绍兴五年南宋朝廷“渐图恢复”下的对金态度

绍兴四年十二月,南宋朝廷挫败了伪齐与金人的联兵入侵,扭转了自建炎以来被动奔避的局面。"大作规模措置","渐图恢复"成为了南宋朝廷在绍兴五年的根本任务,朝臣们以此为主题,围绕着国家政治、军事、外交的实际状况,提出了乘衅待时、和战相间的策略。

注定的失败:沉没成本与南宋对金战和困境

自开禧伐金失败到端平元年宋蒙联军亡金的28年中南宋的对金政策是战略决策反复自我否定的经典案例。前景理论中的沉没成本学说假定前期投入的成本将干扰决策者的风险认知,继而影响后继政策的发展。然而,尽管南宋在宋金关系中付出的惨痛代价构成了其决策集团的沉没成本,但这些成本未能促使南宋采取坚定的北伐政策。鉴于既有研究的解释力不足,需要对沉没成本假定进行修正:决策者对于沉没成本的敏感度存在差异,决策集团内部还存在着沉没成本的类型差异。敏感度与类型的差异造成的沉没成本竞争和排序使得共同沉没成本效应复杂化。此时,即便决策集团存在共同沉没成本,也可能受其他沉没成本影响而产生严重的内部分歧。修正后的假定在很大程度上解释了南宋决策集团在伐金问题上的犹豫和反复:君主、权相和士大夫集团都受到对金交往屈辱历史的深刻影响,但他们在伐金还是和金的路线选择上存在着明显的敏感度差异,国内政治造成的普遍不安全感作为其他类型的沉没成本干扰着决策集团达成共识。最终,政治上的内讧使南宋丧失了最后的战略机遇期,未能坚定选择伐金与和金两种选项中的任意一项。

论敦煌类书《籯金》写本《储君篇》与《诸王篇》的分野

通过考察敦煌类书《籯金》写本《储君篇》和《诸王篇》录事与叙文的关系,对比《籯金·诸王篇》与《语对·王部》录事可见,现存《籯金》写本《储君篇》“诸王”之后的“帝子、天孙,大王风、小山桂,瑶枝、琼萼,派裔五潢,祚土、分茅,猿岩、兔苑”等事当属《诸王篇》。《籯金·诸王篇》与《语对·王部》在录事上相似性很高,这说明唐代私修类书在编纂实践中或已逐步形成一些常设部类,部类内或已逐步凝聚了一批核心事例。

Experiments and modeling of double-peak precipitation hardening and strengthening mechanisms in Al-Zn-Mg alloy

The aim of the present work is to develop a model for simulating double-peak precipitation hardening kinetics in Al-Zn-Mg alloy with the simultaneous formation of different types of precipitates at elevated temperatures based on the modified Langer-Schwartz approach. The double aging peaks are present in the long time age-hardening curves of Al-Zn-Mg alloys. The physically-based model, while taking explicitly into account nucleation, growth, coarsening of the new phase precipitations and two strengthening mechanisms associated with particle-dislocation interaction （shearing and bypassing）, was used for the analysis of precipitates evolution and precipitation hardening during aging of Al-Zn-Mg alloy. Model predictions were compared with the measurements of Al-Zn-Mg alloy. The systematic and quantitative results show that the predicted hardness profiles of double peaks via adding a shape dependent parameter in the growth equation for growth and coarsening generally agree well with the measured ones. Two strengthening mechanisms associated with particle-dislocation interaction （shearing and bypassing） were considered operating simultaneously in view of the particle size-distribution. The transition from shearing to bypassing strengthening mechanism was found to occur at rather early stage of the particle growth. The bypassing was found to be the prevailing strengthening mechanism in the investigated alloys.

Forced convection rheoforming process for preparation of 7075 aluminum alloy semisolid slurry and its numerical simulation

A self-developed forced convection rheoforming （FCR） machine for the preparation of light alloy semisolid slurry was introduced. The microstructure characteristics of 7075 aluminium alloy semisolid slurry at different stirring speeds prepared by the FCR process were analyzed. The experimental results suggest that with the increase of the stirring speed, the mean grain size of the semisolid decreases and the shape factor as well as the number of primary grains increase. Meanwhile, the preparation process of semisolid slurry was numerically simulated. The flow characteristics of the melt in the device and the effect of the stirring speed on temperature field and solid fraction of the melt were investigated. The simulated results show that during the preparation process of semisolid slurry, there is a complex convection within the FCR device that obviously changes the temperature field distribution and solid fraction of the melt. When the convection intensity increases, the scope of the undercooling gradient of the melt is reduced and temperature distribution is improved.

Asymmetric cast-rolling of 1050 aluminum alloy strip under multi-energy field

Technological parameters of asymmetric cast-rolling under multi-energy field were investigated on horizontal twin roll caster（d400 mm×500 mm）, and their effects on structures and properties of 1050 strips were analyzed by comparing with traditional cast-rolling. Results show that when length of cast-rolling area is 70 mm, melt temperature of head box is 670 °C, cast rolling speed is 1.3 m/min, exciting current is 10 A, center frequency is（13±1） Hz, ultrasonic power is 200 W and ultrasonic frequency is（20±0.2） kHz, the 1050 strip with the best microstructure can be prepared successfully; its center segregated layer disappears; the average grain size is reduced by about 40%; the crystal grains are distributed evenly; micro segregation decreases obviously; the precipitated phases are distributed along the grain boundaries evenly; and the tensile strength, yield strength, elongation and micro-hardness of cast-rolled strip are improved by 22.6%, 23.66%, 38.75% and 9.90%, respectively.

Growth mechanism of icosahedral and other five-fold symmetric diamond crystals

Five-fold symmetric diamond crystals（FSDCs） were synthesized by hot filament chemical vapour deposition（HFCVD） methods. Their surface morphologies and defects were characterised by scanning electron microscopy（SEM）. From the perspective of nucleation-growth, a growth mechanism for icosahedral and other five-fold symmetric diamond crystals was discussed. Computer modelling was also carried out. The results show that the dodecahedrane（C20H20） molecule is proposed as a nucleus for the growth of icosahedral diamond crystals（IDCs）, wherein the 20 {111} surface planes develop orthogonal to the direction of the original 20 C—H bonds by sequential H abstraction and CH3 addition reactions. IDC can be pictured as an assembly of isosceles tetrahedra, with each tetrahedron contributing a {111} plane to the surface of the IDC and the remainder of the tetrahedral surfaces forming twin planes with neighbouring tetrahedra. The small mismatch（1.44°） between the {111} surface dihedral angle of a perfect icosahedron and that of a twinned icosahedron reveals itself via twin planes in the IDC grain. The modelling suggests how the relief of strain induced by this distortion could lead to the formation of defects such as concave pentagonal cavities at vertices and grooves along the grain edges that accord well with those observed experimentally. Similar arguments based on growth from the hexacyclo pentadecane（C15H20） nucleus can also account for the observed formation of star and rod shaped FSDCs, and some of their more obvious morphological defects.

Etching Behavior of GaN/GaAs(001) Epilayers Grown by MOVPE

Wet etching characteristics of cubic GaN (c GaN) thin films grown on GaAs(001) by metalorganic vapor phase epitaxy (MOVPE) are investigated.The samples are etched in HCl,H 3PO 4,KOH aqueous solutions,and molten KOH at temperatures in the range of 90～300℃.It is found that different solution produces different etch figure on the surfaces of a sample.KOH based solutions produce rectangular pits rather than square pits.The etch pits elongate in 1 0] direction,indicating asymmetric etching behavior in the two orthogonal <110> directions.An explanation based on relative reactivity of the various crystallographic planes is employed to interpret qualitatively the asymmetric etching behavior.In addition,it is found that KOH aqueous solution would be more suitable than molten KOH and the two acids for the evaluation of stacking faults in c GaN epilayers. direction,indicating asymmetric etching behavior in the two orthogonal <110> directions.An explanation based on relative reactivity of the various crystallographic planes is employed to interpret qualitatively the asymmetric etching behavior.In addition,it is found that KOH aqueous solution would be more suitable than molten KOH and the two acids for the evaluation of stacking faults in c GaN epilayers.

京剧在昭通

京剧是我国戏曲艺术中的一颗明珠,是中华民族至可宝贵的一份文化遗产,它从清代道光、咸丰年间(公元1821年至1861年)形成于北京,后来流传各地,成为全国性的大剧种,抗日战争时期这个剧种也传入了昭通,为昭通人民所喜爱.一、初闻京腔昭通地处滇东北高原,东面与贵州省威宁县相邻,北面与四川省的宜宾地区接壤.在经济、文化上与四川交往甚密,戏曲艺术亦深受四川影响。

Enhanced ductility and reduced asymmetry of Mg-2Al-1Zn alloy plate processed by torsion and annealing

The ductility and plastic asymmetry of an as-annealed magnesium alloy plate were studied in compression through combined process of torsion and subsequent annealing by optical microscope and EBSD. The yield strength（YS） and ultimate compression strength（UCS） as well as the compression ductility（CD） were simultaneously raised by prior torsion at room temperature. The CD was further enhanced by subsequent annealing. Also, the torqued sample followed by annealing experienced a rising CD with the increase in prior strain, leading to the maximum true strain of 0.279, which is twice that of the as-annealed original one. The sample showed a largely reduced tension-compression yield asymmetry by subjecting to pre-torsion alone or combined with a subsequent annealing. The enhanced ductility and reduced asymmetry are attributed to the development of a gradient microstructure with refined grains, and also randomization of the weakened texture due to torsion and subsequent annealing.

Effect of melt convection on primary dendrite arm spacing in directionally solidified Pb-26%Bi hypo-peritectic alloys

Primary dendrite arm spacing（PDAS） of α phase in directionally solidified Pb-26%Bi（mass fraction） hypo-peritectic alloys was measured by considering the effect of melt convection in cylindrical samples with different diameters.The experimental results show the measured PDAS increases with increasing diameter of the sample.At the growth velocity of 5 μm/s,its value changes from 161.5 μm for the sample with 1.8 mm in diameter to 240.4 μm for the sample with 7 mm in diameter.The strong melt convection in large diameter samples causes a high bulk alloy composition and a high concentration gradient in peritectic β phase,resulting in a larger PDAS.Simultaneously,the high concentration gradient could effectively promote the peritectic transformation,enhancing the dissolution of the thin α dendrite.

Influence of counter electrode material during accelerated durability test of non-precious metal electrocatalysts in acidic medium

Significant progress has been made in the development of non-precious metal electrocatalysts （NPMEs） during the past decade. Correspondingly, there is an urgent demand for an appropriate measurement method to be established for the reliable evaluation of NPMEs. In this study, platinum and graphite counter electrodes were used to investigate the impact of counter electrode material on the accelerated durability testing （ADT） of NPMEs in acidic medium. Platinum used as the coun- ter electrode in a traditional three-electrode electrochemical cell was found to dissolve in acidic medium and re-deposit on NPME coated on the working electrode during ADT. Such re-deposition causes the oxygen reduction reaction （ORR） performance of NPMEs to remarkably improve, and thus will seriously mislead our judgment of NPMEs if we are unaware of it. The phenomenon can be avoided using a graphite counter electrode.

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with copper interlayer sheet

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with a copper sheet as interlayer was carried out.Microstructures of the joint were studied by optical microscopy(OM),scanning electron microscopy(SEM) and X-ray diffractometry(XRD).In addition,the mechanical properties of the joint were evaluated by tensile test and the microhardness was measured.These two alloys were successfully welded by adding copper transition layer into the weld.Solid solution with a certain thickness was located at the interfaces between weld and base metal in both sides.Regions inside the weld and near the stainless steel were characterized by solid solution of copper with TiFe2 intermetallics dispersedly distributed in it.While weld near titanium alloy contained Ti-Cu and Ti-Fe-Cu intermetallics layer,in which the hardness of weld came to the highest value.Brittle fracture occurred in the intermetallics layer when the joint was stretched.

A survey of the Internet application in the AEC industry

The Internet is becoming increasingly more valuable in the field ofarchitectural design so that what we conventionally called CAD might soon be changed to Internetaided design (iAD). In order to have a clear vision of what IAD will be or could be, we should firstexamine what is currently available. This research focuses on an investigation of selected Webvendors, which are typical and most influential in providing Internet related services for the AECindustry. By comparing and analyzing their functionality, services provided, business models,technology and financial situation, we have seen that Internet application in the AEC industry isstill in early stage, especially in the area of on-line engineering consulting for architects.

Influence of rolling route on microstructure and mechanical properties of AZ31 magnesium alloy during asymmetric reduction rolling

Four different routes of asymmetric reduction rolling were conducted on AZ31 magnesium alloy to investigate their effect on the microstructure evolution and mechanical properties. Route A is the forward rolling; while during routes B and C the sheets are rotated 180o in rolling direction and normal direction, respectively; route D is the unidirectional rolling. The strain states of rolled sheets were analyzed by the finite element method, while the microstructure and texture were observed using optical microscopy, X-ray diffraction and electron back-scattered diffraction techniques, and the mechanical properties were measured by tensile test. The results show that route D produced the largest effective strain. Compared with other samples, sample D exhibited a homogeneous microstructure with fine grains as well as a weak and tilted texture, in corresponding, it performed excellent tensile properties, which suggested that route D was an effective way to enhance the strength and plasticity of AZ31 sheet.

Elimination of yielding asymmetry in extruded AZ80 alloy by ageing

Samples of AZ80 alloy were hot extruded at 380 ℃ and aged at temperatures of 170 ℃ and 310 ℃ respectively for different periods to compare the effect of precipitate structures on the tensile-compressive yielding asymmetry in magnesium alloy. Uniaxial tension and compression along the extruded direction were carried out at room temperature. It was found that the yielding asymmetry in the aged samples was not as significant as that in the as-extruded samples. This was because twinning occurred less readily in the aged samples. And it was also confirmed by the fact that the increment of the critical resolved shear stress （CRSS） for twinning was higher and the Schmid factor was lower in the aged samples in the presence of precipitate. Thus, it was concluded that the yielding asymmetry could be reduced and even eliminated by increasing the area fraction of the precipitate phase.

Kinetic study on reactive extraction of phenylalanine enantiomers with BINAP-copper complexes

Enantioselective liquid–liquid extraction has attracted considerable attention for its potential use in largescale production. Kinetic data are needed for the reliable scale-up of the process. This paper reports the kinetic study of reactive extraction of phenylalanine(Phe) enantiomers with BINAP–copper complex(BINAP–Cu) as a chiral selector. The theory of extraction accompanied by a chemical reaction was applied.The effects of agitation speed, interfacial area, p H value of aqueous phase, initial concentration of Phe enantiomers and initial concentration of BINAP–Cu on the specific rate of extraction were investigated. The forward rate constants of the reactions in the reactive extraction process are 7.93 × 10-5m5/2·mol-1/2·s-1for D-Phe and 1.29 × 10-4m5/2·mol-1/2·s-1for L-Phe.

Effect of Si-addition as a grain refiner on microstructure and properties of Ti-6Al-4V Alloy

Two different Ti alloys were cast in a graphite mould using vacuum induction skull melting furnace. The first alloy was Ti-6Al-4V and the second was Ti-6Al-4V 0.5Si. Silicon as a grain refiner was added into Ti-6Al-4V alloy, and the effects of Si-addition on the microstructure and properties of the as-cast and swaged alloys were investigated. Hot swaging at 900 °C was performed on the cast samples and then two different thermal treatments were applied. The first treatment was done by heating the swaged samples at 1050 °C to produce fine lamella structure, while the second treatment was carried out at 1050 °C and then decreased the temperature to 800 °C for getting coarse lamella structure. An addition of 0.5% Si to Ti-6Al-4V alloy decreased the grain size of the as-cast sample from 627 to 337 μm. There was an increase in ultimate tensile strength of about 25 MPa for the as-cast Ti-6Al-4V 0.5Si alloy compared to Ti-6Al-4V due to the refinement effect caused by Si addition. A maximum ultimate tensile strength of 1380 MPa and a minimum corrosion rate （1.35×10 6 mm/a in Hank’s solution and 5.78×10 4 mm/a in NaCl solution） were reported for the heat treated fine lamella structure of Ti-6Al-4V 0.5Si alloy. The wear rate was decreased to about 50% by adding 0.5% Si at low sliding speeds and to about 73% at high sliding speeds.

Effect of asymmetric rolling under high friction coefficient on recrystallization texture and plastic anisotropy of AA1050 alloy

In asymmetric rolling(ASR) the circumferential velocities of the working rolls are different. This yields a complex deformation mode with shear, compression and rigid body rotation components. The main microstructural modification is on crystallographic texture, and, for aluminium alloys, this may improve the deformability after recrystallization. This work correlated the process variables, thickness reduction per pass(TRP) and velocity ratio between the upper and bottom rolls, with the texture development and the plastic properties after annealing. Finite element(FE) simulations were performed to quantify the influence of the strain components. Experimental data on texture, and plastic anisotropy were analyzed. In the sheet centre a crystallographic rotation of the compression components about the TD(transverse direction) axis was obtained, which yielded the development of {111}//ND(normal direction) texture components. On the surfaces the local variation of the velocity gradients caused an extra rotation component about ND. This yielded the increment of rotated cube components. After annealing the main texture components at the sheet centre were maintained and the texture intensity decreased. The planar anisotropy(△r) was reduced but the normal anisotropy and deep drawability obtained by the Erichsen test were similar for all conditions. The most favourable reduction of △r was obtained at a velocity ratio of 1.5 and TRP of 10%.

Droplet transition for plasma-MIG welding on aluminium alloys

The synchronous acquisition system of droplet image inspection and arc electric signals were established and the droplet transition characteristics of aluminum alloys were researched in the plasma-MIG welding process.Typical droplet transition modes include globular transfer mode,short circuiting transfer mode,metastable spray transfer mode and projected transfer mode.The result indicates that MIG droplet transfer frequency and droplet transfer modes are changed by introducing the plasma arc in the plasma-MIG welding process compared with the MIG welding on the aluminum alloys,which broadens the range of welding parameters when the stable welding process proceeds.The metastable spray transfer and projected transfer mode are proved to be the most optimal modes by comparing the stability of electronic signal,droplet transition,weld appearance and weld penetration.