Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nan...Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nanopores are found in the anodic films formed in the electrolytes after high-temperature storage(HTS)at 130°C for 240 h.A comparison of the voltage-time curves suggests that the formation of nanopores results from the decrease in formation efficiency of anodic oxide films rather than the corrosion of the electrolytes.FT-IR and UV spectra analysis shows that carboxylate and ethylene glycol in electrolytes can easily react by esterification at high temperatures.Combining the electronic current theory and oxygen bubble mold effect,the change in electrolyte composition could increase the electronic current in the anodizing process.The electronic current decreases the formation efficiency of anodic oxide films,and oxygen bubbles accompanying electronic current lead to the formation of nanopores in the dense films.The continuous electronic current and oxygen bubbles are the prerequisites for the formation of porous anodic oxides rather than the traditional field-assisted dissolution model.展开更多
The development of fracture around pre-existing cylindrical cavities in brittle rocks was examined using physical models and acoustic emission technique. The experimental results indicate that when granite blocks cont...The development of fracture around pre-existing cylindrical cavities in brittle rocks was examined using physical models and acoustic emission technique. The experimental results indicate that when granite blocks containing one pre-existing cylindrical cavity are loaded in uniaxial compression condition, the profiles of cracks around the cavity can be characterized by tensile cracking （splitting parallel to the axial compression direction） at the roof-floor, compressive crack at two side walls, and remote or secondary cracks at the perimeter of the cavity. Moreover, fracture around cavity is size-dependent. In granite blocks containing pre-existing half-length cylindrical cavities, compressive stress concentration is found to initiate at the two sidewalls and induce shear crack propagation and coalescence. In granite blocks containing multiple parallel cylindrical cavities, the adjacent cylindrical cavities can influence each other and the eventual failure mode is determined by the interaction of tensile, compressive and shear stresses. Experimental results show that both tensile and compressive stresses play an important role in fracture evolution process around cavities in brittle rocks.展开更多
The role of oxides in the formation of hole defects in friction stir welded joint of 2519-T87 aluminum alloy has been investigated by using optical microscope, scanning electron microscope, electron backscatter diffra...The role of oxides in the formation of hole defects in friction stir welded joint of 2519-T87 aluminum alloy has been investigated by using optical microscope, scanning electron microscope, electron backscatter diffraction and electron probe microanalyzer to examine the distribution of oxides and the features of hole defects, and using ABAQUS 3D thermo-mechanical coupling finite element model based on arbitrary Lagrangian-Eulerian method to simulate the material flow behavior. Oxides exist at the edge of tunnel hole and in the micropores in the joint. Based on distribution of oxygen and material flow behavior, it is believed that the oxides on the surface of the alloy tend to flow down into the bulk along the flow direction of plastic material during friction stir welding, aggregate in the weak region of material flow at the intersection of the shoulder affected zone and the stir pin-tip affected zone, and consequently prevent the material from contacting and diffusing. Due to the insufficient material flow and therefore the small plastic deformation,the pressure is not high enough to compress the accumulated oxides, resulting in hole defects.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.51777097,51577093)。
文摘Constant-current anodization of pure aluminum was carried out in non-corrosive capacitor working electrolytes to study the formation mechanism of nanopores in the anodic oxide films.Through comparative experiments,nanopores are found in the anodic films formed in the electrolytes after high-temperature storage(HTS)at 130°C for 240 h.A comparison of the voltage-time curves suggests that the formation of nanopores results from the decrease in formation efficiency of anodic oxide films rather than the corrosion of the electrolytes.FT-IR and UV spectra analysis shows that carboxylate and ethylene glycol in electrolytes can easily react by esterification at high temperatures.Combining the electronic current theory and oxygen bubble mold effect,the change in electrolyte composition could increase the electronic current in the anodizing process.The electronic current decreases the formation efficiency of anodic oxide films,and oxygen bubbles accompanying electronic current lead to the formation of nanopores in the dense films.The continuous electronic current and oxygen bubbles are the prerequisites for the formation of porous anodic oxides rather than the traditional field-assisted dissolution model.
基金Projects(51004025,51174044)supported by the National Natural Science Foundation of ChinaProject(2011AA060400)supported by the National High-tech Research and Development Program of China+1 种基金Project(N120501003)supported by Ministry of Education of the People’s Republic of ChinaProject(LJQ2012024)supported by Department of Education of Liaoning Province,China
文摘The development of fracture around pre-existing cylindrical cavities in brittle rocks was examined using physical models and acoustic emission technique. The experimental results indicate that when granite blocks containing one pre-existing cylindrical cavity are loaded in uniaxial compression condition, the profiles of cracks around the cavity can be characterized by tensile cracking （splitting parallel to the axial compression direction） at the roof-floor, compressive crack at two side walls, and remote or secondary cracks at the perimeter of the cavity. Moreover, fracture around cavity is size-dependent. In granite blocks containing pre-existing half-length cylindrical cavities, compressive stress concentration is found to initiate at the two sidewalls and induce shear crack propagation and coalescence. In granite blocks containing multiple parallel cylindrical cavities, the adjacent cylindrical cavities can influence each other and the eventual failure mode is determined by the interaction of tensile, compressive and shear stresses. Experimental results show that both tensile and compressive stresses play an important role in fracture evolution process around cavities in brittle rocks.
文摘The role of oxides in the formation of hole defects in friction stir welded joint of 2519-T87 aluminum alloy has been investigated by using optical microscope, scanning electron microscope, electron backscatter diffraction and electron probe microanalyzer to examine the distribution of oxides and the features of hole defects, and using ABAQUS 3D thermo-mechanical coupling finite element model based on arbitrary Lagrangian-Eulerian method to simulate the material flow behavior. Oxides exist at the edge of tunnel hole and in the micropores in the joint. Based on distribution of oxygen and material flow behavior, it is believed that the oxides on the surface of the alloy tend to flow down into the bulk along the flow direction of plastic material during friction stir welding, aggregate in the weak region of material flow at the intersection of the shoulder affected zone and the stir pin-tip affected zone, and consequently prevent the material from contacting and diffusing. Due to the insufficient material flow and therefore the small plastic deformation,the pressure is not high enough to compress the accumulated oxides, resulting in hole defects.
