基于容性表面和感性表面的耦合机理,在ku波段提出了一种新型的微型频率选择表面(MEFSS)的设计。该单元延续了MEFSS良好的特性,克服了传统谐振单元在低频段,单元尺寸过长,单元间介质层过厚的缺点。使周期单元尺寸不受中心谐振波长的限制...基于容性表面和感性表面的耦合机理,在ku波段提出了一种新型的微型频率选择表面(MEFSS)的设计。该单元延续了MEFSS良好的特性,克服了传统谐振单元在低频段,单元尺寸过长,单元间介质层过厚的缺点。使周期单元尺寸不受中心谐振波长的限制。在0.15mm薄的介质两侧分别贴合圆环单元构成的电容和十字金属栅格构成的电感构成MEFSS,利用全波分析软件对本单元进行全波仿真。并且,通过研究不同的几何参数,总结了传输特性规律。仿真结果显示该设计单元在ku波段-3 d B带宽达到5.29GHz,单元尺寸减小为0.11?,中心频点在14.8 GHz,具有微型化、超宽带,角度稳定性和极化稳定性好的特点。展开更多
The haemocompatibility of Ti-3Zr-2Sn-3Mo-25Nb biomedical alloy was studied after surface heparinization. A layer of sol-gel TiO2 films was applied on the alloy samples followed by active treatment in the bio-functiona...The haemocompatibility of Ti-3Zr-2Sn-3Mo-25Nb biomedical alloy was studied after surface heparinization. A layer of sol-gel TiO2 films was applied on the alloy samples followed by active treatment in the bio-functionalized solution for introducing the OH- and groups, and then the heparin was immobilized on the active TiO2 films through the electrostatic self assembly technology. It is shown that the heparinized films are mainly composed of anatase and rutile with smooth and dense surface. In vitro blood compatibility was evaluated by haemolysis test, clotting time and platelet adhesion behavior tests. The results show that the haemocompatibility of the alloy could be significantly improved by surface heparinization.展开更多
Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surf...Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surface area of a polycrystalline Pd （pc-Pd） electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4μF/cm2 and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined is consistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.展开更多
The nonclassical symmetries of a class of nonlinear partial differential equations obtained by the compatibility method is investigated. We show the nonclassicaJ symmetries obtained in [J. Math. Anal. Appl. 289 （2004...The nonclassical symmetries of a class of nonlinear partial differential equations obtained by the compatibility method is investigated. We show the nonclassicaJ symmetries obtained in [J. Math. Anal. Appl. 289 （2004） 55, J. Math. Anal. Appl. 311 （2005） 479] are not all the nonclassical symmetries. Based on a new assume on the form of invariant surface condition, all the nonclassical symmetries for a class of nonlinear partial differential equations can be obtained through the compatibility method. The nonlinear Klein-Gordon equation and the Cahn-Hilliard equations all serve as examples showing the compatibility method leads quickly and easily to the determining equations for their all nonclassical symmetries for two equations.展开更多
According to the characteristics of the methane hydrate condensing and accumulating methane, authors put forward a new technique thought way to prevent the accident of coal and gas outburst by urging the methane in th...According to the characteristics of the methane hydrate condensing and accumulating methane, authors put forward a new technique thought way to prevent the accident of coal and gas outburst by urging the methane in the coal seams to form hydrate. The paper analyzes the feasibility of forming the methane hydrate in the coal seam from the several sides, such as, temperature,pressure, and gas components, and the primary trial results indicate the problems should be settled before the industrialization appliance realized.展开更多
The determining equations for the nonclassical symmetry reductions of nonlinear partial differential equations with arbitrary order can be obtained by requiring the compatibility between the original equations and the...The determining equations for the nonclassical symmetry reductions of nonlinear partial differential equations with arbitrary order can be obtained by requiring the compatibility between the original equations and the invariant surface conditions. The （2＋1）-dimensional shallow water wave equation, Boussinesq equation, and the dispersive wave equations in shallow water serve as examples i11ustrating how compatibility leads quickly and easily to the determining equations for their nonclassical symmetries.展开更多
Objective:To study the characteristics of the intraocular lens using ion beam sputtering depositing titanium nitride thin film on the intraocular lens(IOLs).Methods:To deposite titanium nitride thin film on the top of...Objective:To study the characteristics of the intraocular lens using ion beam sputtering depositing titanium nitride thin film on the intraocular lens(IOLs).Methods:To deposite titanium nitride thin film on the top of intraocular lens by ion beam sputtering depositing.We analyzed the surface morphology of intraocular lens through SEM and AFM.We detected intraocular lens resolution through the measurement of intraocular lens.Biocompatibility of intraocular lens is preliminary evaluated in this test.Results:The surface morphology of intraocular lens material was not changed,and was in line with the requirements of smoothness.Resolution was in line with national requirements.Unmodified and modified IOLs's cytotoxicity were 1 and 0.6 grade respectively.Hemolytic rates of modified and unmodified were both less than 5%.Conclusion:Ion beam sputtering deposition of objects didn't only affect the surface morphology and the basic optical performance,but also can enhance the biocompatibility of intraocular lens.Ion beam sputtering deposition technique has provided new methods for the surface modification of IOLs and PMMA materials.展开更多
Integration of fast electrochemical double-layer capacitance and large pseudocapacitance is a practical way to improve the overall capability of supercapacitor,yet remains challenging.Herein,an effective cyanogel synt...Integration of fast electrochemical double-layer capacitance and large pseudocapacitance is a practical way to improve the overall capability of supercapacitor,yet remains challenging.Herein,an effective cyanogel synthetic strategy was demonstrated to prepare ultrathin Ni(OH)2 nanosheets coupling with conductive reduced graphene oxide(rGO)(rGO-Ni(OH)2)at ambient condition.Ultrathin Ni(OH)2 nanosheet with 3–4 layers of edge-sharing octahedral MO6 maximally exposes the active surface of Faradic reaction and promotes the ion diffusion,while the conductive rGO sheet boosts the electron transport during the reaction.Even at 30 A g−1,the optimal sample can deliver a specific capacitance of 1119.52 F g−1,and maintain 82.3%after 2000 cycles,demonstrating much higher electrochemical capability than bare Ni(OH)2 nanosheets.A maximum specific energy of 44.3 W h kg^−1(148.5 W kg^−1)is obtained,when assembled in a two-electrode system rGO-Ni(OH)2//rGO.This study provides an insight into efficient construction of two dimensional hybrid electrodes with high performance for the new-generation energy storage system.展开更多
The possible practical limits for the specific surface area and capacitance performance of bulk sp^2 carbon materials were investigated experimentally and theoretically using a variety of carbon materials. We find the...The possible practical limits for the specific surface area and capacitance performance of bulk sp^2 carbon materials were investigated experimentally and theoretically using a variety of carbon materials. We find the limit for the specific surface area to be 3500–3700 m^2 g^(-1), and based on this, the corresponding best capacitance was predicted for various electrolyte systems. A model using an effective ionic diameter for the electrolyte ions was proposed and used to calculate the theoretical capacitance. A linear dependence of experimental capacitance versus effective specific surface area of various sp^2 carbon materials was obtained for all studied ionic liquid, organic and aqueous electrolyte systems. Furthermore, excellent agreement between the theoretical and experimental capacitance was observed for all the tested sp^2 carbon materials in these electrolyte systems, indicating that this model can be applied widely in the evaluation of various carbon materials for supercapacitors.展开更多
The corrosion resistance and cytocompatibility of Ti-20 Zr-10 Nb-4 Ta（TZNT） alloy modified by surface laser treatment were investigated. The scanning electron microscopy（SEM） measurements indicated that laser trea...The corrosion resistance and cytocompatibility of Ti-20 Zr-10 Nb-4 Ta（TZNT） alloy modified by surface laser treatment were investigated. The scanning electron microscopy（SEM） measurements indicated that laser treatment on TZNT alloy generated groove morphologies with the width of^40 μm and the depth of ~10 μm on the surface. The water contact angles along the groove direction decreased by 51%compared with that of the untreated alloy. The laser treatment promoted the oxidation of metallic Ti, Zr and Nb and produced more stable oxides on surface. The corrosion potential increased by 50% and corrosion current density decreased by72% compared with that of the untreated alloy in the anodic polarization test for the alloy in Hank’s solution at 37°C. This indicated the improvement of the corrosion resistance by laser treatment. The cytotoxicity testing results showed that the laser-treated TZNT alloy performed similar MC3 T3-E1 cell viability compared with the untreated alloy. The cells displayed oriented growth along the groove direction due to the increased hydrophilicity. This novel material may be a new candidate in orthopedics and dentistry implantations fields.展开更多
Mesoporous silica nanoparticles （MSNs） are promising for drug delivery and other biomedical applications owing to their excellent chemical stability and biocompatibility. For these applications, a hollow morphology ...Mesoporous silica nanoparticles （MSNs） are promising for drug delivery and other biomedical applications owing to their excellent chemical stability and biocompatibility. For these applications, a hollow morphology with thin shell and open mesopores is preferred for MSNs in order to maximize the loading capacity of drugs. Herein we report a novel and direct synthesis of such an ideal drug delivery system in a dilute and alkaline solution of benzylcetyl- dimethylammonium chloride and diethylene glycol hexadecyl ether. The mixed surfactants can guide the formation of MSNs with cubic Ia3d mesostructure, and at a concentration of sodium hydroxide between 9.8 and 13.5 mM, hollow MSNs with uniform sizes of 90-120 nm and a single-unit-cell-thick shell are formed. A mechanism for the formation of the hollow Ia3d MSNs, designated as MMT-2, is proposed based on in situ small-angle X-ray scattering measurements and other analyses. MMT-2 exhibits much higher loading capacity of ibuprofen and degrades faster in simulated body fluid and phosphate buffered saline than non-hollow MSNs. The degradation of MMT-2 can be significantly retarded by modification with polyethylene glycol. More interestingly, the degradation of MMT-2 involves fragmentation instead of void formation, a phenomenon beneficial for their elimination. The results demonstrate the uniqueness of the hollow Ia3d MSNs and the great potential of the material for drug delivery and biomedical applications.展开更多
文摘基于容性表面和感性表面的耦合机理,在ku波段提出了一种新型的微型频率选择表面(MEFSS)的设计。该单元延续了MEFSS良好的特性,克服了传统谐振单元在低频段,单元尺寸过长,单元间介质层过厚的缺点。使周期单元尺寸不受中心谐振波长的限制。在0.15mm薄的介质两侧分别贴合圆环单元构成的电容和十字金属栅格构成的电感构成MEFSS,利用全波分析软件对本单元进行全波仿真。并且,通过研究不同的几何参数,总结了传输特性规律。仿真结果显示该设计单元在ku波段-3 d B带宽达到5.29GHz,单元尺寸减小为0.11?,中心频点在14.8 GHz,具有微型化、超宽带,角度稳定性和极化稳定性好的特点。
基金Project (31100693/C100302) supported by the National Natural Science Foundation of ChinaProject (31011120049) supported by the Australia-China Special Fund, International Science Linkages Program co-supported by the Department of Innovation, Industry, Science and Research of Australia, and the Ministry of Science and Technology and National Science Foundation of China+1 种基金Project(2010ZDKG-96) supported by the Major Subject of "13115" Programs of Shaan’xi Province, ChinaProject (2012CB619102) supported by the National Basic Research Program of China
文摘The haemocompatibility of Ti-3Zr-2Sn-3Mo-25Nb biomedical alloy was studied after surface heparinization. A layer of sol-gel TiO2 films was applied on the alloy samples followed by active treatment in the bio-functionalized solution for introducing the OH- and groups, and then the heparin was immobilized on the active TiO2 films through the electrostatic self assembly technology. It is shown that the heparinized films are mainly composed of anatase and rutile with smooth and dense surface. In vitro blood compatibility was evaluated by haemolysis test, clotting time and platelet adhesion behavior tests. The results show that the haemocompatibility of the alloy could be significantly improved by surface heparinization.
文摘Four methods, including voltammetric measurement of double layer capacitance, surface oxides reduction, under potential deposition of Cu and carbon monoxide （CO） stripping have been applied to evaluate the real surface area of a polycrystalline Pd （pc-Pd） electrode. The results reveal that the second and third methods lead to consistent results with deviations below 5%. And from the determined double layer capacitance and CO stripping charge, it is deduced that the double layer capacity unit area is 23.1±0.4μF/cm2 and the saturated CO adlayer should be ca. 0.66 ML in order to ensure that the real surface area as determined is consistent with the other two techniques. The applicability as well as the attentions when applying these techniques for the determination of the real surface area of pc-Pd electrodes have been discussed.
基金Supported by National Natural Science Foundation of China under Grant No.10735030Shanghai Leading Academic Discipline Project under Grant No.B412,NSFC No.90718041+1 种基金Program for Changjiang Scholars and Innovative Research Team in University (IRT0734)K.C.Wong Magna Fund in Ningbo University
文摘The nonclassical symmetries of a class of nonlinear partial differential equations obtained by the compatibility method is investigated. We show the nonclassicaJ symmetries obtained in [J. Math. Anal. Appl. 289 （2004） 55, J. Math. Anal. Appl. 311 （2005） 479] are not all the nonclassical symmetries. Based on a new assume on the form of invariant surface condition, all the nonclassical symmetries for a class of nonlinear partial differential equations can be obtained through the compatibility method. The nonlinear Klein-Gordon equation and the Cahn-Hilliard equations all serve as examples showing the compatibility method leads quickly and easily to the determining equations for their all nonclassical symmetries for two equations.
文摘According to the characteristics of the methane hydrate condensing and accumulating methane, authors put forward a new technique thought way to prevent the accident of coal and gas outburst by urging the methane in the coal seams to form hydrate. The paper analyzes the feasibility of forming the methane hydrate in the coal seam from the several sides, such as, temperature,pressure, and gas components, and the primary trial results indicate the problems should be settled before the industrialization appliance realized.
文摘The determining equations for the nonclassical symmetry reductions of nonlinear partial differential equations with arbitrary order can be obtained by requiring the compatibility between the original equations and the invariant surface conditions. The （2＋1）-dimensional shallow water wave equation, Boussinesq equation, and the dispersive wave equations in shallow water serve as examples i11ustrating how compatibility leads quickly and easily to the determining equations for their nonclassical symmetries.
文摘Objective:To study the characteristics of the intraocular lens using ion beam sputtering depositing titanium nitride thin film on the intraocular lens(IOLs).Methods:To deposite titanium nitride thin film on the top of intraocular lens by ion beam sputtering depositing.We analyzed the surface morphology of intraocular lens through SEM and AFM.We detected intraocular lens resolution through the measurement of intraocular lens.Biocompatibility of intraocular lens is preliminary evaluated in this test.Results:The surface morphology of intraocular lens material was not changed,and was in line with the requirements of smoothness.Resolution was in line with national requirements.Unmodified and modified IOLs's cytotoxicity were 1 and 0.6 grade respectively.Hemolytic rates of modified and unmodified were both less than 5%.Conclusion:Ion beam sputtering deposition of objects didn't only affect the surface morphology and the basic optical performance,but also can enhance the biocompatibility of intraocular lens.Ion beam sputtering deposition technique has provided new methods for the surface modification of IOLs and PMMA materials.
基金the National Natural Science Foundation of China(21875133)Xijiang R&D Team(Wang X),the Science and Technology Program of Guangzhou(2019050001)Science and Technology Commission of Shanghai Municipality(19ZR1479500)。
文摘Integration of fast electrochemical double-layer capacitance and large pseudocapacitance is a practical way to improve the overall capability of supercapacitor,yet remains challenging.Herein,an effective cyanogel synthetic strategy was demonstrated to prepare ultrathin Ni(OH)2 nanosheets coupling with conductive reduced graphene oxide(rGO)(rGO-Ni(OH)2)at ambient condition.Ultrathin Ni(OH)2 nanosheet with 3–4 layers of edge-sharing octahedral MO6 maximally exposes the active surface of Faradic reaction and promotes the ion diffusion,while the conductive rGO sheet boosts the electron transport during the reaction.Even at 30 A g−1,the optimal sample can deliver a specific capacitance of 1119.52 F g−1,and maintain 82.3%after 2000 cycles,demonstrating much higher electrochemical capability than bare Ni(OH)2 nanosheets.A maximum specific energy of 44.3 W h kg^−1(148.5 W kg^−1)is obtained,when assembled in a two-electrode system rGO-Ni(OH)2//rGO.This study provides an insight into efficient construction of two dimensional hybrid electrodes with high performance for the new-generation energy storage system.
基金supported by the National Basic Research Program of China(2012CB933401)the National Natural Science Foundation of China(51472124+3 种基金5127309321374050)the Natural Science Foundation of Tianjin(13RCGFGX01121)Science Research Project of Langfang Teachers University(LSLB201401)
文摘The possible practical limits for the specific surface area and capacitance performance of bulk sp^2 carbon materials were investigated experimentally and theoretically using a variety of carbon materials. We find the limit for the specific surface area to be 3500–3700 m^2 g^(-1), and based on this, the corresponding best capacitance was predicted for various electrolyte systems. A model using an effective ionic diameter for the electrolyte ions was proposed and used to calculate the theoretical capacitance. A linear dependence of experimental capacitance versus effective specific surface area of various sp^2 carbon materials was obtained for all studied ionic liquid, organic and aqueous electrolyte systems. Furthermore, excellent agreement between the theoretical and experimental capacitance was observed for all the tested sp^2 carbon materials in these electrolyte systems, indicating that this model can be applied widely in the evaluation of various carbon materials for supercapacitors.
基金supported by the National Natural Science Foundation of China (NSFC, 51771011)the Fundamental Research Funds for the Central Universities (KG12002601)
文摘The corrosion resistance and cytocompatibility of Ti-20 Zr-10 Nb-4 Ta（TZNT） alloy modified by surface laser treatment were investigated. The scanning electron microscopy（SEM） measurements indicated that laser treatment on TZNT alloy generated groove morphologies with the width of^40 μm and the depth of ~10 μm on the surface. The water contact angles along the groove direction decreased by 51%compared with that of the untreated alloy. The laser treatment promoted the oxidation of metallic Ti, Zr and Nb and produced more stable oxides on surface. The corrosion potential increased by 50% and corrosion current density decreased by72% compared with that of the untreated alloy in the anodic polarization test for the alloy in Hank’s solution at 37°C. This indicated the improvement of the corrosion resistance by laser treatment. The cytotoxicity testing results showed that the laser-treated TZNT alloy performed similar MC3 T3-E1 cell viability compared with the untreated alloy. The cells displayed oriented growth along the groove direction due to the increased hydrophilicity. This novel material may be a new candidate in orthopedics and dentistry implantations fields.
文摘Mesoporous silica nanoparticles （MSNs） are promising for drug delivery and other biomedical applications owing to their excellent chemical stability and biocompatibility. For these applications, a hollow morphology with thin shell and open mesopores is preferred for MSNs in order to maximize the loading capacity of drugs. Herein we report a novel and direct synthesis of such an ideal drug delivery system in a dilute and alkaline solution of benzylcetyl- dimethylammonium chloride and diethylene glycol hexadecyl ether. The mixed surfactants can guide the formation of MSNs with cubic Ia3d mesostructure, and at a concentration of sodium hydroxide between 9.8 and 13.5 mM, hollow MSNs with uniform sizes of 90-120 nm and a single-unit-cell-thick shell are formed. A mechanism for the formation of the hollow Ia3d MSNs, designated as MMT-2, is proposed based on in situ small-angle X-ray scattering measurements and other analyses. MMT-2 exhibits much higher loading capacity of ibuprofen and degrades faster in simulated body fluid and phosphate buffered saline than non-hollow MSNs. The degradation of MMT-2 can be significantly retarded by modification with polyethylene glycol. More interestingly, the degradation of MMT-2 involves fragmentation instead of void formation, a phenomenon beneficial for their elimination. The results demonstrate the uniqueness of the hollow Ia3d MSNs and the great potential of the material for drug delivery and biomedical applications.
