Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison....Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison. The result showed that in the TiAl alloy,α2 lamellae thinned and were broken down, and became discontinuous with increasing aging time. The decomposition ofα2 lamella toγ which was characterized by parallel decomposition and breakdown ofα2 lamellae led to the degradation of the lamellar structure. While in the composite, lamellar structure remained relatively stable even after aging at 900 ℃ for 100 h. No breakdown ofα2 lamellae except parallel decomposition and precipitation of fine nitride particles was observed. The better microstructural stability of the composite was mainly attributed to the precipitation of Ti2AlN particles at theα2/γ interface which played an important role in retarding the coarsening of lamellar microstructure in the matrix of composite.展开更多
In this paper,we investigated the effects of temperature,oxygen,antioxidants,and corn germ oil on the stability of astaxanthin from Haematococcus pluvialis under different storage conditions,and changes in the composi...In this paper,we investigated the effects of temperature,oxygen,antioxidants,and corn germ oil on the stability of astaxanthin from Haematococcus pluvialis under different storage conditions,and changes in the composition of astaxanthin esters during storage using high performance liquid chromatography and spectrophotometry.Oxygen and high temperatures(22–25°C) significantly reduced the stability of astaxanthin esters.Corn germ oil and antioxidants(ascorbic acid and vitamin E)failed to protect astaxanthin from oxidation,and actually significantly increased the instability of astaxanthin.A change in the relative composition of astaxanthin esters was observed after 96 weeks of long-term storage.During storage,the relative amounts of free astaxanthin and astaxanthin monoesters declined,while the relative amount of astaxanthin diesters increased.Thus,the ratio of astaxanthin diester to monoester increased,and this ratio could be used to indicate if astaxanthin esters have been properly preserved.If the ratio is greater than 0.2,it suggests that the decrease in astaxanthin content could be higher than 20%.Our results show that storing algal powder from H.pluvialis or other natural astaxanthin products under vacuum and in the dark below 4°C is the most economical and applicable storage method for the large-scale production of astaxanthin from H.pluvialis.This storage method can produce an astaxanthin preservation rate of at least 80%after 96 weeks of storage.展开更多
The effect of uncertainty about stochastic diffusion model on dynamic portfolio choice of an investor who maximizes utility of terminal portfolio wealth was studied.It applied stochastic control method to obtain the c...The effect of uncertainty about stochastic diffusion model on dynamic portfolio choice of an investor who maximizes utility of terminal portfolio wealth was studied.It applied stochastic control method to obtain the closed-form solution of optimal dynamic portfolio,and used the Bayesian rule to estimate the model parameters to do an empirical study on two different samples of Shanghai Exchange Composite Index.Results show,model uncertainty results in positive or negative hedging demand of portfolio,which depends on investor's attitude toward risk;the effect of model uncertainty is more significant with the increasing of investment horizon,the decreasing of investor's risk-aversion degree,and the decreasing of information;predictability of risky asset return increases its allocation in portfolio,at the same time,the effect of model uncertainty also strengthens.展开更多
As-cast microstructure and mechanical properties of Mg-6Zn-2Al-0.3Mn (ZA62) alloys with calcium addition were investigated.The as-cast microstructure of the base alloy ZA62 consists of the α-Mg matrix and eutectic ph...As-cast microstructure and mechanical properties of Mg-6Zn-2Al-0.3Mn (ZA62) alloys with calcium addition were investigated.The as-cast microstructure of the base alloy ZA62 consists of the α-Mg matrix and eutectic phase Mg51Zn20.The Mg51Zn20 eutectic was gradually replaced by MgZn phase and Mg32(Al,Zn)49 phase when calcium is added into the base alloy.Further addition of calcium leads to the increase of grain boundary phases and formation of a new quaternary Mg-Zn-Al-Ca eutectic compound.In comparison with the base alloy,the increase of calcium addition to the base alloy results in the reduction of both strength and ductility at ambient temperature,but increase at elevated temperatures due to the thermal stability of Ca-containing phases.At elevated temperatures,the creep resistance of ZA62 based alloys containing calcium is significantly higher than that of AZ91 which is the most commonly used magnesium alloy.展开更多
In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, doe...In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, does not provide full interaction of a steel beam and a concrete slab. This changes strain distribution in cross-sections of a composite girder and results in redistribution of internal forces in steel and concrete element. In the paper partial interaction index defined on the basis of a neutral axis position, which can be used for verification of steel-concrete interaction in real bridge structures rather than in specimens is proposed. The range of the index value changes, obtained during load testing of a typical steel-concrete composite beam bridge, is presented. The investigation was carried out on a motorway viaduct, consisting of two parallel structures. During the testing values of strains in girders under static and quasi-static loads were measured. The readings from the gauges were used to determine the index, characterizing composite action of the girders. Results of bridge testing under movable load, changing position along the bridge span is presented and obtained in-situ influence functions of strains and index values are commented in the paper.展开更多
The combined gradient representations for generalized Birkhoffian systems in event space are studied.Firstly,the definitions of six kinds of combined gradient systems and corresponding differential equations are given...The combined gradient representations for generalized Birkhoffian systems in event space are studied.Firstly,the definitions of six kinds of combined gradient systems and corresponding differential equations are given.Secondly,the conditions under which generalized Birkhoffian systems become combined gradient systems are obtained. Finally,the characteristics of combined gradient systems are used to study the stability of generalized Birkhoffian systems in event space. Seven examples are given to illustrate the results.展开更多
Three experimental single crystal superalloys with 0%Nb,0.5%Nb,1.0%Nb were cast in the directionally solidified furnace,while other alloying element contents were basically kept unchanged.The effect of Nb on the micro...Three experimental single crystal superalloys with 0%Nb,0.5%Nb,1.0%Nb were cast in the directionally solidified furnace,while other alloying element contents were basically kept unchanged.The effect of Nb on the microstructure,stability at1100°C and stress rupture properties at 1070°C and 160 MPa of the single crystal superalloy were investigated.The experiment results show that the primary dendrite arm spacing decreases and the volume fraction ofγ/γ′eutectic of the alloy increases with the increase of Nb content in the as-cast microstructures.The size ofγ′phase particles becomes small and uniform and the cubic shape does not obviously change with the increase of Nb content.The precipitating rate and volume fraction of TCP phases increase significantly with the increase of Nb content in the process of long term aging at 1100°C.The stress rupture lives increase and elongation decreases with increasing Nb content at 1070°C/160 MPa.At last,the relationship between the microstructures stability,stress rupture properties of the alloy and Nb content is discussed based on JMat Pro software and the lastest relevant database for single crystal superalloy.展开更多
The study of influence of the fractionated and acute ionizing radiation on plants revealed that it is able to induce genomic instability. The hypothesis that transcription rate of several evolutionary conserved DNA re...The study of influence of the fractionated and acute ionizing radiation on plants revealed that it is able to induce genomic instability. The hypothesis that transcription rate of several evolutionary conserved DNA repair genes AtKu 70, AtRAD51 and AtRadl, which keeps genome stability in cells of model plant Arabidopsis thaliana, changes differently depending on dose and mode of ionizing radiation exposure had been tested. Gel electrophoresis-based reverse transcription polymerase chain reaction (RT-PCR) method was used for quantifying mRNA transcription levels. The data demonstrated that mode and dose of irradiation affect transcription rate of the genes AtKuTO, AtRAD51 and AtRadI. The fractionated and acute X-ray irradiation may result in adaptive response through the induction of key DNA double-strand break (DSB) repair genes AtKu70 and AtRAD51, as well as in genome instability through transcriptional activation of error-prone AtRadl-mediated DNA DSB repair combined with decreased expression of AtRAD51. In plants at doses within the range of 3-9 Gy, an adaptive influence is prevailed, but at doses of 12-21 Gy an error-prone repair of double-strand DNA damage is activated. Fractionation of dose has a significant effect on the transcription of the genes AtKuTO, AtRAD51 and AtRadl only at doses of 15 Gy and 21 Gy. Acute dose of 15 Gy activates error-prone AtRadl-mediated DSB repair and repressed both AtRAD51-dependent and AtKu70-dependent repair pathways, while fractionated irradiation at the same total dose induces more accurate homologous recombination and canonical non-homologous end joining of the DNA strands. In case of A. thaliana exposed to X-rays at dose 21 Gy, the situation is going reversed because of strong induction of the all three genome caretaker genes in leaves of acutely irradiated plants in contrast to the plants under fractionated exposure.展开更多
By introducing a stochastic element to the double-jump diffusion framework to measure the Knight uncertainty of asset return process, this paper builds the model of dynamic portfolio choice, which maximizes the expect...By introducing a stochastic element to the double-jump diffusion framework to measure the Knight uncertainty of asset return process, this paper builds the model of dynamic portfolio choice, which maximizes the expected utility of terminal portfolio wealth. Through specifying the state function of uncertainty-aversion, it utilizes the max-min method to derive the analytical solution of the model to study the effect of the time-varying, jumps, and Knight uncertainty of asset return process on dynamic portfolio choice and their interactions. Results of comparative analysis show: The time-varying results in positive or negative intertemporal hedging demand of portfolio, which depends on the coefficient of investor's risk aversion and the correlation coefficient between return shift and volatility shift; the jumps in asset return overall reduce investor's demand for the risky asset, which can be enhanced or weakened by the jumps in volatility; due to the existing of the Knight uncertainty, the investor avoids taking large position on risky asset, and the resulting is the improving of portfolio's steady and immunity. At last, an empirical study is done based on the samples of Shanghai Exchange Composite Index monthly return data from January 1997 to December 2009, which not only tests the theoretical analysis but also demonstrates that the proposed method in the paper is useful from the aspect of portfotio's equivalent utility.展开更多
This paper discusses the inverse center location problem restricted on a tree with different costs and bound constraints. The authors first show that the problem can be formulated as a series of combinatorial linear p...This paper discusses the inverse center location problem restricted on a tree with different costs and bound constraints. The authors first show that the problem can be formulated as a series of combinatorial linear programs, then an O(|V|^2 log |V|) time algorithm to solve the problem is presented. For the equal cost case, the authors further give an O(|V|) time algorithm.展开更多
In this paper,the improved canonical quantization method of the self dual field is given in order to overcome linear combination problem about the second class constraint and the first class constraint number maximiza...In this paper,the improved canonical quantization method of the self dual field is given in order to overcome linear combination problem about the second class constraint and the first class constraint number maximization problem in the Dirac method.In the improved canonical quantization method,there are no artificial linear combination and the first class constraint number maximization problems,at the same time,the stability of the system is considered.Therefore,the improved canonical quantization method is more natural and easier accepted by people than the usual Dirac method.We use the improved canonical quantization method to realize the canonical quantization of the self dual field,which has relation with string theory successfully and the results are equal to the results by using the Dirac method.展开更多
Abstract The rapid development and production of nanomaterials has created some concerns about their potential hazard on the environment, human health and safety. However, since the list of materials that may gen- era...Abstract The rapid development and production of nanomaterials has created some concerns about their potential hazard on the environment, human health and safety. However, since the list of materials that may gen- erate such concerns is very long, it is impossible to test them all. It is therefore usually recommended to use some small compositional nanomaterial libraries to perform ini- tial toxicity screening, based on which combinatorial libraries are then introduced for more in-depth studies. All nanomaterials in the compositional and combinatorial libraries must be rigorously characterized before any bio- logical studies. In this review, several major categories of physicochemical properties that must be characterized are discussed, along with different analytical techniques that are commonly used. Some case studies from the University of California Center for Environmental Implications of Nanotechnology are also chosen to demonstrate the effec- tive use of compositional and combinatorial nanomaterials libraries to identify the role of some key physicochemical properties and to establish true quantitative structure-ac- tivity relationships. Examples on how to use the knowledge generated from those studies to design safer nanomaterials for improved biological applications are also presented.展开更多
基金Project(2011CB605502)supported by the National Basic Research Program of ChinaProject(B08040)supported by Introducing Talents of Discipline to Universities,China
文摘Microstructure stability of in situ synthesized Ti2AlN/Ti-48Al-2Cr-2Nb composite during aging at 900 ℃ was investigated by XRD, OM and TEM, and the unreinforced Ti-48Al-2Cr-2Nb alloy was also examined for comparison. The result showed that in the TiAl alloy,α2 lamellae thinned and were broken down, and became discontinuous with increasing aging time. The decomposition ofα2 lamella toγ which was characterized by parallel decomposition and breakdown ofα2 lamellae led to the degradation of the lamellar structure. While in the composite, lamellar structure remained relatively stable even after aging at 900 ℃ for 100 h. No breakdown ofα2 lamellae except parallel decomposition and precipitation of fine nitride particles was observed. The better microstructural stability of the composite was mainly attributed to the precipitation of Ti2AlN particles at theα2/γ interface which played an important role in retarding the coarsening of lamellar microstructure in the matrix of composite.
基金Supported by the Yunnan Provincial Sciences and Technology Department,China(No.2007AD009)the National Natural Science Foundation of China(No.31272680)the Ministry of Science and Technology of China(No.2013AA065805)
文摘In this paper,we investigated the effects of temperature,oxygen,antioxidants,and corn germ oil on the stability of astaxanthin from Haematococcus pluvialis under different storage conditions,and changes in the composition of astaxanthin esters during storage using high performance liquid chromatography and spectrophotometry.Oxygen and high temperatures(22–25°C) significantly reduced the stability of astaxanthin esters.Corn germ oil and antioxidants(ascorbic acid and vitamin E)failed to protect astaxanthin from oxidation,and actually significantly increased the instability of astaxanthin.A change in the relative composition of astaxanthin esters was observed after 96 weeks of long-term storage.During storage,the relative amounts of free astaxanthin and astaxanthin monoesters declined,while the relative amount of astaxanthin diesters increased.Thus,the ratio of astaxanthin diester to monoester increased,and this ratio could be used to indicate if astaxanthin esters have been properly preserved.If the ratio is greater than 0.2,it suggests that the decrease in astaxanthin content could be higher than 20%.Our results show that storing algal powder from H.pluvialis or other natural astaxanthin products under vacuum and in the dark below 4°C is the most economical and applicable storage method for the large-scale production of astaxanthin from H.pluvialis.This storage method can produce an astaxanthin preservation rate of at least 80%after 96 weeks of storage.
基金Key program of Natural Science Research of High Education of Anhui Province of China(No.KJ2009A157)
文摘The effect of uncertainty about stochastic diffusion model on dynamic portfolio choice of an investor who maximizes utility of terminal portfolio wealth was studied.It applied stochastic control method to obtain the closed-form solution of optimal dynamic portfolio,and used the Bayesian rule to estimate the model parameters to do an empirical study on two different samples of Shanghai Exchange Composite Index.Results show,model uncertainty results in positive or negative hedging demand of portfolio,which depends on investor's attitude toward risk;the effect of model uncertainty is more significant with the increasing of investment horizon,the decreasing of investor's risk-aversion degree,and the decreasing of information;predictability of risky asset return increases its allocation in portfolio,at the same time,the effect of model uncertainty also strengthens.
基金Project(2006BAE04B07) supported by the National Key Technology Research and Development Program Project(BA2005004) supported by Special Program for the Commercialization of Key Science and Technology Achievements by Jiangsu Science and Technology Department
文摘As-cast microstructure and mechanical properties of Mg-6Zn-2Al-0.3Mn (ZA62) alloys with calcium addition were investigated.The as-cast microstructure of the base alloy ZA62 consists of the α-Mg matrix and eutectic phase Mg51Zn20.The Mg51Zn20 eutectic was gradually replaced by MgZn phase and Mg32(Al,Zn)49 phase when calcium is added into the base alloy.Further addition of calcium leads to the increase of grain boundary phases and formation of a new quaternary Mg-Zn-Al-Ca eutectic compound.In comparison with the base alloy,the increase of calcium addition to the base alloy results in the reduction of both strength and ductility at ambient temperature,but increase at elevated temperatures due to the thermal stability of Ca-containing phases.At elevated temperatures,the creep resistance of ZA62 based alloys containing calcium is significantly higher than that of AZ91 which is the most commonly used magnesium alloy.
文摘In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, does not provide full interaction of a steel beam and a concrete slab. This changes strain distribution in cross-sections of a composite girder and results in redistribution of internal forces in steel and concrete element. In the paper partial interaction index defined on the basis of a neutral axis position, which can be used for verification of steel-concrete interaction in real bridge structures rather than in specimens is proposed. The range of the index value changes, obtained during load testing of a typical steel-concrete composite beam bridge, is presented. The investigation was carried out on a motorway viaduct, consisting of two parallel structures. During the testing values of strains in girders under static and quasi-static loads were measured. The readings from the gauges were used to determine the index, characterizing composite action of the girders. Results of bridge testing under movable load, changing position along the bridge span is presented and obtained in-situ influence functions of strains and index values are commented in the paper.
基金supported by the National Natural Science Foundation of China(No.11972241)the Natural Science Foundation of Jiangsu Province (No.BK20191454)the Scientific Research Foundation of Suzhou University of Science and Technology (No.XKZ2017005)。
文摘The combined gradient representations for generalized Birkhoffian systems in event space are studied.Firstly,the definitions of six kinds of combined gradient systems and corresponding differential equations are given.Secondly,the conditions under which generalized Birkhoffian systems become combined gradient systems are obtained. Finally,the characteristics of combined gradient systems are used to study the stability of generalized Birkhoffian systems in event space. Seven examples are given to illustrate the results.
文摘Three experimental single crystal superalloys with 0%Nb,0.5%Nb,1.0%Nb were cast in the directionally solidified furnace,while other alloying element contents were basically kept unchanged.The effect of Nb on the microstructure,stability at1100°C and stress rupture properties at 1070°C and 160 MPa of the single crystal superalloy were investigated.The experiment results show that the primary dendrite arm spacing decreases and the volume fraction ofγ/γ′eutectic of the alloy increases with the increase of Nb content in the as-cast microstructures.The size ofγ′phase particles becomes small and uniform and the cubic shape does not obviously change with the increase of Nb content.The precipitating rate and volume fraction of TCP phases increase significantly with the increase of Nb content in the process of long term aging at 1100°C.The stress rupture lives increase and elongation decreases with increasing Nb content at 1070°C/160 MPa.At last,the relationship between the microstructures stability,stress rupture properties of the alloy and Nb content is discussed based on JMat Pro software and the lastest relevant database for single crystal superalloy.
文摘The study of influence of the fractionated and acute ionizing radiation on plants revealed that it is able to induce genomic instability. The hypothesis that transcription rate of several evolutionary conserved DNA repair genes AtKu 70, AtRAD51 and AtRadl, which keeps genome stability in cells of model plant Arabidopsis thaliana, changes differently depending on dose and mode of ionizing radiation exposure had been tested. Gel electrophoresis-based reverse transcription polymerase chain reaction (RT-PCR) method was used for quantifying mRNA transcription levels. The data demonstrated that mode and dose of irradiation affect transcription rate of the genes AtKuTO, AtRAD51 and AtRadI. The fractionated and acute X-ray irradiation may result in adaptive response through the induction of key DNA double-strand break (DSB) repair genes AtKu70 and AtRAD51, as well as in genome instability through transcriptional activation of error-prone AtRadl-mediated DNA DSB repair combined with decreased expression of AtRAD51. In plants at doses within the range of 3-9 Gy, an adaptive influence is prevailed, but at doses of 12-21 Gy an error-prone repair of double-strand DNA damage is activated. Fractionation of dose has a significant effect on the transcription of the genes AtKuTO, AtRAD51 and AtRadl only at doses of 15 Gy and 21 Gy. Acute dose of 15 Gy activates error-prone AtRadl-mediated DSB repair and repressed both AtRAD51-dependent and AtKu70-dependent repair pathways, while fractionated irradiation at the same total dose induces more accurate homologous recombination and canonical non-homologous end joining of the DNA strands. In case of A. thaliana exposed to X-rays at dose 21 Gy, the situation is going reversed because of strong induction of the all three genome caretaker genes in leaves of acutely irradiated plants in contrast to the plants under fractionated exposure.
基金supported by National Natural Science Foundation of China under Grant Nos.71271003 and 71171003Programming Fund Project of the Humanities and Social Sciences Research of the Ministry of Education of China under Grant No.12YJA790041+1 种基金Natural Science Foundation of Anhui Province under Grant No.1208085MG116Key Program of Natural Science Research of High Education of Anhui Province of China under Grant No.KJ2011A031
文摘By introducing a stochastic element to the double-jump diffusion framework to measure the Knight uncertainty of asset return process, this paper builds the model of dynamic portfolio choice, which maximizes the expected utility of terminal portfolio wealth. Through specifying the state function of uncertainty-aversion, it utilizes the max-min method to derive the analytical solution of the model to study the effect of the time-varying, jumps, and Knight uncertainty of asset return process on dynamic portfolio choice and their interactions. Results of comparative analysis show: The time-varying results in positive or negative intertemporal hedging demand of portfolio, which depends on the coefficient of investor's risk aversion and the correlation coefficient between return shift and volatility shift; the jumps in asset return overall reduce investor's demand for the risky asset, which can be enhanced or weakened by the jumps in volatility; due to the existing of the Knight uncertainty, the investor avoids taking large position on risky asset, and the resulting is the improving of portfolio's steady and immunity. At last, an empirical study is done based on the samples of Shanghai Exchange Composite Index monthly return data from January 1997 to December 2009, which not only tests the theoretical analysis but also demonstrates that the proposed method in the paper is useful from the aspect of portfotio's equivalent utility.
基金The research is supported by the National Natural Science Foundation of China under Grant Nos.70425004,70221001the National Key Research and Development Program of China under Grant No.2002CB312004
文摘This paper discusses the inverse center location problem restricted on a tree with different costs and bound constraints. The authors first show that the problem can be formulated as a series of combinatorial linear programs, then an O(|V|^2 log |V|) time algorithm to solve the problem is presented. For the equal cost case, the authors further give an O(|V|) time algorithm.
基金Supported by National Natural Science Foundation of China under Grant Nos. 11275017 and 11173028
文摘In this paper,the improved canonical quantization method of the self dual field is given in order to overcome linear combination problem about the second class constraint and the first class constraint number maximization problem in the Dirac method.In the improved canonical quantization method,there are no artificial linear combination and the first class constraint number maximization problems,at the same time,the stability of the system is considered.Therefore,the improved canonical quantization method is more natural and easier accepted by people than the usual Dirac method.We use the improved canonical quantization method to realize the canonical quantization of the self dual field,which has relation with string theory successfully and the results are equal to the results by using the Dirac method.
基金supported by the National Science Foundation and the Environmental Protection Agency to UCCEIN under Cooperative Agreement No. DBI-1266377Partial support was also provided by U.S. Public Health Service Grants (R01 ES016746 and U19 ES019528)
文摘Abstract The rapid development and production of nanomaterials has created some concerns about their potential hazard on the environment, human health and safety. However, since the list of materials that may gen- erate such concerns is very long, it is impossible to test them all. It is therefore usually recommended to use some small compositional nanomaterial libraries to perform ini- tial toxicity screening, based on which combinatorial libraries are then introduced for more in-depth studies. All nanomaterials in the compositional and combinatorial libraries must be rigorously characterized before any bio- logical studies. In this review, several major categories of physicochemical properties that must be characterized are discussed, along with different analytical techniques that are commonly used. Some case studies from the University of California Center for Environmental Implications of Nanotechnology are also chosen to demonstrate the effec- tive use of compositional and combinatorial nanomaterials libraries to identify the role of some key physicochemical properties and to establish true quantitative structure-ac- tivity relationships. Examples on how to use the knowledge generated from those studies to design safer nanomaterials for improved biological applications are also presented.