流动液体密度粘度连续测量方案——压差式密度粘度测量系统

提出一种利用压差测量液体密度和粘度的方法。其原理是 :利用压力传感器采集系统(例如管道 )内部两个压力差值 ,将其转变为电信号后输入数据处理系统 ,经过运算求解并记录流动液体的密度和粘度。该方法具有测量范围宽 ,测量精度高的特点 ,可以对管道内流动液体的流变参数进行连续。

新型运动粘度/密度仪SVM3000在润滑油分析中的应用

利用新型运动粘度/密度仪SVM3000对润滑油的基本物理性质进行测试。本文介绍该仪器的基本原理和主要功能,并以试验数据为基础,验证该仪器性能的可靠性。

基于NIR凤香型基酒密度和粘度的建模研究

建立一种凤香型基酒密度和粘度指标的快速分析模型,以期为基酒真实性判别提供一种方法参考。利用近红外光谱技术对样品进行光谱扫描,并结合常规分析方法,通过相关建模软件和算法最终建立了其定量分析模型。结果表明,所建模型的线性关系较好,且各模型内部参数RMSEC和RMSECV值均较小,说明模型的质量较好;另取验证样品对模型进行外部验证,通过与常规分析方法的检测结果进行比较,各模型预测的平均相对误差均小于0.2%,同时两种方法的检测值之间均不存在显著性差异(P>0.05),说明模型具有较好的预测能力。

基于嵌入式系统的油液粘度密度检测系统设计与实现

针对传统油液粘度密度检测方法存在检测准确率低,导致检测油品检测效果不佳的问题,以石英音叉传感器为研究对象,设计一个基于嵌入式系统的油液粘度密度检测系统。首先,对油液粘度密度检测系统进行整体设计;然后分别采用微控制器、阻抗转换器和继电器等数字芯片进行检测系统硬件电路设计;最后将石英音叉传感器应用到油液粘度密度检测中,采用图像化编程软件实现检测系统的上位机界面设计,由此实现油液粘度密度检测结果展示。系统测试表明,粘度范围在(0~16)cP时,系统测量相对误差控制在5.18%~5.64%范围内;当密度范围为(820~950)kg/m~3时,系统测量相对误差范围为5.93%~6.55%。由此分析可知,设计的系统进行油液粘度密度的检测精度较高,可取得较好的检测结果,系统具备一定的有效性。

Densities and Viscosities of the Ionic Liquid [C4mim][PF6]＋ N,N-dimethylformamide Binary Mixtures at 293.15 K to 318.15 K

Viscosities and densities for 1-butyl-3-methylimidazolium hexafluorophosphate （[C4mim][PF6]） and N, N-dimethylformamide （DMF） binary mixtures have been measured at the temperature range from 293.15 K to 318.15 K. It is shown that the viscosities and densities decrease monotonously with temperature and the content of DMF. Various correlation methods including Arrhenius-like equation, Sedclon et al.＇s equation, Redlich-Kister equation with four parameters, and other empirical equations were applied to evaluate these experimental data. A model based on an equation of state Ior estimating the viscosity of mixtures containing ionic liquids were proposed by coupling with the excess Gibbs free energy model of viscosity, which can synchronously calculate the viscosity and the molar volume. The results show that the model gives a deviation of 8.29% for the viscosity, and a deviation of 1.05% for the molar volume when only one temperature-independent adjustable parameter is adopted. The correlation accuracy is further improved when two parameters or one temperature-dependent parameter is used.

Measurement of thermal conductivity,viscosity and density of ionic liquid [EMIM][DEP]-based nanofluids

This article studied experimentally the effect of multi-wall carbon nanotubes （MWCNTs） on the thermo physical properties of ionic liquid-based nanofluids. The nanofluids were composed of ionic liquid, 1-ethyl-3- methylimidazolium diethylphosphate [EMIM][DEP], or its aqueous solution[EMIM][DEP]（1） ＋ H20（2） and MWCNTs without any surfactants. The thermal conductivity, viscosity and density of the nanofluids were mea- sured experimentally. The effects of the mass fraction of MWCNTs, temperature and the mole fraction of water on the thermo physical properties of nanofluids were studied. Results show that the thermal conductivity of nanofluids increases within the range of 1.3%-9.7% compared to their base liquids, and have a well linear depen- dence on temperature. The viscosity and density of the nanofluids exhibit a remarkable increase compared with those of the base liquids. Finally, the correlation of the effective thermal conductivity and viscosity of the nanofluids was made using the models in the literatures.

Density, Viscosity, and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether ＋ Water from 293.15 to 333.15 K at Atmospheric Pressure

Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylerie glycol monoethyl ether [CH3CH2O（CH2）2O（CH2）2OH] ＋ water from 293.15 to 333.15 K at atmospheric pressure, with a capillary pycnometer and Ubbelohde capillary viscometer respectively. From the experimental data, the excess molar volume V^E, viscosity deviation △η, and the excess energy of activation for viscous flow △G^＊E were calculated. These data were correlated by the Redlich-Kister type equations to obtain the coefficients and standard deviations. The results showed a strong molecular interaction between diethylene glycol monoethyl ether and water.

Densities, conductivities, and viscosities of aqueous solutions of N-hexyl,methylpyrrolidinium bromide and N-butyl, methylpyrrolidinium bromide at different temperatures

The densities, conductivities, and viscosities were measured for ternary solutions of N-hexyl,methylpyrrolidinium bromide([PP1,6]Br)- N-butyl,methylpyrrolidinium bromide([PP1,4]Br)-H2 O and its binary subsystems [PP1,6]Br-H2 O and [PP1,4]Br-H2 O at(298.15, 303.15, 308.15, and 313.15) K, respectively. The results were used to test the predictability of the simple equations established for the prediction of density, conductivity,and viscosity of the mixed electrolyte solutions. The results show that the examined simple equations can offer good predictions for density, conductivity, and viscosity of the mixed ionic liquid solutions in terms of the corresponding properties of its binary subsystems of equal ionic strength.

Densities, Viscosities and Related Properties for Binary Mixtures of Sulfolane + p-Xylene, Sulfolane + Ethylbenzene in the Temperature Range from 303.15K to 353.15K

Densities and viscosities of the binary systems of sulfolane + ethylbenzene, sulfolane + p-xylene have been experimentally determined in temperature interval 303.15-353.15 K and at atmospheric pressure for the whole composition range. The excess molar volumes and viscosity deviations were computed. The computed quantities have been fitted to Redlich-Kister equation. Excess molar volumes and viscosity deviation show a systematic change with increasing temperature. Two mixtures exhibit negative excess volumes with a minimum which occurs approximately at x = 0.5. The effect of the size, shape and interaction of components on excess molar volumes and viscosity deviations is discussed.

Asymptotic Lifshitz-Like Solution in Lovelock Gravity (n=3)

With R^2 and R^3 corrections to asymptotical Lifshitz space-time, we obtain pure Lovelock gravity solution and solution with non-trivial matter in 7-dimensional space-time. Then we obtain the general solution for any arbitrary dimensional space. In this paper, we also study black brane solutions in 7-dimensionai Lifshitz space-time via the method of perturbation. And we popularize the black brane solution to arbitrary higher dimensions and discuss the ratio of shear viscosity to entropy density ratio η/s. Then we analyze the result of η/s to find that the correction of n-th （n ≥ 3） order Lovelock term has trivial influence to η/s.

Excess Molar Volumes and Viscosities of Binary Mixture of Diethyl Carbonate+Ethanol at Different Temperatures

The purpose of this work was to report excess molar volumes and dynamic viscosities of the binary mixture of diethyl carbonate （DEC）+ethanol. Densities and viscosities of the binary mixture of DEC+ethanol at temperatures 293.15 K—343.15 K and atmospheric pressure were determined over the entire composition range. Densities of the binary mixture of DEC+ethanol were measured by using a vibrating U-shaped sample tube densimeter. Viscosities were determined by using Ubbelohde suspended-level viscometer. Densities are accurate to 1.0×10-5 g·cm-3, and viscosities are reproducible within ±0.003 mPa·s. From these data, excess molar volumes and deviations in viscosity were calculated. Positive excess molar volumes and negative deviations in viscosity for DEC+ethanol system are due to the strong specific interactions.All excess molar vo-（lumes） and deviations in viscosity fit to the Redlich-Kister polynomial equation.The fitting parameters were presented,and the average deviations and standard deviations were also calculated.The errors of correlation are very small.It proves that it is valuable for estimating densities and viscosities of the binary mixture by the correlated equation.

Non-formation of vacuum states for Navier-Stokes equations with density-dependent viscosity

We consider the Cauchy problem, free boundary problem and piston problem for one-dimensional compressible Navier-Stokes equations with density-dependent viscosity. Using the reduction to absurdity method, we prove that the weak solutions to these systems do not exhibit vacuum states, provided that no vacuum states are present initially. The essential re- quirements on the solutions are that the mass and energy of the fluid are locally integrable at each time, and the Lloc1-norm of the velocity gradient is locally integrable in time.

Intradiffusion, density and viscosity studies in binary liquid systems of acetylacetone + DMF/DMSO/benzene at 303.15 K and 333.15 K

Intradiffusion coefficients of acetylacetone(AcAc) and DMF/DMSO/benzene in binary systems over the entire concentration range at 303.15 K were determined by 1H diffusion-order spectroscopy(DOSY) nuclear magnetic resonance(NMR) method based pulse field gradient(PFG).The densities and viscosities of the above three binary systems at 303.15 K were also studied and employed to calculate the excess molar volumes(V^E) and deviations in viscosity(△η).Besides,experiments were carried out at 333.15 K for the system of AcAc+DMF.The solvent and temperature effect upon the difference in D between enol and keto tautomers,the tautomeric equilibrium and excess properties(V^E and △η) were discussed as well.Isotherms of V^E as a function of mole fraction of AcAc(χ_1) show positive deviations in benzene but negative deviations in DMF and DMSO,whereas isotherms of △ηas a function of χ_1 record positive deviations in DMF but negative in benzene and DMSO.V^E values show more negative and △η values are less positive in the system of AcAc+DMF at 333.15 K compared to 303.15 K.The V^E and △η were fitted to a Redlich-Kister type equation and the measured results were interpreted concerning molecular interactions in the solutions.

Moving least squares-based multi-functional sensing technique for estimating viscosity and density of ternary solution

In the osmotic dehydration process of food,on-line estimation of concentrations of two components in ternary solution with NaCl and sucrose was performed based on multi-functional sensing technique.Moving Least Squares were adopted in approximation procedure to estimate the viscosity of such interested ternary solution with the given data set.As a result,in one mode of using total experimental data as calibration data and validation data,the relative deviations of estimated viscosities are less than ±1.24%.In the other mode,by taking total experimental data except the ones for estimation as calibration data,the relative deviations are less than ±3.47%.In the same way,the density of ternary solution can be also estimated with deviations less than ± 0.11% and ± 0.30% respectively in these two models.The satisfactory and accurate results show the extraordinary efficiency of Moving Least Squares behaved in signal approximation for multi-functional sensors.

Bubble size as a function of some situational variables in mechanical flotation machines

The specific results of the work investigating the effect of gas density and water temperature on bubble size were present.These were surrogate variables designed to investigate the effect of viscosity(varying water temperature) and altitude(varying gas density).The results show that there is a measurable but relatively small effect of gas density on bubble size.The D32 is revealed to increase proportionally as(ρ0/ρg)0.132.The projected impact on flotation kinetics at 4500 m versus sea level is small,of the order of 0.5% recovery loss for a bank of eight flotation cells.The effect of water temperature(4-40 °C) on bubble size is more significant than gas density.The relationship correlates with water viscosity values quite closely.A finding that D32 increases proportionally as(μ/μ20)0.776 highlights the importance of accounting for viscosity effects if,for example,large process temperature fluctuations or deviation from design/test conditions are expected.

Densities and viscosities of binary mixtures of n-decane + 1-pentanol,+1-hexanol,+1-heptanol at temperatures from 293.15 to 363.15 K and atmospheric pressure

Densities(ρ) and dynamic viscosities(η) for three binary mixtures of n-decane with 1-pentanol,1-hexanol and1-heptanol are presented at temperatures from 293.15 to 363.15 K and atmospheric pressure over the entire composition range.The density and viscosity are measured using a vibrating tube densimeter and a cylindrical Couette type rotating viscometer,respectively.Excess molar volumes(V^E),viscosity deviations(△η) and excess Gibbs energy of activation of viscous flow(△G^(*E)) are calculated from the experimental measurements.Intermolecular and structural interactions are indicated by the sign and magnitude of these properties.Partial molar volumes and infinity dilution molar partial volumes are also calculated for each binary system.These results are correlated using Redlich-Kister type equations.

First principles calculation on electronic structure,chemical bonding,elastic and optical properties of novel tungsten triboride

The electronic structures,chemical bonding,elastic and optical properties of the novel hP24 phase WB3 were investigated by using density-functional theory(DFT) within generalized gradient approximation(GGA).The calculated energy band structures show that the hP24 phase WB3 is metallic material.The density of state(DOS) and the partial density of state(PDOS) calculations show that the DOS near the Fermi level is mainly from the W 5d and B 2p states.Population analysis suggests that the chemical bonding in hP24-WB3 has predominantly covalent characteristics with mixed covalent-ionic characteristics.Basic physical properties,such as lattice constant,bulk modulus,shear modulus and elastic constants Cij were calculated.The elastic modulus E and Poisson ratio υ were also predicted.The results show that hP24-WB3 phase is mechanically stable and behaves in a brittle manner.Detailed analysis of all optical functions reveals that WB3 is a better dielectric material,and reflectivity spectra show that WB3 can be promised as good coating material in the energy regions of 8.5-11.4 eV and 14.5-15.5 eV.

Theoretical predictions of viscosity of methane under confined conditions

Density functional theory has been confirmed as a reliable approach in the descriptions of inhomogeneous fluids.By integrating the density functional theory into the revised local average density model, a theoretical approach is constructed to investigate the local shear viscosity in the confined conditions. In the density functional theory,the weighted density approximation for attractive part and the modified fundamental measure theory for repulsion contribution are adopted to accurately describe the inhomogeneous systems. By comparing with simulation data, the theoretical model is tested. In this work, the shear viscosities of methane are calculated in different external fields(on a hard wall, a solvophobic wall and in slit pores with different widths). In addition, the effects of temperature on the local density and viscosity are also considered. It shows that the effect of temperature on the shear viscosity is more obvious on solid surfaces. The calculation provides an approach to determine the viscosity under confined conditions, which is extremely significant in real industrial applications.

Global Smooth Solutions to the 2-D Inhomogeneous Navier-Stokes Equations with Variable Viscosity

Under the assumptions that the initial density ρ0 is close enough to 1 and ρ0-1∈Hs+1(R2);u0∈Hs(R2)∩H_∈(R2) for s>2 and 0<ε<1;the authors prove the global existence and uniqueness of smooth solutions to the 2-D inhomogeneous Navier-Stokes equations with the viscous coefficient depending on the density of the fluid.Furthermore,the L2 decay rate of the velocity field is obtained.

Global well-posedness of 3-D density-dependent Navier-Stokes system with variable viscosity

Given initial data(ρ0, u0) satisfying 0 < m ρ0≤ M, ρ0- 1 ∈ L2∩˙W1,r(R3) and u0 ∈˙H-2δ∩ H1(R3) for δ∈ ]1/4, 1/2[ and r ∈ ]6, 3/1- 2δ[, we prove that: there exists a small positive constant ε1,which depends on the norm of the initial data, so that the 3-D incompressible inhomogeneous Navier-Stokes system with variable viscosity has a unique global strong solution(ρ, u) whenever‖ u0‖ L2 ‖▽u0 ‖L2 ≤ε1 and ‖μ(ρ0)- 1‖ L∞≤ε0 for some uniform small constant ε0. Furthermore, with smoother initial data and viscosity coefficient, we can prove the propagation of the regularities for such strong solution.