By using laser monitoring technique,the solubilities of p -toluic acid in N -methyl-2-pyrrolidone, N,N -dimethylformamide, N,N -dimethylacetamide,chloroform,acetic acid and water are measured in larger temperature int...By using laser monitoring technique,the solubilities of p -toluic acid in N -methyl-2-pyrrolidone, N,N -dimethylformamide, N,N -dimethylacetamide,chloroform,acetic acid and water are measured in larger temperature intervals by synthetic method.As to the solubility of p -toluic acid in water,the experimental and literature data have satisfactory consistency.Given the solubilities of p -toluic acid, a solubility model is proposed. This model is verified by experimental and literature data, and the solubilities calculated by the model show good agreement with experimental and literature data.展开更多
The ethyl esters of terephthalic acid,p toluic acid and the internal standard,octane diacid are obtained from the reaction of iodoethane with tetra methyl ammonium salts of the corresponding acids.The ethyl esters can...The ethyl esters of terephthalic acid,p toluic acid and the internal standard,octane diacid are obtained from the reaction of iodoethane with tetra methyl ammonium salts of the corresponding acids.The ethyl esters can be well separated by SE 30 0.53mm capillary column.This method was used for the determination of p phthalic acid in purified product of p toluic acid.The relative standard deviation and the recovery of the method are 4.55 and 93%～103%,respectively.展开更多
文摘By using laser monitoring technique,the solubilities of p -toluic acid in N -methyl-2-pyrrolidone, N,N -dimethylformamide, N,N -dimethylacetamide,chloroform,acetic acid and water are measured in larger temperature intervals by synthetic method.As to the solubility of p -toluic acid in water,the experimental and literature data have satisfactory consistency.Given the solubilities of p -toluic acid, a solubility model is proposed. This model is verified by experimental and literature data, and the solubilities calculated by the model show good agreement with experimental and literature data.
文摘The ethyl esters of terephthalic acid,p toluic acid and the internal standard,octane diacid are obtained from the reaction of iodoethane with tetra methyl ammonium salts of the corresponding acids.The ethyl esters can be well separated by SE 30 0.53mm capillary column.This method was used for the determination of p phthalic acid in purified product of p toluic acid.The relative standard deviation and the recovery of the method are 4.55 and 93%～103%,respectively.
