.An expected end-to-end distortion model was presented to estimate the distortion introduced in compressed source coding due to quantization and channel bit errors jointly.Based on the proposed end-to-end distortion model,an adaptive joint source-channel bit allocation method was proposed under time-varying error-prone channel conditions.Simulated results show that the proposed methods could utilize the available channel capacity more efficiently and achieve better video quality than the other fixed coding-based bit allocation methods when transmitting over error-prone channels.展开更多
In order to overcome the adverse effects of Doppler wavelength shift on data transmission in the optical satellite networks,a dynamic routing and wavelength assignment algorithm based on crosslayer design( CL-DRWA) is...In order to overcome the adverse effects of Doppler wavelength shift on data transmission in the optical satellite networks,a dynamic routing and wavelength assignment algorithm based on crosslayer design( CL-DRWA) is introduced which can improve robustness of the network. Above all,a cross-layer optimization model is designed,which considers transmission delay and wavelength-continuity constraint,as well as Doppler wavelength shift. Then CL-DRWA is applied to solve this model,resulting in finding an optimal light path satisfying the above constraints for every connection request. In CL-DRWA,Bellman-Ford method is used to find an optimal route and a distributed relative capacity loss method is implemented to get an optimal wavelength assignment result on the optimal route. Moreover,compared with the dynamic routing and wavelength assignment algorithm based on minimum delay strategy( MD-DRWA),CL-DRWA can make an improvement of 5. 3% on the communication success probability. Meanwhile,CL-DRWA can meet the requirement of transmission delay for real-time services.展开更多
This paper investigates the usage of passive harmonic filters to mitigate harmonic distortions when two resonant points are present in a system caused by shunt capacitors used for power factor correction and bus volta...This paper investigates the usage of passive harmonic filters to mitigate harmonic distortions when two resonant points are present in a system caused by shunt capacitors used for power factor correction and bus voltage regulation. Six scenarios were investigated using DIgSILENT 14 power factor)' software. The investigations are with and without power factor correction and capacitors used to increase bus voltage. Passive harmonic filters are designed to reduce harmonic distortions at the PCC (point of common coupling) to fall within the IEEE 519 harmonic voltage and current limits caused by parallel resonance. The results of the case studies are analysed to evaluate the effectiveness of the filter design.展开更多
Areas of planting sugarcane are located in subtropical and tropical parts of Guangxi. These areas are characterized by high temperature, heavy rainfall and nutrients leaching. It results in strong decomposition of soi...Areas of planting sugarcane are located in subtropical and tropical parts of Guangxi. These areas are characterized by high temperature, heavy rainfall and nutrients leaching. It results in strong decomposition of soil mineral and a low cation exchange capacity (CEC), low organic matter, and low phosphorus (P), potassium (K) and sulfur (S) in soils. In about 30% of the soils in the planting sugarcane regions the total sulfur and the plant-available sulfur are under 150 mg/kg and 12 mg/kg, respectively. The sulfur nutrition is usually supplied insufficiently for sugarcane growth. The total sulfur of and available sulfur are under the medium level in nearly 50% of the soils in the planting sugarcane regions. Therefore, with the improvement of production of the sugarcane, the sulfur soil nutrition will influence and limit sugarcane yield. After application of sulfur fertilizer, available stem, single stem weight increased 5.77%-9.43% of sugarcane yield than without the treatment. It still can improve the cane sugar and fibre content. And the sugarcane can obtain better economic benefits to use the sulfur phosphorus ammonium; it is 18.2-20.23 with output/input (VCR) to use the sulfur fertilizer. Amount of sugarcane absorption sulfur reaches 44.1-67 kg/ha. The treatment with no sulfur fertilizer annual sulfur nutrient lose will be 23.67 kg/ha because sugarcane yield uptake from the field.展开更多
This paper presents and investigates planar and coaxial high frequency power transformers used for DC/DC converters in a three phase photo voltaic (PV) power systems. The winding structure including a Faraday shield...This paper presents and investigates planar and coaxial high frequency power transformers used for DC/DC converters in a three phase photo voltaic (PV) power systems. The winding structure including a Faraday shield between the primary and secondary windings is designed to minimize eddy current losses, skin and proximity effects, and to reduce the leakage inductance, and the inter winding coupling capacitance. Finite Element Method is employed to analyze the magnetic flux and eddy current distributions. The two different kinds of prototype high frequency transformers are designed and tested. The simulation and experiment results are demonstrated and compared with non-shielded transformers. The shielded transformers have achieved the expected results with a relatively small coupling capacitance, compared with the conventional high frequency transformer. This shield decreases the inter-winding coupling capacitance Cps. The topology of this shield has to be such that it acts as a Faraday screen while avoiding eddy current generation.展开更多
This paper presents a powerful approach to find the optimal size and location of distributed generation units in a distribution system using GA (Genetic Optimization algorithm). It is proved that GA method is fast a...This paper presents a powerful approach to find the optimal size and location of distributed generation units in a distribution system using GA (Genetic Optimization algorithm). It is proved that GA method is fast and easy tool to enable the planners to select accurate and the optimum size of generators to improve the system voltage profile in addition to reduce the active and reactive power loss. GA fitness function is introduced including the active power losses, reactive power losses and the cumulative voltage deviation variables with selecting weight of each variable. GA fitness function is subjected to voltage constraints, active and reactive power losses constraints and DG size constraint.展开更多
A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavi...A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavior and mechanism of orthorhombic V_(2)O_(5) single-crystalline nanowires in the voltage window of 1.0–4.0 V(vs.Na/Na+).The single-crystalline nanowires exhibit a large irreversible capacity loss during the first discharge/charge cycle,and then show excellent cycling stability in the following cycles.At a current density of 100 mA g^(−1),the nanowires electrode delivers initial discharge/charge capacity of 217/88 mA h g^(−1),corresponding to a Coulombic efficiency of only 40.5%;after 100 cycles,the electrode remains a reversible discharge capacity of 78 mA h g^(−1) with a fading rate of only 0.09%per cycle compared with the 2nd cycle discharge capacity.The sodium ion storage mechanism was investigated,illustrating that the large irreversible capacity loss in the first cycle can be attributed to the initially formed single-crystalline α′-Nax V_(2)O_(5)(0.02<x<0.88),in which sodium ions cannot be electrochemically extracted and the α′-Na0.88 V_(2)O_(5) can reversibly host and release sodium ions via a single-phase(solid solution)reaction,leading to excellent cycling stability.The Na^(+) diffusion coefficient in α′-Nax V_(2)O_(5) ranges from 10^(−12) to 10^(−11.5) cm^(2) s^(−1) as evaluated by galvanostatic intermittent titration technique(GITT).展开更多
In the section ( 351b-358a ) about akrasia (incontinence), Socrates gives the strongest argument for his intellectual paradox: that no one is willing to do what he thinks to be bad. This marvellous accomplishment...In the section ( 351b-358a ) about akrasia (incontinence), Socrates gives the strongest argument for his intellectual paradox: that no one is willing to do what he thinks to be bad. This marvellous accomplishment, nevertheless, is based on the hedonistic view that pleasure is good. It conflicts with our general conception of the historical Socrates and is incompatible with the Socrates emerging in other earlier dialogues of Plato. This paper will argue that Protagoras is not really forced or fooled into recognizing hedonism, but consciously advocates hedonism all the way. In fact, Socrates has positively, though incompletely, fought it back.展开更多
electrolyte. The properties of lithium-ion (Li-ion) battery, such as cycle life, irreversible capacity loss, self-discharge rate, electrode corrosion and safety are usually ascribed to the quality of the SEI, which ar...electrolyte. The properties of lithium-ion (Li-ion) battery, such as cycle life, irreversible capacity loss, self-discharge rate, electrode corrosion and safety are usually ascribed to the quality of the SEI, which are highly dependent on the thickness. Thus, understanding the formation mechanism and the SEI thickness is of prime interest. First, we apply dimensional analysis to obtain an explicit relation between the thickness and the number density in this study. Then the SEI thickness in the initial charge-discharge cycle is analyzed and estimated for the first time using the Cahn-Hilliard phase-field model. In addition, the SEI thickness by molecular dynamics simulation validates the theoretical results. It has been shown that the established model and the simulation in this paper estimate the SEI thickness concisely within order-of-magnitude of nanometers. Our results may help in evaluating the performance of SEI and assist the future design of Li-ion battery.展开更多
文摘The burst error of wireless channels and the two-state Markov wireless model are analyzed. Based on this model and the coding modes of the video encoder,the channel distortion of inter-coding and intra-coding due to burst error is deduced. Then we propose a novel intra refresh scheme in rate-distortion (R-D) framework. This scheme optimizes the error resilience and coding efficiency of wireless video transmission system. It can also stop error propagation and reduce channel distortion effectively. Simulations under different channel conditions verify the improvements of the proposed scheme with respect to error resilience for wireless video communication.
基金Projects(20676152, 20876178) supported by the National Natural Science Foundation of China
文摘A new insight into the constant current-constant voltage (CC-CV) charge protocol based on the spherical diffusion model was presented. From the model, the CV-charge process compensates, to a large extent, the capacity loss in the CC process, and the capacity loss increases with increasing the charging rate and decreases with increasing the lithium-ion diffusion coefficient and using a smaller r value (smaller particle-size and larger diffusion coefficient) and a lower charge rate will be helpful to decreasing the capacity loss. The results show that the CC and the CV charging processes, in some way, are complementary and the capacity loss during the CC charging process due to the large electrochemical polarization can be effectively compensated from the CV charging process.
文摘A novel single-phase Buck converter for power factor correction is proposed. It features simple control due to the constant duty ratio PWM used. It can obtain unity power factor by selecting a suitable LC filter at its input to force the voltage of capacitor to operate in discontinuous capacitor voltage mode. And by using another resonant LC filter at its output, it can not only eliminate the input current distortion at the vicinity of the zero crossing of the supply but also drastically reduce the 100 Hz output voltage ripple. The validity of analysis is confirmed by simulation results and experimental results.
基金National Nature Science Foundation of China (No.60534020)Cultivation Fund of the Key Scientific and Technical Innovation Project from Ministry of Education of China(No.706024)+1 种基金International Science Cooperation Foundation of Shanghai,China(No.061307041)Shanghai Talent Developing Foundation,China(No.010)
文摘Delay Tolerant Network (DTN) is a class of networks that experience frequent and long-duration partitions due to sparse distribution of nodes. It has a broad prospect to new network applications for a better sealability, fault-tolerant, and high performance. In DTNs, path failure occurs frequently, so message transfer is not reliable. Sometimes it is required to change routing even in a very short period, resulting in transmission delay and reception delay. However, some well-known assumptions of traditional networks are no longer true in DTNs. In this paper, we study the problem of path failures in DTNs. The path failure process in DTNs is described when the path appears completely normal, completely failed and partially failed. Traditional approaches based on using precisely known network dynamics have not accounted for message losses. A new fault tolerant scheme to generate redundancy is to use erasure coding and full replication. This can greatly decrease the path failure rate. At last, a traffic DTN model is analyzed. Results reveal the superiority of our scheme in comparison to other present schemes.
文摘In bandpass sigma delta modulator, resonator is the key block, This papcr proposed a new resonator which can simplify the circuit implementation when designing bandpass modulator with Iowpass prototype. The effect of finite gain, finite bandwidth, and path mismatch on the resonator is analyzed. The function of the proposed resonator and the devired equations about path mismatch have been verified by switched capacitor software SWITCAR.
基金Supported by Applied Basic Research Project of Sichuan Province (No.2006J13-014)Innovation Fund of Panzhihua University
文摘In order to obtain anatase TiO2/expanded graphite with high expansion volume, titania gel was introduced to expandable graphite surface by sol-gel process, and then the composite was expanded and calcined at high tempera- ture. The samples were analysed by using scanning electron microscope (SEM), X-ray diffraction(XRD), energy disperse spectroscopy (EDS), and differential scanning calorimetry (DSC). The optimal conditions for preparation are as follows: the molar ratio of tetrabutyl orthotitanate to triethanolamine is 1 : 0.4, and the calcination and expansion temperature is in the range of 650--750 ~C. Under such conditions, the expansion volume of composites could reach 98 mE/g, and the mass loss ratio is less than 5%. The analysis shows that lower temperature and smaller particle size of graphite are helpful to the formation of anatase-type of TiO2, but larger particle size will lead to lower mass loss ratio, and higher temperature and larger particle size will lead to higher expansion volume.
基金National High-Tech Research and Development Plan of China(No.2003AA1Z2130)Science and Technology Project of Zhejiang Province,China(No.2006C11200)
文摘An adaptive joint source channel bit allocation method for video communications over error-prone channel is proposed.To protect the bit-streams from the channel bit errors,the rate compatible punctured convolution(RCPC)code is used to produce coding rates varying from 4/5 to 1/2 using the same encoder and the Viterbi decoder.An expected end-to-end distortion model was presented to estimate the distortion introduced in compressed source coding due to quantization and channel bit errors jointly.Based on the proposed end-to-end distortion model,an adaptive joint source-channel bit allocation method was proposed under time-varying error-prone channel conditions.Simulated results show that the proposed methods could utilize the available channel capacity more efficiently and achieve better video quality than the other fixed coding-based bit allocation methods when transmitting over error-prone channels.
基金Supported by the National Natural Science Foundation of China(No.61675033,61575026,61675232,61571440)the National High Technology Research and Development Program of China(No.2015AA015504)
文摘In order to overcome the adverse effects of Doppler wavelength shift on data transmission in the optical satellite networks,a dynamic routing and wavelength assignment algorithm based on crosslayer design( CL-DRWA) is introduced which can improve robustness of the network. Above all,a cross-layer optimization model is designed,which considers transmission delay and wavelength-continuity constraint,as well as Doppler wavelength shift. Then CL-DRWA is applied to solve this model,resulting in finding an optimal light path satisfying the above constraints for every connection request. In CL-DRWA,Bellman-Ford method is used to find an optimal route and a distributed relative capacity loss method is implemented to get an optimal wavelength assignment result on the optimal route. Moreover,compared with the dynamic routing and wavelength assignment algorithm based on minimum delay strategy( MD-DRWA),CL-DRWA can make an improvement of 5. 3% on the communication success probability. Meanwhile,CL-DRWA can meet the requirement of transmission delay for real-time services.
文摘This paper investigates the usage of passive harmonic filters to mitigate harmonic distortions when two resonant points are present in a system caused by shunt capacitors used for power factor correction and bus voltage regulation. Six scenarios were investigated using DIgSILENT 14 power factor)' software. The investigations are with and without power factor correction and capacitors used to increase bus voltage. Passive harmonic filters are designed to reduce harmonic distortions at the PCC (point of common coupling) to fall within the IEEE 519 harmonic voltage and current limits caused by parallel resonance. The results of the case studies are analysed to evaluate the effectiveness of the filter design.
文摘Areas of planting sugarcane are located in subtropical and tropical parts of Guangxi. These areas are characterized by high temperature, heavy rainfall and nutrients leaching. It results in strong decomposition of soil mineral and a low cation exchange capacity (CEC), low organic matter, and low phosphorus (P), potassium (K) and sulfur (S) in soils. In about 30% of the soils in the planting sugarcane regions the total sulfur and the plant-available sulfur are under 150 mg/kg and 12 mg/kg, respectively. The sulfur nutrition is usually supplied insufficiently for sugarcane growth. The total sulfur of and available sulfur are under the medium level in nearly 50% of the soils in the planting sugarcane regions. Therefore, with the improvement of production of the sugarcane, the sulfur soil nutrition will influence and limit sugarcane yield. After application of sulfur fertilizer, available stem, single stem weight increased 5.77%-9.43% of sugarcane yield than without the treatment. It still can improve the cane sugar and fibre content. And the sugarcane can obtain better economic benefits to use the sulfur phosphorus ammonium; it is 18.2-20.23 with output/input (VCR) to use the sulfur fertilizer. Amount of sugarcane absorption sulfur reaches 44.1-67 kg/ha. The treatment with no sulfur fertilizer annual sulfur nutrient lose will be 23.67 kg/ha because sugarcane yield uptake from the field.
文摘This paper presents and investigates planar and coaxial high frequency power transformers used for DC/DC converters in a three phase photo voltaic (PV) power systems. The winding structure including a Faraday shield between the primary and secondary windings is designed to minimize eddy current losses, skin and proximity effects, and to reduce the leakage inductance, and the inter winding coupling capacitance. Finite Element Method is employed to analyze the magnetic flux and eddy current distributions. The two different kinds of prototype high frequency transformers are designed and tested. The simulation and experiment results are demonstrated and compared with non-shielded transformers. The shielded transformers have achieved the expected results with a relatively small coupling capacitance, compared with the conventional high frequency transformer. This shield decreases the inter-winding coupling capacitance Cps. The topology of this shield has to be such that it acts as a Faraday screen while avoiding eddy current generation.
文摘This paper presents a powerful approach to find the optimal size and location of distributed generation units in a distribution system using GA (Genetic Optimization algorithm). It is proved that GA method is fast and easy tool to enable the planners to select accurate and the optimum size of generators to improve the system voltage profile in addition to reduce the active and reactive power loss. GA fitness function is introduced including the active power losses, reactive power losses and the cumulative voltage deviation variables with selecting weight of each variable. GA fitness function is subjected to voltage constraints, active and reactive power losses constraints and DG size constraint.
基金financially supported by the National Natural Science Foundation of China (51664012)Guangxi Natural Science Foundation (2017GXNSFAA198117 and2015GXNSFGA139006)the Technology Major Project of Guangxi(AA19046001)
文摘A fundamental understanding of the electrochemical reaction process and mechanism of electrodes is very crucial for developing high-performance electrode materials.In this study,we report the sodium ion storage behavior and mechanism of orthorhombic V_(2)O_(5) single-crystalline nanowires in the voltage window of 1.0–4.0 V(vs.Na/Na+).The single-crystalline nanowires exhibit a large irreversible capacity loss during the first discharge/charge cycle,and then show excellent cycling stability in the following cycles.At a current density of 100 mA g^(−1),the nanowires electrode delivers initial discharge/charge capacity of 217/88 mA h g^(−1),corresponding to a Coulombic efficiency of only 40.5%;after 100 cycles,the electrode remains a reversible discharge capacity of 78 mA h g^(−1) with a fading rate of only 0.09%per cycle compared with the 2nd cycle discharge capacity.The sodium ion storage mechanism was investigated,illustrating that the large irreversible capacity loss in the first cycle can be attributed to the initially formed single-crystalline α′-Nax V_(2)O_(5)(0.02<x<0.88),in which sodium ions cannot be electrochemically extracted and the α′-Na0.88 V_(2)O_(5) can reversibly host and release sodium ions via a single-phase(solid solution)reaction,leading to excellent cycling stability.The Na^(+) diffusion coefficient in α′-Nax V_(2)O_(5) ranges from 10^(−12) to 10^(−11.5) cm^(2) s^(−1) as evaluated by galvanostatic intermittent titration technique(GITT).
文摘In the section ( 351b-358a ) about akrasia (incontinence), Socrates gives the strongest argument for his intellectual paradox: that no one is willing to do what he thinks to be bad. This marvellous accomplishment, nevertheless, is based on the hedonistic view that pleasure is good. It conflicts with our general conception of the historical Socrates and is incompatible with the Socrates emerging in other earlier dialogues of Plato. This paper will argue that Protagoras is not really forced or fooled into recognizing hedonism, but consciously advocates hedonism all the way. In fact, Socrates has positively, though incompletely, fought it back.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11372313, U1562105, and 11611130019)the Chinese Academy of Sciences (CAS) through CAS Interdisciplinary Innovation Team Project, the CAS Key Research Program of Frontier Sciences (Grant No. QYZDJ-SSW-JSC019)the CAS Strategic Priority Research Program (Grant No. XDB22040401)
文摘electrolyte. The properties of lithium-ion (Li-ion) battery, such as cycle life, irreversible capacity loss, self-discharge rate, electrode corrosion and safety are usually ascribed to the quality of the SEI, which are highly dependent on the thickness. Thus, understanding the formation mechanism and the SEI thickness is of prime interest. First, we apply dimensional analysis to obtain an explicit relation between the thickness and the number density in this study. Then the SEI thickness in the initial charge-discharge cycle is analyzed and estimated for the first time using the Cahn-Hilliard phase-field model. In addition, the SEI thickness by molecular dynamics simulation validates the theoretical results. It has been shown that the established model and the simulation in this paper estimate the SEI thickness concisely within order-of-magnitude of nanometers. Our results may help in evaluating the performance of SEI and assist the future design of Li-ion battery.