Two-dimensional covalent organic frameworks(2D COFs)feature extendedπ-conjugation and ordered stacking sequence,showing great promise for high-performance photocatalysis.Periodic atomic frameworks of 2D COFs facilita...Two-dimensional covalent organic frameworks(2D COFs)feature extendedπ-conjugation and ordered stacking sequence,showing great promise for high-performance photocatalysis.Periodic atomic frameworks of 2D COFs facilitate the in-plane photogenerated charge transfer,but the precise ordered alignment is limited due to the non-covalentπ-stacking of COF layers,accordingly hindering out-of-plane transfer kinetics.Herein,we address a chiral induction method to construct a parallelly superimposed stacking chiral COF ultrathin shell on the support of SiO_(2) microsphere.Compared to the achiral COF analogues,the chiral COF shell with the parallel AA-stacking structure is more conducive to enhance the built-in electric field and accumulates photogenerated electrons for the rapid migration,thereby affording superior photocatalytic performance in hydrogen evolution from water splitting.Taking the simplest ketoenamine-linked chiral COF as a shell of SiO_(2) particle,the resulting composite exhibits an impressive hydrogen evolution rate of 107.1 mmol g^(-1)h^(-1)along with the apparent quantum efficiency of 14.31% at 475 nm.Furthermore,the composite photocatalysts could be fabricated into a film device,displaying a remarkable photocatalytic performance of 178.0 mmol m^(-2)h^(-1)for hydrogen evolution.Our work underpins the surface engineering of organic photocatalysts and illustrates the significance of COF stacking structures in regulating electronic properties.展开更多
The electronic packaging shell of high silicon carbide (54%SiC, volume fraction) aluminum-based composites was produced by liquid-solid separation technique. The characteristics of distribution and morphology of SiC...The electronic packaging shell of high silicon carbide (54%SiC, volume fraction) aluminum-based composites was produced by liquid-solid separation technique. The characteristics of distribution and morphology of SiC as well as the shell’s fracture surface were examined by optical microscopy and scanning electron microscopy, and the thermo-physical and mechanical properties of the shell were also tested. The results show that Al matrix has a net-like structure while SiC is uniformly distributed in the Al matrix. The SiCp/Al composites have a low density of 2.93 g/cm^3, and its relative density is 98.7%. Thermal conductivity of the composites is 175 W/(·K), coefficient of thermal expansion (CTE) is 10.3×10^-6 K-1 (25-400 ℃), compressive strength is 496 MPa, bending strength is 404.5 MPa, and the main fracture mode is brittle fracture of SiC particles accompanied by ductile fracture of Al matrix.Its thermal conductivity is higher than that of Si/Al alloy, and its CTE matches with that of the chip material.展开更多
[Objective] The aim was to explore the effect of tomato's resistance to Botrytis cinerea induced by exogenous Chitosan.[Method] The leaf spraying method was used to determine the induced resistance effect of Chitosan...[Objective] The aim was to explore the effect of tomato's resistance to Botrytis cinerea induced by exogenous Chitosan.[Method] The leaf spraying method was used to determine the induced resistance effect of Chitosan to tomato B.cinerea and the chlorophyll content,soluble protein,soluble sugar,proline influence,the activities of peroxidase(POD),malondialdehyde(MDA)and the Proline content in leaves of tomato.[Result] The induced resistance of Chitosan reached 58.26% at 14th d after treatment;Compared with the B.cinerea stress group,the chlorophyll content in leaves of tomato seedlings of B.cinerea stress + Chitosan group had increased by 34.63%,while that of soluble protein content,soluble sugar content,Pro content and POD activity was 5.30%,10.83%,16.21% and 16.88%,respectively(except for the MDA content,which was decreased by 16.54%).[Conclusion] Exogenous Chitosan could improve photosynthetic efficiency and protect enzymes activity to improve the resistance of tomato seedlings to B.cinerea.展开更多
[Objective] The aim was to study effect of Chaetomium globosum ND35 on plant growth and preliminary study of its biocontrol efficacy, and provide basis for popularization and application of this strain.[ Method] With ...[Objective] The aim was to study effect of Chaetomium globosum ND35 on plant growth and preliminary study of its biocontrol efficacy, and provide basis for popularization and application of this strain.[ Method] With endophytic fungus C. globosum ND35 as a tested strain, effect of C. globosumND35 on plant growth and its biocontrol on five plant diseases were investigated in the greenhouse and field,[Result]The results showed that ND35 promoted growth of lateral root and diameter of breast height of poplar. ND35 can induce poplar to resist Poplar Valsa Canker caused by Valsa sordida and Poplar Rust caused by Melampsora puplicola. ND35 was also able to induce tomato and bean to resist Botrytis cinera. Biocontrol of Bean Stem Rot Rhizoctonia by ND35 was effective as well. [Conclusion] Induced systemic resistance by endophytic C. globosum ND35 plays an important role in biocontrol of plant diseases.展开更多
In order to predict acoustic radiation from a structure in waveguide, a method based on wave superposition is proposed, in which the free-space Green's function is used to match the strength of equivalent sources. In...In order to predict acoustic radiation from a structure in waveguide, a method based on wave superposition is proposed, in which the free-space Green's function is used to match the strength of equivalent sources. In addition, in order to neglect the effect of sound reflection from boundaries, necessary treatment is conducted, which makes the method more efficient. Moreover, this method is combined with the sound propagation algorithms to predict the sound radiated from a cylindrical shell in waveguide. Numerical simulations show the effect of how reflections can be neglected if the distance between the structure and the boundary exceeds the maximum linear dimension of the structure. It also shows that the reflection from the bottom of the waveguide can be approximated by plane wave conditionally. The proposed method is more robust and efficient in computation, which can be used to predict the acoustic radiation in waveguide.展开更多
Photocatalysis driven by near-infrared(NIR)light is of scientific and technological interest for ex-ploiting solar energy.In this study,we demonstrate a facile hydrothermal process to synthesize core-shell nanoparti...Photocatalysis driven by near-infrared(NIR)light is of scientific and technological interest for ex-ploiting solar energy.In this study,we demonstrate a facile hydrothermal process to synthesize core-shell nanoparticles combining upconversion nanoparticles(UCNPs)and alloyed ZnxCwhich can be excited using NIR or visible light.Morphologies,phase,and chemical composition have been investigated using field-emission scanning electron microscopy,transmission electron mi-croscopy,X-ray diffraction analysis,and atomic absorption spectroscopy.Moreover,we found that amorphous TiO2 layers existing in the final samples play an important role in formation ofyolk-shell nanoparticles,which bind the as-prepared ZnxCnanoparticlescan be tuna-ble by adjusting the amount of the Cd and Zn source compounds.The photochemical reduction of Cr(Ⅵ)in water has been performed to study the photocatalytic performance under irradiation by NIR light or a simulated solar light,showing efficient photoreduction and Cr(Ⅵ)removal over the/TiO2 yolk-shell nanoparticles.The as-prepared UCNPs@ZnxC/TiO2 nanoparticles show excellent production of hydroxyl radicals,which are responsible for the photochemical reduction of Cr(Ⅵ)to Cr(Ⅲ).This study will provide an alternative strategy for en-vironmental wastewater treatment,making full use of solar energy.展开更多
Serotonin (5-HT) has been found to stimulate meiotic maturation of oocytes in many molluscs. During maturation, several signaling pathways are involved, especially the phosphatidylinositol and cAMP pathways. In order ...Serotonin (5-HT) has been found to stimulate meiotic maturation of oocytes in many molluscs. During maturation, several signaling pathways are involved, especially the phosphatidylinositol and cAMP pathways. In order to examine the possible role of the phosphatidylinositol signaling pathway in regulating oocyte maturation in Mercenaria mercenaria, the effects of the activator/inhibitor of phospholipase (PLC) and protein kinase C (PKC) on serotonin-induced maturation were studied. Results show that high-concentrations of neomycin (inhibitor of PLC) blocked oocyte maturation, while 9, 10-dimethyl-1, 2-benzanthracene (DMBA, activator of PLC) promoted oocyte maturation in the presence of serotonin. It was also found that in the presence of serotonin, phorbol 12-myristate 13-acetate (PMA, activator of PKC) inhibited oocyte maturation, while sphingosine (inhibitor of PKC) stimulated oocyte maturation. These results indicate that serotonin-induced oocyte maturation requires the activation of the phosphatidylinositol pathway. Decrease of PLC inhibited serotonin-induced oocyte maturation, whereas a decrease of PKC stimulated the maturation. Thus, our study indicates that serotonin promotes maturation of M. mercenaria oocytes through PLC stimulated increase in calcium ion concentration via inositol-1, 4, 5-trisphosphate (IP3) but not PKC.展开更多
Due to the unique structural mode and material property of a composite sandwich plate, related research such as fragment impact resistance of a composite mast is short of publication and urgent in this field. In this ...Due to the unique structural mode and material property of a composite sandwich plate, related research such as fragment impact resistance of a composite mast is short of publication and urgent in this field. In this paper, the commonly accepted sandwich core board theory was modified. Damage caused by a fragment attack was simulated onto a sandwich plate model built with solid and shell elements. It was shown that shear failure and vast matrix cracking are the main reasons for outer coat damage, and tension failure and partial matrix cracking are the cause for inner coat damage. Additionally, according to complexities in actual sea battles, different work conditions of missile attacks were set. Ballistic limit values of different fragment sizes were also obtained, which provides references for enhancing the fragment impact resistance of a composite mast.展开更多
In the process of solving Euler vectors based on GNSS horizontal movement field,the number of estimated parameters can affect Euler vector results. This issue is analyzed through theoretical deduction and practical ex...In the process of solving Euler vectors based on GNSS horizontal movement field,the number of estimated parameters can affect Euler vector results. This issue is analyzed through theoretical deduction and practical example in this paper. Firstly,the difference between the results of Euler vectors in different solving models is deduced. Meanwhile, based on GNSS horizontal movement field in the Chinese mainland from 2004 to 2007,two common models( RRM and REHSM) are used to discuss the impact of solving models on Euler vectors and the follow-up study. The result shows that the maximum value of the difference in a block's entire rotation can reach 2. 6mm /a,and should not be ignored. Therefore,the results of horizontal movement are different using different kinematic block models,and this should be paid more attention in the analysis of crustal horizontal movement.展开更多
Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrou...Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrous silicate minerals under controlled temperature, pressure and oxygen fugacity, have helped to constrain the water distribution in the Earth's interior. This paper introduces high pressure and temperature experimental study of electrical conductivity measurement of hydrous minerals such as serpentine, talc, brucite, phase A, super hydrous phase B and phase D, and assesses the data quality of the above minerals. The dehydration effect and the pressure effect on the bulk conductivity of the hydrous minerals are specifically emphasized. The conduction mechanism of hydrous minerals and the electrical structure of the subduction zone are discussed based on the available conductivity data. Finally, the potential research fields of the electrical conductivity of hydrous minerals is presented.展开更多
In order to meet the application requirement of a certain long wavelength infrared (LWIR) seeker, a small volume, light weight and passively athermalized infrared OR) objective is designed in this paper. The two-le...In order to meet the application requirement of a certain long wavelength infrared (LWIR) seeker, a small volume, light weight and passively athermalized infrared OR) objective is designed in this paper. The two-lens telephoto struc- ture is adopted by merely using aluminum alloy as the housing material. By balancing the thermo-optical coefficient and thermal expansion coefficient of materials, an athermalized IR seeker with effective focal length of 90 mm and F number of 1.2 is achieved. The whole optical length is 75 ram, and the weight is only 234 g. The objective can remain fine imaging quality under temperature range from -40 ℃ to 60 ℃, which is beneficial to the lightweight design oflR seekers.展开更多
文摘Two-dimensional covalent organic frameworks(2D COFs)feature extendedπ-conjugation and ordered stacking sequence,showing great promise for high-performance photocatalysis.Periodic atomic frameworks of 2D COFs facilitate the in-plane photogenerated charge transfer,but the precise ordered alignment is limited due to the non-covalentπ-stacking of COF layers,accordingly hindering out-of-plane transfer kinetics.Herein,we address a chiral induction method to construct a parallelly superimposed stacking chiral COF ultrathin shell on the support of SiO_(2) microsphere.Compared to the achiral COF analogues,the chiral COF shell with the parallel AA-stacking structure is more conducive to enhance the built-in electric field and accumulates photogenerated electrons for the rapid migration,thereby affording superior photocatalytic performance in hydrogen evolution from water splitting.Taking the simplest ketoenamine-linked chiral COF as a shell of SiO_(2) particle,the resulting composite exhibits an impressive hydrogen evolution rate of 107.1 mmol g^(-1)h^(-1)along with the apparent quantum efficiency of 14.31% at 475 nm.Furthermore,the composite photocatalysts could be fabricated into a film device,displaying a remarkable photocatalytic performance of 178.0 mmol m^(-2)h^(-1)for hydrogen evolution.Our work underpins the surface engineering of organic photocatalysts and illustrates the significance of COF stacking structures in regulating electronic properties.
文摘The electronic packaging shell of high silicon carbide (54%SiC, volume fraction) aluminum-based composites was produced by liquid-solid separation technique. The characteristics of distribution and morphology of SiC as well as the shell’s fracture surface were examined by optical microscopy and scanning electron microscopy, and the thermo-physical and mechanical properties of the shell were also tested. The results show that Al matrix has a net-like structure while SiC is uniformly distributed in the Al matrix. The SiCp/Al composites have a low density of 2.93 g/cm^3, and its relative density is 98.7%. Thermal conductivity of the composites is 175 W/(·K), coefficient of thermal expansion (CTE) is 10.3×10^-6 K-1 (25-400 ℃), compressive strength is 496 MPa, bending strength is 404.5 MPa, and the main fracture mode is brittle fracture of SiC particles accompanied by ductile fracture of Al matrix.Its thermal conductivity is higher than that of Si/Al alloy, and its CTE matches with that of the chip material.
文摘[Objective] The aim was to explore the effect of tomato's resistance to Botrytis cinerea induced by exogenous Chitosan.[Method] The leaf spraying method was used to determine the induced resistance effect of Chitosan to tomato B.cinerea and the chlorophyll content,soluble protein,soluble sugar,proline influence,the activities of peroxidase(POD),malondialdehyde(MDA)and the Proline content in leaves of tomato.[Result] The induced resistance of Chitosan reached 58.26% at 14th d after treatment;Compared with the B.cinerea stress group,the chlorophyll content in leaves of tomato seedlings of B.cinerea stress + Chitosan group had increased by 34.63%,while that of soluble protein content,soluble sugar content,Pro content and POD activity was 5.30%,10.83%,16.21% and 16.88%,respectively(except for the MDA content,which was decreased by 16.54%).[Conclusion] Exogenous Chitosan could improve photosynthetic efficiency and protect enzymes activity to improve the resistance of tomato seedlings to B.cinerea.
基金Supported by National Natural Science Foundation of China(30872024,30571498)Students Research Training (SRT) of Shandong Agricultural University (0802024)~~
文摘[Objective] The aim was to study effect of Chaetomium globosum ND35 on plant growth and preliminary study of its biocontrol efficacy, and provide basis for popularization and application of this strain.[ Method] With endophytic fungus C. globosum ND35 as a tested strain, effect of C. globosumND35 on plant growth and its biocontrol on five plant diseases were investigated in the greenhouse and field,[Result]The results showed that ND35 promoted growth of lateral root and diameter of breast height of poplar. ND35 can induce poplar to resist Poplar Valsa Canker caused by Valsa sordida and Poplar Rust caused by Melampsora puplicola. ND35 was also able to induce tomato and bean to resist Botrytis cinera. Biocontrol of Bean Stem Rot Rhizoctonia by ND35 was effective as well. [Conclusion] Induced systemic resistance by endophytic C. globosum ND35 plays an important role in biocontrol of plant diseases.
基金Foundation item: Supported by the National Natural Science Foundation of China under Grant No. 11274080, and the Young Scientists Fund of the National Natural Science Foundation of China under Grant No. 11404313.
文摘In order to predict acoustic radiation from a structure in waveguide, a method based on wave superposition is proposed, in which the free-space Green's function is used to match the strength of equivalent sources. In addition, in order to neglect the effect of sound reflection from boundaries, necessary treatment is conducted, which makes the method more efficient. Moreover, this method is combined with the sound propagation algorithms to predict the sound radiated from a cylindrical shell in waveguide. Numerical simulations show the effect of how reflections can be neglected if the distance between the structure and the boundary exceeds the maximum linear dimension of the structure. It also shows that the reflection from the bottom of the waveguide can be approximated by plane wave conditionally. The proposed method is more robust and efficient in computation, which can be used to predict the acoustic radiation in waveguide.
基金supported by the National Natural Science Foundation of China (21471043, 51603059, 31501576)~~
文摘Photocatalysis driven by near-infrared(NIR)light is of scientific and technological interest for ex-ploiting solar energy.In this study,we demonstrate a facile hydrothermal process to synthesize core-shell nanoparticles combining upconversion nanoparticles(UCNPs)and alloyed ZnxCwhich can be excited using NIR or visible light.Morphologies,phase,and chemical composition have been investigated using field-emission scanning electron microscopy,transmission electron mi-croscopy,X-ray diffraction analysis,and atomic absorption spectroscopy.Moreover,we found that amorphous TiO2 layers existing in the final samples play an important role in formation ofyolk-shell nanoparticles,which bind the as-prepared ZnxCnanoparticlescan be tuna-ble by adjusting the amount of the Cd and Zn source compounds.The photochemical reduction of Cr(Ⅵ)in water has been performed to study the photocatalytic performance under irradiation by NIR light or a simulated solar light,showing efficient photoreduction and Cr(Ⅵ)removal over the/TiO2 yolk-shell nanoparticles.The as-prepared UCNPs@ZnxC/TiO2 nanoparticles show excellent production of hydroxyl radicals,which are responsible for the photochemical reduction of Cr(Ⅵ)to Cr(Ⅲ).This study will provide an alternative strategy for en-vironmental wastewater treatment,making full use of solar energy.
基金Supported by the National High Tecnhology Research and Development Program of China (863 Program) (No. 2004AA603810)
文摘Serotonin (5-HT) has been found to stimulate meiotic maturation of oocytes in many molluscs. During maturation, several signaling pathways are involved, especially the phosphatidylinositol and cAMP pathways. In order to examine the possible role of the phosphatidylinositol signaling pathway in regulating oocyte maturation in Mercenaria mercenaria, the effects of the activator/inhibitor of phospholipase (PLC) and protein kinase C (PKC) on serotonin-induced maturation were studied. Results show that high-concentrations of neomycin (inhibitor of PLC) blocked oocyte maturation, while 9, 10-dimethyl-1, 2-benzanthracene (DMBA, activator of PLC) promoted oocyte maturation in the presence of serotonin. It was also found that in the presence of serotonin, phorbol 12-myristate 13-acetate (PMA, activator of PKC) inhibited oocyte maturation, while sphingosine (inhibitor of PKC) stimulated oocyte maturation. These results indicate that serotonin-induced oocyte maturation requires the activation of the phosphatidylinositol pathway. Decrease of PLC inhibited serotonin-induced oocyte maturation, whereas a decrease of PKC stimulated the maturation. Thus, our study indicates that serotonin promotes maturation of M. mercenaria oocytes through PLC stimulated increase in calcium ion concentration via inositol-1, 4, 5-trisphosphate (IP3) but not PKC.
基金Supported by the Research-in-advance Foundation of Naval Armory under Grant No.401030101the National Defense Science and Technology Cooperation Foundation(2007DFR80340)Research-in-advance Foundation of National Defense Science and Technology in Shipbuilding Industry(07J1.1.6)
文摘Due to the unique structural mode and material property of a composite sandwich plate, related research such as fragment impact resistance of a composite mast is short of publication and urgent in this field. In this paper, the commonly accepted sandwich core board theory was modified. Damage caused by a fragment attack was simulated onto a sandwich plate model built with solid and shell elements. It was shown that shear failure and vast matrix cracking are the main reasons for outer coat damage, and tension failure and partial matrix cracking are the cause for inner coat damage. Additionally, according to complexities in actual sea battles, different work conditions of missile attacks were set. Ballistic limit values of different fragment sizes were also obtained, which provides references for enhancing the fragment impact resistance of a composite mast.
基金sponsored by the Special Earthquake Research Project Granted by the China Earthquake Administration(201308009,201208006)
文摘In the process of solving Euler vectors based on GNSS horizontal movement field,the number of estimated parameters can affect Euler vector results. This issue is analyzed through theoretical deduction and practical example in this paper. Firstly,the difference between the results of Euler vectors in different solving models is deduced. Meanwhile, based on GNSS horizontal movement field in the Chinese mainland from 2004 to 2007,two common models( RRM and REHSM) are used to discuss the impact of solving models on Euler vectors and the follow-up study. The result shows that the maximum value of the difference in a block's entire rotation can reach 2. 6mm /a,and should not be ignored. Therefore,the results of horizontal movement are different using different kinematic block models,and this should be paid more attention in the analysis of crustal horizontal movement.
基金supported by the National Natural Science Foundation of China(Grant Nos.41590623&41472040)the Fundamental Research Funds for the Central Universities+2 种基金China University of Geosciences(Grant No.CUGL150801)Special Fund from the State Key Laboratory of Geological Processes and Mineral ResourcesChina University of Geosciences(Grant No.MSFGPMR201408)
文摘Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrous silicate minerals under controlled temperature, pressure and oxygen fugacity, have helped to constrain the water distribution in the Earth's interior. This paper introduces high pressure and temperature experimental study of electrical conductivity measurement of hydrous minerals such as serpentine, talc, brucite, phase A, super hydrous phase B and phase D, and assesses the data quality of the above minerals. The dehydration effect and the pressure effect on the bulk conductivity of the hydrous minerals are specifically emphasized. The conduction mechanism of hydrous minerals and the electrical structure of the subduction zone are discussed based on the available conductivity data. Finally, the potential research fields of the electrical conductivity of hydrous minerals is presented.
基金supported by the National Natural Science Foundation of China(Nos.11372309 and 61304017)the Knowledge Innovation Program of the Chinese Academy of Sciences(No.YYYJ-1122)
文摘In order to meet the application requirement of a certain long wavelength infrared (LWIR) seeker, a small volume, light weight and passively athermalized infrared OR) objective is designed in this paper. The two-lens telephoto struc- ture is adopted by merely using aluminum alloy as the housing material. By balancing the thermo-optical coefficient and thermal expansion coefficient of materials, an athermalized IR seeker with effective focal length of 90 mm and F number of 1.2 is achieved. The whole optical length is 75 ram, and the weight is only 234 g. The objective can remain fine imaging quality under temperature range from -40 ℃ to 60 ℃, which is beneficial to the lightweight design oflR seekers.