Strategic alliance has suffered much instabilities since its first implementation. Scholars have carried out many em- bedded, precise and comprehensive researches from both theory and empiricism. Here we try to find c...Strategic alliance has suffered much instabilities since its first implementation. Scholars have carried out many em- bedded, precise and comprehensive researches from both theory and empiricism. Here we try to find certain stable solutions by employing game theory, in an attempt to construct theoretical bases for strategic alliance, which people called “one of the most important organizational innovation in the end of the 20th century” (Shi, 2001), to exploit its advantages in the process of glob- alization. Finally, this article puts forward some advices for its success.展开更多
By means of the continuation theorem of the coincidence degree theory,the existence of two periodic solutions of a delayed single species model with feedback regulation and harvest term is obtained.
This paper is on a distribution question of Ⅰ type in the combinatorics (see: 'Ke Zhao, Wei WanDi, combinatorial theory, science press, 1981. '). Suppose n distrinct balls, m distinct boxes. The capacity set...This paper is on a distribution question of Ⅰ type in the combinatorics (see: 'Ke Zhao, Wei WanDi, combinatorial theory, science press, 1981. '). Suppose n distrinct balls, m distinct boxes. The capacity set of every box is Now,place the n balls into the m boxes. Thenumber of distinct placed ways is expressed by , and simply by And it is called the distribution number.Main result is:Theorem The exponential generating function of sequence isThus .there is the recurrence relationhere (integer set).展开更多
Density, ρ, ultrasonic speed, u, and viscosity, η, of binary mixtures of 2-methyl-2-propanol (2M2P) with acetonitrile (AN), propionitrile (PN) and butyronitrile (BN) including those of pure liquids are measured over...Density, ρ, ultrasonic speed, u, and viscosity, η, of binary mixtures of 2-methyl-2-propanol (2M2P) with acetonitrile (AN), propionitrile (PN) and butyronitrile (BN) including those of pure liquids are measured over the entire composition range at temperatures 298.15, 303.15 and 308.15 K. From these experimental data, the excess available volume, E a V , excess free volume, E f V , excess isothermal compressibility, E T β , excess thermal expansion coefficient, E α , and excess internal pressure, E i π , are calculated. The variation of these properties with composition and temperature are discussed in terms of molecular interactions between unlike molecules of the mixtures. It is found that the values of E a V , E f V , E T β and E α are positive and those of E i π are negative for all the mixtures at each temperature studied, indicating the presence of weak interactions between 2M2P and AN/PN/BN molecules. The variations of E a V , E f V , E T β , E α and E i π values with composition indicate that the interactions in these mixtures follow the order: AN<PN<BN, i.e., the 2M2P-nitrile interaction decreases with the increase of alkyl chain length in these nitrile molecules. In addition, the theoretical ultrasonic velocity is calculated using the scaled particle theory and compared with the experimental values.展开更多
This paper introduces the calculation of the deformation of the surroundings of roadways and the division of surroundings into 5 levels by means of fuzzy integral assess matrix, which serves as the scientific basis fo...This paper introduces the calculation of the deformation of the surroundings of roadways and the division of surroundings into 5 levels by means of fuzzy integral assess matrix, which serves as the scientific basis for selecting supporting pattern of roadways and determining the parameters of support.展开更多
We investigate synchronization in an array network of nearest-neighbor coupled chaotic oscillators. By using of the Lyapunov stability theory and matrix theory, a criterion for stability of complete synchronization is...We investigate synchronization in an array network of nearest-neighbor coupled chaotic oscillators. By using of the Lyapunov stability theory and matrix theory, a criterion for stability of complete synchronization is deduced. Meanwhile, an estimate of the critical coupling strength is obtained to ensure achieving chaos synchronization. As an example application, a model of coupled Chua's circuits with linearly bidirectional coupling is studied to verify the validity of the criterion.展开更多
In order to study the mechanism of water inrush from a concealed, confined karst cave, we established a fluid–solid coupling model of water inrush from a concealed karst cave ahead of a roadway and a strength reducti...In order to study the mechanism of water inrush from a concealed, confined karst cave, we established a fluid–solid coupling model of water inrush from a concealed karst cave ahead of a roadway and a strength reduction method in a rock pillar for preventing water inrush based on catastrophic theory. Fluid–solid coupling effects and safety margins in a rock pillar were studied. Analysis shows that rock pillar instability, exerted by disturbance stress and seepage stress, is the process of rock pillar catastrophic destabilization induced by nonlinear extension of plastic zones in the rock pillar. Seepage flow emerges in the rock pillar for preventing water inrush, accompanied by mechanical instability of the rock pillar. Taking the accident of a confined karst cave water-inrush of Qiyi Mine as an example, by studying the safety factor of the rock pillar and the relationship between karst cave water pressure and thickness of the rock pillar,it is proposed that rock pillar thickness with a safety factor equal to 1.5 is regarded as the calculated safety thickness of the rock pillar, which should be equal to the sum of the blasthole depth, blasting disturbance depth and the calculated safety thickness of the rock pillar. The cause of the karst water inrush at Qiyi Mine is that the rock pillar was so small that it did not possess a safety margin. Combining fluid–solid coupling theory, catastrophic theory and strength reduction method to study the nonlinear mechanical response of complicated rock engineering, new avenues for quantitative analysis of rock engineering stability evaluation should be forthcoming.展开更多
By restricting the common replacement axiom schema of ZF to ∑~M-formulae,Professor Zhang Jinwen constructed a series of subsystems of Zennelo-Frankel set theory ZF and he called them ZF^M.Zhao Xi shun show that the c...By restricting the common replacement axiom schema of ZF to ∑~M-formulae,Professor Zhang Jinwen constructed a series of subsystems of Zennelo-Frankel set theory ZF and he called them ZF^M.Zhao Xi shun show that the consistency of ZF^M can be deducted from ZF.Professor Zhang Jinwen raised the question whether the consistency of ZF^M can be deducted from ZF^(M+m(M)) for some m(n)≥1.In this paper,we get a positive solution to Professor Zhang's problem.Moreover,we show that the consistency of ZF^M can be deducted from ZF^(M+3).展开更多
In this paper,we propose a novel Intrusion Detection System (IDS) architecture utilizing both the evidence theory and Rough Set Theory (RST). Evidence theory is an effective tool in dealing with uncertainty question. ...In this paper,we propose a novel Intrusion Detection System (IDS) architecture utilizing both the evidence theory and Rough Set Theory (RST). Evidence theory is an effective tool in dealing with uncertainty question. It relies on the expert knowledge to provide evidences,needing the evidences to be independent,and this make it difficult in application. To solve this problem,a hybrid system of rough sets and evidence theory is proposed. Firstly,simplification are made based on Variable Precision Rough Set (VPRS) conditional entropy. Thus,the Basic Belief Assignment (BBA) for all evidences can be calculated. Secondly,Dempster’s rule of combination is used,and a decision-making is given. In the proposed approach,the difficulties in acquiring the BBAs are solved,the correlativity among the evidences is reduced and the subjectivity of evidences is weakened. An illustrative example in an intrusion detection shows that the two theories combination is feasible and effective.展开更多
Nitrogen molecules Nx have been the subject of much recent research because of their potential as high-energy materials. Many nitrogen molecules dissociate with very low barriers, including molecules such as acyclic N...Nitrogen molecules Nx have been the subject of much recent research because of their potential as high-energy materials. Many nitrogen molecules dissociate with very low barriers, including molecules such as acyclic N4 that are essentially unbound. A number of studies have reported the ability of heteroatoms to stabilize complex nitrogen molecules. In the present study, the energetic and electronic properties of scandium(Ⅰ) and titanium(Ⅱ) complexes with N2 and N4 are calculated and discussed. Dissociation energies and singlet-triplet energies are determined by theoretical calculations using second-order perturbation theory (MP2) in conjunction with the Dunning basis sets.展开更多
Coordination polymeric solid, {[Ag 2 (bpp) 2 (H 2 O) 2 ](chd)·9H 2 O} n (1) (bpp = 1,3-bis(4-pyridyl) propane, H 2 chd = 1,4-cyclo-hexanedicarboxylic acid), has been obtained by the solution phase ultrasonic synt...Coordination polymeric solid, {[Ag 2 (bpp) 2 (H 2 O) 2 ](chd)·9H 2 O} n (1) (bpp = 1,3-bis(4-pyridyl) propane, H 2 chd = 1,4-cyclo-hexanedicarboxylic acid), has been obtained by the solution phase ultrasonic synthesis techniques. The structure established through X-ray structural analysis shows that the compound traps an interesting 1D water tape built by the alternating "three-pointed star" cage-like pentameric and D 2h tetrameric clusters (C2/c, Z = 4; a = 30.37(2) , b = 9.271(5) , and c = 18.89(1) ; β = 128.47°; V = 4164(4) 3 ). The novelty of the present complex is the rarely crystallographic example of the cage-shaped water pentamer, which is usually ascribed to a less-stable species. A first-principle density functional theory (DFT) calculation demonstrates that the interconnectivity between cage-like pentamers and D 2h tetramers is beneficial for contribution to the structural stabilization of these less-stable water cluster species.展开更多
We consider a reaction-diffusion model which describes the spatial Wolbachia spread dynamics for a mixed population of infected and uninfected mosquitoes. By using linearization method, comparison principle and Leray-...We consider a reaction-diffusion model which describes the spatial Wolbachia spread dynamics for a mixed population of infected and uninfected mosquitoes. By using linearization method, comparison principle and Leray-Schauder degree theory, we investigate the influence of diffusion on the Wolbachia infection dynamics.After identifying the system parameter regions in which diffusion alters the local stability of constant steadystates, we find sufficient conditions under which the system possesses inhomogeneous steady-states. Surprisingly,our mathematical analysis, with the help of numerical simulations, indicates that diffusion is able to lower the threshold value of the infection frequency over which Wolbachia can invade the whole population.展开更多
In this paper,we study lag synchronization between two coupled networks and apply two types of control schemes,including the open-plus-closed-loop(OPCL) and adaptive controls.We then design the corresponding control a...In this paper,we study lag synchronization between two coupled networks and apply two types of control schemes,including the open-plus-closed-loop(OPCL) and adaptive controls.We then design the corresponding control algorithms according to the OPCL and adaptive feedback schemes.With the designed controllers,we obtain two theorems on the lag synchronization based on Lyapunov stability theory and Barbalat's lemma.Finally we provide numerical examples to show the effectiveness of the obtained controllers and see that the adaptive control is stronger than the OPCL control when realizing the lag synchronization between two coupled networks with different coupling structures.展开更多
Consider the following system of double coupled Schrodinger equations arising from Bose-Einstein condensates etc., where μ1, μ2 are positive and fixed; κ and β are linear and nonlinear coupling parameters respect...Consider the following system of double coupled Schrodinger equations arising from Bose-Einstein condensates etc., where μ1, μ2 are positive and fixed; κ and β are linear and nonlinear coupling parameters respectively. We first use critical point theory and Liouville type theorem to prove some existence and nonexistence results on the positive solutions of this system. Then using the positive and non-degenerate solution to the scalar equation -△ω + ω = ω3, ω ∈ Hr1(RN), we construct a synchronized solution branch to prove that for/3 in certain range and fixed, there exist a series of bifurcations in product space R×Hr1(RN)×Hr1(RN) with parameter κ,展开更多
By applying nonequilibrium Green's function formalism combined with the first-principles density functional theory, we investigate the electronic transport in two molecular junctions constituted by a substituted o...By applying nonequilibrium Green's function formalism combined with the first-principles density functional theory, we investigate the electronic transport in two molecular junctions constituted by a substituted oligo (phenylene ehtynylene) sand-wiched between two Au electrodes. Our calculations show that the weak molecule-electrode coupling is responsible for the observation of the negative differential resistance (NDR) effect in experiments. When the coupling is weak, the projected density of states (PDOS) of the molecule and the electrodes undergoes a mismatch-match-mismatch procedure, which increases and then decreases the transmission peak intensities, leading to a NDR effect. We also find that the localization/delocalization of the molecular orbitals and the change of charge state of the molecule have no direct relation with the NDR effect, because they change little as the voltage increases.展开更多
With the usual definitions for the entropy and the temperature associated with the apparent horizon, we discuss the first law of the thermodynamics on the apparent in the general scalar-tensor theory of gravity with t...With the usual definitions for the entropy and the temperature associated with the apparent horizon, we discuss the first law of the thermodynamics on the apparent in the general scalar-tensor theory of gravity with the kinetic term of the scalar field nonminimally coupling to Einstein tensor. We show the equivalence between the first law of thermodynamics on the apparent horizon and Friedmann equation for the general models, by using a mass-like function which is equal to the Misner-Sharp mass on the apparent horizon. The results further support the universal relationship between the first law of thermodynamics and Friedmann equation.展开更多
基金Project (No. 05JA630052) supported by the Literature and Social Science Foundation of Ministry of Education of China
文摘Strategic alliance has suffered much instabilities since its first implementation. Scholars have carried out many em- bedded, precise and comprehensive researches from both theory and empiricism. Here we try to find certain stable solutions by employing game theory, in an attempt to construct theoretical bases for strategic alliance, which people called “one of the most important organizational innovation in the end of the 20th century” (Shi, 2001), to exploit its advantages in the process of glob- alization. Finally, this article puts forward some advices for its success.
基金Supported by the Science and Technical Foundation to Hubei University of Technology[2006(5)]
文摘By means of the continuation theorem of the coincidence degree theory,the existence of two periodic solutions of a delayed single species model with feedback regulation and harvest term is obtained.
文摘This paper is on a distribution question of Ⅰ type in the combinatorics (see: 'Ke Zhao, Wei WanDi, combinatorial theory, science press, 1981. '). Suppose n distrinct balls, m distinct boxes. The capacity set of every box is Now,place the n balls into the m boxes. Thenumber of distinct placed ways is expressed by , and simply by And it is called the distribution number.Main result is:Theorem The exponential generating function of sequence isThus .there is the recurrence relationhere (integer set).
文摘Density, ρ, ultrasonic speed, u, and viscosity, η, of binary mixtures of 2-methyl-2-propanol (2M2P) with acetonitrile (AN), propionitrile (PN) and butyronitrile (BN) including those of pure liquids are measured over the entire composition range at temperatures 298.15, 303.15 and 308.15 K. From these experimental data, the excess available volume, E a V , excess free volume, E f V , excess isothermal compressibility, E T β , excess thermal expansion coefficient, E α , and excess internal pressure, E i π , are calculated. The variation of these properties with composition and temperature are discussed in terms of molecular interactions between unlike molecules of the mixtures. It is found that the values of E a V , E f V , E T β and E α are positive and those of E i π are negative for all the mixtures at each temperature studied, indicating the presence of weak interactions between 2M2P and AN/PN/BN molecules. The variations of E a V , E f V , E T β , E α and E i π values with composition indicate that the interactions in these mixtures follow the order: AN<PN<BN, i.e., the 2M2P-nitrile interaction decreases with the increase of alkyl chain length in these nitrile molecules. In addition, the theoretical ultrasonic velocity is calculated using the scaled particle theory and compared with the experimental values.
文摘This paper introduces the calculation of the deformation of the surroundings of roadways and the division of surroundings into 5 levels by means of fuzzy integral assess matrix, which serves as the scientific basis for selecting supporting pattern of roadways and determining the parameters of support.
基金supported by National Natural Science Foundation under Grant Nos.10872014 and 10702023
文摘We investigate synchronization in an array network of nearest-neighbor coupled chaotic oscillators. By using of the Lyapunov stability theory and matrix theory, a criterion for stability of complete synchronization is deduced. Meanwhile, an estimate of the critical coupling strength is obtained to ensure achieving chaos synchronization. As an example application, a model of coupled Chua's circuits with linearly bidirectional coupling is studied to verify the validity of the criterion.
基金Financial supports for this work, provided by the National Natural Science Foundation of China (No. 51274097)the Scientific Research Fund of Hunan Provincial Education Department of China (No. 13A020)the Open Projects of State Key Laboratory of Coal Resources and Safe Mining, CUMT (No. 13KF03)
文摘In order to study the mechanism of water inrush from a concealed, confined karst cave, we established a fluid–solid coupling model of water inrush from a concealed karst cave ahead of a roadway and a strength reduction method in a rock pillar for preventing water inrush based on catastrophic theory. Fluid–solid coupling effects and safety margins in a rock pillar were studied. Analysis shows that rock pillar instability, exerted by disturbance stress and seepage stress, is the process of rock pillar catastrophic destabilization induced by nonlinear extension of plastic zones in the rock pillar. Seepage flow emerges in the rock pillar for preventing water inrush, accompanied by mechanical instability of the rock pillar. Taking the accident of a confined karst cave water-inrush of Qiyi Mine as an example, by studying the safety factor of the rock pillar and the relationship between karst cave water pressure and thickness of the rock pillar,it is proposed that rock pillar thickness with a safety factor equal to 1.5 is regarded as the calculated safety thickness of the rock pillar, which should be equal to the sum of the blasthole depth, blasting disturbance depth and the calculated safety thickness of the rock pillar. The cause of the karst water inrush at Qiyi Mine is that the rock pillar was so small that it did not possess a safety margin. Combining fluid–solid coupling theory, catastrophic theory and strength reduction method to study the nonlinear mechanical response of complicated rock engineering, new avenues for quantitative analysis of rock engineering stability evaluation should be forthcoming.
文摘By restricting the common replacement axiom schema of ZF to ∑~M-formulae,Professor Zhang Jinwen constructed a series of subsystems of Zennelo-Frankel set theory ZF and he called them ZF^M.Zhao Xi shun show that the consistency of ZF^M can be deducted from ZF.Professor Zhang Jinwen raised the question whether the consistency of ZF^M can be deducted from ZF^(M+m(M)) for some m(n)≥1.In this paper,we get a positive solution to Professor Zhang's problem.Moreover,we show that the consistency of ZF^M can be deducted from ZF^(M+3).
基金Supported by the National Natural Science Foundation of China (No. 60774029)
文摘In this paper,we propose a novel Intrusion Detection System (IDS) architecture utilizing both the evidence theory and Rough Set Theory (RST). Evidence theory is an effective tool in dealing with uncertainty question. It relies on the expert knowledge to provide evidences,needing the evidences to be independent,and this make it difficult in application. To solve this problem,a hybrid system of rough sets and evidence theory is proposed. Firstly,simplification are made based on Variable Precision Rough Set (VPRS) conditional entropy. Thus,the Basic Belief Assignment (BBA) for all evidences can be calculated. Secondly,Dempster’s rule of combination is used,and a decision-making is given. In the proposed approach,the difficulties in acquiring the BBAs are solved,the correlativity among the evidences is reduced and the subjectivity of evidences is weakened. An illustrative example in an intrusion detection shows that the two theories combination is feasible and effective.
基金The Alabama Supercomputer Authority is gratefully acknowledged for a grant of computer time on the SGI Altix in Huntsville, AL. This work was supported by the National Science Foundation (NSF/HBCU-UP grant 0505872). SJ is supported by NSF/HBCU-UP as an undergraduate scholar. This work was also supported by the National Institutes of Health (NIHINCMHD 1P20MD000547-01) and the Petroleum Research Fund, administered by the American Chemical Society (PRF 43798-B6). AH is supported by the NIH as an undergraduate scholar in the Minority Access to Research Careers program (NIH/NIGMS 2T34GM008167-22A 1). The taxpayers of the state of Alabama in particular and the United States in general are gratefully acknowledged.
文摘Nitrogen molecules Nx have been the subject of much recent research because of their potential as high-energy materials. Many nitrogen molecules dissociate with very low barriers, including molecules such as acyclic N4 that are essentially unbound. A number of studies have reported the ability of heteroatoms to stabilize complex nitrogen molecules. In the present study, the energetic and electronic properties of scandium(Ⅰ) and titanium(Ⅱ) complexes with N2 and N4 are calculated and discussed. Dissociation energies and singlet-triplet energies are determined by theoretical calculations using second-order perturbation theory (MP2) in conjunction with the Dunning basis sets.
基金supported by the National Natural Science Foundation of China (50971063)the Natural Science Foundation of Fujian Province (2003F006, 2010J01042, 2011J01047)+1 种基金the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry of Chinathe Startup Package Funding of Huaqiao University (10BS210) for supporting
文摘Coordination polymeric solid, {[Ag 2 (bpp) 2 (H 2 O) 2 ](chd)·9H 2 O} n (1) (bpp = 1,3-bis(4-pyridyl) propane, H 2 chd = 1,4-cyclo-hexanedicarboxylic acid), has been obtained by the solution phase ultrasonic synthesis techniques. The structure established through X-ray structural analysis shows that the compound traps an interesting 1D water tape built by the alternating "three-pointed star" cage-like pentameric and D 2h tetrameric clusters (C2/c, Z = 4; a = 30.37(2) , b = 9.271(5) , and c = 18.89(1) ; β = 128.47°; V = 4164(4) 3 ). The novelty of the present complex is the rarely crystallographic example of the cage-shaped water pentamer, which is usually ascribed to a less-stable species. A first-principle density functional theory (DFT) calculation demonstrates that the interconnectivity between cage-like pentamers and D 2h tetramers is beneficial for contribution to the structural stabilization of these less-stable water cluster species.
基金supported by National Natural Science Foundation of China (Grant Nos. 11471085, 91230104 and 11301103)Program for Changjiang Scholars and Innovative Research Team in University (Grant No. IRT1226)+1 种基金Program for Yangcheng Scholars in Guangzhou (Grant No. 12A003S)Guangdong Innovative Research Team Program (Grant No. 2011S009)
文摘We consider a reaction-diffusion model which describes the spatial Wolbachia spread dynamics for a mixed population of infected and uninfected mosquitoes. By using linearization method, comparison principle and Leray-Schauder degree theory, we investigate the influence of diffusion on the Wolbachia infection dynamics.After identifying the system parameter regions in which diffusion alters the local stability of constant steadystates, we find sufficient conditions under which the system possesses inhomogeneous steady-states. Surprisingly,our mathematical analysis, with the help of numerical simulations, indicates that diffusion is able to lower the threshold value of the infection frequency over which Wolbachia can invade the whole population.
基金Supported by the National Natural Science Foundation of China under Grant No.61304173Foundation of Liaoning Educational Committee(No.13-1069)and Hangzhou Polytechnic(No.KZYZ-2009-2)
文摘In this paper,we study lag synchronization between two coupled networks and apply two types of control schemes,including the open-plus-closed-loop(OPCL) and adaptive controls.We then design the corresponding control algorithms according to the OPCL and adaptive feedback schemes.With the designed controllers,we obtain two theorems on the lag synchronization based on Lyapunov stability theory and Barbalat's lemma.Finally we provide numerical examples to show the effectiveness of the obtained controllers and see that the adaptive control is stronger than the OPCL control when realizing the lag synchronization between two coupled networks with different coupling structures.
基金supported by National Natural Science Foundation of China(Grant Nos.11325107,11271353 and 11331010)the China Postdoctoral Science Foundation
文摘Consider the following system of double coupled Schrodinger equations arising from Bose-Einstein condensates etc., where μ1, μ2 are positive and fixed; κ and β are linear and nonlinear coupling parameters respectively. We first use critical point theory and Liouville type theorem to prove some existence and nonexistence results on the positive solutions of this system. Then using the positive and non-degenerate solution to the scalar equation -△ω + ω = ω3, ω ∈ Hr1(RN), we construct a synchronized solution branch to prove that for/3 in certain range and fixed, there exist a series of bifurcations in product space R×Hr1(RN)×Hr1(RN) with parameter κ,
基金supported by the National Basic Research Program of China (Grant No. 2009CB929204)the National Natural Science Foundation of China (Grant Nos. 10874100, 10904082 and 11074146)the Natural Science Foundation of Shandong Province (Grant No. ZR2009AL004)
文摘By applying nonequilibrium Green's function formalism combined with the first-principles density functional theory, we investigate the electronic transport in two molecular junctions constituted by a substituted oligo (phenylene ehtynylene) sand-wiched between two Au electrodes. Our calculations show that the weak molecule-electrode coupling is responsible for the observation of the negative differential resistance (NDR) effect in experiments. When the coupling is weak, the projected density of states (PDOS) of the molecule and the electrodes undergoes a mismatch-match-mismatch procedure, which increases and then decreases the transmission peak intensities, leading to a NDR effect. We also find that the localization/delocalization of the molecular orbitals and the change of charge state of the molecule have no direct relation with the NDR effect, because they change little as the voltage increases.
基金supported by the National Natural Science Foundation of China(Grant Nos.11175270 and 11475065)the Program for New Century Excellent Talents in University(Grant No.NCET-12-0205)
文摘With the usual definitions for the entropy and the temperature associated with the apparent horizon, we discuss the first law of the thermodynamics on the apparent in the general scalar-tensor theory of gravity with the kinetic term of the scalar field nonminimally coupling to Einstein tensor. We show the equivalence between the first law of thermodynamics on the apparent horizon and Friedmann equation for the general models, by using a mass-like function which is equal to the Misner-Sharp mass on the apparent horizon. The results further support the universal relationship between the first law of thermodynamics and Friedmann equation.