In order to increase the processability and process window of the selective laser melting(SLM)-fabricated Al−Mn−Mg−Er−Zr alloy,a novel Si-modified Al−Mn−Mg−Er−Zr alloy was designed.The effect of Si alloying on the sur...In order to increase the processability and process window of the selective laser melting(SLM)-fabricated Al−Mn−Mg−Er−Zr alloy,a novel Si-modified Al−Mn−Mg−Er−Zr alloy was designed.The effect of Si alloying on the surface quality,processability,microstructure,and mechanical properties of the SLM-fabricated alloy was studied.The results showed that introducing Si into the Al−Mn−Mg−Er−Zr alloy prevented balling and keyhole formation,refined the grain size,and reduced the solidification temperature,which eliminated cracks and increased the processability and process window of the alloy.The maximum relative density of the SLM-fabricated Si/Al−Mn−Mg−Er−Zr alloy reached 99.6%.The yield strength and ultimate tensile strength of the alloy were(371±7)MPa and(518±6)MPa,respectively.These values were higher than those of the SLM-fabricated Al−Mn−Mg−Er−Zr and other Sc-free Al−Mg-based alloys.展开更多
Effects of process parameters on microstructure and mechanical properties of the AM50A magnesium alloy components formed by double control forming (DCF) were investigated via a four-factor and four-level orthogonal ...Effects of process parameters on microstructure and mechanical properties of the AM50A magnesium alloy components formed by double control forming (DCF) were investigated via a four-factor and four-level orthogonal experiment. The variable curves of DCF showed that the forging procedure was started in the following 35 ms after the injection procedure was completed. It was confirmed that the high-speed filling and high-pressure densifying were combined together in the DCF process. Better surface quality and higher mechanical properties were achieved in the components formed by DCF as compared to die casting (DC) due to the refined and uniform microstructure with a few defects or without defects. Injection speed affected more effectively the yield strength (YS), ultimate tensile strength (UTS) and elongation as compared to pouring temperature, die temperature and forging force. But the pouring temperature had a more significant effect on hardness as compared to injection speed, die temperature and forging force. Pouring temperature of 675 °C, injection speed of 2.7 m/s and forging force of 4000 kN except for die temperature were the optimal parameters for obtaining the highest YS, UTS, elongation and Vickers hardness. Die temperatures of 205, 195, 195 and 225 °C were involved in achieving the highest YS, UTS, elongation and Vickers hardness, respectively. Obvious microporosity and microcracks were found on the fracture surface of the components formed by DC, deteriorating the mechanical properties. However, the tensile fracture morphology of the components formed by DCF was characterized by ductile fracture due to a large number of dimples and no defects, which was beneficial for improving the mechanical properties.展开更多
A series of rod samples with diameter of 3 mm(Zr0.55Al0.10Ni0.05Cu0.30)100-xFex(x=0,1,2,3,4) were prepared by magnetic suspend melting and copper mold suction casting method.The effects of a small amount of Fe on ...A series of rod samples with diameter of 3 mm(Zr0.55Al0.10Ni0.05Cu0.30)100-xFex(x=0,1,2,3,4) were prepared by magnetic suspend melting and copper mold suction casting method.The effects of a small amount of Fe on glass forming ability(GFA) and mechanical properties of Zr55Al10Ni5Cu30 bulk metallic glass(BMG) were investigated.The results show that the addition of an appropriate amount(less than 3%,mole fraction) of Fe enhances GFA,as indicated by the increase in the reduced glass transition temperature Trg(=Tg/Tl) and the parameter γ(=Tx/(Tg+Tl)) with increasing Fe content,and GFA gets deteriorated by further Fe addition(4%).The addition of Fe also effectively improves the compressive plasticity and increases the compressive fracture strength in these Zr-based BMGs.Compressive tests on BMG sample with 3 mm in diameter and 6 mm in length reveal work-hardening and a certain plastic strain in the alloy containing 2% Fe.The BMG composite containing 4% Fe also exhibits a high fracture strength along with significant plasticity.展开更多
In order to study the hot fractures in relation to the semi-solid processing, the tensile tests of an extruded 7075 aluminum alloy which is based on Al?Zn?Mg?Cu system were carried out in the high temperature solid an...In order to study the hot fractures in relation to the semi-solid processing, the tensile tests of an extruded 7075 aluminum alloy which is based on Al?Zn?Mg?Cu system were carried out in the high temperature solid and semi-solid states at different strain rates. The results show that the tensile behavior can be divided into three regimes with increasing the liquid fraction. The alloy first behaves in a ductile character, and as the temperature increases, the fracture mechanism changes from ductile to brittle which is determined by both of liquid and solid, and lastly the fracture mechanism is brittle which is totally dominated by liquid. At strain rates of 1×10?4, 1×10?3 and 1×10?2 s?1, the brittle temperature ranges are 515?526, 519?550 and 540?580 °C, respectively. Two equations which are critical for tensile behavior are proposed.展开更多
Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in a...Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in an acid aqueous solution. The chemical compositions, surface morphologies and mechanical properties of the films were investigated by X-ray photoelectron spectrometer(XPS), scanning electron microscopy(SEM) and nanoindentation depth-sensing technique, respectively. The results indicate that the major chemical compositions of the films are Ti and O. The principal mechanism for the nucleation and growth of the films is homogeneous nucleation, and the layer number of films has great influence on the surface morphology and roughness of the films. In addition, mechanical nanoindentation testing presents a significant increase in hardness and fracture toughness of titanium dioxide multilayered films compared with single-layer titanium dioxide thin film.展开更多
The glassy rods were successfully fabricated in the Cu-Zr-Ti-In alloy system by casting into a copper mold. The value of ATx reaches a maximum of 66 K for the BMG CusoZraTTi8In5 alloy. The reasons for enhancing glass ...The glassy rods were successfully fabricated in the Cu-Zr-Ti-In alloy system by casting into a copper mold. The value of ATx reaches a maximum of 66 K for the BMG CusoZraTTi8In5 alloy. The reasons for enhancing glass forming ability of Cu-based BMGs with the addition of indium were discussed from atomic size and thermodynamics. Alternatively, the BMG Cu52Zra7Ti8In3 exhibits the highest compressive strength (1981 MPa) and the best plasticity among glassy Cu55-xZra7TisInx (x_〈5). The total plastic deformation of Cu52Zr37TisIn3 before fracture approaches 1.2%.展开更多
Bulk metallic glass(BMG) rods Fe71Mo5-xNbxP12C10B2(x=1,2,3,4 and 5) with diameter of 1 or 2 mm were synthesized by copper mold casting.The effects of Nb substitution for Mo on the structure,thermal and mechanical ...Bulk metallic glass(BMG) rods Fe71Mo5-xNbxP12C10B2(x=1,2,3,4 and 5) with diameter of 1 or 2 mm were synthesized by copper mold casting.The effects of Nb substitution for Mo on the structure,thermal and mechanical properties of Fe71Mo5-xNbxP12C10B2 alloys were studied by X-ray diffraction,differential scanning calorimetry and compressive testing.The results show that the substitution of Nb for Mo leads to a decreased glass forming ability,but with plasticity of 1.0%,the fracture strength of Fe71Mo2Nb3P12C10B2 alloy increases up to 4.0 GPa.The improvement of the fracture strength is discussed in terms of the enhancement of atomic bonding nature and the favorite formation of a network-like structure due to the substitution of Nb for Mo.展开更多
A sloping semisolid rheo-rolling process of Mg-3Sn-1Mn alloy was developed, and the effects of process parameters on the microstructure and mechanical properties of Mg-3Sn-lMn alloy strip were studied. The results sho...A sloping semisolid rheo-rolling process of Mg-3Sn-1Mn alloy was developed, and the effects of process parameters on the microstructure and mechanical properties of Mg-3Sn-lMn alloy strip were studied. The results show that the primary grain average diameter of the strip increases with the increase of the roll speed. The primary grain average diameter decreases firstly and then increases with the increase of the vibration frequency, and the tensile strength and elongation of the strip increase firstly and then decrease with the increase of the vibration frequency. The primary grain average diameter increases with the increase of casting temperature, and the tensile strength and elongation of the strip decrease correspondingly. When the casting temperature is 670℃, the roll speed is 52 mm/s, and the vibration frequency is 60 Hz, Mg-3Sn-1Mn alloy strip with good properties is produced. The mechanical properties of the present product are higher than those of Mg-3Sn-lMn alloy casting with the addition of 0.87% Ce (mass fraction).展开更多
Objective: To study the pharmacokinetics of native r SAK in rabbit's femoral artery thrombosis model, the “lytic circle' method was used to determine plasma levels of r SAK. Methods: Thirty New Zealand rabb...Objective: To study the pharmacokinetics of native r SAK in rabbit's femoral artery thrombosis model, the “lytic circle' method was used to determine plasma levels of r SAK. Methods: Thirty New Zealand rabbits were randomly assigned to the control (saline 10 ml, 30 min), r SAK low dose (0.25 mg/kg, 30 min), medial dose (0.50 mg/kg, 30 min), high dose (1.00 mg/kg, 30 min), single bolus (0.50 mg/kg, 2 min) and conjunctive therapy (initiated with heparin 200 U/kg, followed by infusion of r SAK 0.50 mg/kg for 30 min, and subsequently infused heparin 50 U/(kg·h) to endpoint) groups. The right femoral artery thrombosis model in rabbit was made by balloon injury, then the thrombolytic agents were infused through parallel ear vein and the blood samples were collected pre thrombolysis and at different time post thrombolysis to determine the plasma levels of r SAK by “lytic circle' method, the plasma levels of r SAK were processed by pharmacokinetic computing procedure to fit the model. Results: The plasma levels of r SAK and the diameters of lytic circles showed a pretty good linear correlation under the scope of 2.0×10 4 2.0×10 6 U/L, and the averaged recycle rate was (96.05±11.35)%(RSD =±11.82%).All peak concentration time in each infusion group was 30 min, and the peak concentrations positively correlated with the doses administrated in infusion groups(r=0.999 98, P <0.000 1). In single bolus group, Peak concentration time was 2 min, and the peak concentration reached (5.16±1.02) mg/L, which was significant higher than that in the same dose r SAK infusion group ( P <0.01). In conjunctive therapy group, the peak concentration showed no significant difference from that in the same dose r SAK infusion group ( P >0.05). The plasma levels of r SAK fit in two compartment model as processed by pharmacokinetic computing procedure in each group. Conclusion: The “lytic circle' method is a simple, practical and reliable method to determine the plasma level of r SAK, and the pharmacokinetics of native r SAK infusion fits in two compartment model in rabbit's femoral artery thrombosis model.展开更多
To investigate the effects of thickness and grain size on mechanical and deformation properties of C5210 phosphor bronze thin sheets, samples with different grain sizes were obtained through annealing heat treatment a...To investigate the effects of thickness and grain size on mechanical and deformation properties of C5210 phosphor bronze thin sheets, samples with different grain sizes were obtained through annealing heat treatment at different temperatures; and then tensile tests of samples with different thicknesses and grain sizes were conducted at room temperature. The results show that yield strength increases with decreasing thickness from 800 to 50 μm, but work hardening exponent and total elongation decrease, and a modified model was proposed to describe the relation between yield strength and thickness; yield strength decreases as the grain size increases, but work hardening exponent shows an increasing trend, total elongation increases to a peak and then decreases. Fracture morphology of tensile specimens was observed by SEM, which indicates that all tensile specimens are ductile fracture. The dimple intensity increases as the specimen thickness increases but reduces with the specimen grain size increasing.展开更多
Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al inte...Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al interface;most of TiAl_(3) grains were fine equiaxed with average sizes ranging from hundreds of nanometers to several microns and the TiAl_(3) grain size increased with increasing annealing time and/or temperature,but the effect of annealing temperature on the TiAl_(3) grain size was far greater than that of annealing time.The growth of the TiAl_(3) phase consisted of two stages.The initial stage was governed by chemical reaction with a reaction activation energy of 195.75 kJ/mol,and the reaction rate constant of the TiAl_(3) phase was larger as the Ti/Al interface was bonded with fresh surfaces.At the second stage,the growth was governed by diffusion,the diffusion activation energy was 33.69 kJ/mol,and the diffusion growth rate constant of the TiAl_(3) phase was mainly determined by the grain boundary diffusion owing to the smaller TiAl_(3) grain size.展开更多
The AM50,AM50-0.1 Ca,AM50-0.3 Ca and AM50-0.5 Ca(wt.%) alloys were hot-rolled and their mechanical properties were determined for the purpose of investigating the effect of trace Ca addition on the texture and stretch...The AM50,AM50-0.1 Ca,AM50-0.3 Ca and AM50-0.5 Ca(wt.%) alloys were hot-rolled and their mechanical properties were determined for the purpose of investigating the effect of trace Ca addition on the texture and stretch formability of AM50 alloy.The results show that the addition of trace Ca can effectively modify the basal texture,which is characterized by the split of basal poles deviated from the normal direction(ND) after the hot rolling,while a broad spread of the basal planes toward the transverse direction(TD) after the annealing.Such change of the basal texture is related to the prior formation of massive compression twins and the decrease of the c/a ratio.Erichsen value increases from 2.25 to 4.21 mm with the increase of Ca content.The enhancement of stretch formability is ascribed to the weakened basal texture,which results in the increase of n-value and the decrease of r-value.展开更多
Kinetic data of methane hydrate formation in the presence of purewater, brines with single salt and mixed salts, and aqueous solutionsof ethylene glycol (EG) and salt + EG were measured. A new kineticmodel of hydrate ...Kinetic data of methane hydrate formation in the presence of purewater, brines with single salt and mixed salts, and aqueous solutionsof ethylene glycol (EG) and salt + EG were measured. A new kineticmodel of hydrate formation for the methane + water systems wasdeveloped based on a four-step formation mechanism and reactionkinetics approach. The proposed kinetic model predicts the kineticbehavior of methane hydrate formation in pure water with goodaccuracy. The feasibility of extending the kinetic model to salt (s)and EG containing systems was explored.展开更多
The influences of process parameters on mechanical properties of AA6082in the hot forming and cold-die quenching(HFQ)process were analysed experimentally.Transmission electron microscopy was used to observe the precip...The influences of process parameters on mechanical properties of AA6082in the hot forming and cold-die quenching(HFQ)process were analysed experimentally.Transmission electron microscopy was used to observe the precipitate distribution and to thus clarify strengthening mechanism.A new model was established to describe the strengthening of AA6082by HFQ process in this novel forming technique.The material constants in the model were determined using a genetic algorithm tool.This strengthening model for AA6082can precisely describe the relationship between the strengths of formed workpieces and process parameters.The predicted results agree well with the experimental ones.The Pearson correlation coefficient,average absolute relative error,and root-mean-square error between the calculated and experimental hardness values are0.99402,2.0054%,and2.045,respectively.The model is further developed into an FE code ABAQUS via VUMAT to predict the mechanical property variation of a hot-stamped cup in various ageing conditions.展开更多
The effect of alloy composition and heat treatment, including natural ageing and pre-ageing, on the mechanical performance of eight 6xxx alloys designed with systematically varying Si, Mg and Cu contents was studied. ...The effect of alloy composition and heat treatment, including natural ageing and pre-ageing, on the mechanical performance of eight 6xxx alloys designed with systematically varying Si, Mg and Cu contents was studied. The results show that not only the alloy composition and heat treatment before forming influence the formability, but also they have an effect on the paint bake response of the alloys. Increasing the alloy Si content, decreasing Mg/Si ratio and adding 0.3% Cu (mass fraction) were generally found to improve the tensile ductility and formability of the alloys studied, while pre-ageing was found to decrease these properties. A full property profile of these alloys in terms of strength, tensile ductility, work hardening, strain rate sensitivity, forming limit and paint bake response was presented.展开更多
The decomposition kinetics for formation of CO2 hydrates in 90 cm 3wet natural silica sands were studied systematically using the depressurization method at the temperatures ranging from 273.2 to 277.2 K and the press...The decomposition kinetics for formation of CO2 hydrates in 90 cm 3wet natural silica sands were studied systematically using the depressurization method at the temperatures ranging from 273.2 to 277.2 K and the pressures from 0.5 to 1.0 MPa.The effects of temperature,pressure,particle diameter,porosity,and salinity of formation water on the decomposition kinetics were investigated.The results show that the dissociation percentage increases as temperature increases or as the initial decomposition pressure decreases.An increase in porosity or a decrease in particle diameter of silica sands accelerates the decomposition.Increasing the salinity of the formation water gives rise to a faster decomposition.However,a combination of the present results with the observations in literature reveals that the effect of the coexisting ionic solute depends on its chemical structure.展开更多
基金the National Natural Science Foundation of China(Nos.51801079,52001140)the Portugal National Funds through FCT Project(No.2021.04115).
文摘In order to increase the processability and process window of the selective laser melting(SLM)-fabricated Al−Mn−Mg−Er−Zr alloy,a novel Si-modified Al−Mn−Mg−Er−Zr alloy was designed.The effect of Si alloying on the surface quality,processability,microstructure,and mechanical properties of the SLM-fabricated alloy was studied.The results showed that introducing Si into the Al−Mn−Mg−Er−Zr alloy prevented balling and keyhole formation,refined the grain size,and reduced the solidification temperature,which eliminated cracks and increased the processability and process window of the alloy.The maximum relative density of the SLM-fabricated Si/Al−Mn−Mg−Er−Zr alloy reached 99.6%.The yield strength and ultimate tensile strength of the alloy were(371±7)MPa and(518±6)MPa,respectively.These values were higher than those of the SLM-fabricated Al−Mn−Mg−Er−Zr and other Sc-free Al−Mg-based alloys.
基金Project(51075099)supported by the National Natural Science Foundation of ChinaProject(E201038)supported by the Natural Science Foundation of Heilongjiang Province,China+2 种基金Project(HIT.NSRIF.2013007)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(2011RFQXG010)supported by the Harbin City Young Scientists Foundation,ChinaProject(LBH-T1102)supported by Specially Postdoctoral Science Foundation of Heilongjiang Province,China
文摘Effects of process parameters on microstructure and mechanical properties of the AM50A magnesium alloy components formed by double control forming (DCF) were investigated via a four-factor and four-level orthogonal experiment. The variable curves of DCF showed that the forging procedure was started in the following 35 ms after the injection procedure was completed. It was confirmed that the high-speed filling and high-pressure densifying were combined together in the DCF process. Better surface quality and higher mechanical properties were achieved in the components formed by DCF as compared to die casting (DC) due to the refined and uniform microstructure with a few defects or without defects. Injection speed affected more effectively the yield strength (YS), ultimate tensile strength (UTS) and elongation as compared to pouring temperature, die temperature and forging force. But the pouring temperature had a more significant effect on hardness as compared to injection speed, die temperature and forging force. Pouring temperature of 675 &#176;C, injection speed of 2.7 m/s and forging force of 4000 kN except for die temperature were the optimal parameters for obtaining the highest YS, UTS, elongation and Vickers hardness. Die temperatures of 205, 195, 195 and 225 &#176;C were involved in achieving the highest YS, UTS, elongation and Vickers hardness, respectively. Obvious microporosity and microcracks were found on the fracture surface of the components formed by DC, deteriorating the mechanical properties. However, the tensile fracture morphology of the components formed by DCF was characterized by ductile fracture due to a large number of dimples and no defects, which was beneficial for improving the mechanical properties.
基金Project(50371016) supported by the National Natural Science Foundation of ChinaProject(50611130629) supported by the International Cooperation and Exchange of the National Natural Science Foundation of China
文摘A series of rod samples with diameter of 3 mm(Zr0.55Al0.10Ni0.05Cu0.30)100-xFex(x=0,1,2,3,4) were prepared by magnetic suspend melting and copper mold suction casting method.The effects of a small amount of Fe on glass forming ability(GFA) and mechanical properties of Zr55Al10Ni5Cu30 bulk metallic glass(BMG) were investigated.The results show that the addition of an appropriate amount(less than 3%,mole fraction) of Fe enhances GFA,as indicated by the increase in the reduced glass transition temperature Trg(=Tg/Tl) and the parameter γ(=Tx/(Tg+Tl)) with increasing Fe content,and GFA gets deteriorated by further Fe addition(4%).The addition of Fe also effectively improves the compressive plasticity and increases the compressive fracture strength in these Zr-based BMGs.Compressive tests on BMG sample with 3 mm in diameter and 6 mm in length reveal work-hardening and a certain plastic strain in the alloy containing 2% Fe.The BMG composite containing 4% Fe also exhibits a high fracture strength along with significant plasticity.
基金Project(51405100)supported by the National Natural Science Foundation of ChinaProject(2014M551233)supported by the Postdoctoral Science Foundation of China+1 种基金Project(2014-HT-HGD12)supported by the Astronautical Supporting Technology Foundation of ChinaProject(2015GGX102023)supported by the Plan of Science and Technology Development in Shandong Province,China
文摘In order to study the hot fractures in relation to the semi-solid processing, the tensile tests of an extruded 7075 aluminum alloy which is based on Al?Zn?Mg?Cu system were carried out in the high temperature solid and semi-solid states at different strain rates. The results show that the tensile behavior can be divided into three regimes with increasing the liquid fraction. The alloy first behaves in a ductile character, and as the temperature increases, the fracture mechanism changes from ductile to brittle which is determined by both of liquid and solid, and lastly the fracture mechanism is brittle which is totally dominated by liquid. At strain rates of 1×10?4, 1×10?3 and 1×10?2 s?1, the brittle temperature ranges are 515?526, 519?550 and 540?580 °C, respectively. Two equations which are critical for tensile behavior are proposed.
基金Projects(51204036,51234009)supported by the National Natural Science Foundation of ChinaProject(2014CB643405)supported by the National Basic Research Program of China
文摘Ti O2-organic multilayered nanocomposite films were deposited on a self-assembled monolayer-coated silicon substrate based on layer-by-layer technique and chemical bath deposition method by a hydrolysis of Ti Cl4 in an acid aqueous solution. The chemical compositions, surface morphologies and mechanical properties of the films were investigated by X-ray photoelectron spectrometer(XPS), scanning electron microscopy(SEM) and nanoindentation depth-sensing technique, respectively. The results indicate that the major chemical compositions of the films are Ti and O. The principal mechanism for the nucleation and growth of the films is homogeneous nucleation, and the layer number of films has great influence on the surface morphology and roughness of the films. In addition, mechanical nanoindentation testing presents a significant increase in hardness and fracture toughness of titanium dioxide multilayered films compared with single-layer titanium dioxide thin film.
基金Project(50971041)support by the National Natural Science Foundation of China
文摘The glassy rods were successfully fabricated in the Cu-Zr-Ti-In alloy system by casting into a copper mold. The value of ATx reaches a maximum of 66 K for the BMG CusoZraTTi8In5 alloy. The reasons for enhancing glass forming ability of Cu-based BMGs with the addition of indium were discussed from atomic size and thermodynamics. Alternatively, the BMG Cu52Zra7Ti8In3 exhibits the highest compressive strength (1981 MPa) and the best plasticity among glassy Cu55-xZra7TisInx (x_〈5). The total plastic deformation of Cu52Zr37TisIn3 before fracture approaches 1.2%.
基金Project (SWU110046) supported by the Doctorate Foundation of Southwest University,China
文摘Bulk metallic glass(BMG) rods Fe71Mo5-xNbxP12C10B2(x=1,2,3,4 and 5) with diameter of 1 or 2 mm were synthesized by copper mold casting.The effects of Nb substitution for Mo on the structure,thermal and mechanical properties of Fe71Mo5-xNbxP12C10B2 alloys were studied by X-ray diffraction,differential scanning calorimetry and compressive testing.The results show that the substitution of Nb for Mo leads to a decreased glass forming ability,but with plasticity of 1.0%,the fracture strength of Fe71Mo2Nb3P12C10B2 alloy increases up to 4.0 GPa.The improvement of the fracture strength is discussed in terms of the enhancement of atomic bonding nature and the favorite formation of a network-like structure due to the substitution of Nb for Mo.
基金Project(51222405) supported by the National Science Foundation of Outstanding Young Scholars of ChinaProject(51034002) supported by the National Natural Science Foundation of China+1 种基金Project(132002) supported by the Fok Ying Tong Education FoundationProject (2011CB610405) supported by the National Basic Research Program of China
文摘A sloping semisolid rheo-rolling process of Mg-3Sn-1Mn alloy was developed, and the effects of process parameters on the microstructure and mechanical properties of Mg-3Sn-lMn alloy strip were studied. The results show that the primary grain average diameter of the strip increases with the increase of the roll speed. The primary grain average diameter decreases firstly and then increases with the increase of the vibration frequency, and the tensile strength and elongation of the strip increase firstly and then decrease with the increase of the vibration frequency. The primary grain average diameter increases with the increase of casting temperature, and the tensile strength and elongation of the strip decrease correspondingly. When the casting temperature is 670℃, the roll speed is 52 mm/s, and the vibration frequency is 60 Hz, Mg-3Sn-1Mn alloy strip with good properties is produced. The mechanical properties of the present product are higher than those of Mg-3Sn-lMn alloy casting with the addition of 0.87% Ce (mass fraction).
文摘Objective: To study the pharmacokinetics of native r SAK in rabbit's femoral artery thrombosis model, the “lytic circle' method was used to determine plasma levels of r SAK. Methods: Thirty New Zealand rabbits were randomly assigned to the control (saline 10 ml, 30 min), r SAK low dose (0.25 mg/kg, 30 min), medial dose (0.50 mg/kg, 30 min), high dose (1.00 mg/kg, 30 min), single bolus (0.50 mg/kg, 2 min) and conjunctive therapy (initiated with heparin 200 U/kg, followed by infusion of r SAK 0.50 mg/kg for 30 min, and subsequently infused heparin 50 U/(kg·h) to endpoint) groups. The right femoral artery thrombosis model in rabbit was made by balloon injury, then the thrombolytic agents were infused through parallel ear vein and the blood samples were collected pre thrombolysis and at different time post thrombolysis to determine the plasma levels of r SAK by “lytic circle' method, the plasma levels of r SAK were processed by pharmacokinetic computing procedure to fit the model. Results: The plasma levels of r SAK and the diameters of lytic circles showed a pretty good linear correlation under the scope of 2.0×10 4 2.0×10 6 U/L, and the averaged recycle rate was (96.05±11.35)%(RSD =±11.82%).All peak concentration time in each infusion group was 30 min, and the peak concentrations positively correlated with the doses administrated in infusion groups(r=0.999 98, P <0.000 1). In single bolus group, Peak concentration time was 2 min, and the peak concentration reached (5.16±1.02) mg/L, which was significant higher than that in the same dose r SAK infusion group ( P <0.01). In conjunctive therapy group, the peak concentration showed no significant difference from that in the same dose r SAK infusion group ( P >0.05). The plasma levels of r SAK fit in two compartment model as processed by pharmacokinetic computing procedure in each group. Conclusion: The “lytic circle' method is a simple, practical and reliable method to determine the plasma level of r SAK, and the pharmacokinetics of native r SAK infusion fits in two compartment model in rabbit's femoral artery thrombosis model.
文摘To investigate the effects of thickness and grain size on mechanical and deformation properties of C5210 phosphor bronze thin sheets, samples with different grain sizes were obtained through annealing heat treatment at different temperatures; and then tensile tests of samples with different thicknesses and grain sizes were conducted at room temperature. The results show that yield strength increases with decreasing thickness from 800 to 50 μm, but work hardening exponent and total elongation decrease, and a modified model was proposed to describe the relation between yield strength and thickness; yield strength decreases as the grain size increases, but work hardening exponent shows an increasing trend, total elongation increases to a peak and then decreases. Fracture morphology of tensile specimens was observed by SEM, which indicates that all tensile specimens are ductile fracture. The dimple intensity increases as the specimen thickness increases but reduces with the specimen grain size increasing.
基金the financial supports from the S&T Program of Hebei Province,China(No.20373901D)the National Natural Science Foundation of China(Nos.51807047,51804095)+2 种基金the National Science Foundation of Hebei Province,China(No.E2019402433)the Youth Top Talents Science and Technology Research Project of Hebei Province University,China(No.BJ2019003)the Research and Development Project of Science and Technology of Handan City,China(No.19422111008-19).
文摘Cold-rolled Ti/Al laminated composites were annealed at 525−625℃for 0−128 h,and the interfacial microstructure evolution was investigated.The results indicate that only the TiAl_(3) phase was formed at the Ti/Al interface;most of TiAl_(3) grains were fine equiaxed with average sizes ranging from hundreds of nanometers to several microns and the TiAl_(3) grain size increased with increasing annealing time and/or temperature,but the effect of annealing temperature on the TiAl_(3) grain size was far greater than that of annealing time.The growth of the TiAl_(3) phase consisted of two stages.The initial stage was governed by chemical reaction with a reaction activation energy of 195.75 kJ/mol,and the reaction rate constant of the TiAl_(3) phase was larger as the Ti/Al interface was bonded with fresh surfaces.At the second stage,the growth was governed by diffusion,the diffusion activation energy was 33.69 kJ/mol,and the diffusion growth rate constant of the TiAl_(3) phase was mainly determined by the grain boundary diffusion owing to the smaller TiAl_(3) grain size.
基金Projects(51801186,51974281)supported by the National Natural Science Foundation of ChinaProject(SKLSP201814)supported by the Fund of the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University,China
文摘The AM50,AM50-0.1 Ca,AM50-0.3 Ca and AM50-0.5 Ca(wt.%) alloys were hot-rolled and their mechanical properties were determined for the purpose of investigating the effect of trace Ca addition on the texture and stretch formability of AM50 alloy.The results show that the addition of trace Ca can effectively modify the basal texture,which is characterized by the split of basal poles deviated from the normal direction(ND) after the hot rolling,while a broad spread of the basal planes toward the transverse direction(TD) after the annealing.Such change of the basal texture is related to the prior formation of massive compression twins and the decrease of the c/a ratio.Erichsen value increases from 2.25 to 4.21 mm with the increase of Ca content.The enhancement of stretch formability is ascribed to the weakened basal texture,which results in the increase of n-value and the decrease of r-value.
基金Supported by the National Natural Science Foundation(No. 20003010) and Postdoctoral Research Foundation.
文摘Kinetic data of methane hydrate formation in the presence of purewater, brines with single salt and mixed salts, and aqueous solutionsof ethylene glycol (EG) and salt + EG were measured. A new kineticmodel of hydrate formation for the methane + water systems wasdeveloped based on a four-step formation mechanism and reactionkinetics approach. The proposed kinetic model predicts the kineticbehavior of methane hydrate formation in pure water with goodaccuracy. The feasibility of extending the kinetic model to salt (s)and EG containing systems was explored.
基金Project(P2014-15)supported by the State Key Laboratory of Materials Processing and Die and Mould Technology,Huazhong University of Science and Technology,ChinaProject(20120006110017)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China+1 种基金Project(2015M580977)supported by China Postdoctoral Science FoundationProject supported by Beijing Laboratory of Metallic Materials and Processing for Modern Transportation,China
文摘The influences of process parameters on mechanical properties of AA6082in the hot forming and cold-die quenching(HFQ)process were analysed experimentally.Transmission electron microscopy was used to observe the precipitate distribution and to thus clarify strengthening mechanism.A new model was established to describe the strengthening of AA6082by HFQ process in this novel forming technique.The material constants in the model were determined using a genetic algorithm tool.This strengthening model for AA6082can precisely describe the relationship between the strengths of formed workpieces and process parameters.The predicted results agree well with the experimental ones.The Pearson correlation coefficient,average absolute relative error,and root-mean-square error between the calculated and experimental hardness values are0.99402,2.0054%,and2.045,respectively.The model is further developed into an FE code ABAQUS via VUMAT to predict the mechanical property variation of a hot-stamped cup in various ageing conditions.
文摘The effect of alloy composition and heat treatment, including natural ageing and pre-ageing, on the mechanical performance of eight 6xxx alloys designed with systematically varying Si, Mg and Cu contents was studied. The results show that not only the alloy composition and heat treatment before forming influence the formability, but also they have an effect on the paint bake response of the alloys. Increasing the alloy Si content, decreasing Mg/Si ratio and adding 0.3% Cu (mass fraction) were generally found to improve the tensile ductility and formability of the alloys studied, while pre-ageing was found to decrease these properties. A full property profile of these alloys in terms of strength, tensile ductility, work hardening, strain rate sensitivity, forming limit and paint bake response was presented.
基金Supported by the National Natural Science Foundation of China(40673043 20576073) the Program for New Century Excellent Talents in University from Ministry of Education of China(NCET-06-0088)
文摘The decomposition kinetics for formation of CO2 hydrates in 90 cm 3wet natural silica sands were studied systematically using the depressurization method at the temperatures ranging from 273.2 to 277.2 K and the pressures from 0.5 to 1.0 MPa.The effects of temperature,pressure,particle diameter,porosity,and salinity of formation water on the decomposition kinetics were investigated.The results show that the dissociation percentage increases as temperature increases or as the initial decomposition pressure decreases.An increase in porosity or a decrease in particle diameter of silica sands accelerates the decomposition.Increasing the salinity of the formation water gives rise to a faster decomposition.However,a combination of the present results with the observations in literature reveals that the effect of the coexisting ionic solute depends on its chemical structure.