“演示—导构—体验”教学模式构建及教学设计策略

本文介绍了“演示－导构－体验”教学模式提出的背莆，构建了“演示－导构－体验”教学模式，并解读了“演示－导构－体验”教学模式的内涵，在阐述“演示－导构－体验”教学模式运用原则及特点的基础上．以“压力和压强”课题为例进行教学设计。

Polycrystalline ZSM-5 Aggregates Induced by Seed and Catalytic Performance in Methanol to Hydrocarbon

Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use of organic templates and the subsequent calcination procedure.This not only reduces the cost of synthesis,but also prevents environmental pollution from the combustion of organic templates,representing an eco-friendly approach.Despite this,literature suggests that even so-called template-free synthesis systems often involve trace amount of organic substances like alcohol.In the present work,a calcined commercial ZSM-5 zeolite was served as seed,with sodium aluminate as aluminum source and silica sol as silicon source,ensuring an entirely template-free synthesis system.Polycrystalline ZSM-5 aggregates consisted of rod-like nanocrystals were successfully prepared in the completely OSDA-free system.Effects of the Si/Al ratio in ZSM-5 seed,dosage and crystallization conditions such as crystallization temperature and crystallization time on ZSM-5 synthesis were investigated.The results show that a highly crystallinity ZSM-5 aggregate consisting of primary nano-sized crystals less than 100 nm is produced from a gel precursor with 5.6%(in mass)seed after hydrothermal treatment for 48 h.Furthermore,the Si/Al ratio in ZSM-5 seed has little effect on the topological structure and pore structure of the synthesized samples.However,the seeds with a low Si/Al ratio facilitate faster crystallization of zeolite and enhance the acidity,especially the strong acid centers,of the catalyst.The catalytic performance of the synthesized polycrystalline ZSM-5 was evaluated during dehydration of methanol and compared with a commercial reference ZSM-5r.The results exhibit that as compared with the reference catalyst,the fabricated sample has a longer catalytic lifetime(16 h vs 8 h)attributed to its hierarchical pores derived from the loosely packed primary nanoparticles.Additionally,the prepared polycrystalline catalyst also exhibits a higher aromatics selectivity(28.1%-29.8%vs 26.5%).

谈《神农颂》的编导构想

今年三四月,我回湖南省株洲中毕业实习,参与市文化局大型歌舞剧《神农颂》的编导工作。 《神农颂》是歌颂人文始祖——炎帝,开拓南方,创造和传播文明的功绩。在编导过程中,我以在校学习到的各种理论和方法,用观摩各种演出与录像的体会,用自己对现代中国舞台呈现的各种流派,

Boosting photocatalytic hydrogen evolution enabled by SiO_(2)-supporting chiral covalent organic frameworks with parallel stacking sequence

Two-dimensional covalent organic frameworks(2D COFs)feature extendedπ-conjugation and ordered stacking sequence,showing great promise for high-performance photocatalysis.Periodic atomic frameworks of 2D COFs facilitate the in-plane photogenerated charge transfer,but the precise ordered alignment is limited due to the non-covalentπ-stacking of COF layers,accordingly hindering out-of-plane transfer kinetics.Herein,we address a chiral induction method to construct a parallelly superimposed stacking chiral COF ultrathin shell on the support of SiO_(2) microsphere.Compared to the achiral COF analogues,the chiral COF shell with the parallel AA-stacking structure is more conducive to enhance the built-in electric field and accumulates photogenerated electrons for the rapid migration,thereby affording superior photocatalytic performance in hydrogen evolution from water splitting.Taking the simplest ketoenamine-linked chiral COF as a shell of SiO_(2) particle,the resulting composite exhibits an impressive hydrogen evolution rate of 107.1 mmol g^(-1)h^(-1)along with the apparent quantum efficiency of 14.31%at 475 nm.Furthermore,the composite photocatalysts could be fabricated into a film device,displaying a remarkable photocatalytic performance of 178.0 mmol m^(-2)h^(-1)for hydrogen evolution.Our work underpins the surface engineering of organic photocatalysts and illustrates the significance of COF stacking structures in regulating electronic properties.

Research on High-Velocity Impact Damage Monitoring Method of CFRP Based on Guided Wave

Carbon fiber-reinforced polymer(CFRP)is widely used in aerospace applications.This kind of material may face the threat of high-velocity impact in the process of dedicated service,and the relevant research mainly considers the impact resistance of the material,and lacks the high-velocity impact damage monitoring research of CFRP.To solve this problem,a real high-velocity impact damage experiment and structural health monitoring(SHM)method of CFRP plate based on piezoelectric guided wave is proposed.The results show that CFRP has obvious perforation damage and fiber breakage when high-velocity impact occurs.It is also proved that guided wave SHM technology can be effectively used in the monitoring of such damage,and the damage can be reflected by quantifying the signal changes and damage index(DI).It provides a reference for further research on guided wave structure monitoring of high/hyper-velocity impact damage of CFRP.

Formation of mesophase microbeads from bulk mesophase pitch induced by fullerene

A transformation of naphthalene-based coalescenced mesophase pitch(NMP)to mesophase microbeads was achieved by heating a mixture of NMP and fullerene(C_(60)).This is different from the conventional process of the liquid-phase carbonization of isotropic pitch to the emergence of carbon microbeads in the matrix and finally their growth to form a 100%anisotropic bulk meso-phase,but rather a reverse transformation.The effects of C_(60) loading and reaction temperature on the morphological transformation of mesophase were investigated by polarizing optical and scanning electron microscopies.The physical changes in the NMP induced by C_(60) were characterized by thermogravimetric analysis,Fourier transform infrared spectroscopy,X-ray diffractometry and Raman spectroscopy.The results show that the coalesced NMP can be converted to a spherical type at 300-320℃ with the addition of 5%C_(60),and the size of the mesophase microbeads increases with increasing temperature.Furthermore,a model is established to ex-plain the unique induction effect of C_(60) in the transformation process.This work makes the morphological transformation of MP con-trollable,and provides a new idea for the understanding and research of mesophase pitch.

Improving autoencoder-based unsupervised damage detection in uncontrolled structural health monitoring under noisy conditions

Structural health monitoring is widely utilized in outdoor environments,especially under harsh conditions,which can introduce noise into the monitoring system.Therefore,designing an effective denoising strategy to enhance the performance of guided wave damage detection in noisy environments is crucial.This paper introduces a local temporal principal component analysis(PCA)reconstruction approach for denoising guided waves prior to implementing unsupervised damage detection,achieved through novel autoencoder-based reconstruction.Experimental results demonstrate that the proposed denoising method significantly enhances damage detection performance when guided waves are contaminated by noise,with SNR values ranging from 10 to-5 dB.Following the implementation of the proposed denoising approach,the AUC score can elevate from 0.65 to 0.96 when dealing with guided waves corrputed by noise at a level of-5 dB.Additionally,the paper provides guidance on selecting the appropriate number of components used in the denoising PCA reconstruction,aiding in the optimization of the damage detection in noisy conditions.

范德华络合物Rg-HCl、Rg-ClH(Rg=Ne,Ar)异构化的量子化学及热力学的分析

对标题异构化体系，在 Ｇａｕｓｓｉａｎ ９４程序的高水平 ＭＰ４／６－３１１Ｇ＊＊下，进行了全参数几何优化、能量、频率等计算，得到了它们电子结构的相对稳定性。同时用统计热力学计算了Ｒｇ－ＨＣＩ、Ｒｇ－ＣＩＨ（Ｒｇ＝ Ｎｅ， Ａｒ）等异构体的热力学性质及它们的相互转化的平衡常数等。结果表明：不同构型的稳定性是随实验温度变化的，两种构型也可在某一温度下共存。这一结果不同于仅通过电子结构能所作出的某异构体较稳定的简单推断，而是提醒人们对一些弱键体系，要考虑温度与熵效应的重要性。

Variable Structure Proportional Navigation for Homing Missile

The purpose of this paper is to design control loop and guidance loop for the homing missile, to prove that the modified variable structure proportional navigation (VSPN) can be used in passive homing guidance system, and to compare the VSPN with the proportional navigation (PN). Angular rate and linear acceleration are fed back to improve the stability and robust of autopilot, VSPN and PN are compared in mathematics simulation of homing missile in attacking tanks and helicopters. The damp and the stability of the missile body are increased. The VSPN cuts down the overload of guidance phase dramatically, makes the ballistic trajectory straighter than PN and leads to smaller missdistance. The VSPN can be used for passive homing guidance system, and is especially suitable for attacking helicopter.

First-Principle Calculation of the Electronic Structure of Sb-Doped SrTiO_3

The electronic structure,including band structure,density of states （DOS）, and partial density of states of SrTi1-xSbxO3 with x = 0,0. 125,0.25,and 0.33 is calculated from the first principles of plane wave ultra-soft pseudo-potential technology based on density function theory. The calculated results reveal that due to the electron doping,the Fermi level moves into the conduction bands for SrTi1-xSbxO3 with x = 0. 125 and the system shows metallic behavior. In addition, the DOS moves towards low energy and the optical band gap is broadened. The wide band gap and the low density of the states in the conduction band result in the transparency of the films.

异构数据层基于多关系半连接查询优化算法

查询效率是异构数据层必须面临的一大挑战,由于普通多关系半连接优化算法,异构数据层缓冲区不能作为查询中间结果的最后装配站点,采用半连接方法优化连接操作,并在半连接的基础上提出了多个站点的半连接执行优化算法,该算法根据半连接生成有向无序树,使多个半连接操作能够并行执行。结果表明改进的多关系半连接查询优化算法明显减少了中间结果的数据量,有效地降低了网络通信总代价,提高了全局查询效率。

Experimental study of low-temperature electrical radiant floor heating system

To evaluate the thermal performance of a low-temperature electrical radiant floor heating system,an experimental facility equipped with a constant temperature chamber and different specimen floors is designed and built.The heating cable is installed in the floor slab with a unit-rated power of 30 W/m.Twenty-four different schemes are worked out and tested,which include three kinds of composite floor structures and eight kinds of cable distances.The cable distances are 30,40,50,60,80,100,130,150 mm.The main affective factors of the thermal performance and their influencing regularity are discussed.The experimental results show that the system has good stability and reliability,and the ratio of the radiation heat-transfer rate to the gross heat-transfer rate is greater than 50%.When the floor structure and the cable distance are fixed,the gross heat-transfer rate of the upper floor surface has a maximum value at an optimal cable distance.Under the experimental conditions in this paper,the optimal cable distance is 50 mm.

A DC-to-32GHz 2Bit MEMS Phase Shifter

A two-bit phase shifter with distributed microelectromechanical system (MEMS) transmission line (DMTL) is developed,and a novel structure which be actuated by coplanar waveguide transmission line (CPW-actuation structure) is proposed,which can reduce the actuation voltage significantly.The measured result,with actuation voltage less than 20V,0°/20.1°/41.9°/68.2° phase shift and -1.2dB insert loss at 20GHz,is demonstrated,and insertion loss/return loss is better than -1.8dB/-11dB from DC to 32GHz.The experimental results highlight the potential of a low-loss and broadband digital MEMS phase shifter on a high-permittivity substrate.

Ambient electrical conductivity of carbon cathode materials for aluminum reduction cells

The ambient electrical conductivity (AEC) of carbon cathode materials was investigated in respect to their open porosity, crystal structure and graphite content using hydrostatic method, four-probe technique and X-ray diffraction (XRD), respectively. The AEC is proportional to the specific conductivity (σ0) and the exponential of (1?ε) (ε is porosity) by a quasi-uniform formula based on the percolation theory. Theσ0 can reflect the intrinsic conductivity of the carbon cathodes free of pores, and it depends on the mean crystallite size parallel to the layer (002). The exponentn is dependent on the materials nature of the cathode aggregates, while an averaged value, 4.65, can practically work well with 5 types of cathode materials. The calculation ofσ0 can be extended to the graphitic cathodes containing different aggregates using the simple rule of mixture.

小剧场话剧·刘子枫·根雕

金秋的一天下午,我按图索骥沿着梧桐叶已开始飘落的华山路找到了刘子枫的家宅。在他家楼下的电话亭里,我拨通了电话:“请问您是刘老师吗?”“我是刘子枫……”他的声音充满了平和的味道。 在他家的那间根雕满墙的书房中,我与他随便地聊起天来。

Energy Stabilities, Magnetic Properties, and Electronic Structures of Diluted Magnetic Semiconductor Zn1-xMnxS（001） Thin Films

We investigate the electronic and magnetic properties of the diluted magnetic semiconductors Zn1-xMnxS（001） thin films with different Mn doping concentrations using the total energy density functional theory. The energy stability and density of states of a single Mn atom and two Mn atoms at various doped configurations and different magnetic coupling state were calculated. Different doping configurations have different degrees of p-d hybridization, and because Mn atoms are located in different crystal-field environment, the 3d projected densities of states peak splitting of different Mn doping configurations are quite different. In the two Mn atoms doped, the calculated ground states of three kinds of stable configurations are anti-ferromagnetic state. We analyzed the 3d density of states diagram of three kinds of energy stability configurations with the two Mn atoms in different magnetic coupling state. When the two Mn atoms are ferromagnetic coupling, due to d-d electron interactions, density of states of anti-bonding state have significant broadening peaks. As the concentration of Mn atoms increases, there is a tendency for Mn atoms to form nearest neighbors and cluster around S. For such these configurations, the antiferromagnetic coupling between Mn atoms is energetically more favorable.

A High Speed IGBT Based on Dynamic Controlled Anode-Short

IGBT with high switching speed is described based on the dynamic controlled anode- short,which incorpo- rates a normally- on,p- MOSFET controlled by the anode voltage indirectly.This device works just as normal when it is in on- state since the channel of the p- MOSFET is pinched- off.During the course of turning off,the channel of the p- MOSFET will prevent the injection of m inorities and introduce an extra access for the carriers to flow to the anode directly,which m akes the IGBT reach its off- state in a shorter time.The simulation results prove that the new structure can reduce the turn- off time by m ore than75 % compared with the normal one under the same break- down voltage and on- state perform ance.Only two more resistors are needed when using this structure,and the re- quirement of the drive circuits is just the sam e as normal.

浅谈新课改下课堂教学模式

如今的教育与有史以来的教育相比,已发生重大的变革。现在回顾自己走过那么多年的教育历程和教学生涯,还真的感到有种紧迫感,不能再固步自封,在原地踏步,不思进取,而要随着时代的改革不断地去尝试新的东西,否则就会落伍,甚至被淘汰。不要把旧的、落后的教学方法带进今天教学的课堂,要教给学生探究知识的过程和方法,要将乐学会学作为具有终身价值的教育目标。要把"以教师为中心"转变为"以学生为中心",把"教师的教为中心转变为以学生的学为中心""教会学生学习"的课堂教学模式。

Effect of KOH treatment on structural and photovoltaic properties of ZnO nanorod arrays

ZnO nanorod arrays （NRs） were synthesized on the fluorine-doped SnO2 transparent conductive glass （FTO） by a simple chemical bath deposition （CBD） method combined with alkali-etched method in potassium hydroxide （KOH） solution. X-ray diffraction （XRD）, scanning electron microscopy （SEM） and current-voltage （I-V） curve were used to characterize the structure, morphologies and optoelectronic properties. The results demonstrated that ZnO NRs had wurtzite structures, the morphologies and photovoltaic properties of ZnO NRs were closely related to the concentration of KOH and etching time, well-aligned and uniformly distributed ZnO NRs were obtained after etching with 0.1 mol/L KOH for 1 h. ZnO NRs treated by KOH had been proved to have superior photovoltaic properties compared with high density ZnO NRs. When using ZnO NRs etched with 0.1 mol/L KOH for 1 h as the anode of solar cell, the conversion efficiency, short circuit current and open circuit voltage, compared with the unetched ZnO NRs, increased by 0.71%, 2.79 mA and 0.03 V, respectively.