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农林生物质定向液化制备甲基-α-D-葡萄糖苷的研究 被引量:2
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作者 冯君锋 蒋剑春 +3 位作者 徐俊明 王奎 苏秋丽 杨中志 《林产化学与工业》 EI CAS CSCD 北大核心 2016年第4期23-30,共8页
以硫酸为催化剂、甲醇为溶剂,在反应温度为200℃、压力6 MPa、反应时间为10 min的条件下,考察竹材、甘蔗渣、杨木、桉木、松木和麦秆6种原料的定向液化,通过对定向液化的产物进行过滤、中和、萃取分离和旋蒸等一系列分级处理操作,得到... 以硫酸为催化剂、甲醇为溶剂,在反应温度为200℃、压力6 MPa、反应时间为10 min的条件下,考察竹材、甘蔗渣、杨木、桉木、松木和麦秆6种原料的定向液化,通过对定向液化的产物进行过滤、中和、萃取分离和旋蒸等一系列分级处理操作,得到甲基糖苷类化合物。结果显示:6种原料的液化率均在78%以上,甲基糖苷类化合物主要为甲基-α-D-葡萄糖苷(MLG)和甲基-α-D-木糖苷,其分别来自于纤维素和半纤维素的甲醇酸解,并且甲基糖苷类化合物的得率均为原料质量的40%左右;其中甘蔗渣加压液化制备甲基糖苷类的效果最好,甲基糖苷类GC含量86.81%。将甲基糖苷类化合物进行脱色和重结晶处理,得到甲基-α-D-葡萄糖苷晶体,对其进行HSQC NMR、FT-IR和X射线单晶衍射分析可知,实验所制备的甲基-α-D-葡萄糖苷晶体纯度几乎接近于标准样品,具有规则的晶体结构,晶体属于正交晶系,空间群为P212121。 展开更多
关键词 生物质 定向液化 甲基葡萄糖苷
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生物质定向热裂解液化装置的开发Ⅱ:进料特性与流化规律 被引量:5
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作者 任学勇 王文亮 +3 位作者 司慧 苟进胜 郭晓慧 常建民 《木材加工机械》 北大核心 2012年第4期15-18,49,共5页
对所研发的生物质定向热裂解液化装置(BDFP)的进料特性和流态化规律进行了试验研究。试验探明了进料载气流速、颗粒粒径、电机转速与进料速率的匹配关系,系统考察了床料单独流化和与生物质颗粒混合流化时的流态化规律。通过优化分析确定... 对所研发的生物质定向热裂解液化装置(BDFP)的进料特性和流态化规律进行了试验研究。试验探明了进料载气流速、颗粒粒径、电机转速与进料速率的匹配关系,系统考察了床料单独流化和与生物质颗粒混合流化时的流态化规律。通过优化分析确定,合适的工艺参数范围为:进料载气流量为2.2L/min,电机转速范围为25~100r/min,冷态流化气速范围0.35~0.65m/s,冷态气体流量范围为66.7~125L/min(4.0~7.5m3/h),热态气体流量范围为33.3-58.3 L/min(2.0~3.5m3/h),综合考虑确定热态气体操作流量为45 L/min。 展开更多
关键词 生物质 定向热裂解液化装置 进料性能 流化规律
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Science Letters:Research on 3D fiber orientation distribution in arbitrary planar flows 被引量:1
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作者 ZHOU Kun LIN Jian-zhong 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第7期1021-1025,共5页
A non-stretchable fiber rotation in planar flows has been solved. The fiber will rotate periodically or run to the asymptotical direction decided by a discriminant defined in the paper involving the fiber aspect ratio... A non-stretchable fiber rotation in planar flows has been solved. The fiber will rotate periodically or run to the asymptotical direction decided by a discriminant defined in the paper involving the fiber aspect ratio and the flow characteristics. Subsequently the fiber orientation distribution is derived directly without the bother of solving the Fokker-Planck equation. The research clearly indicates the overall configuration of a fiber rotation movement in planar flows. 展开更多
关键词 Fiber suspension flow Jeffery orbit Fiber orientation distribution
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Preliminary Study on Element Leaching and Current Soil-Forming Process of Red Soils 被引量:4
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作者 ZHANQI-GUO XUESHI-KUI 《Pedosphere》 SCIE CAS CSCD 1991年第2期117-126,共10页
The leaching characteristics and the element concentration in soil solution of red soils derived from sandstone,granite,Quaternary red clay and basalt have been studied in the Red Earth Ecological Experimental Station... The leaching characteristics and the element concentration in soil solution of red soils derived from sandstone,granite,Quaternary red clay and basalt have been studied in the Red Earth Ecological Experimental Station,Academia Sinica,using 12 lysimeters.Results obtained show that the element leaching process of red soils occurs mainly from January to the beginning of July annually.The elements with higher concentration in leaching solution of red soils are Si,Ca,Na,K,Mg,and N.The desilication and the leaching process of base cations occur simultaneously in the red soils.Using the first order differential equation and measured parameters of Si leaching,the leaching models of Si for red soils derived from different parent materials are constructed.The leaching process of Si is simulated with the models.Both the absolute and relative ages of red soils derived from different parent materials are discussed based on the simulation result.On the basis of element leaching,composition of soil solution and thermodynamics,the current soil-forming process is discussed.According to the phase diagram,the kaolinization is prevailing in the current formation of different red soils. 展开更多
关键词 element leaching LYSIMETER red soils soil-forming process
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