By virtue of a 3∶1 complementary coordination strategy,a chiral heteroleptic metal-organic cage that con-tains divergent functional units,Pd‑R(Zn),was precisely constructed via self-assembly of monodentate variationa...By virtue of a 3∶1 complementary coordination strategy,a chiral heteroleptic metal-organic cage that con-tains divergent functional units,Pd‑R(Zn),was precisely constructed via self-assembly of monodentate variational Zn-salen ligands RZn and NADH(reduced nicotinamide adenine dinucleotide)mimic modified tridentate ligands with square-planar Pd ions.UV-Vis and luminescence spectra experiments reveal that different anions could selec-tively interact with different sites of Zn-salen modified metal-organic cages to achieve the structural regulation of cage compound,by using the differentiated host-guest electrostatic interactions of counter ions with metal-organic hosts.Compared to other anions,the presence of chloride ions caused the most significant fluorescence emission enhancement of Pd‑R(Zn),meanwhile,the UV-Vis absorption band attributed to the salen aromatic backbone showed an absorption decrease,and the metal-to-ligand induced peak displayed a blue shift effect.Circular dichro-ism and ^(1)H NMR spectra further demonstrate that the introduction of chloride anions is beneficial to keeping a more rigid scaffold.展开更多
This paper is concerned with the stability of multiclass queueing networks of 2 stations and4 buffers under the longest queue first served discipline(LQFS).For this network,the service priority of a customer is determ...This paper is concerned with the stability of multiclass queueing networks of 2 stations and4 buffers under the longest queue first served discipline(LQFS).For this network,the service priority of a customer is determined by the length of the queue that customer resides in at that time.The main result includes two parts.Firstly,the corresponding fluid model is established,and then it is shown that the queueing networks under LQFS are stable whenever the traffic intensity is strictly less than one for each station.展开更多
文摘By virtue of a 3∶1 complementary coordination strategy,a chiral heteroleptic metal-organic cage that con-tains divergent functional units,Pd‑R(Zn),was precisely constructed via self-assembly of monodentate variational Zn-salen ligands RZn and NADH(reduced nicotinamide adenine dinucleotide)mimic modified tridentate ligands with square-planar Pd ions.UV-Vis and luminescence spectra experiments reveal that different anions could selec-tively interact with different sites of Zn-salen modified metal-organic cages to achieve the structural regulation of cage compound,by using the differentiated host-guest electrostatic interactions of counter ions with metal-organic hosts.Compared to other anions,the presence of chloride ions caused the most significant fluorescence emission enhancement of Pd‑R(Zn),meanwhile,the UV-Vis absorption band attributed to the salen aromatic backbone showed an absorption decrease,and the metal-to-ligand induced peak displayed a blue shift effect.Circular dichro-ism and ^(1)H NMR spectra further demonstrate that the introduction of chloride anions is beneficial to keeping a more rigid scaffold.
基金supported by the National Natural Science Foundation of China under Grant No.11101050
文摘This paper is concerned with the stability of multiclass queueing networks of 2 stations and4 buffers under the longest queue first served discipline(LQFS).For this network,the service priority of a customer is determined by the length of the queue that customer resides in at that time.The main result includes two parts.Firstly,the corresponding fluid model is established,and then it is shown that the queueing networks under LQFS are stable whenever the traffic intensity is strictly less than one for each station.
