Marine source rocks are considered to be mainly composed of the Cambrian-Ordovician deposit in Tarim Basin. Based on the previous studies made by other researchers, the authors calculated the thickness and distributio...Marine source rocks are considered to be mainly composed of the Cambrian-Ordovician deposit in Tarim Basin. Based on the previous studies made by other researchers, the authors calculated the thickness and distribution scale of these Cambrian-Ordovician source rocks by integrating sequence stratigraphy with investigations on sedimentary environments, well-shooting demarcating and calibrating the thickness of unknown source rocks with the thickness of the known ones according to characteristics of the source rocks that have "double track" seismic lineup reflectance. The results showed that the distribution area of the Lower-Cambrian Yuertusi Fm. source rock in platform inner depressions, slopes and deep basins is much bigger than that of the Middle Cambrian evaporite-lagoon source rock. Moreover, the former is superior to the latter in terms of the source rock quality. Likewise, the Middle-Ordovician Heituao Fm. source rock in the slopes and deep basins has a much wider distribution and better quality than the Upper Ordovician, and its quality is also better than those of the Shaergan and Yinggan Fms. source rock within platforms as well as the lime-mud-mound source rock along the fringe of the Upper-Ordovician platform. Most good Lower-Cambrian source rocks of the Kalpin outcrop lie on the initial ingression surface or in the condensed member of the Type I sequence. In this section, the source rock in Type II is inferior to that in Type I, even being far from an effective one (TOC: <0.5%). Likewise, the good Middle-Ordovician Heituao source rock also lies on the initial ingression surface or in the condensed member of the Type I sequence, while the poor Yinggan source rock and the lime-mud-mound along the fringe of the platform develop all in the Type II sequence. Under the condition of the same sea-level rising altitude and time, the ingression displacement (S1) at the base border in Type I is larger than S2 in Type II. Thus, the distribution of the source rock developed above the base border in Type I is wider than that in Type II. The maximal ingression range dominates the ultimate distribution of source rocks. Because S1 is greater than S2, the relative rate of ingression on the base border of Type I is obviously bigger than that of Type II. The difference in ingression rate is one of the factors that lead to the superiority of the source rock at the base border in Type I to that Type II . Therefore, it is of great significance to study the spatial distribution, developing era and quality determination of source rocks by means of sequence stratigrahpy.展开更多
Oil and gas breakthroughs have been achieved in the Zhongshen 1(ZS1) and 1 C(ZS1 C) wells in Cambrian pre-salt from the Tarim Basin in northwest China. However, Middle and Lower Cambrian reservoirs reveal substantial ...Oil and gas breakthroughs have been achieved in the Zhongshen 1(ZS1) and 1 C(ZS1 C) wells in Cambrian pre-salt from the Tarim Basin in northwest China. However, Middle and Lower Cambrian reservoirs reveal substantial differences in the geochemistry and secondary alteration characteristics between the oils collected from the two wells. High concentrations of thiadiamondoids and diamondoidthiols, including thiatetramantanes, tetramantanethiols, thiapentamantanes, and pentamantanethiols, are detected in the organic sulfur compound fraction of concentrated oil collected from the ZS1 C well, which samples the Lower Cambrian Xiaoerbulake Formation. Higher diamondoids, such as tetramantanes, pentamantanes, hexamantanes, and cyclohexamantane, also occur in the saturate fractions of the concentrated ZS1 C oil. The presence of these compounds is verified by mass spectra analysis and comparison with previous studies. During thermochemical sulfate reduction(TSR), the cage of higher diamondoids is interpreted to open because of sulfur radicals forming open-cage higher diamondoid-like thiols, followed by cyclization that leads to the formation of high thiadiamondoids. Using D_(16)-adamantane as an internal standard, the concentrations of lower diamondoids and thiadiamondoids of non-concentrated Cambrian oil from well ZS1 C are 83874 and8578 μg/g, respectively, which are far higher than Cambrian oil from well ZS1 and most Ordovician oils in the Tarim Basin. The high concentrations of lower thiadiamondoids and occurrence of higher thiadiamondoids and diamondoidthiols support that the oil from well ZS1 C is a product of severe TSR alteration.展开更多
Piperock, a kind of characteristic ichnofabrics in Phanerozoic, was thought to decline gradually from Cambrian to Ordovician. A new compilation on the occurrences of the Cambrian and Ordovician piperocks of China and ...Piperock, a kind of characteristic ichnofabrics in Phanerozoic, was thought to decline gradually from Cambrian to Ordovician. A new compilation on the occurrences of the Cambrian and Ordovician piperocks of China and the world shows that piperocks generally flourished in Cambrian and declined in Ordovician, but a sharp decrease occurred during Middle and Late Cambrian. The case-study on the piperocks from the Lower-Middle Ordovician Hongshiya Formation at Dabaochang of Qiaojia, northern Yunnan Province, Southwest China indicates that the forming and preservation of piperocks were controlled by the depositional environment, the intensities of predation, competition, bioturbation, and the contents of nutrition and oxygen in watermass. A careful study on the development of the Cambrian and Ordovician piperocks suggests that the decrease of nearshore siliciclastic sediments and the low contents of oxygen and nutrition in the watermass may have contributed to the decline of piperocks in Middle and Late Cambrian.展开更多
基金the PetroChina Scientific Research & Technological Development (Grant No. G19990433)
文摘Marine source rocks are considered to be mainly composed of the Cambrian-Ordovician deposit in Tarim Basin. Based on the previous studies made by other researchers, the authors calculated the thickness and distribution scale of these Cambrian-Ordovician source rocks by integrating sequence stratigraphy with investigations on sedimentary environments, well-shooting demarcating and calibrating the thickness of unknown source rocks with the thickness of the known ones according to characteristics of the source rocks that have "double track" seismic lineup reflectance. The results showed that the distribution area of the Lower-Cambrian Yuertusi Fm. source rock in platform inner depressions, slopes and deep basins is much bigger than that of the Middle Cambrian evaporite-lagoon source rock. Moreover, the former is superior to the latter in terms of the source rock quality. Likewise, the Middle-Ordovician Heituao Fm. source rock in the slopes and deep basins has a much wider distribution and better quality than the Upper Ordovician, and its quality is also better than those of the Shaergan and Yinggan Fms. source rock within platforms as well as the lime-mud-mound source rock along the fringe of the Upper-Ordovician platform. Most good Lower-Cambrian source rocks of the Kalpin outcrop lie on the initial ingression surface or in the condensed member of the Type I sequence. In this section, the source rock in Type II is inferior to that in Type I, even being far from an effective one (TOC: <0.5%). Likewise, the good Middle-Ordovician Heituao source rock also lies on the initial ingression surface or in the condensed member of the Type I sequence, while the poor Yinggan source rock and the lime-mud-mound along the fringe of the platform develop all in the Type II sequence. Under the condition of the same sea-level rising altitude and time, the ingression displacement (S1) at the base border in Type I is larger than S2 in Type II. Thus, the distribution of the source rock developed above the base border in Type I is wider than that in Type II. The maximal ingression range dominates the ultimate distribution of source rocks. Because S1 is greater than S2, the relative rate of ingression on the base border of Type I is obviously bigger than that of Type II. The difference in ingression rate is one of the factors that lead to the superiority of the source rock at the base border in Type I to that Type II . Therefore, it is of great significance to study the spatial distribution, developing era and quality determination of source rocks by means of sequence stratigrahpy.
基金supported by the National Natural Science Foundation of China (Grant No. 41772153)State Key Laboratory of Organic Geochemistry, GIGCAS (Grant No. SKLOG2017-02)+1 种基金National Science and Technology Major Project of the Ministry of Science and Technology of China (Grant No. 2017ZX05005-002)SINOPEC Ministry of Science and Technology (Grant No. P16090, P17049-1)
文摘Oil and gas breakthroughs have been achieved in the Zhongshen 1(ZS1) and 1 C(ZS1 C) wells in Cambrian pre-salt from the Tarim Basin in northwest China. However, Middle and Lower Cambrian reservoirs reveal substantial differences in the geochemistry and secondary alteration characteristics between the oils collected from the two wells. High concentrations of thiadiamondoids and diamondoidthiols, including thiatetramantanes, tetramantanethiols, thiapentamantanes, and pentamantanethiols, are detected in the organic sulfur compound fraction of concentrated oil collected from the ZS1 C well, which samples the Lower Cambrian Xiaoerbulake Formation. Higher diamondoids, such as tetramantanes, pentamantanes, hexamantanes, and cyclohexamantane, also occur in the saturate fractions of the concentrated ZS1 C oil. The presence of these compounds is verified by mass spectra analysis and comparison with previous studies. During thermochemical sulfate reduction(TSR), the cage of higher diamondoids is interpreted to open because of sulfur radicals forming open-cage higher diamondoid-like thiols, followed by cyclization that leads to the formation of high thiadiamondoids. Using D_(16)-adamantane as an internal standard, the concentrations of lower diamondoids and thiadiamondoids of non-concentrated Cambrian oil from well ZS1 C are 83874 and8578 μg/g, respectively, which are far higher than Cambrian oil from well ZS1 and most Ordovician oils in the Tarim Basin. The high concentrations of lower thiadiamondoids and occurrence of higher thiadiamondoids and diamondoidthiols support that the oil from well ZS1 C is a product of severe TSR alteration.
基金supported by National Natural Science Foundation of China (Grant Nos. 40972020, 40825006)Chinese Academy of Sciences (Grant No. KZCX2-YW-Q05-01)State Key Laboratory of Palaeobiology and Stratigraphy
文摘Piperock, a kind of characteristic ichnofabrics in Phanerozoic, was thought to decline gradually from Cambrian to Ordovician. A new compilation on the occurrences of the Cambrian and Ordovician piperocks of China and the world shows that piperocks generally flourished in Cambrian and declined in Ordovician, but a sharp decrease occurred during Middle and Late Cambrian. The case-study on the piperocks from the Lower-Middle Ordovician Hongshiya Formation at Dabaochang of Qiaojia, northern Yunnan Province, Southwest China indicates that the forming and preservation of piperocks were controlled by the depositional environment, the intensities of predation, competition, bioturbation, and the contents of nutrition and oxygen in watermass. A careful study on the development of the Cambrian and Ordovician piperocks suggests that the decrease of nearshore siliciclastic sediments and the low contents of oxygen and nutrition in the watermass may have contributed to the decline of piperocks in Middle and Late Cambrian.
