Ecological reactive powder concrete (ECO-RPC) with small sized and differentvolume fraction steel fibers was prepared by substitution of ultra-fine industrial waste powder for50% to 60% cement by weight and replacemen...Ecological reactive powder concrete (ECO-RPC) with small sized and differentvolume fraction steel fibers was prepared by substitution of ultra-fine industrial waste powder for50% to 60% cement by weight and replacement of ground fine quartz sand with natural fine aggregate.The effect of steel fiber volume fraction and curing ages on the static mechanical behaviour ofECO-RPC was studied. Using the split Hopkinson pressure bar technique, the dynamic mechanicalbehaviour of ECO-RPC was investigated under different strain rates. The results show that the staticmechanical behaviour of ECO-RPC increases with the increase of steel fiber volume fraction andcuring ages. The type of ECO-RPC with the substitution of 25% ultra-fine slag, 25% ultra-fine flyash and 10% silica fume is better than the others with compressive strength, flexural strength, andfracture energy more than 200 MPa, 60 MPa and 30 kJ/m^2, respectively. ECO-RPC has excellent strainrate stiffening effects under dynamic load. Its peak stress, peak strain and the area understrain-stress curve increase with the increase of strain rate. Its fracture pattern changes frombrittleness to toughness under high strain rates.展开更多
The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay ...The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy (EIS) analysis.展开更多
The microstructure and its effects on the high temperature mechanical behavior of Cu-2.7%Al_2O_3 (volume fraction) dispersion strengthened copper (ADSC) alloy were investigated. The results indicate that fine alum...The microstructure and its effects on the high temperature mechanical behavior of Cu-2.7%Al_2O_3 (volume fraction) dispersion strengthened copper (ADSC) alloy were investigated. The results indicate that fine alumina particles are uniformly distributed in the copper matrix, while a few coarse ones are distributed on the grain boundaries. Tensile tests results show that Hall-Petch mechanism is the main contribution to the yield strength of ADSC alloy at room temperature. Its high temperature strength is attributed to the strong pinning effects of alumina particles on the grain and sub-grain boundaries with dislocations. The ultimate tensile strength can reach 237 MPa and the corresponding yield strength reaches 226 MPa at 700℃. Tensile fracture morphology indicates that the ADSC alloy shows brittleness at elevated temperatures. Creep tests results demonstrate that the steady state creep rates at 400 ℃ are lower than those at 700 ℃. The stress exponents at 400 ℃ and 700℃ are 7 and 5, respectively, and the creep strain rates of the ADSC alloy are controlled by dislocation core diffusion and lattice diffusion.展开更多
The AA6061-10 wt.%B4 C mono composite, AA6061-10 wt.%B4 C-Gr(Gr: graphite) hybrid composites containing 2.5, 5, and 7.5 wt.% Gr particles, and AA6061-10 wt.%B4 C-Mo S2 hybrid composites containing 2.5, 5, and 7.5 wt.%...The AA6061-10 wt.%B4 C mono composite, AA6061-10 wt.%B4 C-Gr(Gr: graphite) hybrid composites containing 2.5, 5, and 7.5 wt.% Gr particles, and AA6061-10 wt.%B4 C-Mo S2 hybrid composites containing 2.5, 5, and 7.5 wt.% Mo S2 particles were fabricated through stir casting. The dry sliding tribological behaviors of the mono composite and hybrid composites were studied as a function of temperature on high temperature pin-on-disc tribotester against EN 31 counterface. The wear rate and friction coefficient of the Gr-reinforced and Mo S2-reinforced hybrid composites decreased in the temperature range of 30-100 ℃ due to the combined lubrication offered by the wear protective layer and its solid lubricant phase. Scanning electron microscopy(SEM) observation of the worn pin surface revealed severe adhesion, delamination, and abrasion wear mechanisms at temperatures of 150, 200, and 250 ℃, respectively. At 150 ℃, transmission electron microscopy(TEM) observation of the hybrid composites revealed the formation of deformation bands due to severe plastic deformation and fine crystalline structure due to dynamic recrystallization.展开更多
The hydrodynamic behavior in a high-density downer reactor was studied. A two-fluid model based on the kinetic theory of granular flow with a k-ε turbulent model was developed to simulate the flow behavior in the sys...The hydrodynamic behavior in a high-density downer reactor was studied. A two-fluid model based on the kinetic theory of granular flow with a k-ε turbulent model was developed to simulate the flow behavior in the system. This simulation achieved an averaged solid fraction in the bed as high as 18% in this operating regime. The flow development in high-density downer consists of 3 regions, which are first acceleration, second acceleration, and fully developed regions. In the fully developed region, the lateral distribution of the solid volume fraction is low and almost uniform in the center region with a high density peak near the wall region. Gas and solid velocities gradually increase toward the wall and form a peak near the wall region. In addition, the solid volume fraction, gas and solid velocities increase with solid circulation rate.展开更多
The dynamic recrystallization behavior of high strength steel during hot deformation was investigated.The hot compression test was conducted in the temperature range of 950-1150 °C under strain rates of 0.1,1 and...The dynamic recrystallization behavior of high strength steel during hot deformation was investigated.The hot compression test was conducted in the temperature range of 950-1150 °C under strain rates of 0.1,1 and 5 s-1.It is observed that dynamic recrystallization(DRX) is the main flow softening mechanism and the flow stress increases with decreasing temperature and increasing strain rate.The relationship between material constants(Q,n,α and ln A) and strain is identified by the sixth order polynomial fit.The constitutive model is developed to predict the flow stress of the material incorporating the strain softening effect and verified.Moreover,the critical characteristics of DRX are extracted from the stress-strain curves under different deformation conditions by linear regression.The dynamic recrystallization volume fraction decreases with increasing strain rate at a constant temperature or decreasing deformation temperature under a constant strain rate.The kinetics of DRX increases with increasing deformation temperature or strain rate.展开更多
Objective: To examine factors of the youth physical activity promotion (YPAP) model that are associated with Chinese international students' meeting PA recommendations (MPAR). Methods: A total of 649 (females ...Objective: To examine factors of the youth physical activity promotion (YPAP) model that are associated with Chinese international students' meeting PA recommendations (MPAR). Methods: A total of 649 (females = 320, males = 329) Chinese international college students participated in the study. This study was conducted in the United States (US.) between June and August in 2011. Participants completed an online survey regarding their demographic, PA, predisposing, enabling, and reinforcing factors. Results: Logistic nested-regression analysis suggested that being male, having a higher body mass index, perceived competence, self-efficacy, attitude, and enjoyment all increased (p 〈 0.001) the participants' odds of MPAR. Except language barriers, all of the enabling and reinforcing factors predicted MPAR indirectly through the predisposing factors (p 〈 0.001). Conclusion: Understanding factors that influence PA among Chinese international students is an important step in the process of promoting their long-term health and wellbeing. Designing program that address the identified key factors may help colleges and universities achieve this goal.展开更多
The elastic behavior of the polymer chain was investigated in a three-dimensional off-lattice model. We sample more than 109 conformations of each kind of polymer chain by using a Monte Carlo algorithm, then analyze t...The elastic behavior of the polymer chain was investigated in a three-dimensional off-lattice model. We sample more than 109 conformations of each kind of polymer chain by using a Monte Carlo algorithm, then analyze them with the non-Gaussian theory of rubberlike elasticity, and end with a statistical study. Through observing the effect of the chain flexibility and the stretching ratio on the mean-square end-to-end distance, the average energy, the average Helmholtz free energy, the elastic force, the contribution of energy to the elastic force, and the entropy contribution to elastic force of the polymer chain, we find that a rigid polymer chain is much easier to stretch than a flexible polymer chain. Also, a rigid polymer chain will become difficult to stretch only at a quite high stretching ratio because of the effect of the entropy contribution. These results of our simulation calculation may explain some of the macroscopic phenomena of polymer and biomacromolecular elasticity.展开更多
A 48-year old male with longstanding and extensive pancolitis developed a high grade and rapidly lethal malignant lesion in the ascending colon characterized by a neuroendocrine carcinoma.Prior biopsies obtained from ...A 48-year old male with longstanding and extensive pancolitis developed a high grade and rapidly lethal malignant lesion in the ascending colon characterized by a neuroendocrine carcinoma.Prior biopsies obtained from multiple sites in the colon during endoscopic surveillance were reported to show only inflammatory changes without dysplasia.Although operator-dependent,repeated endoscopic studies may have limitations during surveillance programs because the biological behavior of some colonic neoplastic lesions may have a rapid and very aggressive clinical course.展开更多
Network has not only become a habit and lifestyle for university student, but also brought all sorts of ethical misconducts and ethical issues in society. Based on the analysis of college students' frustrations, this...Network has not only become a habit and lifestyle for university student, but also brought all sorts of ethical misconducts and ethical issues in society. Based on the analysis of college students' frustrations, this paper explores the causes of network behavior anomie for college students, which mainly include: dissatisfaction in real communication, game addiction to the network, craving online pornography, and hooking on online shopping. In addition, it also investigates the ways to wipe out mental frustration in such a cyber era. These ways mainly are to strenzthen online education and management, to make psychological counseling, and to carry on frustration education.展开更多
IN706 superalloy is particularly sensitive to the parameters of hot working process.The flow stress of the IN706 superalloy was investigated during reduction deformation of 30%,45%,and 60%under the isothermal compress...IN706 superalloy is particularly sensitive to the parameters of hot working process.The flow stress of the IN706 superalloy was investigated during reduction deformation of 30%,45%,and 60%under the isothermal compression conditions of temperature at 1143–1393 K and strain rate at 0.01,0.1,0.5,and 1 s^(−1).The exponent-type Zener-Hollomon equation was used to describe the impact of strain and temperature on the thermal deformation.Meanwhile,the strain effect of various material constants,such asα,n,Q,and lnA,was considered in the constitutive equation considering the strain compensation,and the correlation coefficient R and the average absolute relative error were verified.On the basis of constitutive equation construction,the hot processing map of IN706 superalloy was drawn,and the instability region was obtained based on the Murty criterion.Results show that the reasonable thermal working process parameter window is strain rate of 0.1 s^(−1)and temperature of 1313–1353 K.展开更多
Experimental investigation was conducted to characterize the responses of pseudo-ductile cementitious composites (PDCCs) when subjected to uniaxial and biaxial compression.The PDCCs is a class of fiber reinforced ceme...Experimental investigation was conducted to characterize the responses of pseudo-ductile cementitious composites (PDCCs) when subjected to uniaxial and biaxial compression.The PDCCs is a class of fiber reinforced cementitious composites with ultra-high ductility by using a low volume fraction (2%) of polyvinyl alcohol (PVA) fiber.Two different strength grades of PDCC were examined with cubic specimen size of 100 mm in the tests.The specimens were loaded with a servo-hydraulic jack at different stress ratios.The principle stresses and strains of the specimens were recorded,and the failure modes with various stress states were examined.The test results indicated that the ultimate strength of PDCCs increased due to the lateral confinement in the other principal stress direction,and the maximum ultimate strength occurred at the biaxial stress ratio of 0.25,which was very different from common concrete material.For the PDCC specimens,the biaxial strength may be lower than the uniaxial strength when subjected to biaxial compression with the stress ratio of 1.0,and the failure mode showed a shear-type failure because of the bridging effect of fibers.Finally,a failure criterion was proposed for PDCCs under biaxial compression.展开更多
The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,...The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,3-triazolium nitrate(1b),3,4,5triamino-1,2,4-triazolium nitrate(2a),3,4,5-triamino-1,2,4-triazolium dinitramide(2b)were precisely measured using a Calvet Microcalorimeter.The thermochemical equation,differential enthalpies of dissolution(△difH m ),standard molar enthalpies of dissolution(△difH m ),apparent activation energy(E),pre-exponential constant(A),kinetic equation,linear relationship of specific heat capacity with temperature over the temperature range from 283 to 353 K,standard molar heat capacity(C p,m)and enthalpy,entropy and Gibbs free energy at 283–353 K,taking 298.15 K as the benchmark for 1a,1b,2a and 2b were obtained with treating experimental data and theoretical calculation method.The kinetic and thermodynamic parameters of thermal decomposition reaction,critical temperature of thermal explosion(Tb),self-accelerating decomposition temperature(TSADT)and adiabatic time-to-explosion(t)of 1a,1b,2a and 2b were calculated.Their heat-resistance abilities were evaluated.Information was obtained on the relation between molecular structures and properties of 1a,1b,2a and 2b.展开更多
In order to predict the mechanism of the formation and propagation of rolling contact fatigue cracks in Hadfield steel railway crossings(HSRC),the residual strain,microstructure,crystal orientation,and microhardness s...In order to predict the mechanism of the formation and propagation of rolling contact fatigue cracks in Hadfield steel railway crossings(HSRC),the residual strain,microstructure,crystal orientation,and microhardness surrounding fatigue cracks were investigated.Results show that the formation and propagation of fatigue cracks in HSRC have no correlation with the crystal orientation and boundaries of grains.The hardness and residual strain in the field around the fatigue crack are lower than those in other regions.The compressive strain around the fatigue crack is released after crack propagates,which reduces the hardness around the fatigue crack.Deformation twins and dislocations play a key role in the work hardening of HSRC.展开更多
This paper focuses on the dynamics of binary opinions {+1,-1} on online social networks consisting of heterogeneous actors. In our model, actors update their opinions under the interplay of social influence and self-...This paper focuses on the dynamics of binary opinions {+1,-1} on online social networks consisting of heterogeneous actors. In our model, actors update their opinions under the interplay of social influence and self- affirmation, which leads to rich dynamical behaviors on online social networks. We find that the opinion leading to the consensus features an advantage of the initially weighted fraction based on actors' strength over the other, instead of the population. For the role of specific actors, the consensus converges towards the opinion that a small fraction of high-strength actors hold, and individual diversity of self-amrmation slows down the ordering process of consensus. These indicate that high-strength actors play an essential role in opinion formation with strong social influence as well as high persistence. Further investigations show that the initial fraction of high-strength actors to dominate the evolution depends on the heterogeneity of the strength distribution, and less high-strength actors are needed in the case of a smaller exponent of power-law distribution of actors' strength. Our study provides deep insights into the role of social influence and self-affirmation on opinion formation on online social networks.展开更多
文摘Ecological reactive powder concrete (ECO-RPC) with small sized and differentvolume fraction steel fibers was prepared by substitution of ultra-fine industrial waste powder for50% to 60% cement by weight and replacement of ground fine quartz sand with natural fine aggregate.The effect of steel fiber volume fraction and curing ages on the static mechanical behaviour ofECO-RPC was studied. Using the split Hopkinson pressure bar technique, the dynamic mechanicalbehaviour of ECO-RPC was investigated under different strain rates. The results show that the staticmechanical behaviour of ECO-RPC increases with the increase of steel fiber volume fraction andcuring ages. The type of ECO-RPC with the substitution of 25% ultra-fine slag, 25% ultra-fine flyash and 10% silica fume is better than the others with compressive strength, flexural strength, andfracture energy more than 200 MPa, 60 MPa and 30 kJ/m^2, respectively. ECO-RPC has excellent strainrate stiffening effects under dynamic load. Its peak stress, peak strain and the area understrain-stress curve increase with the increase of strain rate. Its fracture pattern changes frombrittleness to toughness under high strain rates.
基金Project(RDCPJ346365-06)supported by the Natural Sciences and Engineering Research Council of CanadaProject(51208193)supported by the National Natural Science Foundation of ChinaProject(11jj6034)supported by the Hunan Provincial Natural Science Foundation
文摘The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy (EIS) analysis.
基金Project(51271203)supported by the National Natural Science Foundation of Chinathe PPP project between the CSC(China Scholarship Council)and the DAAD(German Academic Exchange Service)+2 种基金Project(11JJ2025)supported by Hunan Provincial Natural Science Foundation of ChinaProject(YSZN2013CL06)supported by the Nonferrous Metals Science Foundation of HNG-CSUProject supported by the Aid program for Science Technology Innovative Research Team in Higher Educational Institutions of Hunan Province,China
文摘The microstructure and its effects on the high temperature mechanical behavior of Cu-2.7%Al_2O_3 (volume fraction) dispersion strengthened copper (ADSC) alloy were investigated. The results indicate that fine alumina particles are uniformly distributed in the copper matrix, while a few coarse ones are distributed on the grain boundaries. Tensile tests results show that Hall-Petch mechanism is the main contribution to the yield strength of ADSC alloy at room temperature. Its high temperature strength is attributed to the strong pinning effects of alumina particles on the grain and sub-grain boundaries with dislocations. The ultimate tensile strength can reach 237 MPa and the corresponding yield strength reaches 226 MPa at 700℃. Tensile fracture morphology indicates that the ADSC alloy shows brittleness at elevated temperatures. Creep tests results demonstrate that the steady state creep rates at 400 ℃ are lower than those at 700 ℃. The stress exponents at 400 ℃ and 700℃ are 7 and 5, respectively, and the creep strain rates of the ADSC alloy are controlled by dislocation core diffusion and lattice diffusion.
文摘The AA6061-10 wt.%B4 C mono composite, AA6061-10 wt.%B4 C-Gr(Gr: graphite) hybrid composites containing 2.5, 5, and 7.5 wt.% Gr particles, and AA6061-10 wt.%B4 C-Mo S2 hybrid composites containing 2.5, 5, and 7.5 wt.% Mo S2 particles were fabricated through stir casting. The dry sliding tribological behaviors of the mono composite and hybrid composites were studied as a function of temperature on high temperature pin-on-disc tribotester against EN 31 counterface. The wear rate and friction coefficient of the Gr-reinforced and Mo S2-reinforced hybrid composites decreased in the temperature range of 30-100 ℃ due to the combined lubrication offered by the wear protective layer and its solid lubricant phase. Scanning electron microscopy(SEM) observation of the worn pin surface revealed severe adhesion, delamination, and abrasion wear mechanisms at temperatures of 150, 200, and 250 ℃, respectively. At 150 ℃, transmission electron microscopy(TEM) observation of the hybrid composites revealed the formation of deformation bands due to severe plastic deformation and fine crystalline structure due to dynamic recrystallization.
文摘The hydrodynamic behavior in a high-density downer reactor was studied. A two-fluid model based on the kinetic theory of granular flow with a k-ε turbulent model was developed to simulate the flow behavior in the system. This simulation achieved an averaged solid fraction in the bed as high as 18% in this operating regime. The flow development in high-density downer consists of 3 regions, which are first acceleration, second acceleration, and fully developed regions. In the fully developed region, the lateral distribution of the solid volume fraction is low and almost uniform in the center region with a high density peak near the wall region. Gas and solid velocities gradually increase toward the wall and form a peak near the wall region. In addition, the solid volume fraction, gas and solid velocities increase with solid circulation rate.
基金Project (51322405) supported by the National Natural Science Foundation of ChinaProject (CX2013B085) supported by Hunan Provincial Innovation Foundation for Postgraduate,China
文摘The dynamic recrystallization behavior of high strength steel during hot deformation was investigated.The hot compression test was conducted in the temperature range of 950-1150 °C under strain rates of 0.1,1 and 5 s-1.It is observed that dynamic recrystallization(DRX) is the main flow softening mechanism and the flow stress increases with decreasing temperature and increasing strain rate.The relationship between material constants(Q,n,α and ln A) and strain is identified by the sixth order polynomial fit.The constitutive model is developed to predict the flow stress of the material incorporating the strain softening effect and verified.Moreover,the critical characteristics of DRX are extracted from the stress-strain curves under different deformation conditions by linear regression.The dynamic recrystallization volume fraction decreases with increasing strain rate at a constant temperature or decreasing deformation temperature under a constant strain rate.The kinetics of DRX increases with increasing deformation temperature or strain rate.
文摘Objective: To examine factors of the youth physical activity promotion (YPAP) model that are associated with Chinese international students' meeting PA recommendations (MPAR). Methods: A total of 649 (females = 320, males = 329) Chinese international college students participated in the study. This study was conducted in the United States (US.) between June and August in 2011. Participants completed an online survey regarding their demographic, PA, predisposing, enabling, and reinforcing factors. Results: Logistic nested-regression analysis suggested that being male, having a higher body mass index, perceived competence, self-efficacy, attitude, and enjoyment all increased (p 〈 0.001) the participants' odds of MPAR. Except language barriers, all of the enabling and reinforcing factors predicted MPAR indirectly through the predisposing factors (p 〈 0.001). Conclusion: Understanding factors that influence PA among Chinese international students is an important step in the process of promoting their long-term health and wellbeing. Designing program that address the identified key factors may help colleges and universities achieve this goal.
基金This work was supported by the National Science Fund for Distinguished Young Scholars (No.20525416), the National Natural Science Foundation of China (No.20490220, No.20374050, and No.90403022), and the National Basic Research Program of China (No.2005CB623800).
文摘The elastic behavior of the polymer chain was investigated in a three-dimensional off-lattice model. We sample more than 109 conformations of each kind of polymer chain by using a Monte Carlo algorithm, then analyze them with the non-Gaussian theory of rubberlike elasticity, and end with a statistical study. Through observing the effect of the chain flexibility and the stretching ratio on the mean-square end-to-end distance, the average energy, the average Helmholtz free energy, the elastic force, the contribution of energy to the elastic force, and the entropy contribution to elastic force of the polymer chain, we find that a rigid polymer chain is much easier to stretch than a flexible polymer chain. Also, a rigid polymer chain will become difficult to stretch only at a quite high stretching ratio because of the effect of the entropy contribution. These results of our simulation calculation may explain some of the macroscopic phenomena of polymer and biomacromolecular elasticity.
文摘A 48-year old male with longstanding and extensive pancolitis developed a high grade and rapidly lethal malignant lesion in the ascending colon characterized by a neuroendocrine carcinoma.Prior biopsies obtained from multiple sites in the colon during endoscopic surveillance were reported to show only inflammatory changes without dysplasia.Although operator-dependent,repeated endoscopic studies may have limitations during surveillance programs because the biological behavior of some colonic neoplastic lesions may have a rapid and very aggressive clinical course.
文摘Network has not only become a habit and lifestyle for university student, but also brought all sorts of ethical misconducts and ethical issues in society. Based on the analysis of college students' frustrations, this paper explores the causes of network behavior anomie for college students, which mainly include: dissatisfaction in real communication, game addiction to the network, craving online pornography, and hooking on online shopping. In addition, it also investigates the ways to wipe out mental frustration in such a cyber era. These ways mainly are to strenzthen online education and management, to make psychological counseling, and to carry on frustration education.
文摘IN706 superalloy is particularly sensitive to the parameters of hot working process.The flow stress of the IN706 superalloy was investigated during reduction deformation of 30%,45%,and 60%under the isothermal compression conditions of temperature at 1143–1393 K and strain rate at 0.01,0.1,0.5,and 1 s^(−1).The exponent-type Zener-Hollomon equation was used to describe the impact of strain and temperature on the thermal deformation.Meanwhile,the strain effect of various material constants,such asα,n,Q,and lnA,was considered in the constitutive equation considering the strain compensation,and the correlation coefficient R and the average absolute relative error were verified.On the basis of constitutive equation construction,the hot processing map of IN706 superalloy was drawn,and the instability region was obtained based on the Murty criterion.Results show that the reasonable thermal working process parameter window is strain rate of 0.1 s^(−1)and temperature of 1313–1353 K.
基金supported by the National Natural Science Foundation of China (Grant No. 51278118)the National Basic Research Program of China ("973" Program) (Grant No. 2009CB623200)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘Experimental investigation was conducted to characterize the responses of pseudo-ductile cementitious composites (PDCCs) when subjected to uniaxial and biaxial compression.The PDCCs is a class of fiber reinforced cementitious composites with ultra-high ductility by using a low volume fraction (2%) of polyvinyl alcohol (PVA) fiber.Two different strength grades of PDCC were examined with cubic specimen size of 100 mm in the tests.The specimens were loaded with a servo-hydraulic jack at different stress ratios.The principle stresses and strains of the specimens were recorded,and the failure modes with various stress states were examined.The test results indicated that the ultimate strength of PDCCs increased due to the lateral confinement in the other principal stress direction,and the maximum ultimate strength occurred at the biaxial stress ratio of 0.25,which was very different from common concrete material.For the PDCC specimens,the biaxial strength may be lower than the uniaxial strength when subjected to biaxial compression with the stress ratio of 1.0,and the failure mode showed a shear-type failure because of the bridging effect of fibers.Finally,a failure criterion was proposed for PDCCs under biaxial compression.
基金supported by the National Natural Science Foundation of China (20573098)the Science and Technology Foundation of National Key Lab of Science and Technology on Combustion and Explosion in China (9140C3503030805)
文摘The properties of dissolution in different solvents,the specific heat capacity and thermal decomposition process under the non-isothermal conditions for energetic triazole ionic salts 1,2,4-triazolium nitrate(1a),1,2,3-triazolium nitrate(1b),3,4,5triamino-1,2,4-triazolium nitrate(2a),3,4,5-triamino-1,2,4-triazolium dinitramide(2b)were precisely measured using a Calvet Microcalorimeter.The thermochemical equation,differential enthalpies of dissolution(△difH m ),standard molar enthalpies of dissolution(△difH m ),apparent activation energy(E),pre-exponential constant(A),kinetic equation,linear relationship of specific heat capacity with temperature over the temperature range from 283 to 353 K,standard molar heat capacity(C p,m)and enthalpy,entropy and Gibbs free energy at 283–353 K,taking 298.15 K as the benchmark for 1a,1b,2a and 2b were obtained with treating experimental data and theoretical calculation method.The kinetic and thermodynamic parameters of thermal decomposition reaction,critical temperature of thermal explosion(Tb),self-accelerating decomposition temperature(TSADT)and adiabatic time-to-explosion(t)of 1a,1b,2a and 2b were calculated.Their heat-resistance abilities were evaluated.Information was obtained on the relation between molecular structures and properties of 1a,1b,2a and 2b.
基金supported by the National Science Foundation for Distinguished Young Scholars(Grant No.50925522)
文摘In order to predict the mechanism of the formation and propagation of rolling contact fatigue cracks in Hadfield steel railway crossings(HSRC),the residual strain,microstructure,crystal orientation,and microhardness surrounding fatigue cracks were investigated.Results show that the formation and propagation of fatigue cracks in HSRC have no correlation with the crystal orientation and boundaries of grains.The hardness and residual strain in the field around the fatigue crack are lower than those in other regions.The compressive strain around the fatigue crack is released after crack propagates,which reduces the hardness around the fatigue crack.Deformation twins and dislocations play a key role in the work hardening of HSRC.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 60902094,60903225Research Fund for the Doctoral Program of Higher Education of China under Grant No. 20114307110008
文摘This paper focuses on the dynamics of binary opinions {+1,-1} on online social networks consisting of heterogeneous actors. In our model, actors update their opinions under the interplay of social influence and self- affirmation, which leads to rich dynamical behaviors on online social networks. We find that the opinion leading to the consensus features an advantage of the initially weighted fraction based on actors' strength over the other, instead of the population. For the role of specific actors, the consensus converges towards the opinion that a small fraction of high-strength actors hold, and individual diversity of self-amrmation slows down the ordering process of consensus. These indicate that high-strength actors play an essential role in opinion formation with strong social influence as well as high persistence. Further investigations show that the initial fraction of high-strength actors to dominate the evolution depends on the heterogeneity of the strength distribution, and less high-strength actors are needed in the case of a smaller exponent of power-law distribution of actors' strength. Our study provides deep insights into the role of social influence and self-affirmation on opinion formation on online social networks.