The Ti-46A1-6Nb （mole fraction, %） ingots that were directionally solidified by cold crucible were cyclic heat treated at 1330 ℃ in the a phase region. The microstructures and mechanical properties of the ingots be...The Ti-46A1-6Nb （mole fraction, %） ingots that were directionally solidified by cold crucible were cyclic heat treated at 1330 ℃ in the a phase region. The microstructures and mechanical properties of the ingots before and after heat treatment were investigated. The results show that the large columnar grains are changed into equiaxed grains after heat treatment. The grain size decreases with increasing the cyclic times, which is caused by the recrystallization and the transition from the large grain of small lamellae to the small grain of large lamellae. Four times of cyclic heat treatment refines the grain size from 1.33 mm to 0.59 turn, nevertheless the lamellar spacing increases from 0.71 ~tm to 1.38 lim. Extending the holding time and increasing the cyclic times of heat treatment eliminate the fl-segregation at the grain boundary and the interlamellar. The compression testing shows that the compressive strength of the directionally solidified ingot in the parallel and perpendicular directions are 1385.09 MPa and 1267.79 MPa, respectively, which are improved to 1449.75 MPa and 1527.76 MPa after two and four times of cyclic heat treatment, respectively, while that is 1180.64 MPa for the as-cast sample. The fracture mode of the sample after cyclic heat treatment is quasi-cleavage fracture.展开更多
NiTi shape memory alloy(SMA)with nominal composition of Ni 50.8 at%and Ti 49.2 at%was additively manufactured(AM)by selective laser melting(SLM)and laser directed energy deposition(DED)for a comparison study,with emph...NiTi shape memory alloy(SMA)with nominal composition of Ni 50.8 at%and Ti 49.2 at%was additively manufactured(AM)by selective laser melting(SLM)and laser directed energy deposition(DED)for a comparison study,with emphasis on its phase composition,microstructure,mechanical property and deformation mechanism.The results show that the yield strength and ductility obtained by SLM are 100 MPa and 8%,respectively,which are remarkably different from DED result with 700 MPa and 2%.The load path of SLM sample presents shape memory effect,corresponding to martensite phase detected by XRD;while the load path of DED presents pseudo-elasticity with austenite phase.In SLM sample,fine grain and hole provide a uniform deformation during tensile test,resulting in a better elongation.Furthermore,the nonequilibrium solidification was studied by a temperature field simulation to understand the difference of the two 3D printing methods.Both temperature gradient G and growth rate R determine the microstructure and phase in the SLM sample and DED sample,which leads to similar grain morphologies because of similar G/R.While higher G×R of SLM leads to a finer grain size in SLM sample,providing enough driving force for martensite transition and subsequently changing texture compared to DED sample.展开更多
The unsteady performance of drag and double reverse propeller podded propulsors in open water was numerically simulated using a computational fluid dynamics （CFD） method. A moving mesh method was used to more realis...The unsteady performance of drag and double reverse propeller podded propulsors in open water was numerically simulated using a computational fluid dynamics （CFD） method. A moving mesh method was used to more realistically simulate propulsor working conditions, and the thrust, torque, and lateral force coefficients of both propulsors were compared and analyzed. Forces acting on different parts of the propulsors along with the flow field distribution of steady and unsteady results at different advance coefficients were compared. Moreover, the change of the lateral force and the difference between the abovementioned two methods were mainly analyzed. It was shown that the thrust and torque results of both methods were similar, with the lateral force results having the highest deviation展开更多
High temperature plastic deformation behavior of non-orientated electrical steel was investigated by Gleeble 1500 thermo-mechanical simulator at strain rate of 0.01-10 s^-1 and high temperature of 500-1 200 ℃. The st...High temperature plastic deformation behavior of non-orientated electrical steel was investigated by Gleeble 1500 thermo-mechanical simulator at strain rate of 0.01-10 s^-1 and high temperature of 500-1 200 ℃. The stress level factor （a）, stress exponent （n）, structural factor （A） and activation energy （Q） of high temperature plastic deformation process of non-orientated electrical steel in different temperature ranges were calculated by the Arrhenius model. The results show that, with dynamic elevation of deformation temperature, phase transformation from α-Fe to γ-Fe takes place simultaneously during plastic deformation, dynamic recovery and dynamic recrystallization process, leading to an irregular change of the steady flow stress. For high temperature plastic deformation between 500 and 800 ℃, the calculated values of a, n, A, and Q are 0.039 0 MPa 1, 7.93, 1.9× 10^18 s^-1, and 334.8 kJ/mol, respectively, and for high temperature plastic deformation between 1 050 and 1 200 ℃, the calculated values of a, n, A, and Q are 0.125 8 MPa1, 5.29, 1.0 × 10^28 s^-1, and 769.9 kJ/mol, respectively.展开更多
The present work is concerned with extracting information about intermolecular potential energies of binary mixtures of CO2 with C2H6, C3H8, n-C4Hlo and iso-C4Hlo, by the usage of the inversion method, and then predic...The present work is concerned with extracting information about intermolecular potential energies of binary mixtures of CO2 with C2H6, C3H8, n-C4Hlo and iso-C4Hlo, by the usage of the inversion method, and then predicting the dilute gas transport properties of the mixtures. Using the inverted pair potential energies, the Chap- man-Enskog version of the kinetic theory was applied to calculate transport properties, except thermal conductivity of mixtures. The calculation of thermal conductivity through the methods of Schreiber et al. and Uribe et al. was discussed. Calculations were performed over a wide temperature range and equimolar composition. Rather accurate correlations for the viscosity coefficients of the mixtures in the temperature range were reproduced from the pre- sent unlike intermolecular potential energies. Our estimated accuracies for the viscosity are within ±2%. Acceptable agreement between the predicted values of the viscosity and thermal conductivity with the literature values demon- strates the predictive power of the inversion scheme. In the case of thermal conductivity our results are in favor of the preference of Uribe et al.＇s method over Schreiber et al.＇s scheme.展开更多
The realization of tunable nonlinear optical(NLO)responses in a single nano-/micro-structure is extremely important.However,in lack of effective ways to integrate multiple performances,it still faces severe limitation...The realization of tunable nonlinear optical(NLO)responses in a single nano-/micro-structure is extremely important.However,in lack of effective ways to integrate multiple performances,it still faces severe limitations during applications.Herein,we demonstrate a wavelength-dependent NLO micro-structure based on host-guest metal-organic framework(MOF)materials through encapsulating linear dye molecules into periodic one-dimensional(1D)channels.The confinement to non-centrosymmetric polar dye molecules enhances the second-/third-order NLO responses of the hybrid crystals,causing obvious two-photon luminescence(TPL),second harmonic generation(SHG)and third harmonic generation(THG)responses in the as-prepared composites.The highly ordered structures of MOFs impart spatial regulation on the linear dye molecules to realize orientation alignment,resulting in the polarized anisotropy emission.NIR-to-NIR(NIR,near-infrared region)two-photon pumped lasing is realized with the natural whispering gallery mode resonance cavities of MOFs under the excitation of a 1200-nm fs laser.Furthermore,tunable NLO properties such as TPL,SHG and THG are achieved through switching the incident excitation wavelength from 800 to 1500 nm.Such hybrid materials with tunable NLO responses may open a new avenue toward designing multifunctional NLO devices in the future.展开更多
Tin-based nanomaterials have been extensively explored as high-capacity anode materials for lithium ion batteries（LIBs）. However,the large volume changes upon repeated cycling always cause the pulverization of the e...Tin-based nanomaterials have been extensively explored as high-capacity anode materials for lithium ion batteries（LIBs）. However,the large volume changes upon repeated cycling always cause the pulverization of the electrode materials. Herein,we report the fabrication of uniform SnS_2@C hollow microspheres from hydrothermally prepared SnO_2@C hollow microspheres by a solid-state sulfurization process. The as-prepared hollow SnS_2@C microspheres with unique carbon shell,as electrodes in LIBs,exhibit high reversible capacity of 814 mA h g^（-1） at a current density of 100 mA g^（-1）,good cycling performance（783 mA h g^（-1） for 200 cycles maintained with an average degradation rate of 0.02% per cycle） and remarkable rate capability（reversible capabilities of 433 mA h g^（-1）at 2C）. The hollow space could serve as extra space for volume expansion during the charge-discharge cycling,while the carbon shell can ensure the structural integrity of the microspheres. The preeminent electrochemical performances of the SnS_2@C electrodes demonstrate their promising application as anode materials in the next-generation LIBs.展开更多
To minimize the auto body's posture change caused by steering and uneven road, and improve the vehicle's riding comfort and handling stability, this paper presents an H∞ robust controller of the active suspen...To minimize the auto body's posture change caused by steering and uneven road, and improve the vehicle's riding comfort and handling stability, this paper presents an H∞ robust controller of the active suspension system, which considers the effects of different steering conditions on its dynamic performance. The vehicle's vibration in the yaw, roll, pitch and vertical direction and the suspension's dynamic deflection in the steering process are taken into account for the designed H∞ robust controller, and it introduces the frequency weight function to improve the riding comfort in the specific sensitive frequency bands to human body. The proposed robust controller is testified through simulation and steering wheel angle step test. The results show that the active suspension with the designed robust controller can enhance the anti-roll capability of the vehicle, inhibit the changes of the body, and improve the riding comfort of the vehicle under steering condition. The results of this study can provide certain theoretical basis for the research and application of active suspension system.展开更多
The analysis on the traditional asymmetric Mach-Zehnder interferometer (AMZI) optical filter based on two 3 dB directional couplers (DCs) shows that by adding an additional nonlinear phase generated by phase-generatin...The analysis on the traditional asymmetric Mach-Zehnder interferometer (AMZI) optical filter based on two 3 dB directional couplers (DCs) shows that by adding an additional nonlinear phase generated by phase-generating coupler (PGC) to the original phase difference of the AMZI, its non-periodic frequency response can be modified, and a strictly periodic spectrum can be obtained. A novel structure of the AMZI filter using two PGCs before and after the AMZI region is proposed. With the needed free spectrum range (FSR) of 20 nm, the design and optimization of the device are performed using polymer SU-8 as the core and PMMA-GMA as the buffer. Though the insertion loss (IL) gets larger than that of the traditional AMZI filter, the FSR is nearly uniform as the expected period of 20 nm.展开更多
In a classical layout process of a fan the quantity of losses is estimated as a sum and expressed in the overall efficiency rote However the characteristic of the pressure rise, the losses and the efficiency rate besi...In a classical layout process of a fan the quantity of losses is estimated as a sum and expressed in the overall efficiency rote However the characteristic of the pressure rise, the losses and the efficiency rate beside the design point is not known. Against this background a numerical model was developed to calculate quantitative values of occurring losses at radial fan impellers at an early stage in the design process. It allows to estimate the pressure rise and efficiency rate of a given fan geometry at and beside the design point. The physics of losses are described in literature, but obtaining quantitative values is still a challenge. As common in hydraulic theory the losses are calculated with analytic formulas supported by coefficients and efficiency rates, which have to be determined empirically. This paper shows the method how to determine the coefficients for a given radial fan. Therefore a representative radial fan with backward curved blades was designed in reference to classical design guidelines. Performance measuring was done conform to ISO 5801. The flow was calculated at 8 different operation points using CFD methods. The RANS equations are solved by using the SST-k-omega turbulence model. The flow do- main consists of one blade section including inlet channel and outflow chamber. Spatial discretization is done by a block-structured mesh of approx. 1.8 million cells. Performance data show a very good agreement between measurement and calculation.展开更多
基金Project(2011CB605504) supported by the National Basic Research Program of ChinaProject(NCET-12-0153) supported by the Program of New Century Excellent Talents in UniversityProject(51274076) supported by the National Natural Science of Foundation of China
文摘The Ti-46A1-6Nb （mole fraction, %） ingots that were directionally solidified by cold crucible were cyclic heat treated at 1330 ℃ in the a phase region. The microstructures and mechanical properties of the ingots before and after heat treatment were investigated. The results show that the large columnar grains are changed into equiaxed grains after heat treatment. The grain size decreases with increasing the cyclic times, which is caused by the recrystallization and the transition from the large grain of small lamellae to the small grain of large lamellae. Four times of cyclic heat treatment refines the grain size from 1.33 mm to 0.59 turn, nevertheless the lamellar spacing increases from 0.71 ~tm to 1.38 lim. Extending the holding time and increasing the cyclic times of heat treatment eliminate the fl-segregation at the grain boundary and the interlamellar. The compression testing shows that the compressive strength of the directionally solidified ingot in the parallel and perpendicular directions are 1385.09 MPa and 1267.79 MPa, respectively, which are improved to 1449.75 MPa and 1527.76 MPa after two and four times of cyclic heat treatment, respectively, while that is 1180.64 MPa for the as-cast sample. The fracture mode of the sample after cyclic heat treatment is quasi-cleavage fracture.
基金Project(2020JJ2046)supported by the Science Fund for Hunan Distinguished Young Scholars,ChinaProject(S2020GXKJGG0416)supported by the Special Project for Hunan Innovative Province Construction,China+1 种基金Project(2018RS3007)supported by the Huxiang Young Talents,ChinaProject(GuikeAB19050002)supported by the Science Project of Guangxi,China。
文摘NiTi shape memory alloy(SMA)with nominal composition of Ni 50.8 at%and Ti 49.2 at%was additively manufactured(AM)by selective laser melting(SLM)and laser directed energy deposition(DED)for a comparison study,with emphasis on its phase composition,microstructure,mechanical property and deformation mechanism.The results show that the yield strength and ductility obtained by SLM are 100 MPa and 8%,respectively,which are remarkably different from DED result with 700 MPa and 2%.The load path of SLM sample presents shape memory effect,corresponding to martensite phase detected by XRD;while the load path of DED presents pseudo-elasticity with austenite phase.In SLM sample,fine grain and hole provide a uniform deformation during tensile test,resulting in a better elongation.Furthermore,the nonequilibrium solidification was studied by a temperature field simulation to understand the difference of the two 3D printing methods.Both temperature gradient G and growth rate R determine the microstructure and phase in the SLM sample and DED sample,which leads to similar grain morphologies because of similar G/R.While higher G×R of SLM leads to a finer grain size in SLM sample,providing enough driving force for martensite transition and subsequently changing texture compared to DED sample.
基金Supported by National Natural Science Foundation of China （41176074, 51209048,51379043,51409063） High tech ship research project of Ministry of industry and technology （G014613002） The support plan for youth backbone teachers of Harbin Engineering University （HEUCFQ1408）
文摘The unsteady performance of drag and double reverse propeller podded propulsors in open water was numerically simulated using a computational fluid dynamics （CFD） method. A moving mesh method was used to more realistically simulate propulsor working conditions, and the thrust, torque, and lateral force coefficients of both propulsors were compared and analyzed. Forces acting on different parts of the propulsors along with the flow field distribution of steady and unsteady results at different advance coefficients were compared. Moreover, the change of the lateral force and the difference between the abovementioned two methods were mainly analyzed. It was shown that the thrust and torque results of both methods were similar, with the lateral force results having the highest deviation
基金Project(2005038560) supported by the Postdoctoral Foundation of ChinaProject(05GK1002-2) supported by Key Program of Hunan Province
文摘High temperature plastic deformation behavior of non-orientated electrical steel was investigated by Gleeble 1500 thermo-mechanical simulator at strain rate of 0.01-10 s^-1 and high temperature of 500-1 200 ℃. The stress level factor （a）, stress exponent （n）, structural factor （A） and activation energy （Q） of high temperature plastic deformation process of non-orientated electrical steel in different temperature ranges were calculated by the Arrhenius model. The results show that, with dynamic elevation of deformation temperature, phase transformation from α-Fe to γ-Fe takes place simultaneously during plastic deformation, dynamic recovery and dynamic recrystallization process, leading to an irregular change of the steady flow stress. For high temperature plastic deformation between 500 and 800 ℃, the calculated values of a, n, A, and Q are 0.039 0 MPa 1, 7.93, 1.9× 10^18 s^-1, and 334.8 kJ/mol, respectively, and for high temperature plastic deformation between 1 050 and 1 200 ℃, the calculated values of a, n, A, and Q are 0.125 8 MPa1, 5.29, 1.0 × 10^28 s^-1, and 769.9 kJ/mol, respectively.
基金supports from the Shiraz University of Technology
文摘The present work is concerned with extracting information about intermolecular potential energies of binary mixtures of CO2 with C2H6, C3H8, n-C4Hlo and iso-C4Hlo, by the usage of the inversion method, and then predicting the dilute gas transport properties of the mixtures. Using the inverted pair potential energies, the Chap- man-Enskog version of the kinetic theory was applied to calculate transport properties, except thermal conductivity of mixtures. The calculation of thermal conductivity through the methods of Schreiber et al. and Uribe et al. was discussed. Calculations were performed over a wide temperature range and equimolar composition. Rather accurate correlations for the viscosity coefficients of the mixtures in the temperature range were reproduced from the pre- sent unlike intermolecular potential energies. Our estimated accuracies for the viscosity are within ±2%. Acceptable agreement between the predicted values of the viscosity and thermal conductivity with the literature values demon- strates the predictive power of the inversion scheme. In the case of thermal conductivity our results are in favor of the preference of Uribe et al.＇s method over Schreiber et al.＇s scheme.
基金the National Natural Science Foundation of China(51632008,U1609219 and 61721005)。
文摘The realization of tunable nonlinear optical(NLO)responses in a single nano-/micro-structure is extremely important.However,in lack of effective ways to integrate multiple performances,it still faces severe limitations during applications.Herein,we demonstrate a wavelength-dependent NLO micro-structure based on host-guest metal-organic framework(MOF)materials through encapsulating linear dye molecules into periodic one-dimensional(1D)channels.The confinement to non-centrosymmetric polar dye molecules enhances the second-/third-order NLO responses of the hybrid crystals,causing obvious two-photon luminescence(TPL),second harmonic generation(SHG)and third harmonic generation(THG)responses in the as-prepared composites.The highly ordered structures of MOFs impart spatial regulation on the linear dye molecules to realize orientation alignment,resulting in the polarized anisotropy emission.NIR-to-NIR(NIR,near-infrared region)two-photon pumped lasing is realized with the natural whispering gallery mode resonance cavities of MOFs under the excitation of a 1200-nm fs laser.Furthermore,tunable NLO properties such as TPL,SHG and THG are achieved through switching the incident excitation wavelength from 800 to 1500 nm.Such hybrid materials with tunable NLO responses may open a new avenue toward designing multifunctional NLO devices in the future.
基金supported by the National Natural Science Foundation of China (51302323)the Program for New Century Excellent Talents in University (NCET-13-0594)the Innovationdriven Project of Central South University (2017CX001)
文摘Tin-based nanomaterials have been extensively explored as high-capacity anode materials for lithium ion batteries（LIBs）. However,the large volume changes upon repeated cycling always cause the pulverization of the electrode materials. Herein,we report the fabrication of uniform SnS_2@C hollow microspheres from hydrothermally prepared SnO_2@C hollow microspheres by a solid-state sulfurization process. The as-prepared hollow SnS_2@C microspheres with unique carbon shell,as electrodes in LIBs,exhibit high reversible capacity of 814 mA h g^（-1） at a current density of 100 mA g^（-1）,good cycling performance（783 mA h g^（-1） for 200 cycles maintained with an average degradation rate of 0.02% per cycle） and remarkable rate capability（reversible capabilities of 433 mA h g^（-1）at 2C）. The hollow space could serve as extra space for volume expansion during the charge-discharge cycling,while the carbon shell can ensure the structural integrity of the microspheres. The preeminent electrochemical performances of the SnS_2@C electrodes demonstrate their promising application as anode materials in the next-generation LIBs.
基金supported by the Fundamental Research Funds for the Central Universities(Grant No.NS2015020)
文摘To minimize the auto body's posture change caused by steering and uneven road, and improve the vehicle's riding comfort and handling stability, this paper presents an H∞ robust controller of the active suspension system, which considers the effects of different steering conditions on its dynamic performance. The vehicle's vibration in the yaw, roll, pitch and vertical direction and the suspension's dynamic deflection in the steering process are taken into account for the designed H∞ robust controller, and it introduces the frequency weight function to improve the riding comfort in the specific sensitive frequency bands to human body. The proposed robust controller is testified through simulation and steering wheel angle step test. The results show that the active suspension with the designed robust controller can enhance the anti-roll capability of the vehicle, inhibit the changes of the body, and improve the riding comfort of the vehicle under steering condition. The results of this study can provide certain theoretical basis for the research and application of active suspension system.
基金supported by the National Natural Science Foundation of China (Nos.61107021, 61177027, 61077041 and 60807029)the Ministry of Education of China (Nos.20110061120052 and 20090061110041)+1 种基金the China Postdoctoral Science Foundation Funded Project (No.20110491299)the Special Funds of Basic Science and Technology of Jilin University (Nos.201103076 and 200905005)
文摘The analysis on the traditional asymmetric Mach-Zehnder interferometer (AMZI) optical filter based on two 3 dB directional couplers (DCs) shows that by adding an additional nonlinear phase generated by phase-generating coupler (PGC) to the original phase difference of the AMZI, its non-periodic frequency response can be modified, and a strictly periodic spectrum can be obtained. A novel structure of the AMZI filter using two PGCs before and after the AMZI region is proposed. With the needed free spectrum range (FSR) of 20 nm, the design and optimization of the device are performed using polymer SU-8 as the core and PMMA-GMA as the buffer. Though the insertion loss (IL) gets larger than that of the traditional AMZI filter, the FSR is nearly uniform as the expected period of 20 nm.
文摘In a classical layout process of a fan the quantity of losses is estimated as a sum and expressed in the overall efficiency rote However the characteristic of the pressure rise, the losses and the efficiency rate beside the design point is not known. Against this background a numerical model was developed to calculate quantitative values of occurring losses at radial fan impellers at an early stage in the design process. It allows to estimate the pressure rise and efficiency rate of a given fan geometry at and beside the design point. The physics of losses are described in literature, but obtaining quantitative values is still a challenge. As common in hydraulic theory the losses are calculated with analytic formulas supported by coefficients and efficiency rates, which have to be determined empirically. This paper shows the method how to determine the coefficients for a given radial fan. Therefore a representative radial fan with backward curved blades was designed in reference to classical design guidelines. Performance measuring was done conform to ISO 5801. The flow was calculated at 8 different operation points using CFD methods. The RANS equations are solved by using the SST-k-omega turbulence model. The flow do- main consists of one blade section including inlet channel and outflow chamber. Spatial discretization is done by a block-structured mesh of approx. 1.8 million cells. Performance data show a very good agreement between measurement and calculation.
