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索拉非尼无定形体系结晶动力学稳定性评价及结晶抑制剂筛选
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作者 孙嘉汝 田雅雯 +3 位作者 董雪晴 李元春 闫承业 杨彩琴 《医药导报》 CAS 北大核心 2023年第7期964-969,共6页
目的制备索拉非尼无定形体系,评价其结晶动力学稳定性,探讨聚合物对无定形的抑制结晶效应。方法旋转蒸发法制备索拉非尼无定形态,非等温多速率差式扫描量热分析法研究无定形形成能力和结晶动力学稳定性,溶解度和体外溶出实验考察聚合物... 目的制备索拉非尼无定形体系,评价其结晶动力学稳定性,探讨聚合物对无定形的抑制结晶效应。方法旋转蒸发法制备索拉非尼无定形态,非等温多速率差式扫描量热分析法研究无定形形成能力和结晶动力学稳定性,溶解度和体外溶出实验考察聚合物对无定形的抑制结晶效应。结果动力学脆性指数48,玻璃化转变温度与熔融温度之比0.8,降低结晶温度0.51,结晶活化能152.15 kJ·mol^(-1),Avrami指数约为2,含有50μg·mL^(-1)甲基纤维素M450溶液,无定形体系溶解度与累积溶出度分别提高1.43和2.17倍。结论索拉非尼无定形具有较高的动力学稳定性,甲基纤维素可延长无定形体系过饱和时间。 展开更多
关键词 索拉非尼 定形形成能力 结晶动力学 聚合物
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多孔炭基定形相变储热材料的研究进展
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作者 冯利利 侯玉星 +2 位作者 余润翔 赵蕾 刘一曼 《煤炭学报》 EI CAS CSCD 北大核心 2022年第9期3328-3338,共11页
储能技术可以解决能源供需在时空上不匹配的矛盾,从而提高能源利用效率。相变储热是一种极具潜力的储能技术,广泛应用于太阳能、节能建筑、工业余废热回收和热管理系统,其储热介质为相变材料,具有潜热大、相变温度恒定等优点,可实现储... 储能技术可以解决能源供需在时空上不匹配的矛盾,从而提高能源利用效率。相变储热是一种极具潜力的储能技术,广泛应用于太阳能、节能建筑、工业余废热回收和热管理系统,其储热介质为相变材料,具有潜热大、相变温度恒定等优点,可实现储热与控温双重目的。固-液相变材料是研究较多的一类相变材料,具有储能密度高、相变温度可调、化学性质稳定、价格低廉等优点,但存在相变泄漏、热导率低等问题,一定程度上阻碍了其应用,将多孔材料引入固-液相变材料构筑定形相变材料可以解决上述问题。特别是,以多孔炭作为定形基体制备的定形相变材料机械强度增强,导热率显著提升,封装性和稳定性优良。对多孔炭基定形相变材料的研究进展进行了系统总结,分析了膨胀石墨、碳纳米管、石墨烯氧化物、生物炭等多孔碳材料的孔结构、表面改性、质量分数、分子间作用力等因素对定形相变材料定形能力、热性能和相变行为的影响,讨论了其他多孔碳基体如活性炭、泡沫炭、氮化碳制备的定形相变储热材料的性能,概述了多孔碳基定形相变材料的应用研究现状。最后,通过对比不同种类多孔碳基体制备的定形相变材料的主要性能及所呈现出的不同优势,提出应用时的材料选择建议,并对未来的研究方向进行了展望。 展开更多
关键词 储热 固-液相变材料 多孔炭基体 定形能力 热性能
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Stability control of water-enriched roofs of coal drifts 被引量:1
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作者 LI Xue-hua YAO Qiang-ling +2 位作者 DING Xiao-lei WANG Yi-pin ZHANG Lei 《Mining Science and Technology》 EI CAS 2009年第4期467-472,共6页
Excavation-and-support induced disturbances are likely to make water-enriched roofs to become weathered and fractured.The development and connection of cracks provide new water channels which may result in water loss,... Excavation-and-support induced disturbances are likely to make water-enriched roofs to become weathered and fractured.The development and connection of cracks provide new water channels which may result in water loss,seriously affecting the in-tegrity and stability of roofs,leading to incidents of roof fall.Control of water-enriched rocks surrounding coal drifts is quite diffi-cult in China.Based on the practical situation of a water-enriched roof of a coal drift in working face 112201 of the Meihuajing coal mine,we studied the deformation features of surrounding rocks and the development of fractured areas and analyzed the major reasons for the decrease in load-carrying capacity,indicating that the key to maintain roof stability of this kind of coal drift is water retention.In addition,we proposed a staged control technology consisting of:1) surface grouting;2) cable anchor strengthening and 3) roof grouting,which has proven to be successful in this practical application.Our study indicates that,after the problem of water loss from the water-enriched roof had been effectively solved,a combined support system with high performance bolts can maintain the stability of the bearing structure,resulting in the control of roof stability in this kind of coal drift. 展开更多
关键词 AQUIFER roof stability water retention staged control
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Effects of Anisotropy on Scalar Field Ghost Dark Energy and the Non-Equilibrium Thermodynamics in Fractal Cosmology
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作者 A.Najafi H.Hossienkhani 《Communications in Theoretical Physics》 SCIE CAS CSCD 2017年第10期553-564,共12页
Since the fractal cosmology has been created in early universe, therefore their models were mostly isotropic. The majority of previous studies had been based on FRW universe, while in the early universe, the best mode... Since the fractal cosmology has been created in early universe, therefore their models were mostly isotropic. The majority of previous studies had been based on FRW universe, while in the early universe, the best model for describing fractal cosmology is actually the anisotropic universe. Therefore in this work, by assuming the anisotropic universe, the cosmological implications of ghost and generalized ghost dark energy models with dark matter in fractal cosmology has been discussed. Moreover, the different kinds of dark energy models such as quintessence and tachyon field, with the generalized ghost dark energy in fractal universe has been investigated. In addition, we have reconstructed the Hubble parameter, H, the energy density, p, the deceleration parameter, q, the equations of state parameter, wD, for both ghost and generalized ghost dark energy models. This correspondence allows us to reconstruct the potential and the dynamics of a fractal canonical scalar field according to the evolution of generalized ghost dark energy density. Eventually, thermodynamics of the cosmological apparent horizon in fractal cosmology was investigated and the validity of the Generalized second law of thermodynamics (GSLT) have been examined in an anisotropic universe. The results show the influence of the anisotropy on the OSLT of thermodynamics in a fractal cosmology. 展开更多
关键词 anisotropic universe fractal cosmology ghost DE generalized ghost DE non-equilibrium ther-modynamics generalized second law
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