The accumulative roll-bonding(ARB)process was applied on the strips of aluminum alloy 1050 in two processing conditions:cold ARB and warm ARB.The results of tensile tests and microhardness measurement show that the wa...The accumulative roll-bonding(ARB)process was applied on the strips of aluminum alloy 1050 in two processing conditions:cold ARB and warm ARB.The results of tensile tests and microhardness measurement show that the warm ARB process exhibits the lower tensile strength and microhardness,more homogeneous distribution of the microhardness,higher elongation,and especially superior planar isotropy of the tensile properties in comparison to the cold ARB,because of the intermediate heat treatment as well as the elevated temperature rolling in the warm ARB process.Furthermore,with increasing the cycles of both processes,the planar isotropy decreases progressively.展开更多
2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory （DFT） method at B3LYP/6-31G （d） level. The structure of syn-2,4-di-p-tolylpentane-2,4...2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory （DFT） method at B3LYP/6-31G （d） level. The structure of syn-2,4-di-p-tolylpentane-2,4-diol （2b） was characterized by X-ray diffraction and compared with the crystal structures of anti- and syn-2,4-diphenylpentane-2,4-diols （la and lb）. X-ray diffraction indicates that inter and intra-molecular hydrogen bonds are formed in the crystal structures. There is n-n staking interaction in lb and 2b. Good linear correlations and similar results are found between the experimental 1H and 13C NMR chemical shifts （6~exp） and GIAO （Gauge Independent Atomic Orbital） method calculated magnetic isotropic shielding tensors （acalc）. HOMO and LUMO molecular orbitals were calculated at the same levels with the different results. UV-vis absorption spectra of the compounds were recorded in EtOH, MeCN, n-BuOH and cyclohexane with different dielectric constants. It is found that the solvent effect is obvious when e is 24.85（EtOH）, 35.69（MeCN） and it is weak when e is decreased to 17.33（n-BuOH）, 1.18 （cyclohexane）.展开更多
Based on non-equilibrium thermodynamic theory, a temperature field model of gun muzzle is setup We obtain not only a solitary solution, but also a bifurcation solution. The physical picture of the solutions is corresp...Based on non-equilibrium thermodynamic theory, a temperature field model of gun muzzle is setup We obtain not only a solitary solution, but also a bifurcation solution. The physical picture of the solutions is corresponding to the center flame and secondary flame of the gun muzzle.展开更多
文摘The accumulative roll-bonding(ARB)process was applied on the strips of aluminum alloy 1050 in two processing conditions:cold ARB and warm ARB.The results of tensile tests and microhardness measurement show that the warm ARB process exhibits the lower tensile strength and microhardness,more homogeneous distribution of the microhardness,higher elongation,and especially superior planar isotropy of the tensile properties in comparison to the cold ARB,because of the intermediate heat treatment as well as the elevated temperature rolling in the warm ARB process.Furthermore,with increasing the cycles of both processes,the planar isotropy decreases progressively.
基金Projects(21072053,20772028)supported by the National Natural Science Foundation of ChinaProjects(10K025,11C0527)supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(LKF0901)supported by the Open Foundation of Key Laboratory of Theoretical Chemistry and Molecular Simulation of Ministry of Education,Hunan University of Science and Technology,China
文摘2,4-diphenylpentane- and 2,4-di-p-tolylpentane-2,4-diols were investigated employing experimental and density functional theory （DFT） method at B3LYP/6-31G （d） level. The structure of syn-2,4-di-p-tolylpentane-2,4-diol （2b） was characterized by X-ray diffraction and compared with the crystal structures of anti- and syn-2,4-diphenylpentane-2,4-diols （la and lb）. X-ray diffraction indicates that inter and intra-molecular hydrogen bonds are formed in the crystal structures. There is n-n staking interaction in lb and 2b. Good linear correlations and similar results are found between the experimental 1H and 13C NMR chemical shifts （6~exp） and GIAO （Gauge Independent Atomic Orbital） method calculated magnetic isotropic shielding tensors （acalc）. HOMO and LUMO molecular orbitals were calculated at the same levels with the different results. UV-vis absorption spectra of the compounds were recorded in EtOH, MeCN, n-BuOH and cyclohexane with different dielectric constants. It is found that the solvent effect is obvious when e is 24.85（EtOH）, 35.69（MeCN） and it is weak when e is decreased to 17.33（n-BuOH）, 1.18 （cyclohexane）.
文摘Based on non-equilibrium thermodynamic theory, a temperature field model of gun muzzle is setup We obtain not only a solitary solution, but also a bifurcation solution. The physical picture of the solutions is corresponding to the center flame and secondary flame of the gun muzzle.
