Zero-dimensional metal halide perovskites have captured intense research interest owing to their unique optoelectronic properties.Particularly,metal halides with the ns^(2) electronic configuration are of great intere...Zero-dimensional metal halide perovskites have captured intense research interest owing to their unique optoelectronic properties.Particularly,metal halides with the ns^(2) electronic configuration are of great interest owing to the high-temperature sensitivity of their photoluminescence,which could be applied to remote optical thermometry(ROT).Herein,all-inorganic and lead-free halide perovskite Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O single crystals(SCs)were prepared through the hydrothermal method and showed a strong temperature dependence of photoluminescence lifetime.Upon Te^(4+) doping,the nonemissive Cs_(2)InCl_(5)·H_(2)O SC exhibits a bright orange emission at 660 nm with a wide full width at half maximum of 180 nm.The strong phonon-exciton coupling promotes the formation of self-trapped excitons in the soft lattice of the zero-dimensional Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O SC.The Te^(4+) ions with the 5 s^(2) electronic configuration endow the Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O SC with a strong temperaturedependent photoluminescence lifetime.This SC reaches a maximum specific sensitivity of 0.062 K^(-1) at 320 K,thereby showing the potential advantages of indium-based metal halide perovskites in ROT applications.展开更多
To study the pressure distribution of the volute casing, front casing and back casing in a prototype centrifugal pump, the pressure experiments and numerical simulations are carried out at six working conditions in th...To study the pressure distribution of the volute casing, front casing and back casing in a prototype centrifugal pump, the pressure experiments and numerical simulations are carried out at six working conditions in this paper. The experimental results shows that the asymmetry of static pressure distribution on volute casing and front cavity is caused by the tongue of the volute and it may result in high radial and axial resultant force which can cause vibration and noise in the centrifugal pump. With the increasing of flow rote, the asymmetry of static pressure distribution and the magnitude of static pressure values reduce. The numerical results indicate that the pressure fluctuation near the tongue is strongest and it becomes slighter at point away from the tongue. With the increasing of flow rote, the local high=pressure region in impeller passage reduces and the flow becomes smoother accordingly, whereas the fluid speed becomes much higher which may cause further flow losses. The results predicted by numcrical simulation are in coincident with the experimental ones. It shows that the turbulence model for simulating the flow field in centrifugal pumps is feasible.展开更多
基金supported by the National Natural Science Foundation of China(U2001214)the Natural Science Foundation of Guangdong Province(2019B1515120050)the Fundamental Research Funds for the Central Universities。
文摘Zero-dimensional metal halide perovskites have captured intense research interest owing to their unique optoelectronic properties.Particularly,metal halides with the ns^(2) electronic configuration are of great interest owing to the high-temperature sensitivity of their photoluminescence,which could be applied to remote optical thermometry(ROT).Herein,all-inorganic and lead-free halide perovskite Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O single crystals(SCs)were prepared through the hydrothermal method and showed a strong temperature dependence of photoluminescence lifetime.Upon Te^(4+) doping,the nonemissive Cs_(2)InCl_(5)·H_(2)O SC exhibits a bright orange emission at 660 nm with a wide full width at half maximum of 180 nm.The strong phonon-exciton coupling promotes the formation of self-trapped excitons in the soft lattice of the zero-dimensional Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O SC.The Te^(4+) ions with the 5 s^(2) electronic configuration endow the Te^(4+)-doped Cs_(2)InCl_(5)·H_(2)O SC with a strong temperaturedependent photoluminescence lifetime.This SC reaches a maximum specific sensitivity of 0.062 K^(-1) at 320 K,thereby showing the potential advantages of indium-based metal halide perovskites in ROT applications.
基金supported by the Joint Project from National Natural Science Foundation of China and Liaoning Province(U1608258)
文摘To study the pressure distribution of the volute casing, front casing and back casing in a prototype centrifugal pump, the pressure experiments and numerical simulations are carried out at six working conditions in this paper. The experimental results shows that the asymmetry of static pressure distribution on volute casing and front cavity is caused by the tongue of the volute and it may result in high radial and axial resultant force which can cause vibration and noise in the centrifugal pump. With the increasing of flow rote, the asymmetry of static pressure distribution and the magnitude of static pressure values reduce. The numerical results indicate that the pressure fluctuation near the tongue is strongest and it becomes slighter at point away from the tongue. With the increasing of flow rote, the local high=pressure region in impeller passage reduces and the flow becomes smoother accordingly, whereas the fluid speed becomes much higher which may cause further flow losses. The results predicted by numcrical simulation are in coincident with the experimental ones. It shows that the turbulence model for simulating the flow field in centrifugal pumps is feasible.
