The Micro pore volume in porous materials usually interests many researchers. However, there has been few, if not, direct method to determine it. A strategy of combining mercury porosimetry with pre adsorption is pr...The Micro pore volume in porous materials usually interests many researchers. However, there has been few, if not, direct method to determine it. A strategy of combining mercury porosimetry with pre adsorption is proposed in the present paper. The total pore volume in activated carbon is determined through direct measurements for the first time. The application scope of mercury porosimetry is also enlarged. Besides, the present experiments also confirmed the preference of adsorption to the smaller pores even in the range of meso and macro pores.展开更多
Porous sol-gel glass of CaO-SiO2-P2O5 system with macropores larger than 100 μm was prepared by adding stearic acid as pore former when the sintering was carried out at 700 ℃ for 3h.The sol-gel porous glass shows an...Porous sol-gel glass of CaO-SiO2-P2O5 system with macropores larger than 100 μm was prepared by adding stearic acid as pore former when the sintering was carried out at 700 ℃ for 3h.The sol-gel porous glass shows an amorphous structure. The diameter of the pore created by pore former varies from 100 to 300 μm, and macroporous glass has a narrow and small pore size distribution in mesoporous scale. The porosity and pore size of macroporous bioactive glass can be controlled.展开更多
While hysteresis in the adsorption of fluids in porous material is known since about one century, the thermodynamic treatment of this phenomenon is still not settled. We propose to accept that thermodynamics is not de...While hysteresis in the adsorption of fluids in porous material is known since about one century, the thermodynamic treatment of this phenomenon is still not settled. We propose to accept that thermodynamics is not designed to deal with confined systems and we propose to introduce a new set of rules for describing the behavior of confined systems. This proposal is based on a large number of simulation calculations. The employed method of simulation has been shown to describe static and dynamic phenomena encountered in this field. The newly formulated theory incorporates the phenomenon of hysteresis without inconsistencies. Further, it will be shown that the theory allows simulating diffusional and convectional transport (nanofluidics) by a unified approach without the need to introduce capillary forces (surface or interface tensions) by phenomenological parameters. The second part of the paper is devoted to the potential for practical use. It turns out that the new concepts open the route to employing unusual states of matter found in porous systems which may lead to improved applications. In particular we will focus on the possibility to drive a fluid in a pore into states with negative pressure under static and under dynamic conditions. It turns out that states with negative pressure can be reproducibly controlled. Negative pressure states are in principal known since the time of Torricelli and they have been discussed in the literature as experimentally accessible situations. Still, they have not been turned into practical usefulness which is likely to be caused by the notion of their metastability in macroscopic systems. Possible applications refer to controlling chemical reactions as well as new routes to efficient separation processes that are difficult to handle by conventional techniques.展开更多
The state of roof collapse in tunnels is actually three-dimensional, so constructing a three-dimensional failure collapse mechanism is crucial so as to reflect the realistic collapsing scopes more reasonably. Accordin...The state of roof collapse in tunnels is actually three-dimensional, so constructing a three-dimensional failure collapse mechanism is crucial so as to reflect the realistic collapsing scopes more reasonably. According to Hoek-Brown failure criterion and the upper bound theorem of limit analysis, the solution for describing the shape of roof collapse in circular or rectangular tunnels subjected to seepage forces is derived by virtue of variational calculation. The seepage forces calculated from the gradient of excess pore pressure distribution are taken as external loading in the limit analysis, and it is of great convenience to compute the pore pressure with pore pressure coefficient. Consequently, the effect of seepage forces is taken as a work rate of external force and incorporated into the upper bound limit analysis. The numerical results of collapse dimensions with different rock parameters show great validity and agreement by comparing with the results of that with two-dimensional failure mechanism.展开更多
In this research, determination of final slope for Maiduk copper mine of Kerman is investigated according to destabilizing factors of the mine. The development of the Maiduk Mine caused the extension of the mine area ...In this research, determination of final slope for Maiduk copper mine of Kerman is investigated according to destabilizing factors of the mine. The development of the Maiduk Mine caused the extension of the mine area and also withdrawal of its wall. So, optimizing possibility of mine slope is essential. Finally,the magnitude of optimized slopes for different walls of the mine in association with executive commands with better factors of safety is provided. The results show that the most important destabilizer factors are the presence of water and pore pressure in the faults and the main joints. With the omission of pore pressure, mine wall for the designed depth is quite stable. This requires a drainage pattern in the lifetime of the mine. In an optimistic point of view, the minimum factor of safety of the wall will be 2.81 even without drainage. This conclusion allows optimizing the slope to its maximum magnitude of 51 degree. With the pessimistic engineering judgment and with the higher SF, the magnitude of the slope is optimized to 47 degree.展开更多
A case study of seismic response of an earth embankment foundation on liquefiable soils in Kansai area,western Japan was presented. Based on a calibrated cyclic elasto-plastic constitutive model for liquefiable sand a...A case study of seismic response of an earth embankment foundation on liquefiable soils in Kansai area,western Japan was presented. Based on a calibrated cyclic elasto-plastic constitutive model for liquefiable sand and Biot dynamic coupled theory,the seismic analysis was carried out by using a dynamic effective stress finite element method under plane strain condition. A recent design study was illustrated in detail for a river earth embankment subjected to seismic excitation on the saturated deposits with liquefiable sands. Simulated results of the embankment foundation during liquefaction were obtained for acceleration,displacement,and excess pore water pressures,which were considered to yield useful results for earthquake geotechnical design. The results show that the foundation soil reaches a fully liquefied state with high excess pore pressure ratios approaching to 1.0 due to the earthquake shaking. At the end of the earthquake,the extensive liquefaction causes about 1.0 m lateral spreading at the toe and 60 cm settlement at the crest of the earth embankment.展开更多
The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification...The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification and discharge at the interface under certain condition. It is of significant importance to take an insight into the phenomenon occurring at the interface. Through experiment, the pressboard is found as a porous material. The interface changes abruptly from bulk pressboard to the bulk oil as a result of the porous structure. A new model is proposed which divides the interface into bulk oil region, transition region, and bulk pressboard region. The width of the transition region is decided according to the microtome figure. The effective permittivity of the transition region is calculated using a new model based on fractal theory. The model is validated and compared with previous calculation model. The effect of the existence of transition region on the electric field distribution is discussed.展开更多
This paper presents the experimental pressure loss of water flow through perforated plates with geometry similar to the ones of the bottom end piece of a Pressurized Water Reactors (PWR) fuel element. Geometric feat...This paper presents the experimental pressure loss of water flow through perforated plates with geometry similar to the ones of the bottom end piece of a Pressurized Water Reactors (PWR) fuel element. Geometric features like the number, pattern and diameter of holes were evaluated as well as different inlet chamfers. The recovering pressure profile downstream of the plates was also measured. The experimental results were compared with numerical modeling performed with the commercial Computational Fluid Dynamics (CFD) code CFX 11.0. The analysis of the results shows that the standard k-e turbulence model presents the best compromise between computing time and accuracy for the calculation of the total pressure loss through the perforated plates tested.展开更多
Analyses of the effects of some parameters were performed to determine the admittance functions in a common two-compartment building with background porosity by the imposed excitation method.Variations of the magnific...Analyses of the effects of some parameters were performed to determine the admittance functions in a common two-compartment building with background porosity by the imposed excitation method.Variations of the magnification factors of fluctuating internal pressures were analyzed using 96 model cases under random fluctuating external pressure,and then corresponding design equations were fitted.The results show that the Helmholtz resonance peaks of the admittance functions in both compartments increase with increasing the area of windward or partition wall opening.With increasing the volume of the compartment with an external opening,the resonance peak in this compartment at the higher Helmholtz frequency significantly decreases,at the same time,the resonance peak in the other compartment at the lower Helmholtz frequency also decreases.With increasing the volume of the compartment with background porosity,both resonance peaks in this compartment at the lower and higher Helmholtz frequencies decrease,meanwhile,the resonance peak at the lower Helmholtz frequency for the other compartment also decreases,whereas the resonance peak at the higher Helmholtz frequency increases.Both resonance peaks of the admittance functions in the two compartments decrease with increasing the amplitude of fluctuating external pressure coefficients or reference wind speed.展开更多
Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the ...Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the underlying untreated stratum. Due to the changing permeability property of CFG piles, the whole consolidation process of the composite ground with CFG piles was divided into two stages, i.e., the early stage(permeable CFG pile bodies) and the later stage(impermeable pile bodies). Then, the consolidation equation of the composite foundation with CFG piles was established by using the Terzaghi one-dimensional consolidation theory. Consequently, the unified formula to calculate the excess pore water pressure was derived with the specific solutions for the consolidation degree of composite ground, reinforced area and underlying stratum under instant load obtained respectively. Finally, combined with a numerical example, influencing rules by main factors(including the replacement rate m, the treatment depth h1, the permeability coefficient Ks1, Kv2 and compression modulus Es1, Es2 of reinforced area and underlying stratum) on the consolidation property of composite ground with CFG piles were discussed in detail. The result shows that the consolidation velocity of underlying stratum is slower than that of the reinforced area. However, the consolidation velocity of underlying stratum is slow at first then fast as a result of the transferring of effective stress to the underlying stratum during the dissipating process of excess pore water pressure.展开更多
The accurate prediction of fracturing pressure for pay zone is the very important guidance to hydraulic fracturing design and operation. The pore pressure around the wellbore happens to change variously as the fractur...The accurate prediction of fracturing pressure for pay zone is the very important guidance to hydraulic fracturing design and operation. The pore pressure around the wellbore happens to change variously as the fracturing fluid entering the pay zone. The change of pore pressure affects the stress-state and the fracturing pressure around the wellbore. In this paper, a new concept of the effective membrane pressure coefficient is presented according to the wall building capacity of the fracturing fluid, then the change of pore pressure around the wellbore is studied, and it is proven that the prediction model for fracturing pressure is improved.展开更多
Conventional PCC pile technique has been widely used as embankment piles for highway construction in China. To further improve the PCC pile capacity, the expansive concrete technique has been applied to the PCC pile t...Conventional PCC pile technique has been widely used as embankment piles for highway construction in China. To further improve the PCC pile capacity, the expansive concrete technique has been applied to the PCC pile to replace the normal concrete recently. The use of expansive concrete for the PCC pile could increase the pile diameter as well as the contact pressure at the pile-soil interface due to the expansion process of concrete, which allows the improved PCC pile to provide higher capacity than the conventional PCC pile. This paper presents a theoretical model for the new improved PCC pile using expansive concrete technique. The model is formulated by assuming the PCC pile installation process as large strain undrained cylindrical cavity expansion and the subsequent pile shaft expansion combined with soil consolidation process is simulated by the small strain cylindrical cavity expansion combined with strain-controlled consolidation. Then, similarity solution technique is used to solve the problem of cavity expansion in modified cam Clay (MCC) model, while the strain-controlled consolidation is calculated through the finite difference method (FDM). Subsequently, the suitability of the cavity expansion solution in the interpretation of the PCC pile installation is verified by comparing the calculated excess pore pressure with the measured value in an instrumented field test. The stress changes and excess pore pressure during the PCC pile installation and subsequent pile shaft expansion are investigated by means of parametric study. The proposed theoretical model first reveals and quantifies the fundamental mechanism of the PCC pile using expansive concrete technique and it provides a theoretical basis for developing design methods of the new improved PCC pile in the future.展开更多
文摘The Micro pore volume in porous materials usually interests many researchers. However, there has been few, if not, direct method to determine it. A strategy of combining mercury porosimetry with pre adsorption is proposed in the present paper. The total pore volume in activated carbon is determined through direct measurements for the first time. The application scope of mercury porosimetry is also enlarged. Besides, the present experiments also confirmed the preference of adsorption to the smaller pores even in the range of meso and macro pores.
基金Project(50174059) supported by the National Natural Science Foundation of China
文摘Porous sol-gel glass of CaO-SiO2-P2O5 system with macropores larger than 100 μm was prepared by adding stearic acid as pore former when the sintering was carried out at 700 ℃ for 3h.The sol-gel porous glass shows an amorphous structure. The diameter of the pore created by pore former varies from 100 to 300 μm, and macroporous glass has a narrow and small pore size distribution in mesoporous scale. The porosity and pore size of macroporous bioactive glass can be controlled.
基金The theoretical basis of this study has been developed with financial support by the German Science Foundation under grant Mo288/26 within the Priority program 1105 "Non equilibrium processes in Fluid/fluid systems". Dr. Yves-Gorat Stommel has contributed to the application part of the paper by motivating calculations on separation and by critical comments.
文摘While hysteresis in the adsorption of fluids in porous material is known since about one century, the thermodynamic treatment of this phenomenon is still not settled. We propose to accept that thermodynamics is not designed to deal with confined systems and we propose to introduce a new set of rules for describing the behavior of confined systems. This proposal is based on a large number of simulation calculations. The employed method of simulation has been shown to describe static and dynamic phenomena encountered in this field. The newly formulated theory incorporates the phenomenon of hysteresis without inconsistencies. Further, it will be shown that the theory allows simulating diffusional and convectional transport (nanofluidics) by a unified approach without the need to introduce capillary forces (surface or interface tensions) by phenomenological parameters. The second part of the paper is devoted to the potential for practical use. It turns out that the new concepts open the route to employing unusual states of matter found in porous systems which may lead to improved applications. In particular we will focus on the possibility to drive a fluid in a pore into states with negative pressure under static and under dynamic conditions. It turns out that states with negative pressure can be reproducibly controlled. Negative pressure states are in principal known since the time of Torricelli and they have been discussed in the literature as experimentally accessible situations. Still, they have not been turned into practical usefulness which is likely to be caused by the notion of their metastability in macroscopic systems. Possible applications refer to controlling chemical reactions as well as new routes to efficient separation processes that are difficult to handle by conventional techniques.
基金Project(2013CB036004) supported by the National Basic Research Program of ChinaProject(51178468) supported by the National Natural Science Foundation of ChinaProject(2013zzts235) supported by Innovation Fund of Central South University of China
文摘The state of roof collapse in tunnels is actually three-dimensional, so constructing a three-dimensional failure collapse mechanism is crucial so as to reflect the realistic collapsing scopes more reasonably. According to Hoek-Brown failure criterion and the upper bound theorem of limit analysis, the solution for describing the shape of roof collapse in circular or rectangular tunnels subjected to seepage forces is derived by virtue of variational calculation. The seepage forces calculated from the gradient of excess pore pressure distribution are taken as external loading in the limit analysis, and it is of great convenience to compute the pore pressure with pore pressure coefficient. Consequently, the effect of seepage forces is taken as a work rate of external force and incorporated into the upper bound limit analysis. The numerical results of collapse dimensions with different rock parameters show great validity and agreement by comparing with the results of that with two-dimensional failure mechanism.
文摘In this research, determination of final slope for Maiduk copper mine of Kerman is investigated according to destabilizing factors of the mine. The development of the Maiduk Mine caused the extension of the mine area and also withdrawal of its wall. So, optimizing possibility of mine slope is essential. Finally,the magnitude of optimized slopes for different walls of the mine in association with executive commands with better factors of safety is provided. The results show that the most important destabilizer factors are the presence of water and pore pressure in the faults and the main joints. With the omission of pore pressure, mine wall for the designed depth is quite stable. This requires a drainage pattern in the lifetime of the mine. In an optimistic point of view, the minimum factor of safety of the wall will be 2.81 even without drainage. This conclusion allows optimizing the slope to its maximum magnitude of 51 degree. With the pessimistic engineering judgment and with the higher SF, the magnitude of the slope is optimized to 47 degree.
基金Projects (40802070, 40841014) supported by the National Natural Science Foundation of ChinaProject (B308) supported by Shanghai Leading Academic Discipline Project, China
文摘A case study of seismic response of an earth embankment foundation on liquefiable soils in Kansai area,western Japan was presented. Based on a calibrated cyclic elasto-plastic constitutive model for liquefiable sand and Biot dynamic coupled theory,the seismic analysis was carried out by using a dynamic effective stress finite element method under plane strain condition. A recent design study was illustrated in detail for a river earth embankment subjected to seismic excitation on the saturated deposits with liquefiable sands. Simulated results of the embankment foundation during liquefaction were obtained for acceleration,displacement,and excess pore water pressures,which were considered to yield useful results for earthquake geotechnical design. The results show that the foundation soil reaches a fully liquefied state with high excess pore pressure ratios approaching to 1.0 due to the earthquake shaking. At the end of the earthquake,the extensive liquefaction causes about 1.0 m lateral spreading at the toe and 60 cm settlement at the crest of the earth embankment.
基金Project(2009CB724504)supported by the National Basic Research Program of China
文摘The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification and discharge at the interface under certain condition. It is of significant importance to take an insight into the phenomenon occurring at the interface. Through experiment, the pressboard is found as a porous material. The interface changes abruptly from bulk pressboard to the bulk oil as a result of the porous structure. A new model is proposed which divides the interface into bulk oil region, transition region, and bulk pressboard region. The width of the transition region is decided according to the microtome figure. The effective permittivity of the transition region is calculated using a new model based on fractal theory. The model is validated and compared with previous calculation model. The effect of the existence of transition region on the electric field distribution is discussed.
文摘This paper presents the experimental pressure loss of water flow through perforated plates with geometry similar to the ones of the bottom end piece of a Pressurized Water Reactors (PWR) fuel element. Geometric features like the number, pattern and diameter of holes were evaluated as well as different inlet chamfers. The recovering pressure profile downstream of the plates was also measured. The experimental results were compared with numerical modeling performed with the commercial Computational Fluid Dynamics (CFD) code CFX 11.0. The analysis of the results shows that the standard k-e turbulence model presents the best compromise between computing time and accuracy for the calculation of the total pressure loss through the perforated plates tested.
基金Projects(51278367,50878159)supported by the National Natural Science Foundation of ChinaProject(90715040)supported by the Major Research Program of National Natural Science Foundation of China
文摘Analyses of the effects of some parameters were performed to determine the admittance functions in a common two-compartment building with background porosity by the imposed excitation method.Variations of the magnification factors of fluctuating internal pressures were analyzed using 96 model cases under random fluctuating external pressure,and then corresponding design equations were fitted.The results show that the Helmholtz resonance peaks of the admittance functions in both compartments increase with increasing the area of windward or partition wall opening.With increasing the volume of the compartment with an external opening,the resonance peak in this compartment at the higher Helmholtz frequency significantly decreases,at the same time,the resonance peak in the other compartment at the lower Helmholtz frequency also decreases.With increasing the volume of the compartment with background porosity,both resonance peaks in this compartment at the lower and higher Helmholtz frequencies decrease,meanwhile,the resonance peak at the lower Helmholtz frequency for the other compartment also decreases,whereas the resonance peak at the higher Helmholtz frequency increases.Both resonance peaks of the admittance functions in the two compartments decrease with increasing the amplitude of fluctuating external pressure coefficients or reference wind speed.
基金Project(51378197)supported by the National Natural Science Foundation of China
文摘Based on the double-layered foundation theory, the composite ground with partially penetrated cement fly-ash gravel(CFG) piles was regarded as a double-layered foundation including the surface reinforced area and the underlying untreated stratum. Due to the changing permeability property of CFG piles, the whole consolidation process of the composite ground with CFG piles was divided into two stages, i.e., the early stage(permeable CFG pile bodies) and the later stage(impermeable pile bodies). Then, the consolidation equation of the composite foundation with CFG piles was established by using the Terzaghi one-dimensional consolidation theory. Consequently, the unified formula to calculate the excess pore water pressure was derived with the specific solutions for the consolidation degree of composite ground, reinforced area and underlying stratum under instant load obtained respectively. Finally, combined with a numerical example, influencing rules by main factors(including the replacement rate m, the treatment depth h1, the permeability coefficient Ks1, Kv2 and compression modulus Es1, Es2 of reinforced area and underlying stratum) on the consolidation property of composite ground with CFG piles were discussed in detail. The result shows that the consolidation velocity of underlying stratum is slower than that of the reinforced area. However, the consolidation velocity of underlying stratum is slow at first then fast as a result of the transferring of effective stress to the underlying stratum during the dissipating process of excess pore water pressure.
文摘The accurate prediction of fracturing pressure for pay zone is the very important guidance to hydraulic fracturing design and operation. The pore pressure around the wellbore happens to change variously as the fracturing fluid entering the pay zone. The change of pore pressure affects the stress-state and the fracturing pressure around the wellbore. In this paper, a new concept of the effective membrane pressure coefficient is presented according to the wall building capacity of the fracturing fluid, then the change of pore pressure around the wellbore is studied, and it is proven that the prediction model for fracturing pressure is improved.
基金supported by the National Natural Science Foundation of China(Grant No.51420105013)
文摘Conventional PCC pile technique has been widely used as embankment piles for highway construction in China. To further improve the PCC pile capacity, the expansive concrete technique has been applied to the PCC pile to replace the normal concrete recently. The use of expansive concrete for the PCC pile could increase the pile diameter as well as the contact pressure at the pile-soil interface due to the expansion process of concrete, which allows the improved PCC pile to provide higher capacity than the conventional PCC pile. This paper presents a theoretical model for the new improved PCC pile using expansive concrete technique. The model is formulated by assuming the PCC pile installation process as large strain undrained cylindrical cavity expansion and the subsequent pile shaft expansion combined with soil consolidation process is simulated by the small strain cylindrical cavity expansion combined with strain-controlled consolidation. Then, similarity solution technique is used to solve the problem of cavity expansion in modified cam Clay (MCC) model, while the strain-controlled consolidation is calculated through the finite difference method (FDM). Subsequently, the suitability of the cavity expansion solution in the interpretation of the PCC pile installation is verified by comparing the calculated excess pore pressure with the measured value in an instrumented field test. The stress changes and excess pore pressure during the PCC pile installation and subsequent pile shaft expansion are investigated by means of parametric study. The proposed theoretical model first reveals and quantifies the fundamental mechanism of the PCC pile using expansive concrete technique and it provides a theoretical basis for developing design methods of the new improved PCC pile in the future.