In this study,a new method is presented to correlate the shear viscosity of nanofluids by local composition theory.The Eyring theory and nonrandom two-liquid(NRTL)equation are used for this purpose.The effects of temp...In this study,a new method is presented to correlate the shear viscosity of nanofluids by local composition theory.The Eyring theory and nonrandom two-liquid(NRTL)equation are used for this purpose.The effects of temperature and particle volume concentration on the viscosity are investigated.The adjustable parameters of NRTL equation are obtained by fitting with experimental data.The calculated shear viscosities for nanofluids of CuO/water with 29 nm particle size,Al2O3/water with two different particle diameters,36 nm and 47 nm,and CuO/(ethylene glycol,water)are compared with experimental data and the average absolute deviation(AAD)is 1.2%,while the results from some conventional models yield an AAD of 190%.The results of this study are in excellent agreement with experimental data.展开更多
Many structure-property/activity studies use graph theoretical indices, which are based on the topological properties of a molecule viewed as a graph. Since topological indices can be derived directly from the molecul...Many structure-property/activity studies use graph theoretical indices, which are based on the topological properties of a molecule viewed as a graph. Since topological indices can be derived directly from the molecular structure without any experimental effort, they provide a simple and straightforward method for property prediction. In this work the flash point of alkanes was modeled by a set of molecular connectivity indices （Х）, modified molecular connectivity indices （ ^mХ^v ） and valance molecular connectivity indices （ ^mХ^v ）, with ^mХ^v calculated using the hydrogen perturbation. A stepwise Multiple Linear Regression （MLR） method was used to select the best indices. The predicted flash points are in good agreement with the experimental data, with the average absolute deviation 4.3 K.展开更多
Egg yolk phosphatidylcholine(EYPC) is being widely used in food and pharmaceutical industries nowadays owing to its surface activity,pharmaceutical usefulness,and so on.Common determination methods of phospholipids we...Egg yolk phosphatidylcholine(EYPC) is being widely used in food and pharmaceutical industries nowadays owing to its surface activity,pharmaceutical usefulness,and so on.Common determination methods of phospholipids were based on the American Oil Chemists' Society(AOCS) Official Method Ja7b-91,in which n-hexane/2-propanol/acetate buffer was used as the mobile phase.In order to achieve desired results,gradient elu-tion or buffer solution was used,which made the detection process more complicated.Moreover,water or buffer solution could affect the silica gel column both on its lifespan and the separation efficiency significantly.In this study,different mobile phase and detector were used to simplify EYPC analyzing process instead of using water within the mobile phase.The optimized HPLC operating conditions are as follows:pure methanol as a mobile phase,flow rate of 1.0 ml·min-1,silica gel column(250 mm×4.6 mm,5 μm,Inertsil GLTM),column temperature 30 ℃ and low temperature evaporative light scattering detector(40 ℃,0.35 MPa) as used.Under this optimal condition,the linear relative coefficient of the standard curve is 0.998 and the recovery was in the range of 96.83%-101.58% with a relative standard deviation of 1.79%(n=6).展开更多
This paper is a further investigation of large deviations for sums of random variables Sn=i=1∑n Xi and S（t）=i=1∑N（t）Xi,（t≥0）, where {X_n,n≥1） are independent identically distribution and non-negative random...This paper is a further investigation of large deviations for sums of random variables Sn=i=1∑n Xi and S（t）=i=1∑N（t）Xi,（t≥0）, where {X_n,n≥1） are independent identically distribution and non-negative random variables, and {N（t）,t≥0} is a counting process of non-negative integer-valued random variables, independent of {X_n,n≥1}. In this paper, under the suppose F∈G, which is a bigger heavy-tailed class than C, proved large deviation results for sums of random variables.展开更多
The relativistic mean-field （RMF） theory is used to calculate the properties of A =7-9 drip-line nuclei ^7Li, ^7;9Be, ^8;9B, and ^9C. Systematic deviations between experimental and theoretical binding energies are f...The relativistic mean-field （RMF） theory is used to calculate the properties of A =7-9 drip-line nuclei ^7Li, ^7;9Be, ^8;9B, and ^9C. Systematic deviations between experimental and theoretical binding energies are found. Possible reasons of these systematic deviations are discussed in terms of pairing energy. The root-mean-square （rms） radii of matter distributions for these nuclei agree with the experimental data quite well. The one-proton halo structure in ^8B is reproduced well, and the two-proton halo in ^9C is predicted. The calculations show that the RMF theory is valid in studying the properties of light drip-line nuclei.展开更多
The authors consider the partially linear model relating a response Y to predictors （x, T） with a mean function x^Tβ0 ＋ g（T） when the x＇s are measured with an additive error. The estimators of parameter β0 are...The authors consider the partially linear model relating a response Y to predictors （x, T） with a mean function x^Tβ0 ＋ g（T） when the x＇s are measured with an additive error. The estimators of parameter β0 are derived by using the nearest neighbor-generalized randomly weighted least absolute deviation （LAD for short） method. The resulting estimator of the unknown vector 30 is shown to be consistent and asymptotically normal. In addition, the results facilitate the construction of confidence regions and the hypothesis testing for the unknown parameters. Extensive simulations are reported, showing that the proposed method works well in practical settings. The proposed methods are also applied to a data set from the study of an AIDS clinical trial group.展开更多
文摘In this study,a new method is presented to correlate the shear viscosity of nanofluids by local composition theory.The Eyring theory and nonrandom two-liquid(NRTL)equation are used for this purpose.The effects of temperature and particle volume concentration on the viscosity are investigated.The adjustable parameters of NRTL equation are obtained by fitting with experimental data.The calculated shear viscosities for nanofluids of CuO/water with 29 nm particle size,Al2O3/water with two different particle diameters,36 nm and 47 nm,and CuO/(ethylene glycol,water)are compared with experimental data and the average absolute deviation(AAD)is 1.2%,while the results from some conventional models yield an AAD of 190%.The results of this study are in excellent agreement with experimental data.
文摘Many structure-property/activity studies use graph theoretical indices, which are based on the topological properties of a molecule viewed as a graph. Since topological indices can be derived directly from the molecular structure without any experimental effort, they provide a simple and straightforward method for property prediction. In this work the flash point of alkanes was modeled by a set of molecular connectivity indices （Х）, modified molecular connectivity indices （ ^mХ^v ） and valance molecular connectivity indices （ ^mХ^v ）, with ^mХ^v calculated using the hydrogen perturbation. A stepwise Multiple Linear Regression （MLR） method was used to select the best indices. The predicted flash points are in good agreement with the experimental data, with the average absolute deviation 4.3 K.
文摘Egg yolk phosphatidylcholine(EYPC) is being widely used in food and pharmaceutical industries nowadays owing to its surface activity,pharmaceutical usefulness,and so on.Common determination methods of phospholipids were based on the American Oil Chemists' Society(AOCS) Official Method Ja7b-91,in which n-hexane/2-propanol/acetate buffer was used as the mobile phase.In order to achieve desired results,gradient elu-tion or buffer solution was used,which made the detection process more complicated.Moreover,water or buffer solution could affect the silica gel column both on its lifespan and the separation efficiency significantly.In this study,different mobile phase and detector were used to simplify EYPC analyzing process instead of using water within the mobile phase.The optimized HPLC operating conditions are as follows:pure methanol as a mobile phase,flow rate of 1.0 ml·min-1,silica gel column(250 mm×4.6 mm,5 μm,Inertsil GLTM),column temperature 30 ℃ and low temperature evaporative light scattering detector(40 ℃,0.35 MPa) as used.Under this optimal condition,the linear relative coefficient of the standard curve is 0.998 and the recovery was in the range of 96.83%-101.58% with a relative standard deviation of 1.79%(n=6).
文摘This paper is a further investigation of large deviations for sums of random variables Sn=i=1∑n Xi and S（t）=i=1∑N（t）Xi,（t≥0）, where {X_n,n≥1） are independent identically distribution and non-negative random variables, and {N（t）,t≥0} is a counting process of non-negative integer-valued random variables, independent of {X_n,n≥1}. In this paper, under the suppose F∈G, which is a bigger heavy-tailed class than C, proved large deviation results for sums of random variables.
基金supported by the Knowledge Innovation Project of Chinese Academy of Sciences under Grant No.KJCX3-SYW-N2
文摘The relativistic mean-field （RMF） theory is used to calculate the properties of A =7-9 drip-line nuclei ^7Li, ^7;9Be, ^8;9B, and ^9C. Systematic deviations between experimental and theoretical binding energies are found. Possible reasons of these systematic deviations are discussed in terms of pairing energy. The root-mean-square （rms） radii of matter distributions for these nuclei agree with the experimental data quite well. The one-proton halo structure in ^8B is reproduced well, and the two-proton halo in ^9C is predicted. The calculations show that the RMF theory is valid in studying the properties of light drip-line nuclei.
文摘The authors consider the partially linear model relating a response Y to predictors （x, T） with a mean function x^Tβ0 ＋ g（T） when the x＇s are measured with an additive error. The estimators of parameter β0 are derived by using the nearest neighbor-generalized randomly weighted least absolute deviation （LAD for short） method. The resulting estimator of the unknown vector 30 is shown to be consistent and asymptotically normal. In addition, the results facilitate the construction of confidence regions and the hypothesis testing for the unknown parameters. Extensive simulations are reported, showing that the proposed method works well in practical settings. The proposed methods are also applied to a data set from the study of an AIDS clinical trial group.
