A laser lap welding process for zinc-coated steel has a well-known unsolved problem-porosity formation. The boiling temperature of coated zinc is lower than the melting temperature of the base metal, which is steel. I...A laser lap welding process for zinc-coated steel has a well-known unsolved problem-porosity formation. The boiling temperature of coated zinc is lower than the melting temperature of the base metal, which is steel. In the autogenous laser welding, the zinc vapor generates from the lapped surfaces expels the molten pool and the expulsion causes numerous weld defects, such as spatters and blow holes on the weld surface and porosity inside the welds. The laser-arc hybrid welding was suggested as an alternative method for the laser lap welding because the arc can preheat or post-beat the weldment according to the arrangement of the laser beam and the arc. CO2 laser-micro plasma hybrid welding was applied to the lap welding of zinc-coated steel with zero-gap. The relationships among the weld quality and process parameters of the laser-arc arrangement, and the laser-arc interspacing distance and arc current were investigated using a full-factorial experimental design. The effect of laser-arc arrangement is dominant because the leading plasma arc partially melts the upper steel sheets and vaporizes or oxidizes the coated zinc on the lapped surfaces. Compared with the result from the laser-TIG hybrid welding, the heat input from arc can be reduced by 40%.展开更多
Drag reduction features in the transition regime of channel flow with fibre suspension were analyzed in terms of the linear stability theory. The modified stability equation was obtained based on the slender-body theo...Drag reduction features in the transition regime of channel flow with fibre suspension were analyzed in terms of the linear stability theory. The modified stability equation was obtained based on the slender-body theory and natural closure approximation. Results of the stability analysis show attenuating effects of fibre additives to the flow instability. For the cases leading to transition, drag reduction rate increases with the characteristic parameter H of fibres. The mechanism of drag reduction by fibres is revealed through the variation of velocity profile and the decrease of wall shear stress. The theoretical results are qualitatively consistent with some typical experiments.展开更多
Despite being a promising photoanode material for water splitting,WO_(3) has low conductivity,high onset potential,and sluggish water oxidation kinetics.In this study,we designed Ti-doped WO_(3) nanoplate arrays on fl...Despite being a promising photoanode material for water splitting,WO_(3) has low conductivity,high onset potential,and sluggish water oxidation kinetics.In this study,we designed Ti-doped WO_(3) nanoplate arrays on fluoride-doped tin oxide by a seed-free hydrothermal method,and the effects of doping on the photoelectrochemical performance were investigated.The optimal Ti-doped WO_(3) electrode achieved a photocurrent density of 0.53 mA/cm^(2) at 0.6 V(vs Ag/AgCl),110%higher than that of pure WO_(3) nanoplate arrays.Moreover,a significant cathodic shift in the onset potential was observed after doping.X-ray photoelectron spectroscopy valence band and ultraviolet–visible spectra revealed that the band positions of Ti-doped WO_(3) photoanodes moved upward,yielding a lower onset potential.Furthermore,electrochemical impedance spectroscopy measurements revealed that the conductivities of the WO_(3) photoanodes improved after doping,because of the rapid separation of photo-generated charge carriers.Thus,we report a new design route toward efficient and low-cost photoanodes for photoelectrochemical applications.展开更多
Cu2O is a promising photocatalyst,but it suffers from poor photocatalytic activity and stability,especially for Cu2O cubes.Herein,we report the deposition of CuO and Au nanodomains on Cu2O cubes to form dual surface h...Cu2O is a promising photocatalyst,but it suffers from poor photocatalytic activity and stability,especially for Cu2O cubes.Herein,we report the deposition of CuO and Au nanodomains on Cu2O cubes to form dual surface heterostructures(HCs)to improve photocatalytic activity and stability.The apparent quantum efficiency of Au/CuO/Cu2O HCs was ca.123 times that of pristine Cu2O.In addition,the Au/CuO/Cu2O HCs maintained nearly 80%of its original activity after eight cycles in contrast to five cycles for the Au/Cu2O material.Therefore,CuO and Au domains greatly improved the photocatalytic activity and stability of the Cu2O cubes due to the synergistic effect of the HCs.展开更多
Since the volume variation of silicon particles during cycling,the binding spots between Cu current collector and silicon anode raised to be one of the critical binding problems.In this work,an amino-modified Cu curre...Since the volume variation of silicon particles during cycling,the binding spots between Cu current collector and silicon anode raised to be one of the critical binding problems.In this work,an amino-modified Cu current collector(Cu^(*))is fabricated to tackle this issue.The amino groups on Cu^(*)surface increase its hydrophilicity,which is conducive to the curing process of aqueous slurry on its surface.Meanwhile,these amino groups can form abundant amide bonds with carboxyl groups from the adopted polyacrylic acid(PAA)binder.The combined action composed of the covalent bond and mechanical interlocking could reduce the contact loss inside the electrode.However,high concentration silane coupling agent treatment will weaken the surface roughness of Cu^(*)and weaken mechanical interlocking.What is more,the insulation of silane coupling agent reduces the conductivity of Cu and increases the impedance of battery.Considering the effect of silane coupling agent comprehensively,electrochemical performance of Cu^(*)-0.05%is best.展开更多
In this work, we proposed a novel three-dimensional (3D) plasmonic nanostructure based on porous graphene/nickel foam (GNF) and gas-phase deposited Ag nanoparticles (NPs). Ag NPs with high density were directly deposi...In this work, we proposed a novel three-dimensional (3D) plasmonic nanostructure based on porous graphene/nickel foam (GNF) and gas-phase deposited Ag nanoparticles (NPs). Ag NPs with high density were directly deposited on the surface of 3D GNF by performing a novel cluster beam deposition approach. In comparison with traditional Ag substrate (SiO2/Ag), such hot-spots enriched 3D nanostructure showed extremely high electromag-netic field enhancement under incident light irradiation which could be used as a sensitive chemical sensor based on surface enhanced Raman scattering (SERS). The experimental results demonstrated that the proposed nanostructure showed superior SERS performance in terms of Raman signal reproducibility and sensitivity for the probe molecules. 3D full-wave simulation showed that the enhanced SERS performance in this 3D hierarchical plasmonic nanostructure was mainly obtained from the hot-spots between Ag NPs and the near-field coupling between Ag NPs and GNF sca olds. This work can provide a novel assembled SERS substrate as a SERS-based chemical sensor in practical applications.展开更多
A numerical model was established for simulating wave impact on a horizontal deck by an improved incompressible smoothed particle hydrodynamics (ISPH). As a grid-less particle method, the ISPH method has been widely u...A numerical model was established for simulating wave impact on a horizontal deck by an improved incompressible smoothed particle hydrodynamics (ISPH). As a grid-less particle method, the ISPH method has been widely used in the free-surface hydrodynamic flows with good accuracy. The improvement includes the employment of a corrective function for enhancement of angular momentum conservation in a particle-based calculation and a new estimation method to predict the pressure on the horizontal deck. The simulation results show a good agreement with the experiment. The present numerical model can be used to study wave impact load on the horizontal deck.展开更多
The particle simulation method is used to solve free-surface slurry flow problems that may be encountered in several scientific and engineering fields.The main idea behind the use of the particle simulation method is ...The particle simulation method is used to solve free-surface slurry flow problems that may be encountered in several scientific and engineering fields.The main idea behind the use of the particle simulation method is to treat granular or other materials as an assembly of many particles.Compared with the continuum-mechanics-based numerical methods such as the finite element and finite volume methods,the movement of each particle is accurately described in the particle simulation method so that the free surface of a slurry flow problem can be automatically obtained.The major advantage of using the particle simulation method is that only a simple numerical algorithm is needed to solve the governing equation of a particle simulation system.For the purpose of illustrating how to use the particle simulation method to solve free-surface flow problems,three examples involving slurry flow on three different types of river beds have been considered.The related particle simulation results obtained from these three examples have demonstrated that:1) The particle simulation method is a promising and useful method for solving free-surface flow problems encountered in both the scientific and engineering fields;2) The shape and irregular roughness of a river bed can have a significant effect on the free surface morphologies of slurry flow when it passes through the river bed.展开更多
Smoothed particle hydrodynamics (SPH) is a Lagrangian meshless particle method. It is one of the best method for simulating violent free surface flows in fluids and solving large fluid deformations. Dam breaking is a ...Smoothed particle hydrodynamics (SPH) is a Lagrangian meshless particle method. It is one of the best method for simulating violent free surface flows in fluids and solving large fluid deformations. Dam breaking is a typical example of these problems. The basis of SPH was reviewed, including some techniques for governing equation resolution, such as the stepping method and the boundary handling method. Then numerical results of a dam breaking simulation were discussed, and the benefits of concepts like artificial viscosity and position correction were analyzed in detail. When compared with dam breaking simulated by the volume of fluid (VOF) method, the wave profile generated by SPH had good agreement, but the pressure had only reasonable agreement. Improving pressure results is clearly an important next step for research.展开更多
We present a conceptually-new approach “dual manipulation effect” using the surfactant passivation and the electron carrier doping for mediating intrinsic ferromagnetism in Codoped ZnO dilute magnetic semiconductor ...We present a conceptually-new approach “dual manipulation effect” using the surfactant passivation and the electron carrier doping for mediating intrinsic ferromagnetism in Codoped ZnO dilute magnetic semiconductor (DMS) thin films. The first-principles calculations show that the surface passivation by hydrogen serves as a magnetism switch for the Co-O-Co magnetic coupling at the surface of the thin film, and thus can control the spin polarization of the doped Co atoms. Meanwhile, the electron carrier doping can further function as an effective layerlike ferromagnetism mediator for the underneath layer. The dual manipulation effect sheds light on the essential magnetism origin of n-type Co:ZnO DMS thin films, and may be used as an alternative strategy for enhancing the ferromagnetism in other n-type DMS oxides thin films.展开更多
Grassland devoted about 90% of agricultural Irish land. Anion retention capacity of most agriculture soils is less than cation retention capacity, therefore chemical analyzed for anion (NO3 (nitrate), CI- (chlorid...Grassland devoted about 90% of agricultural Irish land. Anion retention capacity of most agriculture soils is less than cation retention capacity, therefore chemical analyzed for anion (NO3 (nitrate), CI- (chloride), SO42 (sulphate) and HPO4 (biphosphate)) in different water flow types (overland flow, interflow and vertical flow or drainage) samples. In this work, simple equipment was used to operationally distinguish between overland flow and interflow while vertical flow collected in different depths using soil water sampler equipments. Episodes of overland flow and interflow occurred even though the site is located in the lowest rainfall in Ireland and on well-drained soil. Samples of different origin showed marked differences in their anion contents, while HPO4 concentrations were almost equal to zero in all water flow types, nitrate where relatively high in overland and interflow samples and was very high in drainage samples. No sampling was carried out below the root zone but it must be assumed that the high concentrations measured in drainage samples would constitute a threat to groundwater resources. When overland flow and interflow did occur, NO3 concentrations were usually close to or in excess of the maximum admissible concentrations for drinking water and it will be constituted a threat to inland surface water bodies.展开更多
A special device was designed to measure temperature difference in this study of heat transfer of water and oil cross flow inside vertical upward tubes. A new heat transfer correlation was obtained for cross flow. The...A special device was designed to measure temperature difference in this study of heat transfer of water and oil cross flow inside vertical upward tubes. A new heat transfer correlation was obtained for cross flow. The experimental results showed that the dependence of heat transfer on Reynolds is much smaller in a narrow space than that in a wide space. It was found that the heat transfer correlation of cross flow in a narrow space is obviously different from that in a wide space, and that the heat transfer correlation obtained in a wide space may not be applicable to the cross-flow heat transfer in a narrow space. Further, the single-phase heat transfer capability of water cross flow was compared with that of oil cross flow. The experimental results showed that the average heat transfer coefficient of water is about 2~3 times that ofoil when they have the same superficial velocity.展开更多
This paper investigated the electrodeposition of sulfur on polycrystalline platinum from sulfide polluted brine. Anodic polarization, potentiostatic and electrochemical impedance spectroscopy (EIS) techniques were p...This paper investigated the electrodeposition of sulfur on polycrystalline platinum from sulfide polluted brine. Anodic polarization, potentiostatic and electrochemical impedance spectroscopy (EIS) techniques were performed. The slope of Warburg straight line in Nyquiest plot of the EIS spectra performed at 0.0 V indicates diffusion control mechanism of the electrodeposition process. At 0.5 V the Rp (determined from EIS measurements) increased rapidly with time indicating more sulfur deposition and more passivation of platinum surface. Samples subjected to potentiostatic experiments at 0.4, 0.9 and 1.0 V were investigated under Scanning Electron Microscope (SEM). SEM images reveal the deposition of sulfur on the sample surfaces. The degree of sulfur deposit coverage and its morphology depend on both the potential and time of deposition.展开更多
The phase transition of Heisenberg fluid has been investigated with the density functional theory in mean-field approximation (MF). The matrix of the second derivatives of the grand canonical potential Ω with respe...The phase transition of Heisenberg fluid has been investigated with the density functional theory in mean-field approximation (MF). The matrix of the second derivatives of the grand canonical potential Ω with respect to the particle density fluctuations and the magnetization fluctuations has been investigated and diagonalized. The smallest eigenvalue being 0 signalizes the phase instability and the related eigenvector characterizes this phase transition. We find a Curie line where the order parameter is pure magnetization and a spinodal where the order parameter is a mixture of particle density and magnetization. Along the spinodal, the character of phase instability changes continuously from predominant condensation to predominant ferromagnetic phase transition with the decrease of total density. The spinodal meets the Curie line at the critical endpoint with the reduced density p*=pσ3=0.224 and the reduced temperature T* =kT/ε=1.87 (σ is the diameter of Heisenberg hard sphere and e is the coupling constant).展开更多
The goal of this research was to determine the impact of nonionic surfactants on drag reduction effect in water and metal oxide nanofluid. Two nonionic surfactants (Rokacet 07 and Rokanol KT) and copper(II) oxide ...The goal of this research was to determine the impact of nonionic surfactants on drag reduction effect in water and metal oxide nanofluid. Two nonionic surfactants (Rokacet 07 and Rokanol KT) and copper(II) oxide wa- ter-based nanofluid were examined. Friction factors in a 4 mm diameter pipe for the Reynolds number between 8000 and 50000 were determined. Results showed that addition of nonionic surfactants caused the decrease of fric- tion factor in water and nanofluid. The drag reduction effect was similar in both cases. Presence of nanoparticles in the system has no great influence on drag reduction effect.展开更多
The density functional theory, simplified by the local density approximation and mean-field approxi-mation, is applied to study the surface properties of pure non-polar fluids. A reasonable long rang correction is ado...The density functional theory, simplified by the local density approximation and mean-field approxi-mation, is applied to study the surface properties of pure non-polar fluids. A reasonable long rang correction is adopted to avoid the truncation of the potential. The perturbation theory is applied to establish the equation for the phase equilibrium, in which the hard-core chain fluid is as the reference fluid and the Yukawa potential is used as the perturbation term. Three parameters, ε/κ, d and ms, are regressed frorn the vapor-liquid equilibria, and the surface properties, including density profile, surface tension and local surface tension profile are predicted with these parameters.展开更多
A novel subtype of influenza A virus 09H1N1 has rapidly spread across the world. Evolutionary analyses of this virus have revealed that 09H1N1 is a triple reassortant of segments from swine, avian and human influenza ...A novel subtype of influenza A virus 09H1N1 has rapidly spread across the world. Evolutionary analyses of this virus have revealed that 09H1N1 is a triple reassortant of segments from swine, avian and human influenza viruses. In this study, we investigated factors shaping the codon usage bias of 09H1N1 and carried out cluster analysis of 60 strains of influenza A virus from different subtypes based on their codon usage bias. We discovered that more preferentially used codons of 09H1N1 are A-ended or U-ended, and the intra-genomic codon usage bias of 09H1N1 is quite low. Base composition constraint, dinucleotide biases and translational selection are the main factors influencing the codon usage bias of 09H1N1. At the genome level, we find that the codon usage bias of 09H1N1 is similar to H1N1 (A/swine/Kansas/77778/2007H1N1), H9N2 from Asia, H1N2 from Asia and North America and H3N2 from North America. Our results provide insight for understanding the processes governing evolution, regulation of gene expression, and revealing the evolution of 09H1N1.展开更多
Effects caused by precipitation on the measurements of three-dimensional sonic anemometer are analyzed based on a field observational experiment conducted in Maoming, Guangdong Province, China. Obvious fluctuations in...Effects caused by precipitation on the measurements of three-dimensional sonic anemometer are analyzed based on a field observational experiment conducted in Maoming, Guangdong Province, China. Obvious fluctuations induced by precipitation are observed for the outputs of sonic anemometer-derived temperature and wind velocity components. A technique of turbulence spectra and cospectra normalized in the framework of similarity theory is utilized to validate the measured variables and calculated fluxes. It is found that the sensitivity of sonic anemometer-derived temperature to precipitation is significant, compared with that of the wind velocity components. The spectra of wind velocity and cospectra of momentum flux resemble the standard universal shape with the slopes of the spectra and cospectra at the inertial subrange, following the-2/3 and-4/3 power law, respectively, even under the condition of heavy rain. Contaminated by precipitation, however, the spectra of temperature and cospectra of sensible heat flux do not exhibit a universal shape and have obvious frequency loss at the inertial subrange. From the physical structure and working principle of sonic anemometer, a possible explanation is proposed to describe this difference, which is found to be related to the variations of precipitation particles. Corrections for errors of sonic anemometer-derived temperature under precipitation is needed, which is still under exploration.展开更多
The wave guides and optical fibers have long been known to transmit light and electromagnetic fields in large dimensions. Recently, surface plasmons, which are collective plasma oscillations of valence electrons at me...The wave guides and optical fibers have long been known to transmit light and electromagnetic fields in large dimensions. Recently, surface plasmons, which are collective plasma oscillations of valence electrons at metal surfaces, have been introduced as an entity that is able to guide light on the surfaces of the metal and to concentrate light in subwavelength volumes. It has been found that periodic array of metallic nanospheres, could be able to enhance the light transmission, and guiding light at nanoscale. The coupling between two nanoparticles in these devices is very important. The Bloch-Jensen hydrodynamical method has been used for computing surface plasmons' frequencies of a single metallic nanosphere. It contains the entire pole spectrum automatically, so it is more exactly than the other computational methods. In this research, we have computed the surface plasmons' frequencies of two adjacent nanospheres by Bloch-Jensen hydrodynamical model for the first time. The results show that there are two modes for this system, which depend explicitly on interparticle spacing. In addition, we have shown that the excitation modes yield to a single mode of a nanoparticle as the interparticle spacing increases.展开更多
文摘A laser lap welding process for zinc-coated steel has a well-known unsolved problem-porosity formation. The boiling temperature of coated zinc is lower than the melting temperature of the base metal, which is steel. In the autogenous laser welding, the zinc vapor generates from the lapped surfaces expels the molten pool and the expulsion causes numerous weld defects, such as spatters and blow holes on the weld surface and porosity inside the welds. The laser-arc hybrid welding was suggested as an alternative method for the laser lap welding because the arc can preheat or post-beat the weldment according to the arrangement of the laser beam and the arc. CO2 laser-micro plasma hybrid welding was applied to the lap welding of zinc-coated steel with zero-gap. The relationships among the weld quality and process parameters of the laser-arc arrangement, and the laser-arc interspacing distance and arc current were investigated using a full-factorial experimental design. The effect of laser-arc arrangement is dominant because the leading plasma arc partially melts the upper steel sheets and vaporizes or oxidizes the coated zinc on the lapped surfaces. Compared with the result from the laser-TIG hybrid welding, the heat input from arc can be reduced by 40%.
基金the National Natural Science Foundation of China (No. 10372090 and No. 10102017).
文摘Drag reduction features in the transition regime of channel flow with fibre suspension were analyzed in terms of the linear stability theory. The modified stability equation was obtained based on the slender-body theory and natural closure approximation. Results of the stability analysis show attenuating effects of fibre additives to the flow instability. For the cases leading to transition, drag reduction rate increases with the characteristic parameter H of fibres. The mechanism of drag reduction by fibres is revealed through the variation of velocity profile and the decrease of wall shear stress. The theoretical results are qualitatively consistent with some typical experiments.
基金Project(Qian Jiao He KY Zi [2021]257) supported provided by the Natural Science Research Project of Education Department of Guizhou Province,ChinaProject(GZSQCC2019003) supported by the High-level Innovative Talent Cultivation Project of Guizhou Province,ChinaProjects(GZLGXM-01,GZLGXM-08) supported by the Academic New Seedling Cultivation and Innovation Exploration Project of Guizhou Institute of Technology,China。
文摘Despite being a promising photoanode material for water splitting,WO_(3) has low conductivity,high onset potential,and sluggish water oxidation kinetics.In this study,we designed Ti-doped WO_(3) nanoplate arrays on fluoride-doped tin oxide by a seed-free hydrothermal method,and the effects of doping on the photoelectrochemical performance were investigated.The optimal Ti-doped WO_(3) electrode achieved a photocurrent density of 0.53 mA/cm^(2) at 0.6 V(vs Ag/AgCl),110%higher than that of pure WO_(3) nanoplate arrays.Moreover,a significant cathodic shift in the onset potential was observed after doping.X-ray photoelectron spectroscopy valence band and ultraviolet–visible spectra revealed that the band positions of Ti-doped WO_(3) photoanodes moved upward,yielding a lower onset potential.Furthermore,electrochemical impedance spectroscopy measurements revealed that the conductivities of the WO_(3) photoanodes improved after doping,because of the rapid separation of photo-generated charge carriers.Thus,we report a new design route toward efficient and low-cost photoanodes for photoelectrochemical applications.
基金supported by National Natural Science Foundation of China(21573263,21872157,51402346)National Key Research and Development Program of China from Ministry of Science and Technology of China(2016YFE0105700)+2 种基金Jiangsu Provincial Fundamental Research Foundation of China(BK20151236)Henan provincial co-operation and open foundation(60)China Postdoctoral Science Foundation(2018M632984)~~
文摘Cu2O is a promising photocatalyst,but it suffers from poor photocatalytic activity and stability,especially for Cu2O cubes.Herein,we report the deposition of CuO and Au nanodomains on Cu2O cubes to form dual surface heterostructures(HCs)to improve photocatalytic activity and stability.The apparent quantum efficiency of Au/CuO/Cu2O HCs was ca.123 times that of pristine Cu2O.In addition,the Au/CuO/Cu2O HCs maintained nearly 80%of its original activity after eight cycles in contrast to five cycles for the Au/Cu2O material.Therefore,CuO and Au domains greatly improved the photocatalytic activity and stability of the Cu2O cubes due to the synergistic effect of the HCs.
基金Project(2019R01006)supported by the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang Province,ChinaProject(2018YFB0104300)supported by the National Key R&D Program of China。
文摘Since the volume variation of silicon particles during cycling,the binding spots between Cu current collector and silicon anode raised to be one of the critical binding problems.In this work,an amino-modified Cu current collector(Cu^(*))is fabricated to tackle this issue.The amino groups on Cu^(*)surface increase its hydrophilicity,which is conducive to the curing process of aqueous slurry on its surface.Meanwhile,these amino groups can form abundant amide bonds with carboxyl groups from the adopted polyacrylic acid(PAA)binder.The combined action composed of the covalent bond and mechanical interlocking could reduce the contact loss inside the electrode.However,high concentration silane coupling agent treatment will weaken the surface roughness of Cu^(*)and weaken mechanical interlocking.What is more,the insulation of silane coupling agent reduces the conductivity of Cu and increases the impedance of battery.Considering the effect of silane coupling agent comprehensively,electrochemical performance of Cu^(*)-0.05%is best.
基金supported by the National Natural Science Foundation of China (No.11604161)the Natural Science Foundation of Jiangsu Province (No.BK20160914)+2 种基金the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (No.16KJB140009)the Foundation from Nanjing University of Posts and Telecommunication (No.NY216012)the European Union’s Horizon 2020 Research and Innovation Programme under the Marie Sk lodowska-Curie Grant (No.752102)
文摘In this work, we proposed a novel three-dimensional (3D) plasmonic nanostructure based on porous graphene/nickel foam (GNF) and gas-phase deposited Ag nanoparticles (NPs). Ag NPs with high density were directly deposited on the surface of 3D GNF by performing a novel cluster beam deposition approach. In comparison with traditional Ag substrate (SiO2/Ag), such hot-spots enriched 3D nanostructure showed extremely high electromag-netic field enhancement under incident light irradiation which could be used as a sensitive chemical sensor based on surface enhanced Raman scattering (SERS). The experimental results demonstrated that the proposed nanostructure showed superior SERS performance in terms of Raman signal reproducibility and sensitivity for the probe molecules. 3D full-wave simulation showed that the enhanced SERS performance in this 3D hierarchical plasmonic nanostructure was mainly obtained from the hot-spots between Ag NPs and the near-field coupling between Ag NPs and GNF sca olds. This work can provide a novel assembled SERS substrate as a SERS-based chemical sensor in practical applications.
基金the National High Technology Research and Development Program of China (863 Program,Grant No.2007AA11Z130)
文摘A numerical model was established for simulating wave impact on a horizontal deck by an improved incompressible smoothed particle hydrodynamics (ISPH). As a grid-less particle method, the ISPH method has been widely used in the free-surface hydrodynamic flows with good accuracy. The improvement includes the employment of a corrective function for enhancement of angular momentum conservation in a particle-based calculation and a new estimation method to predict the pressure on the horizontal deck. The simulation results show a good agreement with the experiment. The present numerical model can be used to study wave impact load on the horizontal deck.
基金Project(11272359)supported by the National Natural Science Foundation of China
文摘The particle simulation method is used to solve free-surface slurry flow problems that may be encountered in several scientific and engineering fields.The main idea behind the use of the particle simulation method is to treat granular or other materials as an assembly of many particles.Compared with the continuum-mechanics-based numerical methods such as the finite element and finite volume methods,the movement of each particle is accurately described in the particle simulation method so that the free surface of a slurry flow problem can be automatically obtained.The major advantage of using the particle simulation method is that only a simple numerical algorithm is needed to solve the governing equation of a particle simulation system.For the purpose of illustrating how to use the particle simulation method to solve free-surface flow problems,three examples involving slurry flow on three different types of river beds have been considered.The related particle simulation results obtained from these three examples have demonstrated that:1) The particle simulation method is a promising and useful method for solving free-surface flow problems encountered in both the scientific and engineering fields;2) The shape and irregular roughness of a river bed can have a significant effect on the free surface morphologies of slurry flow when it passes through the river bed.
基金Supported by the National Natural Science Foundation of China under Grant No. 10572041 and 50779008
文摘Smoothed particle hydrodynamics (SPH) is a Lagrangian meshless particle method. It is one of the best method for simulating violent free surface flows in fluids and solving large fluid deformations. Dam breaking is a typical example of these problems. The basis of SPH was reviewed, including some techniques for governing equation resolution, such as the stepping method and the boundary handling method. Then numerical results of a dam breaking simulation were discussed, and the benefits of concepts like artificial viscosity and position correction were analyzed in detail. When compared with dam breaking simulated by the volume of fluid (VOF) method, the wave profile generated by SPH had good agreement, but the pressure had only reasonable agreement. Improving pressure results is clearly an important next step for research.
基金supported by the Fundamental Research Funds for the Central Universities (No.WK2310000070)the National Natural Science Foundation of China (No.11875257, No.U1532265, and No.21603207)
文摘We present a conceptually-new approach “dual manipulation effect” using the surfactant passivation and the electron carrier doping for mediating intrinsic ferromagnetism in Codoped ZnO dilute magnetic semiconductor (DMS) thin films. The first-principles calculations show that the surface passivation by hydrogen serves as a magnetism switch for the Co-O-Co magnetic coupling at the surface of the thin film, and thus can control the spin polarization of the doped Co atoms. Meanwhile, the electron carrier doping can further function as an effective layerlike ferromagnetism mediator for the underneath layer. The dual manipulation effect sheds light on the essential magnetism origin of n-type Co:ZnO DMS thin films, and may be used as an alternative strategy for enhancing the ferromagnetism in other n-type DMS oxides thin films.
文摘Grassland devoted about 90% of agricultural Irish land. Anion retention capacity of most agriculture soils is less than cation retention capacity, therefore chemical analyzed for anion (NO3 (nitrate), CI- (chloride), SO42 (sulphate) and HPO4 (biphosphate)) in different water flow types (overland flow, interflow and vertical flow or drainage) samples. In this work, simple equipment was used to operationally distinguish between overland flow and interflow while vertical flow collected in different depths using soil water sampler equipments. Episodes of overland flow and interflow occurred even though the site is located in the lowest rainfall in Ireland and on well-drained soil. Samples of different origin showed marked differences in their anion contents, while HPO4 concentrations were almost equal to zero in all water flow types, nitrate where relatively high in overland and interflow samples and was very high in drainage samples. No sampling was carried out below the root zone but it must be assumed that the high concentrations measured in drainage samples would constitute a threat to groundwater resources. When overland flow and interflow did occur, NO3 concentrations were usually close to or in excess of the maximum admissible concentrations for drinking water and it will be constituted a threat to inland surface water bodies.
文摘A special device was designed to measure temperature difference in this study of heat transfer of water and oil cross flow inside vertical upward tubes. A new heat transfer correlation was obtained for cross flow. The experimental results showed that the dependence of heat transfer on Reynolds is much smaller in a narrow space than that in a wide space. It was found that the heat transfer correlation of cross flow in a narrow space is obviously different from that in a wide space, and that the heat transfer correlation obtained in a wide space may not be applicable to the cross-flow heat transfer in a narrow space. Further, the single-phase heat transfer capability of water cross flow was compared with that of oil cross flow. The experimental results showed that the average heat transfer coefficient of water is about 2~3 times that ofoil when they have the same superficial velocity.
文摘This paper investigated the electrodeposition of sulfur on polycrystalline platinum from sulfide polluted brine. Anodic polarization, potentiostatic and electrochemical impedance spectroscopy (EIS) techniques were performed. The slope of Warburg straight line in Nyquiest plot of the EIS spectra performed at 0.0 V indicates diffusion control mechanism of the electrodeposition process. At 0.5 V the Rp (determined from EIS measurements) increased rapidly with time indicating more sulfur deposition and more passivation of platinum surface. Samples subjected to potentiostatic experiments at 0.4, 0.9 and 1.0 V were investigated under Scanning Electron Microscope (SEM). SEM images reveal the deposition of sulfur on the sample surfaces. The degree of sulfur deposit coverage and its morphology depend on both the potential and time of deposition.
基金supported by the National Natural Science Foundation of China under Grant No.10325418
文摘The phase transition of Heisenberg fluid has been investigated with the density functional theory in mean-field approximation (MF). The matrix of the second derivatives of the grand canonical potential Ω with respect to the particle density fluctuations and the magnetization fluctuations has been investigated and diagonalized. The smallest eigenvalue being 0 signalizes the phase instability and the related eigenvector characterizes this phase transition. We find a Curie line where the order parameter is pure magnetization and a spinodal where the order parameter is a mixture of particle density and magnetization. Along the spinodal, the character of phase instability changes continuously from predominant condensation to predominant ferromagnetic phase transition with the decrease of total density. The spinodal meets the Curie line at the critical endpoint with the reduced density p*=pσ3=0.224 and the reduced temperature T* =kT/ε=1.87 (σ is the diameter of Heisenberg hard sphere and e is the coupling constant).
基金Supported by the State Committee for Scientific Research(Poland)(NN209764040)Michal Drzazga received the Scholarship under the Project DoktoRIS-Scholarship Program for Innovative Silesia Co-financed by the European Union under the European Social Fund
文摘The goal of this research was to determine the impact of nonionic surfactants on drag reduction effect in water and metal oxide nanofluid. Two nonionic surfactants (Rokacet 07 and Rokanol KT) and copper(II) oxide wa- ter-based nanofluid were examined. Friction factors in a 4 mm diameter pipe for the Reynolds number between 8000 and 50000 were determined. Results showed that addition of nonionic surfactants caused the decrease of fric- tion factor in water and nanofluid. The drag reduction effect was similar in both cases. Presence of nanoparticles in the system has no great influence on drag reduction effect.
基金Supported by the National Natural Science Foundation of China (No. 20102007) and the Fundamental Research Fund of Tsinghua University of China (No. JZ2002003).
文摘The density functional theory, simplified by the local density approximation and mean-field approxi-mation, is applied to study the surface properties of pure non-polar fluids. A reasonable long rang correction is adopted to avoid the truncation of the potential. The perturbation theory is applied to establish the equation for the phase equilibrium, in which the hard-core chain fluid is as the reference fluid and the Yukawa potential is used as the perturbation term. Three parameters, ε/κ, d and ms, are regressed frorn the vapor-liquid equilibria, and the surface properties, including density profile, surface tension and local surface tension profile are predicted with these parameters.
文摘A novel subtype of influenza A virus 09H1N1 has rapidly spread across the world. Evolutionary analyses of this virus have revealed that 09H1N1 is a triple reassortant of segments from swine, avian and human influenza viruses. In this study, we investigated factors shaping the codon usage bias of 09H1N1 and carried out cluster analysis of 60 strains of influenza A virus from different subtypes based on their codon usage bias. We discovered that more preferentially used codons of 09H1N1 are A-ended or U-ended, and the intra-genomic codon usage bias of 09H1N1 is quite low. Base composition constraint, dinucleotide biases and translational selection are the main factors influencing the codon usage bias of 09H1N1. At the genome level, we find that the codon usage bias of 09H1N1 is similar to H1N1 (A/swine/Kansas/77778/2007H1N1), H9N2 from Asia, H1N2 from Asia and North America and H3N2 from North America. Our results provide insight for understanding the processes governing evolution, regulation of gene expression, and revealing the evolution of 09H1N1.
基金supported by the National Key Basic Research Program of China (Grant Nos. 2014CB953903,2015CB953904)the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA 11010403)the CAS/SAFEA International Partnership Program for Creative Research Teams
文摘Effects caused by precipitation on the measurements of three-dimensional sonic anemometer are analyzed based on a field observational experiment conducted in Maoming, Guangdong Province, China. Obvious fluctuations induced by precipitation are observed for the outputs of sonic anemometer-derived temperature and wind velocity components. A technique of turbulence spectra and cospectra normalized in the framework of similarity theory is utilized to validate the measured variables and calculated fluxes. It is found that the sensitivity of sonic anemometer-derived temperature to precipitation is significant, compared with that of the wind velocity components. The spectra of wind velocity and cospectra of momentum flux resemble the standard universal shape with the slopes of the spectra and cospectra at the inertial subrange, following the-2/3 and-4/3 power law, respectively, even under the condition of heavy rain. Contaminated by precipitation, however, the spectra of temperature and cospectra of sensible heat flux do not exhibit a universal shape and have obvious frequency loss at the inertial subrange. From the physical structure and working principle of sonic anemometer, a possible explanation is proposed to describe this difference, which is found to be related to the variations of precipitation particles. Corrections for errors of sonic anemometer-derived temperature under precipitation is needed, which is still under exploration.
文摘The wave guides and optical fibers have long been known to transmit light and electromagnetic fields in large dimensions. Recently, surface plasmons, which are collective plasma oscillations of valence electrons at metal surfaces, have been introduced as an entity that is able to guide light on the surfaces of the metal and to concentrate light in subwavelength volumes. It has been found that periodic array of metallic nanospheres, could be able to enhance the light transmission, and guiding light at nanoscale. The coupling between two nanoparticles in these devices is very important. The Bloch-Jensen hydrodynamical method has been used for computing surface plasmons' frequencies of a single metallic nanosphere. It contains the entire pole spectrum automatically, so it is more exactly than the other computational methods. In this research, we have computed the surface plasmons' frequencies of two adjacent nanospheres by Bloch-Jensen hydrodynamical model for the first time. The results show that there are two modes for this system, which depend explicitly on interparticle spacing. In addition, we have shown that the excitation modes yield to a single mode of a nanoparticle as the interparticle spacing increases.