Influence of amorphous degree on crystallization kinetics of Zr_(60)Al_(15)Ni_(25) bulk metallic glass

The microstructure of as-cast Zr60Al15Ni25 bulk metallic glass was investigated by high-resolution transmission electron microscopy. It is found that there exist numerous short-range order regions （SRORs） in the metallic glass though it is identified to be amorphous by X-ray diffraction method. Furthermore, the amorphous degree shows a close correlation with the microstructure of corresponding mother ingot. The crystallization kinetics was investigated by differential scanning calorimetry under isochronal and isothermal conditions. The results show that the crystallization is triggered by the growth of the pre-existing SRORs and the growth is three-dimension diffusion-controlled. The amorphous degree of Zr60Al15Ni25 bulk metallic glass considerably influences its crystallization kinetics, namely, the more homogeneous distribution of atoms results in a more sluggish nucleation behavior.

EFFICIENT NUMERICAL METHOD FOR DYNAMIC ANALYSIS OF FLEXIBLE ROD HIT BY RIGID BALL

Impact dynamics of flexible solids is important in engineering practice. Obtaining its dynamic response is a challenging task and usually achieved by numerical methods. The objectives of the study are twofold. Firstly, the discrete singular convolution （DSC） is used for the first time to analyze the impact dynamics. Secondly, the efficiency of various numerical methods for dynamic analysis is explored via an example of a flexible rod hit by a rigid ball. Three numerical methods, including the conventional finite element （FE） method, the DSC algorithm, and the spectral finite element （SFE） method, and one proposed modeling strategy, the improved spectral finite element （ISFE） method, are involved. Numerical results are compared with the known analytical solutions to show their efficiency. It is demonstrated that the proposed ISFE modeling strategy with a proper length of con- ventional FE yields the most accurate contact stress among the four investigated models. It is also found that the DSC algorithm is an alternative method for collision problems.

Numerical Investigation of Hydrodynamic Flow Over an AUV Moving in the Water-surface Vicinity Considering the Laminar-turbulent Transition

Nowadays, Autonomous Underwater Vehicles(AUVs) are frequently used for exploring the oceans. The hydrodynamics of AUVs moving in the vicinity of the water surface are significantly different at higher depths. In this paper, the hydrodynamic coefficients of an AUV in non-dimensional depths of 0.75, 1, 1.5, 2, and 4D are obtained for movement close to the free-surface. Reynolds Averaged Navier Stokes Equations(RANS) are discretized using the finite volume approach and the water-surface effects modeled using the Volume of Fraction(VOF) method. As the operating speeds of AUVs are usually low, the boundary layer over them is not fully laminar or fully turbulent, so the effect of boundary layer transition from laminar to turbulent flow was considered in the simulations. Two different turbulence/transition models were used: 1) a full-turbulence model, the k-ε model, and 2) a turbulence/transition model, Menter's Transition-SST model. The results show that the Menter's Transition-SST model has a better consistency with experimental results. In addition, the wave-making effects of these bodies are studied at different immersion depths in the sea-surface vicinity or at finite depths. It is observed that the relevant pitch moments and lift coefficients are non-zero for these axi-symmetric bodies when they move close to the sea-surface. This is not expected for greater depths.

Dynamic analysis and modal test of long-span cable-stayed bridge based on ambient excitation

To study the stiffness distribution of girder and the method to identify modal parameters of cable-stayed bridge, a simplified dynamical finite element method model named three beams model was established for the girder with double ribs. Based on the simplified model four stiffness formulae were deduced according to Hamilton principle. These formulae reflect well the contribution of the flexural, shearing, free torsion and restricted torsion deformation, respectively. An identification method about modal parameters was put forward by combining method of peak value and power spectral density according to modal test under ambient excitation. The dynamic finite element method analysis and modal test were carried out in a long-span concrete cable-stayed bridge. The results show that the errors of frequencies between theoretical analysis and test results are less than 10% mostly, and the most important modal parameters for cable-stayed bridge are determined to be the longitudinal floating mode, the first vertical flexural mode and the first torsional mode, which demonstrate that the method of stiffness distribution for three beams model is accurate and method to identify modal parameters is effective under ambient excitation modal test.

Kinetics of Photocatalytic Degradation of Gaseous Organic Compounds on Modified TiO_2/AC Composite Photocatalyst

This study is focused on the kinetic characteristics of photocatalytic degradation of gaseous organic compounds on modified titanium dioxide/activated carbon composite photocatalyst(MTA).The MTA,which co-doping with iron(Fe) and nitrogen(N),was synthesized by a sol-gel method,and its photocatalytic performance was investigated under different reaction conditions.The experimental data obtained were tested by the zero,first and second order kinetic model,and the factors affecting the kinetic model were analyzed.It was clearly demonstrated that the experimental data of toluene and acetone on MTA fit quite well with second order kinetic model equation,but the experimental data of formaldehyde fits well with zero order kinetic model equation.

Dynamic response analysis of a moored crane-ship with a flexible boom

The dynamic response of moored crane-ship is studied. Governing equations for the dynamic response of a crane-ship coupled with the pendulum motion of the payload are derived based on Lagrange’s equations. The boom is modeled based on finite element method, while the payload is modeled as a planar pendulum of point mass. The dynamic response was studied using numerical method. The calculation results show that the large-amplitude responses occur at wave periods near the natural period of the payload. Load swing angle is smaller for crane-ship with flexible boom, in comparison with rigid boom. The ship surge mo- tions have large vibrations for crane-ship with flexible boom, which were not observed for a rigid boom. The analysis identifies the significance of key parameters and reveals how the system design can be adjusted to avoid critical conditions.

Dynamics of vertical pipe in deep-ocean mining system

A 3-D geometrical nonlinear model for the entire lift system of 1000-m sea trial system of China Ocean Mineral Resources R&D Association was established with finite element method.The model was utilized to analyze the dynamic characteristics of the vertical pipe under the influence of moving velocity,current direction and wave.The simulation results show that the axial stress is dominant on the vertical pipe,its maximum is located at the pipe top,all stresses are much less than the allowable value of the vertical pipe and joint;the heave motion leads to violent fluctuation of the force and stress,but a period of 8 s is not likely to resonate the present pipe;against the current,0.50 m/s is the suggested moving velocity of the ship and miner,while along the current,the moving velocity can be slightly higher than 0.75 m/s.

Thermodynamic Properties of NH_4^+ Fixation in Manured Loess Soil in Shaanxi Province, China

Some thermodynamic properties of NHk fixation by loess soil in plowing and clay layers are discussed.The. results indicate that the four ion adsorption equations commonly used can describe the properties of NHk fixation in these soils under constant temperature. Among the four adsorption equations, the singlesurface Langmuir equation is the best. When the concentration of NH4Cl solution is 10-1 mol below, the Freundlich equation can be used.The changes of apparent standard free energy (△Go), enthalpy (△Ho) and entropy (△So) illustrate that NHk fixation in soil is an endothermic adsorption and spontaneous reaction, and the process can be enhanced by a higher temperature and clay content in soil.The "proper value of NHk fixation by soil (K1×qm) increased with increasing clay content and temperature. The heat of NHk fixation in soil (Qm) confirms the conclusions made in this paper.

A novel adsorbent of three-dimensional ordered macro/mesoporous carbon for removal of malachite green dye

Three-dimensional ordered macro/mesoporous carbon(3DOM/m-C)with high specific surface area was synthesized by colloid crystal template method with chemical activation by KOH and used as the adsorbent for removing malachite green(MG)in aqueous solution.The microstructures of the adsorbents were characterized by FESEM,TEM and BET,and the effects of initial dye concentration,contact time,solution pH,and temperature on adsorption performance were investigated.The results show that the 3DOM/m-C exhibits extremely high adsorption capacity of 3541.1 mg/g within 2 h,which could be attributed to the novel ordered hierarchical structure with mesopores on three-dimensional ordered macroporous carbon walls.And the adsorption behavior conforms to the pseudo-second-order kinetic and Langmuir adsorption isotherm.3DOM/m-C can be recycled after being desorbed by absolute ethanol,and still maintains a high capacity of 2762.06 mg/g after 5 cycles.

Properties of Strange Matter in a Model with Effective lagrangian

The strange hadronic matter with nucleons, -hyperons and -hyperons is studied by using an effective nuclear model in a mean-field approximation. The density and strangeness fraction dependence of the effective baryon masses as well as the saturation properties and stabilities of the strange hadronic matter are discussed.

Kinetic Modelling of Degradation of Organic Compounds in Soils

A set of equations is suggested to describe the kinetics of degradation of organic compounds applied tosoils and the kinetics of growth of the involved microorganisme:where x is the concentration of organic compound at time t, m is the number of forcroorganisms capableof degrading the organic compound at time t, while j, k, f and g are positive constaats. This model cansatisfactorily be used to explain the degradation curve of organic compounds and the growth curve of theinvolved microorganisms.

Analysis and numerical simulation of dynamic effect on rock under high pressure water jet

Based on continuum mechanics and rock dynamics,analyzed the micro-struc- ture damage of rock and the impulsive effect under high pressure water jet and developed the dynamic model.Further,on the assumption of that rock was homogeneous and iso- tropic,a computational model was established based on nonlinear finite element and Arbi- trary Lagrangian-Eulerian(ALE) method.The dynamic effect impacted on rock under high pressure water jet was simulated by the dynamic contact method.The propagation of stress wave in rock was numerically simulated at different impacting velocity.The results show that the propagation velocity of stress wave is proportional to the impacting velocity of high pressure water jet.The faster the impacting velocity is,the quicker the comedown of stress wave.

Heterogeneity of Adsorption Sites and Adsorption Kinetics of n-Hexane on Metal–Organic Framework MIL-101(Cr)

The heterogeneity of adsorption sites and adsorption kinetics of n-hexane on a chromium terephthalate-based metal-organic framework MIL-10^1 （Cr） were studied by gravimetric method and temperature-programmed desorption （TPD） experiments. The MIL-101 crystals were synthesized by microwave irradiation method. The ad- sorption isotherms and kinetic curves of n-hexane on the MIL-101 were measured. Desorption activation energies of n-hexane from the MIL-10^1 were estimated by TPD experiments. The resulthowed that equilibrium amount ofn-hexane adsorbed on the MIL-10^1 was up to 5.62 mmol.g- 1 at 298 K and 1.6 x10^4 Pa, much higher than that of some activated carbons, zeolltes and so on. The isotherms of n-hexane on the MIL-101 could be well fitted with Langmuir-Freundlich model. TPD spectra exhibit two types of adsorption sites on the MIL-101 with desorption activation energies of 39.41 and 86.69 kJ. mol-1. It reflects the surface energy heterogeneity on the MIL-10I frameworks for n-hexane adsorption. The diffusion coefficients of n-hexane are in the range of （1.35- 2.35 ） x 10 - 1 o cm2. s - 1 with ad sorotion activation enerv of 16.33 kl. mol - 1.

A Model Study of Equation of State of QCD at Finite Chemical Potential and Zero Temperature

In this paper, we give a direct method for calculating the partition function, and hence the equation of state （EOS） of QCD at finite chemical potential and zero temperature. In the EOS derived in this paper the pressure density is the sum of two terms： the first term P（μ）｜μ=0 （the pressure density at μ = 0） is a μ-independent constant; the second term, which is totally determined by G[μ] （p） （the dressed quark propagator at finite μ）, contains all the nontrivial μ-dependence. By applying a general result in the rainbow-ladder approximation of the Dyson-Schwinger approach obtained in our previous study [Phys. Rev. C 71 （2005） 015205], G[μ]（p） is calculated from the meromorphic quark propagator proposed in [Phys. Rev. D 67 （2003） 054019]. From this the full analytic expression of the EOS of QCD at finite μ and zero T is obtained （apart from the constant term P（μ）｜μ=0, which can in principle be caJculated from the CJT effective action）. A comparison between our EOS and the cold, perturbative EOS of QCD of Fraga, Pisarski and Schaffner-Bielich is made. It is expected that our EOS can provide a possible new approach for the study of neutron stars.

Evolution of Cooperation in Public Goods Games

We investigate the evolution of cooperation with evolutionary public goods games based on finite populations, where four pure strategies： cooperators, defectors, punishers and loners who are unwilling to participate are considered. By adopting approximate best response dynamics, we show that the magnitude of rationality not only quantitatively explains the experiment results in [Nature （London） 425 （2003） 390], but also it will heavily influence the evolution of cooperation. Compared with previous results of infinite populations, which result in two equilibriums, we show that there merely exists a special equilibrium cooperation. In addition, we characterize that loner＇s and the relevant high value of bounded rationality will sustain payoff plays an active role in the maintenance of cooperation, which will only be warranted for the low and moderate values of loner＇s payoff. It thus indicates the effects of rationality and loner＇s payoff will influence the cooperation. Finally, we highlight the important result that the introduction of voluntary participation and punishment will facilitate cooperation greatly.

Dynamic Multi-class Network Loading Problem

The dynamic network loading problem (DNLP) consists in determining on a congested network, time-dependent arc volumes, together with arc and path travel times, given the time varying path flow departure rates over a finite time horizon. The objective of this pap er is to present the formulation of an analytical dynamic multi-class network loading model. The mo del does not require the assumption of the FIFO condition. The existence of a solution to the model is shown.

Mathematical Model for Takeoff Simulation of a Wing in Proximity to the Ground

Aircraft flying close to the ground benefit from enhanced efficiency owing to decreased induced drag and increased lift. In this study, a mathematical model is developed to simulate the takeoff of a wing near the ground using an Iterative Boundary Element Method （IBEM） and the finite difference scheme. Two stand-alone sub-codes and a mother code, which enables communication between the sub-codes, are developed to solve for the self-excitation of the Wing-In-Ground （WIG） effect. The aerodynamic force exerted on the wing is calculated by the first sub-code using the IBEM, and the vertical displacement of the wing is calculated by the second sub-code using the finite difference scheme. The mother code commands the two sub-codes and can solve for the aerodynamics of the wing and operating height within seconds. The developed code system is used to solve for the force, velocity, and displacement of an NACA6409 wing at a 4° Angle of Attack （AoA） which has various numerical and experimental studies in the literature. The effects of thickness and AoA are then investigated and conclusions were drawn with respect to generated results. The proposed model provides a practical method for understanding the flight dynamics and it is specifically beneficial at the pre-design stages of a WIG effect craft.

Combination of chlorine and magnetic ion exchange resin for drinking water treatment of algae

The effectiveness of a magnetic ion exchange resin （MIEX） for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter （NOM） removal at various MIEX doses and contact time, multiple-loading experiments, impacts of MIEX prior to coagulation on coagulant demands and the effectiveness of combination of MIEX, pre-chlorination and coagulation were investigated. Kinetic experimental results show that more than 80% UV254 and 67% dissolved organic carbon （DOC） from raw water can be removed by the use of MIEX alone. 94% sulfate, 69% nitrate and 98% bromide removals are obtained after the first use of MIEX in multiple-loading experiments. It is suggested that MIEX can be loaded up to 1 250 bed volume （BV, volume ratio of tested water to resin） or more without saturation when regarding organics removal as a target. MIEX can remove organics to a greater extend than coagulation and lower the coagulant demand when combining with coagulation. Chlorination experimental results show that MIEX can remove 57% chlorine demand and 77% trihalomethane formation potential （THMFP） for raw water. Pre-chlorination followed by MIEX and coagulation can give additional organic and THMFP removals. The results suggest that MIEX provides a new method to solve thc problem algae reproduction.

Dynamics analysis of planar armored cable motion in deep-sea ROV system

The armored cable used in a deep-sea remotely operated vehicle(ROV) may undergo large displacement motion when subjected to dynamic actions of ship heave motion and ocean current. A novel geometrically exact finite element model for two-dimensional dynamic analysis of armored cable is presented. This model accounts for the geometric nonlinearities of large displacement of the armored cable, and effects of axial load and bending stiffness. The governing equations are derived by consistent linearization and finite element discretization of the total weak form of the armored cable system, and solved by the Newmark time integration method. To make the solution procedure avoid falling into the local extreme points, a simple adaptive stepping strategy is proposed. The presented model is validated via actual measured data. Results for dynamic configurations, motion and tension of both ends of the armored cable, and resonance-zone are presented for two numerical cases, including the dynamic analysis under the case of only ship heave motion and the case of joint action of ship heave motion and ocean current. The dynamics analysis can provide important reference for the design or product selection of the armored cable in a deep-sea ROV system so as to improve the safety of its marine operation under the sea state of 4 or above.

Coupled analysis of engine noise and interior noise of an automobile

The coupled model of a four-cylinder internal combustion engine and a dash panel was constructed to analyze the relationship between the engine noise and interior noise of an automobile. Finite element analysis, flexible multi-body dynamics, and boundary element analysis were integrated to obtain the tetrahedron-element models, structural vibration response, and radiated noise,respectively. The accuracy of the finite-element model of the engine was validated by modal analysis via single-input multi-output technology, while the dash panel was validated by sound transmission loss experiment. The block was optimized to reduce the radiated acoustic power from the engine surface. The acoustic transfer path between the engine cabin and passenger compartment was then established. The coupled analysis results reveal that the interior noise is optimized due to the engine noise reduction.