The absorption spectrum and photoluminescence spectrum of multiwalled carbon nanotubes(MWNTs) and the peaks related with Van Hove singularities(VHS) were obtained experimentally.Both the VHS formation and the change o...The absorption spectrum and photoluminescence spectrum of multiwalled carbon nanotubes(MWNTs) and the peaks related with Van Hove singularities(VHS) were obtained experimentally.Both the VHS formation and the change of band gaps in MWNTs depend on the intershell interaction.The VHS makes the probability of optical transitions enhanced,but the intershell interaction suppresses such radiative transitions.The excitation in the experiment involves a two-photon absorption process and the emission light has the effect of the optical frequency up-conversion.展开更多
As a demonstration of the spectrum-parity matching condition (SPMC) for quantum state transfer, we investigate the propagation of single-magnon state in the Heisenberg chain in the confined external tangent magnetic...As a demonstration of the spectrum-parity matching condition (SPMC) for quantum state transfer, we investigate the propagation of single-magnon state in the Heisenberg chain in the confined external tangent magnetic field analytically and numerically. It shows that the initial Gaussian wave packet can be retrieved at the counterpart location near-perfectly over a longer distance if the dispersion relation of the system meets the SPMC approximately.展开更多
The Ho3+/yb3+ co-doped a-NaYF4 single crystal was grown successfully for the first time by a modified Bridgman method in which KF was used as assisting flux and a large temperature gradient (70-90℃ /cm) of solid-...The Ho3+/yb3+ co-doped a-NaYF4 single crystal was grown successfully for the first time by a modified Bridgman method in which KF was used as assisting flux and a large temperature gradient (70-90℃ /cm) of solid-liquid interface was adopted. Upconversion emissions at green -544 nm, red -657 and -751 nm were obtained under 980 nm laser diode excitation. The intensity at -544 nm was much stronger than those of -657 and -751 nm. The mechanisms of the upconversion emissions were investigated by studying the relationship between the upconversion intensity and pump power. The optimized Yb3+ concentration was about 8.08moi% when Ho3+ concentration was hold at about 1.0mol%. The results showed that Ho3+/yb3+ doped α-NaYF4 single crystal was a possible candidate upconversion material for the green solid-state laser.展开更多
In recent years, peculiar physical phenomena enabled by non-Hermitian systems, especially the parity-time(PT)-symmetric systems, have drawn tremendous research interests. Particularly, special spectral degeneracies kn...In recent years, peculiar physical phenomena enabled by non-Hermitian systems, especially the parity-time(PT)-symmetric systems, have drawn tremendous research interests. Particularly, special spectral degeneracies known as exceptional points(EPs) and coherent perfect absorber-laser(CPAL) points where zero and infinite large eigenvalues coexist are the most popular topics to be studied. To date, the discussions of EPs that serve as transition boundaries between broken PT-symmetry phase and exact PT-symmetry phase have been intensively presented. However, the theoretical analysis and experimental validations of CPAL points are inadequate. Different from EPs, CPAL points, as a special solution of broken PT-symmetry phase, may exhibit even further counterintuitive physical features, which may have significant implications to study non-Hermitian physics. Here, we review some recent advances of CPAL phenomena in different sub-disciplines of physics, including optics, electronics and electromagnetics, and acoustics.Additionally, we also provide an envision of future directions and applications of CPAL systems.展开更多
In this paper,knotted objects (RS vortices) in the theory of topological phase singularity in electromagneticfield have been investigated in details.By using the Duan's topological current theory,we rewrite the to...In this paper,knotted objects (RS vortices) in the theory of topological phase singularity in electromagneticfield have been investigated in details.By using the Duan's topological current theory,we rewrite the topological currentform of RS vortices and use this topological current we reveal that the Hopf invariant of RS vortices is just the sum ofthe linking and self-linking numbers of the knotted RS vortices.Furthermore,the conservation of the Hopf invariant inthe splitting,the mergence and the intersection processes of knotted RS vortices is also discussed.展开更多
Methyl vinyl ketone oxide,an unsaturated four-carbon Criegee intermediate produced from the ozonolysis of isoprene has been recognized to play a key role in determining the tropospheric OH concentration.It exists in f...Methyl vinyl ketone oxide,an unsaturated four-carbon Criegee intermediate produced from the ozonolysis of isoprene has been recognized to play a key role in determining the tropospheric OH concentration.It exists in four configurations(anti-anti,anti-syn,synanti,and syn-syn)due to two different substituents of saturated methyl and unsaturated vinyl groups.In this study,we have carried out the electronic structure calculation at the multi-configurational CASSCF and multi-state MS-CASPT2 levels,as well as the trajectory surface-hopping nonadiabatic dynamics simulation at the CASSCF level to reveal the different fates of syn/anti configurations in photochemical process.Our results show that the dominant channel for the S1-state decay is a ring closure,isomerization to dioxirane,during which,the syn(C-O)configuration with an intramolecular hydrogen bond shows slower nonadiabatic photoisomerization.More importantly,it has been found for the first time in photochemistry of Criegee intermediate that the cooperation of two heavy groups(methyl and vinyl)leads to an evident pyramidalization of C3 atom in methyl-vinyl Criegee intermediate,which then results in two structurally-independent minimal-energy crossing points(CIs)towards the syn(C-O)and anti(C-O)sides,respectively.The preference of surface hopping for a certain CI is responsible for the different dynamics of each configuration.展开更多
To evaluate the particle dynamics and estimate the POC (particulate organic carbon) export flux from the euphotic zone in the western Arctic Ocean,234 Th238 U disequilibrium was applied during the second Chinese Natio...To evaluate the particle dynamics and estimate the POC (particulate organic carbon) export flux from the euphotic zone in the western Arctic Ocean,234 Th238 U disequilibrium was applied during the second Chinese National Arctic Research Expedition (July 15-September 26,2003).The POC export fluxes are estimated from the measured profiles of the 234 Th/238 U activity ratios and the POC/PTh ratios.The average residence times of the particulate and dissolved 234 Th in the euphotic zone are 33 d and 121 d,and their average export fluxes are 480 dpm/m 2 d and 760 dpm/m 2 d,respectively.The scavenging and removal processes of particle reactive elements are active in the upper layer of the Chukchi Sea.The average residence time of 234 Th increases from shelf to basin,while the export fluxes of 234 Th decrease.The estimated POC export fluxes from the euphotic zone vary from 2.1 to 20.3 mmol/m 2 d,indicating that the western Arctic Ocean is an important carbon sink in summer due to efficient biological pump.展开更多
Based on the proposed partly equidifferent mapping and its specific Differential Amplitude and Pulse Position Modulation(DAPPM) demodulation, a modified FSO scheme for turbulent channel is designed and analyzed. The n...Based on the proposed partly equidifferent mapping and its specific Differential Amplitude and Pulse Position Modulation(DAPPM) demodulation, a modified FSO scheme for turbulent channel is designed and analyzed. The novel Low Density Parity Check(LDPC) coded 4×4 and 4×8 DAPPM Free-Space Optical communication(FSO) system is constructed. The Monte Carlo simulation results show approximately 2d B transmit power reduction against classical LDPC-DAPPM at the identical Bit-Error-Rate in strong turbulent channel. The proposed partly equidifferent mapping is compatible with other modulations, so it enables widespread adoption in other coded FSO systems.展开更多
By suitably choosing the normalization factors we introduce the even- and odd-negative binomial states. In some limit cases they approach the even- and odd-coherent states, respectively. We also derive a new eigenvect...By suitably choosing the normalization factors we introduce the even- and odd-negative binomial states. In some limit cases they approach the even- and odd-coherent states, respectively. We also derive a new eigenvector equation that the negative binomial state satishes as a nonlinear coherent state.展开更多
We present a differential geometric perspective of the IEP for symmetric matrices in the framework of a fibre bundle with structure group SO(n). In particular, a Newton type algorithm is developed to construct a non...We present a differential geometric perspective of the IEP for symmetric matrices in the framework of a fibre bundle with structure group SO(n). In particular, a Newton type algorithm is developed to construct a non singular symmetric matrix for given target eigenvalues using a singular symmetric matrix as the initial matrix for the iteration. Explicit computations are performed for 2 x 2 non singular symmetric matrix to illustrate the result.展开更多
Generating entangled states efficiently is a hot topic in the area of quantum information science.With the approach presented in this paper,a general parity gate could be realized and a wide range of entangled states,...Generating entangled states efficiently is a hot topic in the area of quantum information science.With the approach presented in this paper,a general parity gate could be realized and a wide range of entangled states,including GHZ state,W state,Dicke state,arbitrary graph state and locally maximally entanglable states,can be generated flexibly.The generation of GHZ state,W state,and Dicke state is probabilistic but heralded and the total success probability is unit.In addition,the arbitrary graph state and locally maximally entanglable states generation is deterministic,flexible,and highly efficient.Especially,with the"simultaneous"generation pattern,the complexity of the graph state generation and locally maximally entanglable states generation could be reduced greatly,providing a more efficient and feasible way to generate the entangled states.展开更多
We present exact analytical solutions to parity-time(P T) symmetric optical system describing light transport in P T-symmetric optical couplers. We show that light intensity oscillates periodically between two wavegui...We present exact analytical solutions to parity-time(P T) symmetric optical system describing light transport in P T-symmetric optical couplers. We show that light intensity oscillates periodically between two waveguides for unbroken P T-symmetric phase, whereas light always leaves the system from the waveguide experiencing gain when light is initially input at either waveguide experiencing gain or waveguide experiencing loss for broken P T-symmetric phase. These analytical results agree with the recent experimental observation reported by Ru¨ter et al. [Nat. Phys.6(2010) 192]. Besides, we present a scheme for manipulating P T symmetry by applying a periodic modulation. Our results provide an efficient way to control light propagation in periodically modulated P T-symmetric system by tuning the modulation amplitude and frequency.展开更多
In this paper, we review some results on the spectral methods. We first consider the Jacobi spectral method and the generalized Jacobi spectral method for various problems, including degenerated and singular different...In this paper, we review some results on the spectral methods. We first consider the Jacobi spectral method and the generalized Jacobi spectral method for various problems, including degenerated and singular differential equations. Then we present the generalized Jacobi quasi-orthogonal approximation and its applica- tions to the spectral element methods for high order problems with mixed inhomogeneous boundary conditions. We also discuss the related spectral methods for non-rectangular domains and the irrational spectral methods for unbounded domains. Next, we consider the Hermite spectral method and the generalized Hermite spec- tral method with their applications. Finally, we consider the Laguerre spectral method and the generalized Laguerre spectral method for many problems defined on unbounded domains. We also present the generalized Laguerre quasi-orthogonal approximation and its applications to certain problems of non-standard type and exterior problems.展开更多
We perform a comparative study for the LHC di-photon Higgs signal in three different littlest Higgs models with T-parity (named LHT-Ⅰ, LHT-Ⅱ and LHT-Ⅲ). We find that compared with the Standard Model prediction, the...We perform a comparative study for the LHC di-photon Higgs signal in three different littlest Higgs models with T-parity (named LHT-Ⅰ, LHT-Ⅱ and LHT-Ⅲ). We find that compared with the Standard Model prediction, the di-photon rate is always suppressed and the suppression extent can be different for different models. The LHC will soon give a solid judgement whether the di-photon rate is larger than the SM prediction, which can be utilized as a sensitive probe for the three models.展开更多
We investigate the zero dielectric constant limit to the non-isentropic compressible Euler-Maxwell system.We justify this singular limit rigorously in the framework of smooth solutions and obtain the nonisentropic com...We investigate the zero dielectric constant limit to the non-isentropic compressible Euler-Maxwell system.We justify this singular limit rigorously in the framework of smooth solutions and obtain the nonisentropic compressible magnetohydrodynamic equations as the dielectric constant tends to zero.展开更多
Optical control of exotic properties in strongly correlated electron materials is very attractive owing to their potential applications in optical and electronic devices.Herein,we demonstrate a vertical heterojunction...Optical control of exotic properties in strongly correlated electron materials is very attractive owing to their potential applications in optical and electronic devices.Herein,we demonstrate a vertical heterojunction made of a correlated electron oxide thin film VO_(2) and a conductive 0.05 wt% Nb-doped TiO_(2) single crystal,whose metal-insulator transition(MIT)across the nanoscale heterointerface can be efficiently modulated by visible light irradiation.The magnitude of the MIT decreases from ~350 in the dark state to ~7 in the illuminated state,obeying a power law with respect to the light power density.The junction resistance is switched in a reversible and synchronous manner by turning light on and off.The optical tunability of it is also exponentially proportional to the light power density,and a 320-fold on/off ratio is achieved with an irradiance of 65.6 mW cm^(-2) below the MIT temperature.While the VO_(2) thin film is metallic above the MIT temperature,the optical tunability is remarkably weakened,with a one-fold change remaining under light illumination.These results are co-attributed to a net reduction(~15 meV)in the apparent barrier height and the photocarrier-injection-induced metallization of the VO_(2) heterointerface through a photovoltaic effect,which is induced by deep defect level transition upon the visible light irradiance at low temperature.Additionally,the optical tunability is minimal,resulting from the quite weak modulation of the already metallic band structure in the Schottky-type junction above the MIT temperature.This work enables a remotely optical scheme to manipulate the MIT,implying potential uncooled photodetection and photoswitch applications.展开更多
文摘The absorption spectrum and photoluminescence spectrum of multiwalled carbon nanotubes(MWNTs) and the peaks related with Van Hove singularities(VHS) were obtained experimentally.Both the VHS formation and the change of band gaps in MWNTs depend on the intershell interaction.The VHS makes the probability of optical transitions enhanced,but the intershell interaction suppresses such radiative transitions.The excitation in the experiment involves a two-photon absorption process and the emission light has the effect of the optical frequency up-conversion.
基金The project supported by National Natural Science Foundation of China under Grant No. 10474104 and the National Fundamental Research Program of China under Grant No. 2001CB309310
文摘As a demonstration of the spectrum-parity matching condition (SPMC) for quantum state transfer, we investigate the propagation of single-magnon state in the Heisenberg chain in the confined external tangent magnetic field analytically and numerically. It shows that the initial Gaussian wave packet can be retrieved at the counterpart location near-perfectly over a longer distance if the dispersion relation of the system meets the SPMC approximately.
基金This work was supported by the National Natural Science Foundation of China (No.51472125, No.51272109) and K. C. Wong Magna Fund in Ningbo University.
文摘The Ho3+/yb3+ co-doped a-NaYF4 single crystal was grown successfully for the first time by a modified Bridgman method in which KF was used as assisting flux and a large temperature gradient (70-90℃ /cm) of solid-liquid interface was adopted. Upconversion emissions at green -544 nm, red -657 and -751 nm were obtained under 980 nm laser diode excitation. The intensity at -544 nm was much stronger than those of -657 and -751 nm. The mechanisms of the upconversion emissions were investigated by studying the relationship between the upconversion intensity and pump power. The optimized Yb3+ concentration was about 8.08moi% when Ho3+ concentration was hold at about 1.0mol%. The results showed that Ho3+/yb3+ doped α-NaYF4 single crystal was a possible candidate upconversion material for the green solid-state laser.
文摘In recent years, peculiar physical phenomena enabled by non-Hermitian systems, especially the parity-time(PT)-symmetric systems, have drawn tremendous research interests. Particularly, special spectral degeneracies known as exceptional points(EPs) and coherent perfect absorber-laser(CPAL) points where zero and infinite large eigenvalues coexist are the most popular topics to be studied. To date, the discussions of EPs that serve as transition boundaries between broken PT-symmetry phase and exact PT-symmetry phase have been intensively presented. However, the theoretical analysis and experimental validations of CPAL points are inadequate. Different from EPs, CPAL points, as a special solution of broken PT-symmetry phase, may exhibit even further counterintuitive physical features, which may have significant implications to study non-Hermitian physics. Here, we review some recent advances of CPAL phenomena in different sub-disciplines of physics, including optics, electronics and electromagnetics, and acoustics.Additionally, we also provide an envision of future directions and applications of CPAL systems.
基金supported by National Natural Science Foundation of China and the Cuiying Programme of Lanzhou University
文摘In this paper,knotted objects (RS vortices) in the theory of topological phase singularity in electromagneticfield have been investigated in details.By using the Duan's topological current theory,we rewrite the topological currentform of RS vortices and use this topological current we reveal that the Hopf invariant of RS vortices is just the sum ofthe linking and self-linking numbers of the knotted RS vortices.Furthermore,the conservation of the Hopf invariant inthe splitting,the mergence and the intersection processes of knotted RS vortices is also discussed.
基金supported by the the National Natural Science Foundation of China(No.21873060and No.21473107)the Fundamental Research Funds for the Central Universities(No.GK201901007,No.2018CBLY004)。
文摘Methyl vinyl ketone oxide,an unsaturated four-carbon Criegee intermediate produced from the ozonolysis of isoprene has been recognized to play a key role in determining the tropospheric OH concentration.It exists in four configurations(anti-anti,anti-syn,synanti,and syn-syn)due to two different substituents of saturated methyl and unsaturated vinyl groups.In this study,we have carried out the electronic structure calculation at the multi-configurational CASSCF and multi-state MS-CASPT2 levels,as well as the trajectory surface-hopping nonadiabatic dynamics simulation at the CASSCF level to reveal the different fates of syn/anti configurations in photochemical process.Our results show that the dominant channel for the S1-state decay is a ring closure,isomerization to dioxirane,during which,the syn(C-O)configuration with an intramolecular hydrogen bond shows slower nonadiabatic photoisomerization.More importantly,it has been found for the first time in photochemistry of Criegee intermediate that the cooperation of two heavy groups(methyl and vinyl)leads to an evident pyramidalization of C3 atom in methyl-vinyl Criegee intermediate,which then results in two structurally-independent minimal-energy crossing points(CIs)towards the syn(C-O)and anti(C-O)sides,respectively.The preference of surface hopping for a certain CI is responsible for the different dynamics of each configuration.
基金Supported by the National Natural Science Foundation of China (No.40531007)the China Action Plan of the International Polar Year (Nos.2009DFA22920 and 2008Po5040014-03)+1 种基金the International Science and Technology Cooperation (Nos. 2008DFA20420 and 2009DFA22920)the Polar Atmospheric Environment Remote Sensing Monitoring Technique of the National High Technology Research and DevelopmentProgram of China (863 Program) (No. N2008DFA20420)
文摘To evaluate the particle dynamics and estimate the POC (particulate organic carbon) export flux from the euphotic zone in the western Arctic Ocean,234 Th238 U disequilibrium was applied during the second Chinese National Arctic Research Expedition (July 15-September 26,2003).The POC export fluxes are estimated from the measured profiles of the 234 Th/238 U activity ratios and the POC/PTh ratios.The average residence times of the particulate and dissolved 234 Th in the euphotic zone are 33 d and 121 d,and their average export fluxes are 480 dpm/m 2 d and 760 dpm/m 2 d,respectively.The scavenging and removal processes of particle reactive elements are active in the upper layer of the Chukchi Sea.The average residence time of 234 Th increases from shelf to basin,while the export fluxes of 234 Th decrease.The estimated POC export fluxes from the euphotic zone vary from 2.1 to 20.3 mmol/m 2 d,indicating that the western Arctic Ocean is an important carbon sink in summer due to efficient biological pump.
基金supported by the National High-tech R&D Program (863 Program) 2013AA041003the Natural Science Foundation of China under Grants 51165033the Science and Technology Department of Jiangxi Province of China under grant 20151BBE50046,20142BBE50035 and 20151BAB207052
文摘Based on the proposed partly equidifferent mapping and its specific Differential Amplitude and Pulse Position Modulation(DAPPM) demodulation, a modified FSO scheme for turbulent channel is designed and analyzed. The novel Low Density Parity Check(LDPC) coded 4×4 and 4×8 DAPPM Free-Space Optical communication(FSO) system is constructed. The Monte Carlo simulation results show approximately 2d B transmit power reduction against classical LDPC-DAPPM at the identical Bit-Error-Rate in strong turbulent channel. The proposed partly equidifferent mapping is compatible with other modulations, so it enables widespread adoption in other coded FSO systems.
文摘By suitably choosing the normalization factors we introduce the even- and odd-negative binomial states. In some limit cases they approach the even- and odd-coherent states, respectively. We also derive a new eigenvector equation that the negative binomial state satishes as a nonlinear coherent state.
文摘We present a differential geometric perspective of the IEP for symmetric matrices in the framework of a fibre bundle with structure group SO(n). In particular, a Newton type algorithm is developed to construct a non singular symmetric matrix for given target eigenvalues using a singular symmetric matrix as the initial matrix for the iteration. Explicit computations are performed for 2 x 2 non singular symmetric matrix to illustrate the result.
基金supported by the National Natural Science Foundation of China(Grant No.11005040)the Program for New Century Excellent Talents in Fujian Province University(Grant No.2012FJ-NCET-ZR04)+1 种基金the Natural Science Foundation of Fujian Province of China(Grant No.2014J01015)the Promotion Program for Young and Middle-aged Teacher in Science and Technology Research of Huaqiao University(Grant No.ZQN-PY113)
文摘Generating entangled states efficiently is a hot topic in the area of quantum information science.With the approach presented in this paper,a general parity gate could be realized and a wide range of entangled states,including GHZ state,W state,Dicke state,arbitrary graph state and locally maximally entanglable states,can be generated flexibly.The generation of GHZ state,W state,and Dicke state is probabilistic but heralded and the total success probability is unit.In addition,the arbitrary graph state and locally maximally entanglable states generation is deterministic,flexible,and highly efficient.Especially,with the"simultaneous"generation pattern,the complexity of the graph state generation and locally maximally entanglable states generation could be reduced greatly,providing a more efficient and feasible way to generate the entangled states.
基金Supported by the National Natural Science Foundation of China under Grant No.11465008the Hunan Provincial Natural Science Foundation under Grant Nos.2015JJ4020 and 2015JJ2114the Scientific Research Fund of Hunan Provincial Education Department under Grant No.14A118
文摘We present exact analytical solutions to parity-time(P T) symmetric optical system describing light transport in P T-symmetric optical couplers. We show that light intensity oscillates periodically between two waveguides for unbroken P T-symmetric phase, whereas light always leaves the system from the waveguide experiencing gain when light is initially input at either waveguide experiencing gain or waveguide experiencing loss for broken P T-symmetric phase. These analytical results agree with the recent experimental observation reported by Ru¨ter et al. [Nat. Phys.6(2010) 192]. Besides, we present a scheme for manipulating P T symmetry by applying a periodic modulation. Our results provide an efficient way to control light propagation in periodically modulated P T-symmetric system by tuning the modulation amplitude and frequency.
基金supported by National Natural Science Foundation of China(Grant No.11171227)Fund for Doctoral Authority of China(Grant No.20123127110001)+1 种基金Fund for E-institute of Shanghai Universities(Grant No.E03004)Leading Academic Discipline Project of Shanghai Municipal Education Commission(Grant No.J50101)
文摘In this paper, we review some results on the spectral methods. We first consider the Jacobi spectral method and the generalized Jacobi spectral method for various problems, including degenerated and singular differential equations. Then we present the generalized Jacobi quasi-orthogonal approximation and its applica- tions to the spectral element methods for high order problems with mixed inhomogeneous boundary conditions. We also discuss the related spectral methods for non-rectangular domains and the irrational spectral methods for unbounded domains. Next, we consider the Hermite spectral method and the generalized Hermite spec- tral method with their applications. Finally, we consider the Laguerre spectral method and the generalized Laguerre spectral method for many problems defined on unbounded domains. We also present the generalized Laguerre quasi-orthogonal approximation and its applications to certain problems of non-standard type and exterior problems.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11105116 and 11005089)
文摘We perform a comparative study for the LHC di-photon Higgs signal in three different littlest Higgs models with T-parity (named LHT-Ⅰ, LHT-Ⅱ and LHT-Ⅲ). We find that compared with the Standard Model prediction, the di-photon rate is always suppressed and the suppression extent can be different for different models. The LHC will soon give a solid judgement whether the di-photon rate is larger than the SM prediction, which can be utilized as a sensitive probe for the three models.
基金supported by National Basic Research Program of China (Grant No. 2011CB309705)National Natural Science Foundation of China (Grant Nos. 11229101, 11371065 and 11271184)+2 种基金Program for New Century Excellent Talents in University (Grant No. 110227)the Priority Academic Program Development of Jiangsu Higher Education Institutionsthe Fundamental Research Funds for the Central Universities
文摘We investigate the zero dielectric constant limit to the non-isentropic compressible Euler-Maxwell system.We justify this singular limit rigorously in the framework of smooth solutions and obtain the nonisentropic compressible magnetohydrodynamic equations as the dielectric constant tends to zero.
基金supported by the Fundamental Research Funds for the Central Universities(108-4115100092)the National Key Research and Development Program of China(2016YFA0300102 and 2017YFA0205004)+2 种基金the National Natural Science Foundation of China(11775224,11504358,11804324 and 52072102)the Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology(2018CXFX001)the Natural Science Research Projects for the Colleges and Universities of Anhui Province(KJ2018A0660)。
文摘Optical control of exotic properties in strongly correlated electron materials is very attractive owing to their potential applications in optical and electronic devices.Herein,we demonstrate a vertical heterojunction made of a correlated electron oxide thin film VO_(2) and a conductive 0.05 wt% Nb-doped TiO_(2) single crystal,whose metal-insulator transition(MIT)across the nanoscale heterointerface can be efficiently modulated by visible light irradiation.The magnitude of the MIT decreases from ~350 in the dark state to ~7 in the illuminated state,obeying a power law with respect to the light power density.The junction resistance is switched in a reversible and synchronous manner by turning light on and off.The optical tunability of it is also exponentially proportional to the light power density,and a 320-fold on/off ratio is achieved with an irradiance of 65.6 mW cm^(-2) below the MIT temperature.While the VO_(2) thin film is metallic above the MIT temperature,the optical tunability is remarkably weakened,with a one-fold change remaining under light illumination.These results are co-attributed to a net reduction(~15 meV)in the apparent barrier height and the photocarrier-injection-induced metallization of the VO_(2) heterointerface through a photovoltaic effect,which is induced by deep defect level transition upon the visible light irradiance at low temperature.Additionally,the optical tunability is minimal,resulting from the quite weak modulation of the already metallic band structure in the Schottky-type junction above the MIT temperature.This work enables a remotely optical scheme to manipulate the MIT,implying potential uncooled photodetection and photoswitch applications.