Temperature-dependence and excitation-intensity-dependence of photoluminescence spectra for both disordered and ordered Ga 0.52 In 0.48 P are measured. The disordered sample is characterized by its single peak photolu...Temperature-dependence and excitation-intensity-dependence of photoluminescence spectra for both disordered and ordered Ga 0.52 In 0.48 P are measured. The disordered sample is characterized by its single peak photoluminescence spectrum which is excitation-intensity independent and has different activation energy at different temperature region. The ordered sample shows double peaks, the intensity of the high-energy peak has an anomalous increase firstly and quenches afterwards. The relative phenomena are reasonably explained in terms of lattice ordering and orientation superlattice model.展开更多
To obtain the coupling characteristics between slab wave-guides including left-handed material,we modify the coupled wave equations by using Maxwell’s equations. First,we obtain new-coupled wave equations and new-cou...To obtain the coupling characteristics between slab wave-guides including left-handed material,we modify the coupled wave equations by using Maxwell’s equations. First,we obtain new-coupled wave equations and new-coupling coefficient. Second,the coupling between two identical five-layer slab wave-guides where their cores are left-handed material,but their claddings are right-handed materials is studied. The coupling coefficient for even TE mode which is more complex than that of the riglt-handed material slab wave guides,is obtained.展开更多
A quantum well intermixing（QW1） investigation on double quantum well（DQW） structure with two different emitting wavelength caused by phosphorus ion implantation and following rapid thermal annealing （RTA） was ca...A quantum well intermixing（QW1） investigation on double quantum well（DQW） structure with two different emitting wavelength caused by phosphorus ion implantation and following rapid thermal annealing （RTA） was carried out by means of photoluminescence（PL）. The ion implantation was performed at the energy of 120 keV with the dose ranging from 1 × 10^11cm^-2 to 1× 10^14cm^-2. The RTA was performed at the temperature of 700 ℃ for 30 s under pure nitrogen protection. The PL measurement implied that the band gap blue-shift from the upper well increases with the ion dose faster than that from lower well and the PL peaks from both QWs remained well separated under the lower dose implantation（-1 × 10^11cm^-2） indicating that the implant vacancy distribution affects the QWl. When the ion dose is over - 1 × 10^12cm^-2, the band gap blue-shift from both wells increases with the ion dose and finally the two peaks merge together as one peak indicating the ion implantation caused a total intermixing of both quantum wells.展开更多
Nd2O3 doped BaTiO3ceramics（the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio）were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities thr...Nd2O3 doped BaTiO3ceramics（the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio）were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities through X-ray photoelectron spectrum （XPS）. The results showed that the dielectric characteristics of Nd2O3 doped BaTiO3 ceramics were improved by doping. When Nd2O3 content was 0.003 mol, the results were even better, the dielectric constant was increased, the dielectric loss was decreased, the Curie-temperature （Tc） was 110 ℃, and the frequency characteristic was also good. The resistivity of Nd2O3 doped BaTiO3 ceramics was lower than that of pure BaTiO3 ceramics, when Nd2O3 content was 0.001 mol,the resistivity was （2.364×）108 Ω·m, the smallest. The grain resistance of Nd2O3 doped BaTiO3 ceramics exhibited NTC effect, but the grain boundary resistance showed PTC effect, and the grain boundary resistance was larger than that of the grain resistance, so the PTC effect originated from the grain boundary. The analysis of the element binding energy through X-ray photoelectron spectrum were indicated that the quantivalence of Ba2+and Ti4+in Nd2O3 doped BaTiO3 ceramics was variable, and resulted in the improvement of the conductibility of BaTiO3 ceramics.展开更多
The temperature characteristics for the different lasing modes at 300 K of intracavity contacted InGaAs/GaAs Vertical Cavity Surface Emitting Lasers（VCSELs） have been investigated experimentally by using the SV-32 c...The temperature characteristics for the different lasing modes at 300 K of intracavity contacted InGaAs/GaAs Vertical Cavity Surface Emitting Lasers（VCSELs） have been investigated experimentally by using the SV-32 cryostat and LD200205 test system. In combination with the simulation results of the reflective spectrum and the gain peak at different temperatures, the measurement results have been analyzed. In addition, the dependence of device size on temperature characteristics is discussed. The experimental data can be used to optimally design of VCSEL at high or cryogenic temperature.展开更多
Metal‐organic framework(MOF)‐derived nanomaterials have attracted widespread attention,because the excellent features,such as high surface area,porosity and tunable properties are inherited from MOFs.Moreover,the de...Metal‐organic framework(MOF)‐derived nanomaterials have attracted widespread attention,because the excellent features,such as high surface area,porosity and tunable properties are inherited from MOFs.Moreover,the derivatives avoid the poor conductivity and stability of MOFs.MOF‐derived nanomaterials can easily be regulated by a specific selection of metal nodes and organic linkers,resulting in multifunctionality in photocatalysis.MOF derivatives can be used not only as semiconductor photocatalysts,but also as co‐catalysts for photocatalytic hydrogen evolution,CO_(2) reduction,pollutants degradation,etc.This review focuses on the multifunctional applications of MOF derivatives in the field of photocatalysis.The researches in recent years are analyzed and summarized from the aspects of preparation,modification and application of MOF derivatives.At the end of the review,the development and challenges of MOF derivatives applied in photocatalysis in the future are put forward,in order to provide more references for further research in this field and bring new inspiration.展开更多
We have measured the deep energy level of the InP: Fe which is semi -insulator through the method of OTCS. The effect of light intensity on OTCS measurement is mainly discussed. There are electron trap of E_T =0.34 eV...We have measured the deep energy level of the InP: Fe which is semi -insulator through the method of OTCS. The effect of light intensity on OTCS measurement is mainly discussed. There are electron trap of E_T =0.34 eV and hole trap of E_T = 1.13 eV in InP: Fe under the strong light and low temperature. The location of the OTCS peak of electron trap (E_T = 0.34 eV) moves towards the direction of high temperaturer, when the light intensity was increased, E_T is different under different light intensity. It is corrected in terms of theory that the stuff ratio of the deep energy level is affected by the light intensity. The experiments show that the error is decreased greatly with the correction.展开更多
The electroluminescunce (EL) transient characteristics of erbium-doped zinc sulfide thin film (TF) devices excited by short rectangular pulses are studied, the luminescence delay after de-exciting and the relaxation l...The electroluminescunce (EL) transient characteristics of erbium-doped zinc sulfide thin film (TF) devices excited by short rectangular pulses are studied, the luminescence delay after de-exciting and the relaxation luminance peaks during decay are observed. A model description for energy transfer has been proposed. The experimental results can be theoretically explained with the computer curve fittings.展开更多
Photo-responsive room-temperature phosphorescent(RTP)materials have garnered significant interest due to the advantages of rapid response,spatiotemporal control,and contactless precision manipulation.However,the devel...Photo-responsive room-temperature phosphorescent(RTP)materials have garnered significant interest due to the advantages of rapid response,spatiotemporal control,and contactless precision manipulation.However,the development of such materials remains in its infancy,underscoring the importance of exploiting novel and efficient light-responsive RTP molecules.In this work,three phenothiazine derivatives of TPA-PTZ,TPA-2PTZ,and TPA-3PTZ were successfully synthesized via the Buchwald-Hartwig C—N coupling reaction.By embedding these molecules as RTP guests into polymethyl methacrylate(PMMA)matrix,photo-induced RTP properties were realized.Upon sustained UV irradiation,there was an enhancement of 19 times in the quantum yield to reach a value of 5.68%.Remarkably,these materials exhibit superior alongside robust light and thermal stability,maintaining high phosphorescence intensity even after prolonged UV exposure(irradiation for>200 s by a 365 nm UV lamp with the power of 500μW·cm-2)or at higher temperature up to 75℃.The outstanding properties of these photo-induced RTP materials make them promising candidates for applications in information encryption,anti-counterfeiting,and advanced optical materials.展开更多
Ultralong phosphorescent materials have numerous applications across biological imaging, lightemitting devices, X-ray detection and anti-counterfeiting. Triplet-state molecular phosphorescence typically accompanies th...Ultralong phosphorescent materials have numerous applications across biological imaging, lightemitting devices, X-ray detection and anti-counterfeiting. Triplet-state molecular phosphorescence typically accompanies the singlet-state fluorescence during photoluminescence, and it is still difficult to achieve direct triplet photoemission as ultralong room temperature phosphorescence(RTP). Here, we have designed Zn-IMDC(IMDC, 4,5-imidazoledicarboxylic acid) and Cd-IMDC, two-dimensional(2D)hydrogen-bond organized metal–organic crystalline microsheets that exhibit rarely direct ultralong RTP upon UV excitation, benefiting from the appropriate heavy-atom effect and multiple triplet energy levels. The excitation-dependent and thermally stimulated ultralong phosphorescence endow the metal–organic systems great opportunities for information safety application and temperature-gated afterglow emission. The well-defined 2D microsheets present color-tunable and anisotropic optical waveguides under different excitation and temperature conditions, providing an effective way to obtain intelligent RTP-based photonic systems at the micro-and nano-scales.展开更多
文摘Temperature-dependence and excitation-intensity-dependence of photoluminescence spectra for both disordered and ordered Ga 0.52 In 0.48 P are measured. The disordered sample is characterized by its single peak photoluminescence spectrum which is excitation-intensity independent and has different activation energy at different temperature region. The ordered sample shows double peaks, the intensity of the high-energy peak has an anomalous increase firstly and quenches afterwards. The relative phenomena are reasonably explained in terms of lattice ordering and orientation superlattice model.
基金Creative Graduate Student Foundation of Shanghai University (A.16-0107-07-001)
文摘To obtain the coupling characteristics between slab wave-guides including left-handed material,we modify the coupled wave equations by using Maxwell’s equations. First,we obtain new-coupled wave equations and new-coupling coefficient. Second,the coupling between two identical five-layer slab wave-guides where their cores are left-handed material,but their claddings are right-handed materials is studied. The coupling coefficient for even TE mode which is more complex than that of the riglt-handed material slab wave guides,is obtained.
文摘A quantum well intermixing（QW1） investigation on double quantum well（DQW） structure with two different emitting wavelength caused by phosphorus ion implantation and following rapid thermal annealing （RTA） was carried out by means of photoluminescence（PL）. The ion implantation was performed at the energy of 120 keV with the dose ranging from 1 × 10^11cm^-2 to 1× 10^14cm^-2. The RTA was performed at the temperature of 700 ℃ for 30 s under pure nitrogen protection. The PL measurement implied that the band gap blue-shift from the upper well increases with the ion dose faster than that from lower well and the PL peaks from both QWs remained well separated under the lower dose implantation（-1 × 10^11cm^-2） indicating that the implant vacancy distribution affects the QWl. When the ion dose is over - 1 × 10^12cm^-2, the band gap blue-shift from both wells increases with the ion dose and finally the two peaks merge together as one peak indicating the ion implantation caused a total intermixing of both quantum wells.
文摘Nd2O3 doped BaTiO3ceramics（the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio）were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities through X-ray photoelectron spectrum （XPS）. The results showed that the dielectric characteristics of Nd2O3 doped BaTiO3 ceramics were improved by doping. When Nd2O3 content was 0.003 mol, the results were even better, the dielectric constant was increased, the dielectric loss was decreased, the Curie-temperature （Tc） was 110 ℃, and the frequency characteristic was also good. The resistivity of Nd2O3 doped BaTiO3 ceramics was lower than that of pure BaTiO3 ceramics, when Nd2O3 content was 0.001 mol,the resistivity was （2.364×）108 Ω·m, the smallest. The grain resistance of Nd2O3 doped BaTiO3 ceramics exhibited NTC effect, but the grain boundary resistance showed PTC effect, and the grain boundary resistance was larger than that of the grain resistance, so the PTC effect originated from the grain boundary. The analysis of the element binding energy through X-ray photoelectron spectrum were indicated that the quantivalence of Ba2+and Ti4+in Nd2O3 doped BaTiO3 ceramics was variable, and resulted in the improvement of the conductibility of BaTiO3 ceramics.
文摘The temperature characteristics for the different lasing modes at 300 K of intracavity contacted InGaAs/GaAs Vertical Cavity Surface Emitting Lasers（VCSELs） have been investigated experimentally by using the SV-32 cryostat and LD200205 test system. In combination with the simulation results of the reflective spectrum and the gain peak at different temperatures, the measurement results have been analyzed. In addition, the dependence of device size on temperature characteristics is discussed. The experimental data can be used to optimally design of VCSEL at high or cryogenic temperature.
文摘Metal‐organic framework(MOF)‐derived nanomaterials have attracted widespread attention,because the excellent features,such as high surface area,porosity and tunable properties are inherited from MOFs.Moreover,the derivatives avoid the poor conductivity and stability of MOFs.MOF‐derived nanomaterials can easily be regulated by a specific selection of metal nodes and organic linkers,resulting in multifunctionality in photocatalysis.MOF derivatives can be used not only as semiconductor photocatalysts,but also as co‐catalysts for photocatalytic hydrogen evolution,CO_(2) reduction,pollutants degradation,etc.This review focuses on the multifunctional applications of MOF derivatives in the field of photocatalysis.The researches in recent years are analyzed and summarized from the aspects of preparation,modification and application of MOF derivatives.At the end of the review,the development and challenges of MOF derivatives applied in photocatalysis in the future are put forward,in order to provide more references for further research in this field and bring new inspiration.
文摘We have measured the deep energy level of the InP: Fe which is semi -insulator through the method of OTCS. The effect of light intensity on OTCS measurement is mainly discussed. There are electron trap of E_T =0.34 eV and hole trap of E_T = 1.13 eV in InP: Fe under the strong light and low temperature. The location of the OTCS peak of electron trap (E_T = 0.34 eV) moves towards the direction of high temperaturer, when the light intensity was increased, E_T is different under different light intensity. It is corrected in terms of theory that the stuff ratio of the deep energy level is affected by the light intensity. The experiments show that the error is decreased greatly with the correction.
文摘The electroluminescunce (EL) transient characteristics of erbium-doped zinc sulfide thin film (TF) devices excited by short rectangular pulses are studied, the luminescence delay after de-exciting and the relaxation luminance peaks during decay are observed. A model description for energy transfer has been proposed. The experimental results can be theoretically explained with the computer curve fittings.
文摘Photo-responsive room-temperature phosphorescent(RTP)materials have garnered significant interest due to the advantages of rapid response,spatiotemporal control,and contactless precision manipulation.However,the development of such materials remains in its infancy,underscoring the importance of exploiting novel and efficient light-responsive RTP molecules.In this work,three phenothiazine derivatives of TPA-PTZ,TPA-2PTZ,and TPA-3PTZ were successfully synthesized via the Buchwald-Hartwig C—N coupling reaction.By embedding these molecules as RTP guests into polymethyl methacrylate(PMMA)matrix,photo-induced RTP properties were realized.Upon sustained UV irradiation,there was an enhancement of 19 times in the quantum yield to reach a value of 5.68%.Remarkably,these materials exhibit superior alongside robust light and thermal stability,maintaining high phosphorescence intensity even after prolonged UV exposure(irradiation for>200 s by a 365 nm UV lamp with the power of 500μW·cm-2)or at higher temperature up to 75℃.The outstanding properties of these photo-induced RTP materials make them promising candidates for applications in information encryption,anti-counterfeiting,and advanced optical materials.
基金supported by the Beijing Municipal Natural Science Foundation(JQ20003)the National Natural Science Foundation of China(21771021,21822501,and 22061130206)+3 种基金the Fok Ying-Tong Education Foundation(171008)the Measurements Fund of Beijing Normal Universitythe State Key Laboratory of Heavy Oil Processing。
文摘Ultralong phosphorescent materials have numerous applications across biological imaging, lightemitting devices, X-ray detection and anti-counterfeiting. Triplet-state molecular phosphorescence typically accompanies the singlet-state fluorescence during photoluminescence, and it is still difficult to achieve direct triplet photoemission as ultralong room temperature phosphorescence(RTP). Here, we have designed Zn-IMDC(IMDC, 4,5-imidazoledicarboxylic acid) and Cd-IMDC, two-dimensional(2D)hydrogen-bond organized metal–organic crystalline microsheets that exhibit rarely direct ultralong RTP upon UV excitation, benefiting from the appropriate heavy-atom effect and multiple triplet energy levels. The excitation-dependent and thermally stimulated ultralong phosphorescence endow the metal–organic systems great opportunities for information safety application and temperature-gated afterglow emission. The well-defined 2D microsheets present color-tunable and anisotropic optical waveguides under different excitation and temperature conditions, providing an effective way to obtain intelligent RTP-based photonic systems at the micro-and nano-scales.
