Chlorine dioxide （OC10） is an important indicator for Cl-activation. The monitoring of OC10 appears to be crucial for understanding the chemistry of Cl-initialed oxidation and its impact on air quality in polluted c...Chlorine dioxide （OC10） is an important indicator for Cl-activation. The monitoring of OC10 appears to be crucial for understanding the chemistry of Cl-initialed oxidation and its impact on air quality in polluted coastal regions and industrialized areas. We report the development of a Xe arc lamp based near-ultraviolet （335-375 nm） incoherent broad- band cavity enhanced absorption spectroscopy （IBBCEAS） spectrometer for quantitative assessment of OC10 in an atmospheric simulation chamber. The important intermediate compound CH20, and other key atmospheric trace species （NO2） were also simultaneously measured. The instrumental performance shows a strong potential of this kind of IBBCEAS instrument for field and laboratory studies of atmospheric halogen chemistry.展开更多
Using a low coherence interferometry （LCI） model, a comparison of broadband single-Gaussian and multi-Gaussian light sources has been undertaken. For single-Gaussian sources, the axial resolution improves with the s...Using a low coherence interferometry （LCI） model, a comparison of broadband single-Gaussian and multi-Gaussian light sources has been undertaken. For single-Gaussian sources, the axial resolution improves with the source bandwidth, confirming the coherence length relation that the resolution for single Gaussian sources improves with increasing spectral bandwidth. However, narrow bandwidth light sources result in interferograms with overlapping strata peaks and the loss of individual strata information. For multiple-Gaussian sources with the same bandwidth, spectral side lobes increase, reducing A-scan reliability to show accurate layer information without eliminating the side lobes. The simulations show the conditions needed for the resolution of strata information for broadband light sources using both single and multiple Gaussian models. The potential to use the model to study optical coherence tomography （OCT） light sources including super luminescent diodes （SLDs）, as reviewed in this paper, as well as optical delay lines and sample structures could better characterize these LCI and OCT elements. Forecasting misinformation in the interferogram may allow preliminary corrections. With improvement to the LCI-OCT model, more applications are envisaged.展开更多
基金This work was supported by the National Natural Science Foundation of China （No.41005017）, the Instrument Developing Project of the Chinese Academy of Sciences （No.YZ201121）, Jiangsu Provincial Natural Science Foundation of China （No.BK2011829）, and the Open Research Fund of Key Laboratory of Atmospheric Composition and Optical Radiation. The support of the Groupement de Recherche International SAMIA between CNRS （National Center for Scientific Research, France）, RFBR （Russian Foundation for Basic Research, Russia）, and CAS （Chinese Academy of Sciences, China） is acknowledged. We thank Dr. Albert A. Ruth at university college cork for the helpful discussion on the Xe lamp source based IBBCEAS.
文摘Chlorine dioxide （OC10） is an important indicator for Cl-activation. The monitoring of OC10 appears to be crucial for understanding the chemistry of Cl-initialed oxidation and its impact on air quality in polluted coastal regions and industrialized areas. We report the development of a Xe arc lamp based near-ultraviolet （335-375 nm） incoherent broad- band cavity enhanced absorption spectroscopy （IBBCEAS） spectrometer for quantitative assessment of OC10 in an atmospheric simulation chamber. The important intermediate compound CH20, and other key atmospheric trace species （NO2） were also simultaneously measured. The instrumental performance shows a strong potential of this kind of IBBCEAS instrument for field and laboratory studies of atmospheric halogen chemistry.
文摘Using a low coherence interferometry （LCI） model, a comparison of broadband single-Gaussian and multi-Gaussian light sources has been undertaken. For single-Gaussian sources, the axial resolution improves with the source bandwidth, confirming the coherence length relation that the resolution for single Gaussian sources improves with increasing spectral bandwidth. However, narrow bandwidth light sources result in interferograms with overlapping strata peaks and the loss of individual strata information. For multiple-Gaussian sources with the same bandwidth, spectral side lobes increase, reducing A-scan reliability to show accurate layer information without eliminating the side lobes. The simulations show the conditions needed for the resolution of strata information for broadband light sources using both single and multiple Gaussian models. The potential to use the model to study optical coherence tomography （OCT） light sources including super luminescent diodes （SLDs）, as reviewed in this paper, as well as optical delay lines and sample structures could better characterize these LCI and OCT elements. Forecasting misinformation in the interferogram may allow preliminary corrections. With improvement to the LCI-OCT model, more applications are envisaged.
