The solubility, metastable zone width, and induction time of analgin for unseeded batch cooling crystallization in ethanol–aqueous system were experimentally determined. The solubility data could be well described by...The solubility, metastable zone width, and induction time of analgin for unseeded batch cooling crystallization in ethanol–aqueous system were experimentally determined. The solubility data could be well described by the van't Hoff equation model. The metastable zone width at various cooling rates was measured, and some parameters of nucleation kinetic were calculated using the Ny'vlt theory. Furthermore, the induction period of various temperatures and supersaturation ratios was also measured. According to classical nucleation theory, some nucleation parameters and interfacial energy was calculated through the induction time(t_(ind)) data. Homogeneous nucleation tended to occur when the supersaturation is high, whereas heterogeneous nucleation was more likely to occur when the supersaturation is low.展开更多
From an inelastic excitation and breakup experiment with a12Be beam at 29 MeV/u,a large4He+8He cluster decay width of 1.1(2)MeV is determined for a state at an excitation energy of 10.3 MeV and with a spin parity of 0...From an inelastic excitation and breakup experiment with a12Be beam at 29 MeV/u,a large4He+8He cluster decay width of 1.1(2)MeV is determined for a state at an excitation energy of 10.3 MeV and with a spin parity of 0+.By using the R-matrix analysis,a cluster spectroscopic factor of 0.53(10)is extracted from the cluster partial width,providing a strong support for the clustering structure in12Be.A specially designed zero-degree telescope played an essential role in the present experiment and has been demonstrated to be a promising tool in future studies of the molecular-like resonances near the cluster separation threshold.展开更多
基金Supported by the National Natural Science Foundation of China(21206109)China Ministry of Science and Major National Scientific Instrument Development Project(21527812)
文摘The solubility, metastable zone width, and induction time of analgin for unseeded batch cooling crystallization in ethanol–aqueous system were experimentally determined. The solubility data could be well described by the van't Hoff equation model. The metastable zone width at various cooling rates was measured, and some parameters of nucleation kinetic were calculated using the Ny'vlt theory. Furthermore, the induction period of various temperatures and supersaturation ratios was also measured. According to classical nucleation theory, some nucleation parameters and interfacial energy was calculated through the induction time(t_(ind)) data. Homogeneous nucleation tended to occur when the supersaturation is high, whereas heterogeneous nucleation was more likely to occur when the supersaturation is low.
基金supported by the National Basic Research Program of China(Grant No.2013CB834402)the National Natural Science Foundation of China(Grant Nos.11035001,11275011,11235001,11320101004 andJ1103206)
文摘From an inelastic excitation and breakup experiment with a12Be beam at 29 MeV/u,a large4He+8He cluster decay width of 1.1(2)MeV is determined for a state at an excitation energy of 10.3 MeV and with a spin parity of 0+.By using the R-matrix analysis,a cluster spectroscopic factor of 0.53(10)is extracted from the cluster partial width,providing a strong support for the clustering structure in12Be.A specially designed zero-degree telescope played an essential role in the present experiment and has been demonstrated to be a promising tool in future studies of the molecular-like resonances near the cluster separation threshold.
