Al/conductive coating/α-Pb O2-Ce O2-Ti O2/β-PbO 2-MnO 2-WC-Zr O2 composite electrode material was prepared on Al/conductive coating/α-PbO 2-Ce O2-Ti O2 substrate by electrochemical oxidation co-deposition technique...Al/conductive coating/α-Pb O2-Ce O2-Ti O2/β-PbO 2-MnO 2-WC-Zr O2 composite electrode material was prepared on Al/conductive coating/α-PbO 2-Ce O2-Ti O2 substrate by electrochemical oxidation co-deposition technique. The effects of current density on the chemical composition, electrocatalytic activity, and stability of the composite anode material were investigated by energy dispersive X-ray spectroscopy(EDXS), anode polarization curves, quasi-stationary polarization(Tafel) curves, electrochemical impedance spectroscopy(EIS), scanning electron microscopy(SEM), and X-ray diffraction(XRD). Results reveal that the composite electrode obtained at 1 A/dm2 possesses the lowest overpotential(0.610 V at 500 A/m2) for oxygen evolution, the best electrocatalytic activity, the longest service life(360 h at 40 °C in 150 g/L H2SO4 solution under 2 A/cm2), and the lowest cell voltage(2.75 V at 500 A/m2). Furthermore, with increasing current density, the coating exhibits grain growth and the decrease of content of Mn O2. Only a slight effect on crystalline structure is observed.展开更多
Y and Cd co-doped ZnO nanopowders were prepared via chemical precipitation method in order to modify the band gap and increase the luminescent intensity. The structures and optical properties of the as-synthesized sam...Y and Cd co-doped ZnO nanopowders were prepared via chemical precipitation method in order to modify the band gap and increase the luminescent intensity. The structures and optical properties of the as-synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL). The effects of Y and Cd ions on the optical properties of the samples were studied. Doping of Y into ZnO evidently increases the intensity of UV emission, or co-doping of Y and Cd enhances the UV emission, narrows the band gap of ZnO and hence red shifts the UV emission at the same time. Therefore, Y and Cd co-doped ZnO nanopowders exhibit an intense violet emission in the room temperature PL spectrum, which could be a potential candidate material for optoelectronic applications.展开更多
How to share experience and resources among learners is becoming one of the hottest topics in the field of E-Learning collaborative techniques. An intuitive way to achieve this objective is to group learners which can...How to share experience and resources among learners is becoming one of the hottest topics in the field of E-Learning collaborative techniques. An intuitive way to achieve this objective is to group learners which can help each other into the same community and help them learn collaboratively. In this paper, we proposed a novel community self-organization model based on multi-agent mechanism, which can automatically group learners with similar preferences and capabilities. In particular, we proposed award and exchange schemas with evaluation and preference track records to raise the performance of this algorithm. The description of learner capability, the matchmaking process, the definition of evaluation and preference track records, the rules of award and exchange schemas and the self-organization algorithm are all discussed in this paper. Meanwhile, a prototype has been built to verify the validity and efficiency of the algorithm. Experiments based on real learner data showed that this mechanism can organize learner communities properly and efficiently; and that it has sustainable improved efficiency and scalability.展开更多
Recent technological advances in miniaturization have allowed for a confocal scanning microscope to be integrated into a conventional flexible endoscope,or into trans-endoscopic probes,a technique now known as confoca...Recent technological advances in miniaturization have allowed for a confocal scanning microscope to be integrated into a conventional flexible endoscope,or into trans-endoscopic probes,a technique now known as confocal endomicroscopy or confocal laser endomicroscopy.This newly-developed technology has enabled endoscopists to collect real-time in vivo histological images or "virtual biopsies" of the gastrointestinal mucosa during endoscopy,and has stimulated significant interest in the application of this technique in clinical gastroenterology.This review aims to evaluate the current data on the technical aspects and the utility of this new technology in clinical gastroenterology and its potential impact in the future,particularly in the screening or surveillance of gastrointestinal neoplasia.展开更多
In the present paper, a comparison is made of the three formats in the history of EECU (English education in China's universities). In the first period (1904-1949), English education was conducted separately in g...In the present paper, a comparison is made of the three formats in the history of EECU (English education in China's universities). In the first period (1904-1949), English education was conducted separately in government-managed educational institutions and in institutions sponsored by church-related organizations; English education was well-knit with both general education and specialty education; and self-motivating learning was encouraged. In the second period (1950-1966), almost everything was tinted with a shady color of politics: A halt was addressed drastically to EEC (English education in China) in 1952. In the gradual recovery that started four years later, the second format was sawed and hammered, showing the following features: All non-government-mamaged institutions vanished from the stage; English was taught solely as a language or a system of verbal parts, almost deprived of all cultural loading. The third period (1978 onwards) has witnessed a barrier-free and rapid development of over three decades, resulting in the unprecedented pervasion of EECU. Yet in the third tbrmat, learners' efforts have turned wholly test-oriented, degenerating into the saddening disintegrity of learning as a process into isolated charges to the target of a test at a time; the ignorant reduction of the learning methods to "Vocabulary Booklets Plus Collections of Test Papers". Such a comparison not only provides a multi-dimensional perspective of EECU and a better understanding of it, but also offers some important experiences and lessons for the search of an effective solution to the pervasive problem of"Time-Consumingness and Low-Efficiency".展开更多
The purposes of this research were: (1) to create a training package to prepare secondary school students in northeastern of Thailand toward ASEAN (Association of Southeast Asian Nations) Community; (2) to comp...The purposes of this research were: (1) to create a training package to prepare secondary school students in northeastern of Thailand toward ASEAN (Association of Southeast Asian Nations) Community; (2) to compare the knowledge of secondary school students toward ASEAN before and after use training package; and (3) the expectations of the students in the northeast of their own preparation for the ASEAN community. Experimental research was used in this research. The subject was including 2,000 students who were randomly divided into groups of seven provinces. The statistics used in data analysis were percentage, average, standard deviation, and T-test. The research results showed that: (1) a training package to prepare secondary school students in northeastern of Thailand toward ASEAN Community, the effectiveness index (E.I.) was .57, according to the established criteria; (2) a comparison of pretest and post-test results found the use of cognitive training may vary, statistically significant at the .05 level; (3) an expectation of the secondary school students in the preparation of role into ASEAN Community found that the students who participated in a concept reflect that the knowledge and attitudes to prepare themselves for the ASEAN community.展开更多
The organic π-conjugate d polymers are of major interest materials for the use in electro-optical and no nlinear optical devices. In this work, for a selected polyacetylene chain, the optical absorption spectra in UV...The organic π-conjugate d polymers are of major interest materials for the use in electro-optical and no nlinear optical devices. In this work, for a selected polyacetylene chain, the optical absorption spectra in UV/Vis regime as well as the linear polarizabiliti y and nonlinear hyperpolarizability are calculated by using quantum chemical ab initio and semiempirical methods. The relationship of its optical property to el ectric field is obtained. Some physical mechanism of electric field effect on mo lecular optical property is discussed by means of electron distribution and intr amolecular charge transfer.展开更多
The maximum rate of carboxylation (Vcax) is a key photosynthetic parameter for gross primary produc- tion (GPP) estimation in terrestrial biosphere models. A set of observation-based Vcax values, which take the ni...The maximum rate of carboxylation (Vcax) is a key photosynthetic parameter for gross primary produc- tion (GPP) estimation in terrestrial biosphere models. A set of observation-based Vcax values, which take the ni- trogen limitation on photosynthetic rates into consideration, are used in version 4.5 of the Community Land Model (CLM4.5). However, CLM4.5 with carbon-nitrogen (CN) biogeochemistry (CLM4.5-CN) still uses an inde- pendent decay coefficient for nitrogen after the photosyn- thesis calculation. This means that the nitrogen limitation on the carbon cycle is accounted for twice when CN bio- geochemistry is active. Therefore, to avoid this double nitrogen down-regulation in CLM4.5-CN, the original Vcmax scheme is revised with a new one that only accounts for the transition between Vcmax and its potential value (without nitrogen limitation). Compared to flux tower- based observations, the new Vcmax scheme reduces the root-mean-square error (RMSE) in GPP for China's Mainland by 13.7 g C m-2 yr-1, with a larger decrease over humid areas (39.2 g C m 2 yr-1). Moreover, net primary production and leaf area index are also improved, with reductions in RMSE by 0.8% and 11.5%, respectively.展开更多
Being professional teacher is a process of acting and self empowering of teachers collectively and continuously. A teacher is not merely transferring knowledges and subject matters to the students but also internalizi...Being professional teacher is a process of acting and self empowering of teachers collectively and continuously. A teacher is not merely transferring knowledges and subject matters to the students but also internalizing the values; professionalism, knowledge laedership, community empowerment, etc. Partnership, professional development, and learning community are possibly gained by the teachers through lesson study implementasion interconnectedly and mutually. This paper aims at elaborating on the experience of State Junior High School 1 Srandakan Bantul Yogyakarta in implementing lesson study as a break-through to enhance the teachers' professional development incorporating the three mechanisms of lesson study. This school has conducted lesson study for about three years. The study resulted that 80 percent of teachers achieve their competence in planning, doing, and reflecting the lesson through observing other teachers performance and being observed interchangeably.展开更多
The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conj...The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties.展开更多
Nylon 10 T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10 T and Nylon 10T/1010 was investigated by means of differential scanning cal...Nylon 10 T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10 T and Nylon 10T/1010 was investigated by means of differential scanning calorimetry(DSC). Jeziorny equation and Mo equation were applied to describe the non-isothermal crystallization kinetics of the Nylon 10 T and the Nylon 10T/1010. The activation energies for non-isothermal crystallization were obtained by Vyazovkin's method and Friedman's method, respectively. These results showed that Jeziorny equation and Mo equation well described the non-isothermal crystallization kinetics of the Nylon 10 T and the Nylon 10T/1010. It was found that the values of the activation energy for non-isothermal crystallization of the Nylon 10T/1010 were lower than those of the Nylon 10 T at a given temperature or relative crystallinity degree,which revealed that crystallization ability of the Nylon 10T/1010 was higher. The crystal morphology was observed by means of a polarized optical microscope(POM) and X-ray diffraction(XRD). It was found that the addition of sebacic acid comonomer not only did not change the crystal form of the Nylon 10 T, but also significantly increased the number and decreased the size of spherulites. Comparing with the Nylon 10 T, the crystallization rate was increased with the addition of the sebacic acid comonomer.展开更多
基金Projects(51004056,51004057)supported by the National Natural Science Foundation of ChinaProject(KKZ6201152009)supported by the Opening Foundation of Key Laboratory of Inorganic Coating Materials,Chinese Academy of Sciences+2 种基金Project(2010ZC052)supported by the Applied Basic Research Foundation of Yunnan Province,ChinaProject(20125314110011)supported by the Specialized Research Fund for the Doctoral Program of Higher Education,ChinaProject(2010247)supported by Analysis&Testing Foundation of Kunming University of Science and Technology,China
文摘Al/conductive coating/α-Pb O2-Ce O2-Ti O2/β-PbO 2-MnO 2-WC-Zr O2 composite electrode material was prepared on Al/conductive coating/α-PbO 2-Ce O2-Ti O2 substrate by electrochemical oxidation co-deposition technique. The effects of current density on the chemical composition, electrocatalytic activity, and stability of the composite anode material were investigated by energy dispersive X-ray spectroscopy(EDXS), anode polarization curves, quasi-stationary polarization(Tafel) curves, electrochemical impedance spectroscopy(EIS), scanning electron microscopy(SEM), and X-ray diffraction(XRD). Results reveal that the composite electrode obtained at 1 A/dm2 possesses the lowest overpotential(0.610 V at 500 A/m2) for oxygen evolution, the best electrocatalytic activity, the longest service life(360 h at 40 °C in 150 g/L H2SO4 solution under 2 A/cm2), and the lowest cell voltage(2.75 V at 500 A/m2). Furthermore, with increasing current density, the coating exhibits grain growth and the decrease of content of Mn O2. Only a slight effect on crystalline structure is observed.
基金Project(2010CB631001) supported by the National Basic Research Program of ChinaProject(20121098) supported by the Foundation from of Key Laboratory of Preparation and Applications of Environmental Friendly Materials,Ministry of Education,ChinaProject supported by Graduate Innovation Fund of Jilin University,China
文摘Y and Cd co-doped ZnO nanopowders were prepared via chemical precipitation method in order to modify the band gap and increase the luminescent intensity. The structures and optical properties of the as-synthesized samples were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and photoluminescence (PL). The effects of Y and Cd ions on the optical properties of the samples were studied. Doping of Y into ZnO evidently increases the intensity of UV emission, or co-doping of Y and Cd enhances the UV emission, narrows the band gap of ZnO and hence red shifts the UV emission at the same time. Therefore, Y and Cd co-doped ZnO nanopowders exhibit an intense violet emission in the room temperature PL spectrum, which could be a potential candidate material for optoelectronic applications.
文摘How to share experience and resources among learners is becoming one of the hottest topics in the field of E-Learning collaborative techniques. An intuitive way to achieve this objective is to group learners which can help each other into the same community and help them learn collaboratively. In this paper, we proposed a novel community self-organization model based on multi-agent mechanism, which can automatically group learners with similar preferences and capabilities. In particular, we proposed award and exchange schemas with evaluation and preference track records to raise the performance of this algorithm. The description of learner capability, the matchmaking process, the definition of evaluation and preference track records, the rules of award and exchange schemas and the self-organization algorithm are all discussed in this paper. Meanwhile, a prototype has been built to verify the validity and efficiency of the algorithm. Experiments based on real learner data showed that this mechanism can organize learner communities properly and efficiently; and that it has sustainable improved efficiency and scalability.
文摘Recent technological advances in miniaturization have allowed for a confocal scanning microscope to be integrated into a conventional flexible endoscope,or into trans-endoscopic probes,a technique now known as confocal endomicroscopy or confocal laser endomicroscopy.This newly-developed technology has enabled endoscopists to collect real-time in vivo histological images or "virtual biopsies" of the gastrointestinal mucosa during endoscopy,and has stimulated significant interest in the application of this technique in clinical gastroenterology.This review aims to evaluate the current data on the technical aspects and the utility of this new technology in clinical gastroenterology and its potential impact in the future,particularly in the screening or surveillance of gastrointestinal neoplasia.
文摘In the present paper, a comparison is made of the three formats in the history of EECU (English education in China's universities). In the first period (1904-1949), English education was conducted separately in government-managed educational institutions and in institutions sponsored by church-related organizations; English education was well-knit with both general education and specialty education; and self-motivating learning was encouraged. In the second period (1950-1966), almost everything was tinted with a shady color of politics: A halt was addressed drastically to EEC (English education in China) in 1952. In the gradual recovery that started four years later, the second format was sawed and hammered, showing the following features: All non-government-mamaged institutions vanished from the stage; English was taught solely as a language or a system of verbal parts, almost deprived of all cultural loading. The third period (1978 onwards) has witnessed a barrier-free and rapid development of over three decades, resulting in the unprecedented pervasion of EECU. Yet in the third tbrmat, learners' efforts have turned wholly test-oriented, degenerating into the saddening disintegrity of learning as a process into isolated charges to the target of a test at a time; the ignorant reduction of the learning methods to "Vocabulary Booklets Plus Collections of Test Papers". Such a comparison not only provides a multi-dimensional perspective of EECU and a better understanding of it, but also offers some important experiences and lessons for the search of an effective solution to the pervasive problem of"Time-Consumingness and Low-Efficiency".
文摘The purposes of this research were: (1) to create a training package to prepare secondary school students in northeastern of Thailand toward ASEAN (Association of Southeast Asian Nations) Community; (2) to compare the knowledge of secondary school students toward ASEAN before and after use training package; and (3) the expectations of the students in the northeast of their own preparation for the ASEAN community. Experimental research was used in this research. The subject was including 2,000 students who were randomly divided into groups of seven provinces. The statistics used in data analysis were percentage, average, standard deviation, and T-test. The research results showed that: (1) a training package to prepare secondary school students in northeastern of Thailand toward ASEAN Community, the effectiveness index (E.I.) was .57, according to the established criteria; (2) a comparison of pretest and post-test results found the use of cognitive training may vary, statistically significant at the .05 level; (3) an expectation of the secondary school students in the preparation of role into ASEAN Community found that the students who participated in a concept reflect that the knowledge and attitudes to prepare themselves for the ASEAN community.
基金Natural Science Foundation from Shandong Province of China (Y2002A06)
文摘The organic π-conjugate d polymers are of major interest materials for the use in electro-optical and no nlinear optical devices. In this work, for a selected polyacetylene chain, the optical absorption spectra in UV/Vis regime as well as the linear polarizabiliti y and nonlinear hyperpolarizability are calculated by using quantum chemical ab initio and semiempirical methods. The relationship of its optical property to el ectric field is obtained. Some physical mechanism of electric field effect on mo lecular optical property is discussed by means of electron distribution and intr amolecular charge transfer.
基金supported by the National Natural Science Foundation of China(Grant Nos.91125016 and 41305066)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA05110102)
文摘The maximum rate of carboxylation (Vcax) is a key photosynthetic parameter for gross primary produc- tion (GPP) estimation in terrestrial biosphere models. A set of observation-based Vcax values, which take the ni- trogen limitation on photosynthetic rates into consideration, are used in version 4.5 of the Community Land Model (CLM4.5). However, CLM4.5 with carbon-nitrogen (CN) biogeochemistry (CLM4.5-CN) still uses an inde- pendent decay coefficient for nitrogen after the photosyn- thesis calculation. This means that the nitrogen limitation on the carbon cycle is accounted for twice when CN bio- geochemistry is active. Therefore, to avoid this double nitrogen down-regulation in CLM4.5-CN, the original Vcmax scheme is revised with a new one that only accounts for the transition between Vcmax and its potential value (without nitrogen limitation). Compared to flux tower- based observations, the new Vcmax scheme reduces the root-mean-square error (RMSE) in GPP for China's Mainland by 13.7 g C m-2 yr-1, with a larger decrease over humid areas (39.2 g C m 2 yr-1). Moreover, net primary production and leaf area index are also improved, with reductions in RMSE by 0.8% and 11.5%, respectively.
文摘Being professional teacher is a process of acting and self empowering of teachers collectively and continuously. A teacher is not merely transferring knowledges and subject matters to the students but also internalizing the values; professionalism, knowledge laedership, community empowerment, etc. Partnership, professional development, and learning community are possibly gained by the teachers through lesson study implementasion interconnectedly and mutually. This paper aims at elaborating on the experience of State Junior High School 1 Srandakan Bantul Yogyakarta in implementing lesson study as a break-through to enhance the teachers' professional development incorporating the three mechanisms of lesson study. This school has conducted lesson study for about three years. The study resulted that 80 percent of teachers achieve their competence in planning, doing, and reflecting the lesson through observing other teachers performance and being observed interchangeably.
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China. (No.21103161. No.11274142, No.11304058, No.11274034. and No.11004080) and the China Postdoctoral Science Foundation (No.2011MS00927 and No.2013T60319).
文摘The optical properties of three linear conjugated oligomers (F-P, F-P-F, and P-F-P-F-P), where phenothiazine (P) and fluorene (F) groups arrange alternately, are investigated. With the enhancement of the π-conjugated system, their absorption and emission bands both gradually red shift, and their two-photon properties are also improved. Meanwhile, their fluorescence dynamic traces are analyzed with continuous rate distribution model, exhibiting that their decay rates gradually accelerate and the rate distribution width become narrower. The quantum chemical calculation offers their molecular structures and transition mechanism, showing that the enhancement of π-conjugated system should be responsible for tile improvement of two-photon properties.
基金Supported by the National Science and Technology Support Program of China(No.2013BAE02B01)the Special Project on the Integration of Industry,Education and Research of Guangdong Province(No.2013B090500003)the Commissioner Workstation Project of Guangdong Province(No.2014A090906002)
文摘Nylon 10 T and Nylon 10T/1010 samples were synthesized by direct melt polymerization. The non-isothermal crystallization kinetics of Nylon 10 T and Nylon 10T/1010 was investigated by means of differential scanning calorimetry(DSC). Jeziorny equation and Mo equation were applied to describe the non-isothermal crystallization kinetics of the Nylon 10 T and the Nylon 10T/1010. The activation energies for non-isothermal crystallization were obtained by Vyazovkin's method and Friedman's method, respectively. These results showed that Jeziorny equation and Mo equation well described the non-isothermal crystallization kinetics of the Nylon 10 T and the Nylon 10T/1010. It was found that the values of the activation energy for non-isothermal crystallization of the Nylon 10T/1010 were lower than those of the Nylon 10 T at a given temperature or relative crystallinity degree,which revealed that crystallization ability of the Nylon 10T/1010 was higher. The crystal morphology was observed by means of a polarized optical microscope(POM) and X-ray diffraction(XRD). It was found that the addition of sebacic acid comonomer not only did not change the crystal form of the Nylon 10 T, but also significantly increased the number and decreased the size of spherulites. Comparing with the Nylon 10 T, the crystallization rate was increased with the addition of the sebacic acid comonomer.