The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past...The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past decades,researchers have reported a number of hydrogen evolution reaction(HER)electrocatalysts with activity comparable to that of commercial Pt/C,but most of them are tested within a small current density range,typically no more than 500 mA cm^(-2).To realize the industrial application of hydrogen production from water electrolysis,it is essential to develop high-efficiency HER electrocatalysts at high current density(HCD≥500 mA cm^(-2)).Nevertheless,it remains challenging and significant to rational design HCD electrocatalysts for HER.In this paper,the design strategy of HCD electrocatalysts is discussed,and some HCD electrocatalysts for HER are reviewed in seven categories(alloy,metal oxide,metal hydroxide,metal sulfide/selenide,metal nitride,metal phosphide and other derived electrocatalysts).At the end of this article,we also pro-pose some viewpoints and prospects for the future development and research directions of HCD electrocatalysts for HER.展开更多
The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities.Within prefabricated building construction,...The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities.Within prefabricated building construction,this new heating method presents an opportunity for the development of comprehensive facilities.The parameters for evaluating the effectiveness of such a system are the upper surface layer’s heat flux and temperature.In this paper,thermal resistance analysis calculation based on a simplified model for this unique radiant heating system analysis is presented with the heat transfer mechanism’s evaluation.The results obtained from thermal resistance analysis calculation and numerical simulation indicate that the thermal resistance analysis method is highly accurate with temperature discrepancies ranging from 0.44℃ to−0.44℃ and a heat flux discrepancy of less than 7.54%,which can meet the requirements of practical engineering applications,suggesting a foundation for the prefabricated radiant heating system.展开更多
Cyanide-free silver electroplating was conducted in thiosulfate baths containing AgNO3 and AgBr major salts, respectively. The effects of major salt content and current density on surface quality, deposition rate and ...Cyanide-free silver electroplating was conducted in thiosulfate baths containing AgNO3 and AgBr major salts, respectively. The effects of major salt content and current density on surface quality, deposition rate and microhardness of Ag coatings were investigated. The optimized electroplating parameters were established. The adhesion strength of Ag coating on Cu substrate was evaluated and the grain size of Ag coating was measured under optimized electroplating parameters. The optimized AgNO3 content is 40 g/L with current density of 0.25 A/dm2. The deposited bright, smooth, and well adhered Ag coating had nanocrystalline grains with mean size of 35 nm. The optimized AgBr content was 30 g/L with current density of 0.20 A/dm2. The resultant Ag coating had nanocrystalline grains with mean size of 55 nm. Compared with the bath containing AgBr main salt, the bath containing AgNO3 main salt had a wider current density range, and corresponding Ag coating had a higher microhardness and a smaller grain size.展开更多
Plasma electrolytic oxidation (PEO) ceramic coatings were fabricated in a silicate-based electrolyte with the addition of potassium fluorozirconate (K2ZrF6) on 6063 aluminum alloy, and the effects of current density o...Plasma electrolytic oxidation (PEO) ceramic coatings were fabricated in a silicate-based electrolyte with the addition of potassium fluorozirconate (K2ZrF6) on 6063 aluminum alloy, and the effects of current density on microstructure and properties of the PEO coatings were studied. It was found that pore density of the coatings decreased with increasing the current density. The tribological and hardness tests suggested that the ceramic coating produced under the current density of 15 A/dm2showed the best mechanical property, which matched well with the phase analysis. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves proved that the coating obtained under 15 A/dm2 displayed the best anti-corrosion property, which was directly connected with morphologies of coatings.展开更多
A numerical model for bilayer organic light-emitting diodes (OLEDs) is developed under the basis of trapped charge limited conduction.The dependences of the current density on the layer thickness,trap properties and c...A numerical model for bilayer organic light-emitting diodes (OLEDs) is developed under the basis of trapped charge limited conduction.The dependences of the current density on the layer thickness,trap properties and carrier mobility of the hole transport layer (HTL) and emission layer (EML) in bilayer OLEDs of the structure anode/HTL/EML/cathode are numerically investigated.It is found that,for given values of the total thickness of organic layers,reduced depth of trap,total density of trap,and carrier mobility of HTL as well as EML,there exists an optimal thickness ratio of HTL to EML,by which a maximal quantum efficiency can be achieved.Through optimization of the thickness ratio,an enhancement of current density and quantum efficiency of as much as two orders of magnitude can be obtained.The dependences of the optimal thickness ratio to the characteristic trap energy,total density of trap and carrier mobility are numerically analyzed.展开更多
Radial variation in sap flux density (SFD) as a function of sapwood thickness is of importance in accurately estimating sap flux through sapwood area which, in turn, decides the precision of heat pulse application. Ho...Radial variation in sap flux density (SFD) as a function of sapwood thickness is of importance in accurately estimating sap flux through sapwood area which, in turn, decides the precision of heat pulse application. However, until now, only a few studies have evaluated the magnitude and significance of sampling errors associated with radial gradients in SFD, which were based on the small monitoring measurement data from a few trees. Based on one year of heat pulse observation of two 3 - 4 years old Eucalyptus urophylla S. T.,P Blake plantations in Leizhou Peninsula, Guangdong Province, China, a way of data processing was developed to treat with the lots of SFD data measured from 39 trees. It was found that the radial variation in SFD as a function of sapwood thickness in the two eucalyptus plantation sites could be expressed as y = 3. 667 5x(3) - 7.295 5x(2) + 3.682 6x + 0. 567 4 (R-2 = 0. 939 1, n = 80, P = 0.01), where y is the ratio of SFD of a sensor to the average of four data in different depths, x is the ratio of a sensor depth to tire radial sapwood thickness. It was the same (as in the following equation) in Jijia site, y = 5.006 2x(3) - 9.116 1x(2) + 4. 454 4x + 0.463 4 (R-2 = 0. 806 9, n = 72, P = 0.01) in Hetou site. From cambium to heartwood, SFD showed some increases at first and then decreases continuously. However, because die trees were very young, the maximum SFD was only 0. 33 - 0. 36 times more than the minimum.展开更多
Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the el...Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the electrochemical hydrogen storage properties of the alloys before and after heat treatment. The results show that the maximum discharge capacity of heat-treated Ti2?xMgxNi alloy can reach 275.3 mA·h/g, which is 100 mA·h/g higher than that of the amorphous Ti2?xMgxNi alloy. The heat-treated Ti1.9Mg0.1Ni alloy presents the best cycling stability with a high discharge capacity of 210 mA·h/g after 30 cycles. The results of LP and potential-step measurement of the Ti1.9Mg0.1Ni alloy show that the exchange current density increases from 101.1 to 203.3 mA/g and the hydrogen diffusion coefficient increases from 3.20×10?11 to 2.70×10?10 cm2/s after the heat treatment, indicating that the heat treatment facilitates both the charge-transfer and hydrogen diffusion processes, resulting in an improvement in electrochemical hydrogen storage properties of Ti2?xMgxNi (x=0?0.3) alloys.展开更多
文摘The electrolysis of water powered by renewable energy sources offers a promising method of"green hydrogen"production,which is considered to be at the heart of future carbon-neutral energy systems.In the past decades,researchers have reported a number of hydrogen evolution reaction(HER)electrocatalysts with activity comparable to that of commercial Pt/C,but most of them are tested within a small current density range,typically no more than 500 mA cm^(-2).To realize the industrial application of hydrogen production from water electrolysis,it is essential to develop high-efficiency HER electrocatalysts at high current density(HCD≥500 mA cm^(-2)).Nevertheless,it remains challenging and significant to rational design HCD electrocatalysts for HER.In this paper,the design strategy of HCD electrocatalysts is discussed,and some HCD electrocatalysts for HER are reviewed in seven categories(alloy,metal oxide,metal hydroxide,metal sulfide/selenide,metal nitride,metal phosphide and other derived electrocatalysts).At the end of this article,we also pro-pose some viewpoints and prospects for the future development and research directions of HCD electrocatalysts for HER.
基金Project(NB-2020-JG-07)supported by the Research and Engineering Application of Key Technologies for New Building Industrialization Project of China Northwest Architectural Design and Research Institute Co.,Ltd.Project(2023-CXTD-29)supported by the Key Scientific and Technological Innovation Team of Shaanxi Province,ChinaProject supported by the K.C.Wong Education Foundation。
文摘The utilization of prefabricated light modular radiant heating system has demonstrated significant increases in heat transfer efficiency and energy conservation capabilities.Within prefabricated building construction,this new heating method presents an opportunity for the development of comprehensive facilities.The parameters for evaluating the effectiveness of such a system are the upper surface layer’s heat flux and temperature.In this paper,thermal resistance analysis calculation based on a simplified model for this unique radiant heating system analysis is presented with the heat transfer mechanism’s evaluation.The results obtained from thermal resistance analysis calculation and numerical simulation indicate that the thermal resistance analysis method is highly accurate with temperature discrepancies ranging from 0.44℃ to−0.44℃ and a heat flux discrepancy of less than 7.54%,which can meet the requirements of practical engineering applications,suggesting a foundation for the prefabricated radiant heating system.
基金Project (50771042) supported by the National Natural Science Foundation of ChinaProjects (1041005100052009HASTIT023) supported by the Program for Science and Technology Innovation Talents of Henan Province,China
文摘Cyanide-free silver electroplating was conducted in thiosulfate baths containing AgNO3 and AgBr major salts, respectively. The effects of major salt content and current density on surface quality, deposition rate and microhardness of Ag coatings were investigated. The optimized electroplating parameters were established. The adhesion strength of Ag coating on Cu substrate was evaluated and the grain size of Ag coating was measured under optimized electroplating parameters. The optimized AgNO3 content is 40 g/L with current density of 0.25 A/dm2. The deposited bright, smooth, and well adhered Ag coating had nanocrystalline grains with mean size of 35 nm. The optimized AgBr content was 30 g/L with current density of 0.20 A/dm2. The resultant Ag coating had nanocrystalline grains with mean size of 55 nm. Compared with the bath containing AgBr main salt, the bath containing AgNO3 main salt had a wider current density range, and corresponding Ag coating had a higher microhardness and a smaller grain size.
基金Project(51371039)supported by the National Natural Science Foundation of China
文摘Plasma electrolytic oxidation (PEO) ceramic coatings were fabricated in a silicate-based electrolyte with the addition of potassium fluorozirconate (K2ZrF6) on 6063 aluminum alloy, and the effects of current density on microstructure and properties of the PEO coatings were studied. It was found that pore density of the coatings decreased with increasing the current density. The tribological and hardness tests suggested that the ceramic coating produced under the current density of 15 A/dm2showed the best mechanical property, which matched well with the phase analysis. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization curves proved that the coating obtained under 15 A/dm2 displayed the best anti-corrosion property, which was directly connected with morphologies of coatings.
文摘A numerical model for bilayer organic light-emitting diodes (OLEDs) is developed under the basis of trapped charge limited conduction.The dependences of the current density on the layer thickness,trap properties and carrier mobility of the hole transport layer (HTL) and emission layer (EML) in bilayer OLEDs of the structure anode/HTL/EML/cathode are numerically investigated.It is found that,for given values of the total thickness of organic layers,reduced depth of trap,total density of trap,and carrier mobility of HTL as well as EML,there exists an optimal thickness ratio of HTL to EML,by which a maximal quantum efficiency can be achieved.Through optimization of the thickness ratio,an enhancement of current density and quantum efficiency of as much as two orders of magnitude can be obtained.The dependences of the optimal thickness ratio to the characteristic trap energy,total density of trap and carrier mobility are numerically analyzed.
文摘Radial variation in sap flux density (SFD) as a function of sapwood thickness is of importance in accurately estimating sap flux through sapwood area which, in turn, decides the precision of heat pulse application. However, until now, only a few studies have evaluated the magnitude and significance of sampling errors associated with radial gradients in SFD, which were based on the small monitoring measurement data from a few trees. Based on one year of heat pulse observation of two 3 - 4 years old Eucalyptus urophylla S. T.,P Blake plantations in Leizhou Peninsula, Guangdong Province, China, a way of data processing was developed to treat with the lots of SFD data measured from 39 trees. It was found that the radial variation in SFD as a function of sapwood thickness in the two eucalyptus plantation sites could be expressed as y = 3. 667 5x(3) - 7.295 5x(2) + 3.682 6x + 0. 567 4 (R-2 = 0. 939 1, n = 80, P = 0.01), where y is the ratio of SFD of a sensor to the average of four data in different depths, x is the ratio of a sensor depth to tire radial sapwood thickness. It was the same (as in the following equation) in Jijia site, y = 5.006 2x(3) - 9.116 1x(2) + 4. 454 4x + 0.463 4 (R-2 = 0. 806 9, n = 72, P = 0.01) in Hetou site. From cambium to heartwood, SFD showed some increases at first and then decreases continuously. However, because die trees were very young, the maximum SFD was only 0. 33 - 0. 36 times more than the minimum.
基金Project(51201089)supported by the National Natural Science Foundation of ChinaProject supported by the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions of China
文摘Amorphous Ti2?xMgxNi (x=0?0.3) alloys were prepared by mechanical milling of elemental powders. Charge and discharge test, linear polarization (LP) and potential-step measurement were carried out to investigate the electrochemical hydrogen storage properties of the alloys before and after heat treatment. The results show that the maximum discharge capacity of heat-treated Ti2?xMgxNi alloy can reach 275.3 mA·h/g, which is 100 mA·h/g higher than that of the amorphous Ti2?xMgxNi alloy. The heat-treated Ti1.9Mg0.1Ni alloy presents the best cycling stability with a high discharge capacity of 210 mA·h/g after 30 cycles. The results of LP and potential-step measurement of the Ti1.9Mg0.1Ni alloy show that the exchange current density increases from 101.1 to 203.3 mA/g and the hydrogen diffusion coefficient increases from 3.20×10?11 to 2.70×10?10 cm2/s after the heat treatment, indicating that the heat treatment facilitates both the charge-transfer and hydrogen diffusion processes, resulting in an improvement in electrochemical hydrogen storage properties of Ti2?xMgxNi (x=0?0.3) alloys.
