含长链不饱和酯基的三官能度溶胶-凝胶薄膜制备及发光氧气传感的研究

采用溶胶－凝胶法制备了含发光三吡啶钌[Ｒｕ(ｂｐｙ)３_^(２＋)]分子的三官能度硅氧烷预聚液,并通过旋转涂敷及凝胶处理制备了高性能的薄膜,探讨了载体的微结构和发光分子的微环境效应．与传统的四官能度正硅酸乙酯(ＴＥＯＳ)/Ｒｕ(ｂｐｙ)_３_(２＋)膜体系相比,含长链不饱和酯基的甲基丙烯酸丙酯基三甲氧基硅烷(ＰＭＡ－ＴＭＳ)/Ｒｕ(ｂｐｙ)_３_(２＋)体系具有成膜性能好,气体的猝灭响应值高,响应时间短等特点．

射流控制

A Fluid Control Valve Based on the Viscosity Increase Effects of Dielectric Fluids Caused by Electrodes Planted with Hair-Like Short Fibers (Proposition of a Fiber Planted ER Valve),A THERMO-PNEUMATIC IN-CHANNEL MICRO VALVE WITH PDMS DIAPHRAGM FOR INTEGRATED BLOOD EXAMINATION SYSTEM ON SILICON.Active control of jets in crossflow.ASCO innovative technology.Dynamic compensation of abrasive water jet properties through 3-dimensional jet control.

Selective removal of heavy metal ions from aqueous solutions with surface functionalized silica nanoparticles by different functional groups

The industrial silica fume pretreated by nitric acid at 80 °C was re-used in this work. Then, the obtained silica nanoparticles were surface functionalized by silane coupling agents, such as(3-Mercaptopropyl) triethoxysilane(MPTES) and(3-Amincpropyl) trithoxysilane(APTES). Some further modifications were studied by chloroaceetyl choride and 1,8-Diaminoaphalene for amino modified silica. The surface functionalized silica nanoparticles were characterized by Fourier transform infrared(FI-IR) and X-ray photoelectron spectroscopy(XPS). The prepared adsorbent of surface functionalized silica nanoparticles with differential function groups were investigated in the selective adsorption about Pb2+, Cu2+, Hg2+, Cd2+ and Zn2+ions in aqueous solutions. The results show that the(3-Mercaptopropyl) triethoxysilane functionalized silica nanoparticles(SiO2-MPTES) play an important role in the selective adsorption of Cu2+ and Hg2+, the(3-Amincpropyl) trithoxysilane(APTES) functionalized silica nanoparticles(SiO2-APTES) exhibited maximum removal efficiency towards Pb2+ and Hg2+, the 1,8-Diaminoaphalene functionalized silica nanoparticles was excellent for removal of Hg2+ at room temperature, respectively.

Removal of nickel(Ⅱ) from aqueous solutions using iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers

Iminodiacetic acid functionalized polyglycidyl methacrylate grafted-carbon fibers(PGMA-IDA/CFs) were prepared for Ni(II) removal from aqueous solutions. The effects of solution p H value, temperature and adsorption time were investigated. The maximum adsorption capacity of Ni(II) on PGMA-IDA/CFs is 0.923 mmol·L-1· g-1at pH 5.2 and 50 °C. Kinetic data indicate that the adsorption process matches the pseudo-second-order model and Elovich kinetic model. Thermodynamic data suggest that the adsorption process is endothermic spontaneous reaction.

Investigation on the Key Factors and the Solution for pH Value Decrease in Carbon Filter in O3-BAC Process＊

An investigation was carried out to eliminate the decrease of effluent pH value in carbon filter in O3-biological activated carbon process. The influence factors were examined in a pilot test, and pH was adjusted in the pilot and waterworks. Results show that the carbon filter is an acid-base buffer system and the activated carbon is the key factor. Chemical functional groups on activated carbon surface present acid-base properties to buffer the water but decrease with time, so that effluent pH value decreases. The effects of ozone dosage, CO2 in the carbon filter, and the filter influent quality are negligible. A new method to adjust pH is developed: the activated carbon is first modified by soaking in sodium hydroxide solution to make its pH reach the desired value, and then the pH value of inflow is controlled to certain value by dosing lime in sand filter influent. The method is economical and effective.

Effect of electrochemical oxidation on carbon nanotube electrodes of electric double layer capacitors

Electrochemical oxidation of the carbon nanotube (CNT) polarizable electrodes of electric double layer capacitors (EDLCs) was studied. It indicated that electrochemical oxidation elevated the available surface area of the electrodes and introduced some kinds of functional group on the CNT surfaces. The specific capacitances of the polarizable electrodes with organic electrolyte could be enhanced from 22.4 F g-1 to 78.2 F g-1 after electrolysis oxidization. The enhancement of the specific capacitance depends on the extent of electrochemical oxidation. Using acidic electrolyte for electrochemical oxidation has different effects on modifying the performances of the CNT polarizable electrodes compared to using basic electrolyte.

The reductive mechanism of nitrobenzene catalyzed by nine charcoals in sulfides solution

Due to the different sources of charcoals, there are significant differences in their properties. In order to study the catalytic effect of different charcoals to nitrobenzene (NB), we selected nine charcoal-sources to prepare nine charcoals with different properties. The experiments showed that NB could be rapidly reduced by sulfides in the presence of all charcoals. The surface area normalized reduction rate constants of NB increased with H/C and (O+N)/C ratio of charcoals increasing. The difference of catalytic effect for nine charcoals was mainly due to their different species and content of surface functional groups and original organic matter. Based on the theoretical calculation and experimental results, the reaction mechanism of NB catalyzed by charcoal in sulfides solution was analyzed. Some active surface functional groups and original organic matter of charcoals were regarded as the active sites and played an important role in catalyzing the reduction of NB by accelerating the transfer of electrons from sulfides to NB.

High-selective removal of ultra-low level mercury ions from aqueous solution using oligothymonucleic acid functionalized polyethylene film

We prepare oligothymonucleic acid (OTA) functionalized polyethylene (PE) film and evaluate its selective removal ability of mercury ions at ultra-low levels in aqueous solution. The selective binding of OTA with mercury ions is confirmed by fluorescence in situ hybridization (FISH). The quantitative results via cold-vapor atomic fluorescence spectrometry (CVAFS) indicate that OTA-functionalized PE film is able to remove mercury ions at the sub-ppb level selectively from aqueous solution, even with the coexistence of other metal ions at concentrations 250-fold or higher than that of mercury.

Rapid proton diffusion in hydroxyl functionalized imidazolium ionic liquids

There is considerable interest in using ionic liquids(ILs) as protic electrolytes. However, the reported proton transfer rate in ILs is quite slow. In this study, we report functionalizing imidazolium ILs with alcohol hydroxyls, aiming at constructing hydrogen bonding networks in the electrolyte, can stimulate fast proton hopping transfer. For demonstration, the diffusion of proton and Cl. in 1-(3-hydroxypropyl)-3-methylimidazolium tetrafluoroboride(C_3OHmimBF_4) were studied using cyclic voltammetry and potentiostatic method at 30 °C. The diffusion coefficient of proton is about one order of magnitude higher than that of Cl. in the same electrolyte, and about 5 times that of proton in the non-hydydroxyl 1-(butyl)-3-methylimidazolium tetrafluoroboride(BmimBF_4) when normalized to the diffusion coefficients of Cl. in respective ILs. In the meantime, 1H NMR spectra revealed a strong hydrogen bonding interaction between proton and C_3OHmimBF_4 which is absent between proton and BmimBF_4, thus the significantly higher diffusion coefficient of proton in C_3OHmimBF_4 may suggest the formation of effective hydrogen bonding networks, enabling rapid proton hopping via the Grotthuss mechanism.