单晶和强织构材料宏应力的X光衍射分析方法

定向凝固的镍基合金和硅、锗单晶以及取向硅钢等强织构材料的精确定向和宏应力计算一直是材料领域十分关注的问题,本文采用了一种基于单一极图识别晶体坐标系取向的方法,直接利用宏应力测算中的极角参数来确定晶体坐标系的欧拉角;讨论了将该方法和Suyama等人提出的宏应力X光衍射回归分析方法相结合的算法,使该方法更易于工程应用。

Kinetics on Hydrogenation of Cyclopentadiene over Pd/γ-Al2O3 Catalyst

The macrokinetics of hydrogenation of cyclopentadiene was investigated over Pd/γ-Al2O3 catalyst.Experimental results showed that the relationship between the constituents and reaction time was in agreement with the characteristic of consecutive irreversible first-order reaction. Analysis on the reaction mechanism of selective hydrogenation of cyclopentadiene indicated that it is reasonable to express the hydrogenation rate of cyclopentadiene in the power law form. Parameters of the kinetic model were obtained by the Gauss-Newton method based on the experimental data. From the statistic test and residual error distribution the kinetic model was proved to be adequate.

Progressive failure analysis of composite structure based on micro- and macro-mechanics models

Based on parameter design language, a program of progressive failure analysis in composite structures is proposed. In this program, the relationship between macro- and micro-mechanics is established and the macro stress distribution of the composite structure is calculated by commercial finite element software. According to the macro-stress, the damaged point is found and the micro-stress distribution of representative volume element is calculated by finite-volume direct averaging micromechanics(FVDAM). Compared with the results calculated by failure criterion based on macro-stress field(the maximum stress criteria and Hashin criteria) and micro-stress field(Huang model), it is proven that the failure analysis based on macro- and micro-mechanics model is feasible and efficient.

Caving thickness effects of surrounding rocks macro stress shell evolving characteristics

In order to explore the influence of different caving thicknesses on the MSS distributionand evolving characteristics of surrounding rocks in unsymmetrical disposal andfully mechanized top-coal caving (FMTC),based on unsymmetrical disposal characteristics,the analyses of numerical simulation,material simulation and in-situ observation weresynthetically applied according to the geological and technical conditions of the 1151(3)working face in Xieqiao Mine.The results show that the stress peak value of the MSS-baseand the ratio of MSS-body height to caving thickness are nonlinear and inverselyproportional to the caving thickness.The MSS-base width,the MSS-body height,theMSS-base distance to working face wall and the rise distance of MSS-base beside coalpillar are nonlinear and directly proportional to the caving thickness.The characteristics ofMSS distribution and its evolving rules of surrounding rocks and the integrated cavingthickness effects are obtained.The investigations will provide lots of theoretic referencesto the surrounding rocks' stability control of the working face and roadway,roadway layout,gas extraction and exploitation,and efficiency of caving,etc.

Physical and mechanical properties of sandstone containing a single fissure after exposure to high temperatures

In order to investigate the physical and mechanical properties of sandstone containing fissures after exposure to high temperatures,fissures with different angles α were prefabricated in the plate sandstone samples,and the processed samples were then heated at 5 different temperatures.Indoor uniaxial compression was conducted to analyze the change rules of physical properties of sandstone after exposure to high temperature,and the deformation,strength and failure characteristics of sandstone containing fissures.The results show that,with increasing temperature,the volume of sandstone increases gradually while the quality and density decrease gradually,and the color of sandstone remains basically unchanged while the brightness increases markedly when the temperature is higher than 585 ℃;the peak strength of sandstone containing fissures first decreases then increases when the temperature is between 25℃and 400℃.The peak strain of sandstone containing fissures increases gradually while the average modulus decreases gradually with increasing temperature,and the mechanical properties of sandstone show obvious deterioration after 400 ℃.The peak strain of sandstone containing fissures increases gradually while the average modulus decreases gradually with increasing temperature;with increasing angle αof the fissure,the evolution characteristics of the macro-mechanical parameters of sandstone are closely related to the their own mechanical properties.When the temperature is 800 ℃,the correlation between the peak strength and average modulus of sandstone and the angle α of the fissure is obviously weakened.The failure modes of sandstone containing fissures after high temperature exposure are of three different kinds including:tensile crack failure,tensile and shear cracks mixed failure,and shear crack failure.Tensile and shear crack mixed failure occur mainly at low temperatures and small angles;tensile crack failure occurs at high temperatures and large angles.

A novel method to produce potassium chromate from carbon ferrochrome

The oxidizing roasting of carbon ferrochrome in the presence of potassium carbonate and air was investigated. The effects of reaction temperature, reaction time, ratio of alkali-to-ore were studied, together with a discussion of the thermodynamics and macro kinetics. It is observed that the reaction temperature and reaction time have significant influence on the roasting reaction. The reaction mechanism changes greatly as the temperature varies. A two-stage roasting process is favorable for the roasting reaction, and a recovery ratio of 96.51% is obtained through this two-stage roasting method. The chromium residue yielded from this method is quite little, only one third of the product. Moreover, the component of Fe in the residue is as high as 54.28%. Therefore, it can be easily recovered to produce sponge iron, realizing zero-emission of chromium residue.

A numerical study of macro-mesoscopic mechanical properties of gangue backfill under biaxial compression

Based on the Particle Flow Code(PFC^(2D)) program,we set up gangue backfill models with different gangue contents and bond strength,and studied the stress-strain behaviours,the pattern of shear band and force chains,motion and fragmentation of particles under biaxial compression.The results show that when the bond strength or contents of gangue are high,the peak strength is high and the phenomena of post-peak softening and fluctuation are obvious.When gangue contents are low,the shape of the shear band is symmetrical and most strong force chains transfer in soil particles.With an increase in gangue content,the shape of the shear band becomes irregular and the majority of strong force chains turn to transfer in gangue particles gradually,most of which distribute along the axial direction.When the gangue content is higher than 50%,the interconnectivity of strong force chains decreases gradually:at the same time,the strong force chains become tilted and the stability of the system tends to decrease.With an increase in external loading,the coordination numbers of the system increase at first and then decrease and the main pattern of force chains changes into columnar from annular.However,after the forming of the advantageous shear band,the force chains external to the shear band maintain their columnar shape while the inner ones bend obviously.As a result,annular force chains form.

Effect of heating-rate on failure temperature of pre-loaded magnesium alloy

The response and failure of magnesium alloy AZ31 specimens subjected to different pre-loaded-stress levels and heating rates were investigated with a Gleeble-1500 thermo-mechanical material testing system.It is found that the increases of either pre-loaded stresses or heating-rates decrease the failure temperatures of the specimens.The metallographs of the tested specimens were also observed.It is shown that the high heating-rate may cause stronger local thermal inconsistency,which remarkably increases the microdefects and reduces the macroscopic mechanical properties of the material.

Molecular dynamics study on the nano-void growth and coalescence at grain boundary

Molecular dynamics simulations using embedded atom method (EAM) potential were performed to study nano-void growth and coalescence at grain boundary in face-centered cubic bicrystal copper. Thin-plate specimens subjected to uniaxial tension strain with one-void and two-void at the centered grain boundary were employed to analyze the effect of specimen size, temperature and applied strain rate on the stress-strain response, incipient yield strength and macroscopic effective Young's modulus. The evolutions of dislocations, twin bands and void shapes under different specimen sizes were also presented. The obtained results show that, regardless of the void numbers, the specimen sizes, temperature, the applied strain rate had significant influence on the void shape evolution, stress-strain curve and incipient yield strength, while negligible effects on the macroscopic effective Young's modulus except for the temperature. Moreover, the voids growth rate along the grain boundary was also found to be associated with the specimen sizes.

Biochar-Induced Changes in Soil Resilience:Effects of Soil Texture and Biochar Dosage

Biochars are, amongst other available amendment materials, considered as an attractive tool in agriculture for carbon sequestration and improvement of soil functions. The latter is widely discussed as a consequence of improved physical quality of the amended soil.However, the mechanisms for this improvement are still poorly understood. This study investigated the effect of woodchip biochar amendment on micro-structural development, micro-and macro-structural stability, and resilience of two differently textured soils,fine sand(FS) and sandy loam(SL). Test substrates were prepared by adding 50 or 100 g kg^(-1) biochar to FS or SL. Total porosity and plant available water were significantly increased in both soils. Moreover, compressive strength of the aggregates was significantly decreased when biochar amount was doubled. Mechanical resilience of the aggregates at both micro-and macro-scale was improved in the biochar-amended soils, impacting the cohesion and compressive behavior. A combination of these effects will result in an improved pore structure and aeration. Consequently, the physicochemical environment for plants and microbes is improved. Furthermore, the improved stability properties will result in better capacity of the biochar-amended soil to recover from the myriad of mechanical stresses imposed under arable systems, including vehicle traffic, to the weight of overburden soil. However, it was noted that doubling the amendment rate did not in any case offer any remarkable additional improvement in these properties, suggesting a further need to investigate the optimal amendment rate.

A plastic damage model for concrete structure cracks with two damage variables

Based on the concepts of continuum damage theory,a new plastic damage model for concrete crack failure is developed through studying the basic damage mechanics.Two damage variables,tensile damage variable for tensile damage and shear damage variable for compressive damage,are adopted to represent the influence of microscopic damage on material macromechanics properties under tensile and compressive loadings.The yield criteria and flow rule determining the plasticity of concrete are established in the effective stress space,which is convenient to decouple the damage process from the plastic process and calibrate material parameters with experimental results.Meanwhile,the plastic part of the proposed model can be implemented by back-Euler implicit algorithm,and the damage part is explicit.Consequently,there exist robust algorithms for integrating the constitutive relations using finite element method.Comparison with several experimental results shows that the model is capable of simulating the nonlinear performance of concrete under multiaxial stress state and can be applied to practical concrete structures.