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通过宽线固体核磁共振氢谱研究半晶高分子的相结构 被引量:4
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作者 吴金泽 辛家祥 +1 位作者 付晓彬 姚叶锋 《波谱学杂志》 CAS 北大核心 2019年第1期23-33,共11页
宽线固体核磁共振氢谱(~1H NMR)是一种研究半晶高分子相结构的经典方法.本文以半晶聚乙烯的宽线固体~1H NMR谱为例,探讨了通过Gaussian/Sinc、Gaussian和Lorentzian函数组合对宽线固体~1H NMR谱图进行拟合的方案,并根据半晶聚乙烯的相... 宽线固体核磁共振氢谱(~1H NMR)是一种研究半晶高分子相结构的经典方法.本文以半晶聚乙烯的宽线固体~1H NMR谱为例,探讨了通过Gaussian/Sinc、Gaussian和Lorentzian函数组合对宽线固体~1H NMR谱图进行拟合的方案,并根据半晶聚乙烯的相结构成分对拟合得到的各信号成分进行归属.并在此基础上探讨了各个相结构中分子链运动与信号线型的相关性,以及利用宽线固体~1H NMR谱测量半晶高分子结晶度存在的困难. 展开更多
关键词 线固体核磁共振氢谱 半晶高分子 相结构 界面 分子链运动
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铁磁和反铁磁双层膜中铁磁共振的研究 被引量:5
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作者 周岚 朱蜀梅 《原子与分子物理学报》 CAS CSCD 北大核心 2003年第3期398-402,共5页
采用微磁学理论研究了铁磁 /反铁磁双层膜中的铁磁共振现象。本模型将铁磁薄层抽象为一个单晶 ,具有立方磁晶各向异性和单轴磁晶各向异性 ,而反铁磁层视为厚度趋近于半无穷 ,且只有单轴磁晶各向异性。推导出了该系统的铁磁共振频率和频... 采用微磁学理论研究了铁磁 /反铁磁双层膜中的铁磁共振现象。本模型将铁磁薄层抽象为一个单晶 ,具有立方磁晶各向异性和单轴磁晶各向异性 ,而反铁磁层视为厚度趋近于半无穷 ,且只有单轴磁晶各向异性。推导出了该系统的铁磁共振频率和频率谱宽度的解析式。数值计算表明 ,铁磁共振模式分两支 ,取决于立方磁晶各向异性。而界面的交换耦合 。 展开更多
关键词 铁磁/反铁磁双层膜 交换耦合 铁磁共振 共振
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基于非谐振线圈的磁共振接收前端设计与实现
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作者 巨磊 徐俊成 +2 位作者 沈明 宋一桥 蒋瑜 《信息技术》 2019年第10期41-46,50,共7页
文中介绍了一种基于非谐振线圈的磁共振接收前端的设计原理和电路实现,将商用谱仪上的多通道谐振探头改造为非谐振线圈结构,并设计了一款与非谐振线圈匹配的低噪声放大器(Low Noise Amplifier,LNA),不但能够较好地放大非谐振线圈接收的... 文中介绍了一种基于非谐振线圈的磁共振接收前端的设计原理和电路实现,将商用谱仪上的多通道谐振探头改造为非谐振线圈结构,并设计了一款与非谐振线圈匹配的低噪声放大器(Low Noise Amplifier,LNA),不但能够较好地放大非谐振线圈接收的信号,还可以与后级的商用谱仪系统匹配使用,将信号传输到控制台进行数字化处理。在商用300MHz Bruker AVANCE III谱仪上,通过接收前端成功探测到了重水样品的NMR(Nuclear Magnetic Resonance)信号,与谐振电路相比,文中接收前端具有无需重新调谐的优势,实验结果初步验证了该接收前端宽频探测的可行性。 展开更多
关键词 液体磁共振 频磁共振谱仪器 非谐振线圈 低噪声放大器
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在新星环境下^(33)S(P,γ)^(34)Cl的热核反应率
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作者 隆建宏 张洁 罗志全 《西华师范大学学报(自然科学版)》 2011年第1期23-26,共4页
基于新测出的34Cl核共振能级的核物理信息,本文分析了在新星环境下33S(P,γ)34Cl的热核反应.本工作中同时考虑了非共振、共振两翼和窄共振对热核反应率的贡献,新星环境下33S(P,γ)34Cl的热核反应率的较统计模型给出的结果明显减少,最多... 基于新测出的34Cl核共振能级的核物理信息,本文分析了在新星环境下33S(P,γ)34Cl的热核反应.本工作中同时考虑了非共振、共振两翼和窄共振对热核反应率的贡献,新星环境下33S(P,γ)34Cl的热核反应率的较统计模型给出的结果明显减少,最多可下降约25%.结果可能影响到对新星抛射物中S同位素比率的预测(例如32S/33S),而这个比率可能会被用作新星前身星的一个诊断工具. 展开更多
关键词 共振 共振 宽共振 热核反应率
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Theoretical Research on Scattering Resonance States of Reaction I+HI(v=O)→IH(v'=0)+I: Partial Potential Energy Surface and One-dimensional Quantum Reactive Scattering Calculation
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作者 Hua-yang Wang Xiao-min Sun +1 位作者 Zheng-ting Cai Da-cheng Feng 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 北大核心 2006年第5期411-415,共5页
Based on the vibrational potential curves coupled with the minimum energy reaction path, the partial potential energy surface of the reaction I+HI→IH+I was constructed at the QCISD(T)//MP4SDQ level with pseudo po... Based on the vibrational potential curves coupled with the minimum energy reaction path, the partial potential energy surface of the reaction I+HI→IH+I was constructed at the QCISD(T)//MP4SDQ level with pseudo potential method. And the formation mechanism of the scattering resonance states of this reaction was well interpreted with the partial potential energy surface. The scattering resonance states of this reaction should belong to Feshbach resonance because of the coupling of the vibrational mode and the translational mode. With the one-dimensional square potential well model, the resonance width and lifetime of the I+HI(v=0)→IH(v'=0)+I state-to-state reaction were calculated, which preferably explained the high-resolved threshold photodetachment spectroscopy of the IHI- anion performed by Neumark et al.. 展开更多
关键词 Partial potential energy surface Scattering resonance states Scattering resonance width and lifetime One-dimensional square potential well model
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基于共振隧穿理论的GaAs基RTD的设计与研制 被引量:4
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作者 武一宾 杨瑞霞 +5 位作者 杨克武 商耀辉 卜夏正 牛晨亮 赵辉 王建峰 《光电子.激光》 EI CAS CSCD 北大核心 2011年第2期189-192,共4页
以共振能级的透射系数半峰宽(FWHM)做为共振隧穿二极管(RTD)材料结构设计的依据,对GaAs/A-lAs/In0.1Ga0.9As材料体系的RTD进行了设计。用分子束外延(MBE)进行了RTD结构材料制备,X射线双晶衍射(XRD)分析表明,制备的异质结界面光滑、层厚... 以共振能级的透射系数半峰宽(FWHM)做为共振隧穿二极管(RTD)材料结构设计的依据,对GaAs/A-lAs/In0.1Ga0.9As材料体系的RTD进行了设计。用分子束外延(MBE)进行了RTD结构材料制备,X射线双晶衍射(XRD)分析表明,制备的异质结界面光滑、层厚准确。RTD采用台面结构,器件特性测试结果表明,峰值电流密度为112 kA/cm2时,电流峰-谷比达到8.25。 展开更多
关键词 共振隧穿二极管(RTD) 电流峰-谷比 分子束外延(MBE) 峰电流密度 共振能级的透射系数半峰(HWHM)
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基于圆柱定程干涉法测量气体黏度的探索 被引量:3
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作者 安保林 林鸿 +1 位作者 刘强 段远源 《物理学报》 SCIE EI CAS CSCD 北大核心 2013年第17期305-309,共5页
黏度是流体的重要输运性质,实验测量是获取黏度数据的基本手段.圆柱定程干涉法是目前测量气相声速最精确的方法之一,其测量参数为工质的声学共振频率和共振峰半宽.共鸣腔中气相工质的黏性会导致共振频率的偏移和共振峰半宽的增加,是声... 黏度是流体的重要输运性质,实验测量是获取黏度数据的基本手段.圆柱定程干涉法是目前测量气相声速最精确的方法之一,其测量参数为工质的声学共振频率和共振峰半宽.共鸣腔中气相工质的黏性会导致共振频率的偏移和共振峰半宽的增加,是声速测量中的重要非理想影响因素.但通过对共振频率和共振峰半宽的精确测定,并结合热边界层、进气导管、声学传感器及壳体振动等其他非理想因素的修正,可以精确反推获得黏度.本文从理论上探讨了应用圆柱定程干涉法测量共振频率或者共振峰半宽来得到黏度的新方法,以氩(Ar)为例进行了实验验证,测量结果与文献值具有较好一致性,证实了方法的可行性. 展开更多
关键词 黏度 圆柱共鸣腔 共振频率 共振峰半
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过程e~+e~-→J/ψ→V+X(J^(PC)),X→3P的矩分析
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作者 张霖 郁宏 沈齐兴 《高能物理与核物理》 CSCD 北大核心 1995年第9期800-811,共12页
用推广的矩分析方法对过程e+e-→J/ψ→V+X(JPC),X(JPC)→3P进行了研究,着重讨论了多态耦合的共振峰复杂结构,并由此得到了一些矩的关系式.利用这些关系式,可以通过对实验数据的分析来确定宽共振峰的耦合模... 用推广的矩分析方法对过程e+e-→J/ψ→V+X(JPC),X(JPC)→3P进行了研究,着重讨论了多态耦合的共振峰复杂结构,并由此得到了一些矩的关系式.利用这些关系式,可以通过对实验数据的分析来确定宽共振峰的耦合模式,进而确定它们的质量,宽度,自旋等重要性质。 展开更多
关键词 矩分析 自旋 宇称 宽共振
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Electronic Structure of Helium Atom in a Quantum Dot
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作者 Jayanta K.Saha S.Bhattacharyya T.K.Mukherjee 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第3期347-353,共7页
Bound and resonance states of helium atom have been investigated inside a quantum dot by using explicitly correlated Hylleraas type basis set within the framework of stabilization method.To be specific,precise energy ... Bound and resonance states of helium atom have been investigated inside a quantum dot by using explicitly correlated Hylleraas type basis set within the framework of stabilization method.To be specific,precise energy eigenvalues of bound 1sns(~1S^e)(n=1-6)states and the resonance parameters i.e.positions and widths of^lS^e states due to 2sns(n=2-5)and 2pnp(n=2-5)configurations of confined helium below N=2 ionization threshold of He^+have been estimated.The two-parameter(Depth and Width)finite oscillator potential is used to represent the confining potential due to the quantum dot.It has been explicitly demonstrated that the electronic structural properties become sensitive functions of the dot size.It is observed from the calculations of ionization potential that the stability of an impurity ion within a quantum dot may be manipulated by varying the confinement parameters.A possibility of controlling the autoionization lifetime of doubly excited states of two-electron ions by tuning the width of the quantum cavity is also discussed here. 展开更多
关键词 helium atom variational method quantum dot CORRELATION
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Line-profile analysis of excitation spectroscopy in the even 4p^5(~2P_(1/2))nl′ [K′]_J(l′=1,3) autoionizing resonances of Kr
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作者 LI ChunYan WANG TingTing +1 位作者 ZHEN JunFeng CHEN Yang 《Science China Chemistry》 SCIE EI CAS 2013年第11期1623-1632,共10页
The even-parity autoionizing resonance series 4p^5np' [3/2] 1,2, [ 1/2] 1, and 4p^2nf' [5/213 of krytpon have been investigated by laser excitation from the two metastable states 4p55s [3/2]2 and 4p^55s' [1/2]0 in ... The even-parity autoionizing resonance series 4p^5np' [3/2] 1,2, [ 1/2] 1, and 4p^2nf' [5/213 of krytpon have been investigated by laser excitation from the two metastable states 4p55s [3/2]2 and 4p^55s' [1/2]0 in the photon energy region of 2900(P40000 cm^-1 at experimental bandwidth of -0.1 cm-1. The excitation spectra of the even-parity autoionizing resonance series, most of which are experimentally studied for the first time in this work, show typical asymmetric line shapes. Complementary information on level energies, quantum defects, line profile indices and resonance widths, resonance lifetimes and reduced widths of the auto- ionizing resonances are derived by Fano-type line-shape analyses of the experimental results. Results from this work indicate that the line profile index (q) and the resonance width (F) are approximately proportional to the effective principal quantum number (n*); the line separation of the 4p^5np' autoionizing resonances is also in good agreement with theoretical model 展开更多
关键词 krypton (Kr) autoionizing resonances Fano-type lineshape
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Understanding the structure of d~*(2380) in chiral quark model
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作者 Fei Huang Peng Nian Shen +1 位作者 Yu Bing Dong Zong Ye Zhang 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS CSCD 2016年第2期40-48,共9页
The structure and decay properties of d* have been detailedly investigated in both the chiral SU(3) quark model and the extended chiral SU(3) quark model that describe the energies of baryon ground states and the... The structure and decay properties of d* have been detailedly investigated in both the chiral SU(3) quark model and the extended chiral SU(3) quark model that describe the energies of baryon ground states and the nucleon-nucleon (NN) scattering data satisfactorily. By performing a dynamical coupled-channels study of the system of △△ and hidden-color channel (CC) with quantum numbers l(JP) = 0(3^+) in the framework of the resonating group method (RGM), we find that the d* has a mass of about 2.38-2.42 GeV and a root-mean-square radius (RMS) of about 0.76-0.88 fm. The channel wave function is extracted by a projection of the RGM wave function onto the physical basis, and the fraction of CC component in the d* is found to be about 66%-68%, which indicates that the d* is a hexaquark-dominated exotic state. Based on this scenario the partial decay widths of d* → dπ^0π^0 and d* → dn^+n^- are further explicitly evaluated and the total width is then obtained by use of the branching ratios extracted from the measured cross sections of other possible decay channels. Both the mass and the decay width of d* calculated in this work are compatible with the data (M ≈ 2380 MeV, F ≈ 70 MeV) reported by WASA-at-COSY Collaboration. 展开更多
关键词 hexaquark state d*(2380) quark model hidden-color channel
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