Graphene oxide(GO)has proven to be an effective reinfor-cing filler for rubber[1].GO has superior mechanical properties,barrier properties,large specific surface area and abundant oxygen-containing functional groups[2...Graphene oxide(GO)has proven to be an effective reinfor-cing filler for rubber[1].GO has superior mechanical properties,barrier properties,large specific surface area and abundant oxygen-containing functional groups[2].However,the change in the oxidation degree of GO has a great effect on its chemical properties,the interaction between GO and the matrix,and the dispersion uniformity in the rubber matrix,which has a great effect on the reinforcement of rubber[3].展开更多
The Ti−45Nb(wt.%)alloy properties were investigated in relation to its potential biomedical use.Laser surface modification was utilized to improve its performance in biological systems.As a result of the laser treatme...The Ti−45Nb(wt.%)alloy properties were investigated in relation to its potential biomedical use.Laser surface modification was utilized to improve its performance in biological systems.As a result of the laser treatment,(Ti,Nb)O scale was formed and various morphological features appeared on the alloy surface.The electrochemical behavior of Ti−45Nb alloy in simulated body conditions was evaluated and showed that the alloy was highly resistant to corrosion deterioration regardless of additional laser surface modification treatment.Nevertheless,the improved corrosion resistance after laser treatment was evident(the corrosion current density of the alloy before laser irradiation was 2.84×10^(−8)A/cm^(2),while that after laser treatment with 5 mJ was 0.65×10^(−8)A/cm^(2))and ascribed to the rapid formation of a complex and passivating bi-modal surface oxide layer.Alloy cytotoxicity and effects of the Ti−45Nb alloy laser surface modification on the MRC-5 cell viability,morphology,and proliferation were also investigated.The Ti−45Nb alloy showed no cytotoxic effect.Moreover,cells showed improved viability and adherence to the alloy surface after the laser irradiation treatment.The highest average cell viability of 115.37%was attained for the alloy laser-irradiated with 15 mJ.Results showed that the laser surface modification can be successfully utilized to significantly improve alloy performance in a biological environment.展开更多
In order to review storage performance of the electric double layer capacitor (EDLC) in microgrid applications, charging time and storage efficiency issues are mainly studied aiming at three different charging modes...In order to review storage performance of the electric double layer capacitor (EDLC) in microgrid applications, charging time and storage efficiency issues are mainly studied aiming at three different charging modes, including the constant voltage charging mode (CVCM), the constant current charging mode (CCCM) and the constant power charging mode (CPCM), based on the practical EDLC product. Numerical calculation methods are presented for different charging modes, and the charging efficiency is also reviewed with strict mathematical deductions, which is validated to be accurate enough and applicable through a simple case with the PV/EDLC system illustration. Finally, trade-off problems between charging time and energy loss are also studied. Research results show that the CPCM is more suitable for microgrid networks compared with the traditional constant-voltage and constant-current charging modes. The hybrid charging method is recommended to save energy and keep high efficiency relatively at the same time. However, how to manage the combination percentage of different charging modes in a reasonable way should be dealt with according to the practical requirements.展开更多
Phospahting coated WE43 magnesium alloy was prepared by an immersion method. The microstructure, corrosion resistance and biocompatibility of the coated alloy were investigated. Scanning electron microscopy (SEM) an...Phospahting coated WE43 magnesium alloy was prepared by an immersion method. The microstructure, corrosion resistance and biocompatibility of the coated alloy were investigated. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to examine the microstructure and the composition of the coated alloy. The corrosion resistance was studied by means of potentiodynamic polarization method and the biocompatibility of the surface modified WE43 alloy was evaluated by (3-(4,5)-Dimethylthiazol-2, yl)-2,5-diphenyltetrazolium bromide (MTT) and hemolysis test. The results show that the phosphating coating can enhance the corrosion resistance of WE43 alloy and can be a good candidate to increase the biocompatibility of WE43 alloy.展开更多
[Objective] This study was to reveal the effect of different land use patterns on physical characteristics of soil water in the Yellow River wetland in Shaanxi Province.[Method]Taking Yellow River wetland in Shaanxi P...[Objective] This study was to reveal the effect of different land use patterns on physical characteristics of soil water in the Yellow River wetland in Shaanxi Province.[Method]Taking Yellow River wetland in Shaanxi Province as experimental plot,we compared the physical properties of the soil water under different land use patterns and studied the physical properties and the change law of soil water during the wetland degeneration process.[Result]Under different land use patterns,soil bulk density rose with the increase of soil depth.During the degeneration process of from river wetland to reclaimed wetland(paddy field),finally to abandoned land owing to salinization,the mean soil bulk density reduced correspondingly from 1.474 to 1.522 g/cm3,finally to 1.593 g/cm3 when abandoned.Accompanying wetland degeneration,soil became compact increasingly,and the indicators of soil porosity(total porosity,capillary porosity,non-capillary porosity)were also reduced with the change of land use patterns,in which,capillary porosity and total porosity reached the extremely significant level with the change of land use patterns,and non-capillary porosity reached significant level.The changes of soil porosity condition accelerated the deterioration of wetland.Under different land use patterns,the maximum soil moisture capacity,capillary moisture capacity and minimum moisture capacity all showed a similar change law.Compared with wetland,the maximum soil moisture capacity of reclaimed land(paddy field)and salinized land respectively decreased by 5.7% and 22.3%,capillary moisture capacity by 0.2% and 19.4%,minimum moisture capacity by 2.7% and 15.9%.Of the three land use patterns,wetland displayed both higher water holding capacity and water drainage capacity over reclaimed land(paddy field)and salinized land.By comparison with wetland,the reclaimed land(paddy field)and salinized land respectively decreased by 12.4% and 15.2% in total water holding capacity,and by 2.7% and 15.9% in total water drainage capacity.[Conclusion]To conserve the water resource in Yellow River wetland,regulate the hydrological cycle and enhance drought and water logging resistances,it should be noted that reasonable countermeasures be taken to exploit the state-owned forest land and paddy field around the wetland and the related resources.展开更多
Aluminum capacitor foils with a tunnel etch structure were reacted with boiling water and then anodized at 530 V in boric acid solution or boric acid+citric acid mixed solution.The microstructure and crystallinity of...Aluminum capacitor foils with a tunnel etch structure were reacted with boiling water and then anodized at 530 V in boric acid solution or boric acid+citric acid mixed solution.The microstructure and crystallinity of the resulting anodized film were examined by TEM and XRD.The special capacitance,resistance and withstanding voltage of the film were explored with electrochemical impedance spectroscopy(EIS),LCR meter and small-current charging.The results show that the high voltage anodized oxide film consists of an inner layer with high crystallinity and an outer layer with low crystallinity.However,the crystallinity of the film formed in boric acid+citric acid mixed solution is higher than that of the film formed in only boric acid solution,leading to an increase in film's field strength and special capacitance.Meanwhile,there are more defects from phase transformation in the out layer of the film formed in boric acid+citric acid mixed solution than in that of film formed in only boric acid solution,leading to a decrease in film's resistance and withstanding voltage.展开更多
The effect of heat treatment on the transformation temperature of Ti?52.2%Ni (mole fraction) alloy was studied using differential scanning calorimetry (DSC). The transformation temperatures of the alloy can be adjuste...The effect of heat treatment on the transformation temperature of Ti?52.2%Ni (mole fraction) alloy was studied using differential scanning calorimetry (DSC). The transformation temperatures of the alloy can be adjusted effectively by heat treatment. Dense and stable SiO2 coatings were deposited on the surface of the pre-oxidized TiNi alloy by sol?gel method. The bonding strength of films and matrix was (65.9±1.5) N. The electrochemical corrosion test shows that the TiNi alloy with SiO2 coating has excellent corrosion resistance in the Hank’s simulated body fluid. The release behaviors of Ni ion of the alloy with and without SiO2 coating implanted in the acoustic vesicle of guinea pig were studied by EDS testing, which was inhibited effectively by the dense and stable SiO2 coating on the alloy.展开更多
Anodic electrodes with the mixture of hydrogen storage alloys and different contents of Co3O4(2%,4%,6% and 8%,mass fraction) powders were made.The effects of Co3O4 on the electrochemical performance of the alloy ele...Anodic electrodes with the mixture of hydrogen storage alloys and different contents of Co3O4(2%,4%,6% and 8%,mass fraction) powders were made.The effects of Co3O4 on the electrochemical performance of the alloy electrodes were studied.The constant charge-discharge tests show that the discharge capacity of alloy electrodes with Co3O4 significantly increases,and the maximum discharge capacities of electrodes with 2%,4%,6% and 8% Co3O4 are higher than the electrode with no Co3O4 by 0.83%,4.86%,7.18% and 9.21%,accordingly.Linear polarization(LP) and electrochemical impedance spectroscopy(EIS) tests suggest that charge-transfer resistance decreases by the addition of Co3O4.Cyclic voltammogram(CV),scanning electron microscopy(SEM) and energy dispersive spectrum(EDS) tests indicate that Co3O4 can partly dissolve and experience a reversible oxidation-reduction process of Co to Co(OH)2,leading to the improvement in the electrochemical performance of hydrogen storage alloy.展开更多
Seismic bearing capacity factors of a strip footing placed on soil slope were determined with both associated and nonassociated flow rules. Quasi-static representation of earthquake effects using a seismic coefficient...Seismic bearing capacity factors of a strip footing placed on soil slope were determined with both associated and nonassociated flow rules. Quasi-static representation of earthquake effects using a seismic coefficient concept was adopted for seismic bearing capacity calculations. A multi-wedge translational failure mechanism was used to obtain the seismic bearing capacity factors for different seismic coefficients and various inclined angles. Employing the associated flow rule, numerical results were compared with the published solutions. For bearing capacity factors related to cohesion and equivalent surcharge load, the maximum difference approximates 0.1%. However, the difference of bearing capacity factor related to unit weight is larger. With the two flow rules, the seismic bearing capacity factors were presented in the form of design charts for practical use. The results show that seismic bearing capacity factors related to the cohesion, the equivalent surcharge load and the unit weight increase greatly as the dilatancy angle increases, and that the nonassociated flow rule has important influences on the seismic bearing capacity.展开更多
The coexistence between Bluetooth system and IEEE 802.11 frequency hoppingspread spectrum (FHSS) equipment is analyzed. Based on the capacity formulae and system simulation,the inter-affection between these networks i...The coexistence between Bluetooth system and IEEE 802.11 frequency hoppingspread spectrum (FHSS) equipment is analyzed. Based on the capacity formulae and system simulation,the inter-affection between these networks is compared. A fragment adaptive solution of packetpayload length is presented, which can be used to improve the capacity reduction of IEEE 802.11 FHSSnetwork. Analysis results show that the IEEE 802.11 WLAN standard with its inherent mechanismsupports this fragment length adaptive algorithm. With the increasing of Bluetooth interferingnetworks, this adaptive solution can effectively relieve capacity decreasing of IEEE 802.11 FHSSnetwork. The capacity analysis method and adaptive algorithm adopted in this paper can also begeneralized into other FHSS networks.展开更多
In this paper,we discuss in detail the basic issue of green design and consider an energy efficiency function as the metric to evaluate green cellular networks.Specifically,we investigate the transmit power required f...In this paper,we discuss in detail the basic issue of green design and consider an energy efficiency function as the metric to evaluate green cellular networks.Specifically,we investigate the transmit power required for an expected transmission capacity and propose a capacity-power formula based on the energy conservation and the Shannon capacity theorem.Two novel definitions of cell interference depth and handoff dynamic model are introduced and the corresponding expression of energy efficiency function is derived.Numerical results show that the energy efficiency function is closely correlated with the transmitted/received power required and the cell radius.Our work provides a useful basis for research and evaluation on green design and technology of cellular networks.展开更多
Al specimens were covered with TiO2 film by sol-gel dip-coating and then anodized in ammonium adipate solution.The structure,composition and capacitance properties of the anodic oxide film were investigated by transmi...Al specimens were covered with TiO2 film by sol-gel dip-coating and then anodized in ammonium adipate solution.The structure,composition and capacitance properties of the anodic oxide film were investigated by transmission electron microscopy (TEM),Auger electron spectroscopy (AES),X-ray diffractometry (XRD) and electrochemical impedance spectroscopy (EIS).It was found that an anodic oxide film with a dual-layer structure formed between TiO2 coating and Al substrate.The film consisted of an inner Al2O3 layer and an outer Ti-Al composite oxide layer.The thickness of layers varied with the number of times of sol-gel dip-coating.The capacitance of anodic oxide films formed on coated specimens was at most 80% higher than that without TiO2.In film formation mechanism,it was claimed that the formation of composite oxide film was mainly affected by the structure of micro-pores network in TiO2 coating which had an influence on Al3+ and O2? ions transport during the anodizing.展开更多
On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the qua...On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the quasione-dimensional interehain coupling organic ferromagnets are presented. We find that an obvious feature is to present itself the round peak for the specific heat with the temperature. This indicates unambiguously the presence of the phase transition in the system. The transition temperature plays down with increasing of the interchain coupling t2 or decreasing of the electron repulsion u. The curves of charge density with the temperature debase monotonously. This result illustrates that the higher the temperature is, the more electrons are excited.展开更多
基金Supported by Shanghai Aerospace Science and Technology Innovation Fund Project (SAST 2022-097)。
文摘Graphene oxide(GO)has proven to be an effective reinfor-cing filler for rubber[1].GO has superior mechanical properties,barrier properties,large specific surface area and abundant oxygen-containing functional groups[2].However,the change in the oxidation degree of GO has a great effect on its chemical properties,the interaction between GO and the matrix,and the dispersion uniformity in the rubber matrix,which has a great effect on the reinforcement of rubber[3].
基金the Ministry of Science,Technological Development and Innovation of the Republic of Serbia(No.451-03-47/2023-01/200017)the PhD fellowship of Slađana LAKETIĆ.Authors would also like to acknowledge the help of Dr.Anton HOHENWARTER from the Department of Materials Science,Montanuniversitat Leoben,Austria,during the Ti−45Nb alloy microstructural analysis.
文摘The Ti−45Nb(wt.%)alloy properties were investigated in relation to its potential biomedical use.Laser surface modification was utilized to improve its performance in biological systems.As a result of the laser treatment,(Ti,Nb)O scale was formed and various morphological features appeared on the alloy surface.The electrochemical behavior of Ti−45Nb alloy in simulated body conditions was evaluated and showed that the alloy was highly resistant to corrosion deterioration regardless of additional laser surface modification treatment.Nevertheless,the improved corrosion resistance after laser treatment was evident(the corrosion current density of the alloy before laser irradiation was 2.84×10^(−8)A/cm^(2),while that after laser treatment with 5 mJ was 0.65×10^(−8)A/cm^(2))and ascribed to the rapid formation of a complex and passivating bi-modal surface oxide layer.Alloy cytotoxicity and effects of the Ti−45Nb alloy laser surface modification on the MRC-5 cell viability,morphology,and proliferation were also investigated.The Ti−45Nb alloy showed no cytotoxic effect.Moreover,cells showed improved viability and adherence to the alloy surface after the laser irradiation treatment.The highest average cell viability of 115.37%was attained for the alloy laser-irradiated with 15 mJ.Results showed that the laser surface modification can be successfully utilized to significantly improve alloy performance in a biological environment.
基金The National Natural Science Foundation of China (No.50907010)Ph.D.Programs Foundation of Ministry of Education of China(No.20070286047)Scientific Innovation Foundation for Youngsters of CSEE
文摘In order to review storage performance of the electric double layer capacitor (EDLC) in microgrid applications, charging time and storage efficiency issues are mainly studied aiming at three different charging modes, including the constant voltage charging mode (CVCM), the constant current charging mode (CCCM) and the constant power charging mode (CPCM), based on the practical EDLC product. Numerical calculation methods are presented for different charging modes, and the charging efficiency is also reviewed with strict mathematical deductions, which is validated to be accurate enough and applicable through a simple case with the PV/EDLC system illustration. Finally, trade-off problems between charging time and energy loss are also studied. Research results show that the CPCM is more suitable for microgrid networks compared with the traditional constant-voltage and constant-current charging modes. The hybrid charging method is recommended to save energy and keep high efficiency relatively at the same time. However, how to manage the combination percentage of different charging modes in a reasonable way should be dealt with according to the practical requirements.
基金Project(2011AA030103) supported by the National High-tech Research Program of ChinaProject(201001C0104669453) supported by the Guangdong Innovation R&D Team Project,China
文摘Phospahting coated WE43 magnesium alloy was prepared by an immersion method. The microstructure, corrosion resistance and biocompatibility of the coated alloy were investigated. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to examine the microstructure and the composition of the coated alloy. The corrosion resistance was studied by means of potentiodynamic polarization method and the biocompatibility of the surface modified WE43 alloy was evaluated by (3-(4,5)-Dimethylthiazol-2, yl)-2,5-diphenyltetrazolium bromide (MTT) and hemolysis test. The results show that the phosphating coating can enhance the corrosion resistance of WE43 alloy and can be a good candidate to increase the biocompatibility of WE43 alloy.
基金Supported by National Natural Science Foundation of China(40871119)Key Science and Technology Program of Shaanxi Province,China(2007K01-15-1)~~
文摘[Objective] This study was to reveal the effect of different land use patterns on physical characteristics of soil water in the Yellow River wetland in Shaanxi Province.[Method]Taking Yellow River wetland in Shaanxi Province as experimental plot,we compared the physical properties of the soil water under different land use patterns and studied the physical properties and the change law of soil water during the wetland degeneration process.[Result]Under different land use patterns,soil bulk density rose with the increase of soil depth.During the degeneration process of from river wetland to reclaimed wetland(paddy field),finally to abandoned land owing to salinization,the mean soil bulk density reduced correspondingly from 1.474 to 1.522 g/cm3,finally to 1.593 g/cm3 when abandoned.Accompanying wetland degeneration,soil became compact increasingly,and the indicators of soil porosity(total porosity,capillary porosity,non-capillary porosity)were also reduced with the change of land use patterns,in which,capillary porosity and total porosity reached the extremely significant level with the change of land use patterns,and non-capillary porosity reached significant level.The changes of soil porosity condition accelerated the deterioration of wetland.Under different land use patterns,the maximum soil moisture capacity,capillary moisture capacity and minimum moisture capacity all showed a similar change law.Compared with wetland,the maximum soil moisture capacity of reclaimed land(paddy field)and salinized land respectively decreased by 5.7% and 22.3%,capillary moisture capacity by 0.2% and 19.4%,minimum moisture capacity by 2.7% and 15.9%.Of the three land use patterns,wetland displayed both higher water holding capacity and water drainage capacity over reclaimed land(paddy field)and salinized land.By comparison with wetland,the reclaimed land(paddy field)and salinized land respectively decreased by 12.4% and 15.2% in total water holding capacity,and by 2.7% and 15.9% in total water drainage capacity.[Conclusion]To conserve the water resource in Yellow River wetland,regulate the hydrological cycle and enhance drought and water logging resistances,it should be noted that reasonable countermeasures be taken to exploit the state-owned forest land and paddy field around the wetland and the related resources.
基金Project supported by University New Materials Disciplines Construction Program of Beijing Region
文摘Aluminum capacitor foils with a tunnel etch structure were reacted with boiling water and then anodized at 530 V in boric acid solution or boric acid+citric acid mixed solution.The microstructure and crystallinity of the resulting anodized film were examined by TEM and XRD.The special capacitance,resistance and withstanding voltage of the film were explored with electrochemical impedance spectroscopy(EIS),LCR meter and small-current charging.The results show that the high voltage anodized oxide film consists of an inner layer with high crystallinity and an outer layer with low crystallinity.However,the crystallinity of the film formed in boric acid+citric acid mixed solution is higher than that of the film formed in only boric acid solution,leading to an increase in film's field strength and special capacitance.Meanwhile,there are more defects from phase transformation in the out layer of the film formed in boric acid+citric acid mixed solution than in that of film formed in only boric acid solution,leading to a decrease in film's resistance and withstanding voltage.
基金Project(81170609)supported by the National Natural Science Foundation of ChinaProject(11JJ6087)supported by the Nature Science Foundation of Hunan Province,ChinaProject supported by the Open Project of State Key Laboratory of Powder Metallurgy,Central South University,China
文摘The effect of heat treatment on the transformation temperature of Ti?52.2%Ni (mole fraction) alloy was studied using differential scanning calorimetry (DSC). The transformation temperatures of the alloy can be adjusted effectively by heat treatment. Dense and stable SiO2 coatings were deposited on the surface of the pre-oxidized TiNi alloy by sol?gel method. The bonding strength of films and matrix was (65.9±1.5) N. The electrochemical corrosion test shows that the TiNi alloy with SiO2 coating has excellent corrosion resistance in the Hank’s simulated body fluid. The release behaviors of Ni ion of the alloy with and without SiO2 coating implanted in the acoustic vesicle of guinea pig were studied by EDS testing, which was inhibited effectively by the dense and stable SiO2 coating on the alloy.
基金Projects(21071153,20976198)supported by the National Natural Science Foundation of China
文摘Anodic electrodes with the mixture of hydrogen storage alloys and different contents of Co3O4(2%,4%,6% and 8%,mass fraction) powders were made.The effects of Co3O4 on the electrochemical performance of the alloy electrodes were studied.The constant charge-discharge tests show that the discharge capacity of alloy electrodes with Co3O4 significantly increases,and the maximum discharge capacities of electrodes with 2%,4%,6% and 8% Co3O4 are higher than the electrode with no Co3O4 by 0.83%,4.86%,7.18% and 9.21%,accordingly.Linear polarization(LP) and electrochemical impedance spectroscopy(EIS) tests suggest that charge-transfer resistance decreases by the addition of Co3O4.Cyclic voltammogram(CV),scanning electron microscopy(SEM) and energy dispersive spectrum(EDS) tests indicate that Co3O4 can partly dissolve and experience a reversible oxidation-reduction process of Co to Co(OH)2,leading to the improvement in the electrochemical performance of hydrogen storage alloy.
基金Project(200550) supported by the Foundation for the Author of National Excellent Doctoral Dissertation of ChinaProject(05-0686) supported by the Program for New Century Excellent Talents in University
文摘Seismic bearing capacity factors of a strip footing placed on soil slope were determined with both associated and nonassociated flow rules. Quasi-static representation of earthquake effects using a seismic coefficient concept was adopted for seismic bearing capacity calculations. A multi-wedge translational failure mechanism was used to obtain the seismic bearing capacity factors for different seismic coefficients and various inclined angles. Employing the associated flow rule, numerical results were compared with the published solutions. For bearing capacity factors related to cohesion and equivalent surcharge load, the maximum difference approximates 0.1%. However, the difference of bearing capacity factor related to unit weight is larger. With the two flow rules, the seismic bearing capacity factors were presented in the form of design charts for practical use. The results show that seismic bearing capacity factors related to the cohesion, the equivalent surcharge load and the unit weight increase greatly as the dilatancy angle increases, and that the nonassociated flow rule has important influences on the seismic bearing capacity.
文摘The coexistence between Bluetooth system and IEEE 802.11 frequency hoppingspread spectrum (FHSS) equipment is analyzed. Based on the capacity formulae and system simulation,the inter-affection between these networks is compared. A fragment adaptive solution of packetpayload length is presented, which can be used to improve the capacity reduction of IEEE 802.11 FHSSnetwork. Analysis results show that the IEEE 802.11 WLAN standard with its inherent mechanismsupports this fragment length adaptive algorithm. With the increasing of Bluetooth interferingnetworks, this adaptive solution can effectively relieve capacity decreasing of IEEE 802.11 FHSSnetwork. The capacity analysis method and adaptive algorithm adopted in this paper can also begeneralized into other FHSS networks.
基金the National Science Foundation of China,the Hi-Tech Research and Development Program of China of Mobile Internet
文摘In this paper,we discuss in detail the basic issue of green design and consider an energy efficiency function as the metric to evaluate green cellular networks.Specifically,we investigate the transmit power required for an expected transmission capacity and propose a capacity-power formula based on the energy conservation and the Shannon capacity theorem.Two novel definitions of cell interference depth and handoff dynamic model are introduced and the corresponding expression of energy efficiency function is derived.Numerical results show that the energy efficiency function is closely correlated with the transmitted/received power required and the cell radius.Our work provides a useful basis for research and evaluation on green design and technology of cellular networks.
文摘Al specimens were covered with TiO2 film by sol-gel dip-coating and then anodized in ammonium adipate solution.The structure,composition and capacitance properties of the anodic oxide film were investigated by transmission electron microscopy (TEM),Auger electron spectroscopy (AES),X-ray diffractometry (XRD) and electrochemical impedance spectroscopy (EIS).It was found that an anodic oxide film with a dual-layer structure formed between TiO2 coating and Al substrate.The film consisted of an inner Al2O3 layer and an outer Ti-Al composite oxide layer.The thickness of layers varied with the number of times of sol-gel dip-coating.The capacitance of anodic oxide films formed on coated specimens was at most 80% higher than that without TiO2.In film formation mechanism,it was claimed that the formation of composite oxide film was mainly affected by the structure of micro-pores network in TiO2 coating which had an influence on Al3+ and O2? ions transport during the anodizing.
基金National Natural Science Foundation of China under Grant Nos.10574047 and 20490210
文摘On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the quasione-dimensional interehain coupling organic ferromagnets are presented. We find that an obvious feature is to present itself the round peak for the specific heat with the temperature. This indicates unambiguously the presence of the phase transition in the system. The transition temperature plays down with increasing of the interchain coupling t2 or decreasing of the electron repulsion u. The curves of charge density with the temperature debase monotonously. This result illustrates that the higher the temperature is, the more electrons are excited.