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自组织分层金属掺杂类金刚石薄膜的研究进展 被引量:1
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作者 崔丽 孙丽丽 +2 位作者 郭鹏 柯培玲 汪爱英 《表面技术》 EI CAS CSCD 北大核心 2019年第11期23-35,共13页
近年来,研究学者发现在沉积过程中,某些金属元素掺杂类金刚石薄膜时能够形成一种特殊的自组织分层纳米结构,这种纳米结构克服了人为调控多层薄膜的工艺复杂性及局限性,同时赋予了薄膜更加优异的性能。主要综述了国内外对金属掺杂类金刚... 近年来,研究学者发现在沉积过程中,某些金属元素掺杂类金刚石薄膜时能够形成一种特殊的自组织分层纳米结构,这种纳米结构克服了人为调控多层薄膜的工艺复杂性及局限性,同时赋予了薄膜更加优异的性能。主要综述了国内外对金属掺杂类金刚石薄膜中自组织分层结构的影响因素、形成机理等方面的研究现状。详细阐述了金属类型及含量、沉积条件(脉冲频率、基体偏压、气流比、沉积温度、沉积时间)、沉积方法等参数对自组织分层结构的生成及富金属层厚、富碳层厚、层数等尺寸的作用规律。重点介绍了离子重排机理、金属催化机理、强离子辐照诱导机理和靶中毒机理四种自组织分层结构形成机理的特点,并探讨了目前研究工作中存在的一些不足,如自组织分层结构的形成机理尚不清晰。上述四种机理模型均具有一定的局限性,且如何设计工艺参数实现自组织分层结构的内在调控仍是一个科学难点。针对这些问题,提出了自组织分层结构碳基薄膜的未来研究方向。 展开更多
关键词 金属掺杂类金刚石 相分离 自组织分层 富金属层 碳层 影响因素 形成机理
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Heavy metal distribution patterns and environmental quality assessment of the mariculture areas in Nanao,Shantou
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作者 周艳晖 白燕 +1 位作者 李联盛 杨宇峰 《Marine Science Bulletin》 CAS 2011年第1期71-79,共9页
The Fe, Zn, Mn and Pb concentrations in the seawater dissolved phase were investigated in the sea-surface microlayer (SML), subsurface water (SSW) and bottom water (BW) samples collected at of three mariculture ... The Fe, Zn, Mn and Pb concentrations in the seawater dissolved phase were investigated in the sea-surface microlayer (SML), subsurface water (SSW) and bottom water (BW) samples collected at of three mariculture areas of the Nanao Island ocean zone. The results showed that the SML and the BW were important compartments for these heavy metals in the mariculture areas and the concentrations varied from 23.0 μg/L to 268.0 μg/L(Fe), 11.0 μg/L to 82.2 μg/L(Zn), 1.5 μg/L to 11.0 μg/L(Mn) and 6.0 μg/L to 40.5 μg/L(Pb) in SSW, while a clear enrichment is observed in the SML, where these ranged from 27.5 μg/L to 286.5 μg/L(Fe), 13.5/lg/L to 89.0μg/L(Zn), 3.0μg/L to 12.0 μg/L(Mn) and 7.0 μg/L to 46.0μg/L(Pb). The enrichment factors were in the range of 1.07 - 1.39 which showed a slight enrichment. The average enrichment factors of Fe, Zn, Pb and Mn were 1.18, 1.13, 1.12 and 1.30, respectively. The average enrichment factors in shellfish, fish and gracilaria lemaneaformis farming areas were 1.26, 1.19 and 1.11, respectively, which showed that the surface activity was highest in the shellfish farming area. Furthermore, the heavy metals concentrations were lowest in the gracUaria lemaneaformis farming area. The results of single factor contamination index showed that the investigated areas were slightly contaminated with Zn, while the partial farming areas were seriously contaminated with Pd during a certain period of time. 展开更多
关键词 sea-surface microlayer enrichment factors heavy metal single factorcontamination index
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