贴片封装的光纤Bragg光栅温度传感器

分析了光纤Bragg光栅的传感原理，提出了一种基于铍青铜片封装的光纤光栅温度传感模型。通过用一种耐高温胶将FBG粘贴在膜片材料上，使FBG在温度变化过程中一直保持张紧状态，保证FBG温度传感器有良好的重复性和线性。在20～200℃范围内进行温度实验，实验结果表明，FBG反射波长与温度有很好的线性关系，该温度传感器的温度响应灵敏度为0．0315nm／℃．实验拟舍值与理论值之差仅占理论值的2．9％。该传感器的温度测量范围大，可应用在油气井下较高温度环境的测量。

基于小波变换及Wigner-Ville变换方法的超声导波信号分析

对结构中缺陷的检测和识别是无损检测中的一项重要研究课题,超声导波由于可在短时间内检测很远距离,故它的一个重要应用便是管材的检测。因而对导波检测信号的处理成为一重要研究内容,本文利用时-频分析方法中的小波变换和Wigner-Ville变换对管道和抽油杆缺陷的导波检测信号进行了分析处理。实验结果表明,进行小波变换后,缺陷回波信号的信噪比大大提高,直径仅1mm的小孔缺陷可容易地被识别出来,准确检测出其位置;通过对信号进行Wigner-Ville的相关变换,可同时在时频两域内对缺陷的回波信号进行分析,使缺陷辨别起来简单易行。两种信号处理方法的超声导波应用研究为以后导波信号的处理提供了新的实现依据。

Photoelectrocatalytic hydrogen peroxide production based on transition‐metal‐oxide semiconductors

As a kind of valuable chemicals,hydrogen peroxide(H2O2)has aroused growing attention in many fields.However,H2O2 production via traditional anthraquinone process suffers from challenges of large energy consumption and heavy carbon footprint.Alternatively,photoelectrocatalytic(PEC)production of H2O2 has shown great promises to make H2O2 a renewable fuel to store solar energy.Transition‐metal‐oxide(TMO)semiconductor based photoelectrocatalysts are among the most promising candidates for PEC H2O2 production.In this work,the fundamentals of H2O2 synthesis through PEC process are briefly introduced,followed by the state‐of‐the‐art of TMO semiconductor based photoelectrocatalysts for PEC production H2O2.Then,the progress on H2O2 fuel cells from on‐site PEC production is presented.Furthermore,the challenges and future perspectives of PEC H2O2 production are discussed.This review aims to provide inspiration for the PEC production of H2O2 as a renewable solar fuel.

Screening-Dependent Study of Superconductivity in 3d-Transition Metals Binary Alloys Superconductors

In the present article, we report the screening-dependent study of the superconducting state parameters （SSPs）, viz. electron-phonon coupling strength A, Coulomb pseudopotential μ^＊, transition temperature TC, isotope effect exponent a, and effective interaction strength No V of 3d-band transition metals binary alloys superconductors have been made extensively in the present work using a model potential formalism and employing the pseudo-alloy-atom （PAA） model for the first time. Five local field correction functions proposed by Hartree （H）, Taylor （T）, Ichimaru-Utsumi （IU）, Farid et al. （F） and Sarkar et al. （S） are used in the present investigation to study the screening influence on the aforesaid properties. The present results of the SSPs obtained from H-screening are found in qualitative agreement with the available experimental data wherever exist.

Franck-Condon Factors and Band Origins for MgH in the A2П-X2∑＋ System

We measure the dispersed spectrum of the A2H-X2E＋ system of MgH using laser abla- tion/laser induced Fluorescence method and obtain the Frank-Condon factors and related transition frequencies of the A2H（v＇=0）-X2∑＋（v＂=0,1） system by analyzing the experimental spectrum. Also, we calculate the Franck-Condon factors and transition frequencies of the A2H-X2∑＋ system of MgH. A comparison of our theoretical calculation and experimental results with other reported theoretical results was carried out as well.

Synthesis of Porphyrin-Appended Pyridine as a Fluorescent Chemosensor for Cd（Ⅱ） and Hg（Ⅱ）

In this research, specific molecular sensors are classified according to the type of receptor-cation interaction, that is ligand-metal interactions. Receptors are based on a multidentate protoporphyrin-appended pyridine platform, which leaves at least a vacant coordination site for the incoming metal ions. A protoporphyrin-appended pyridine, 2,5-pyridine dicarboxyamidyl-8,13-bis（vinyl）-3,7,18,17-tetramethyl-21 H, 23 H-porphyrin（P-PTP）, was designed and synthesized. Its application as potential fluoroionophore for recognition of cadmium and mercury ions is reported. P-PTP shows chelation-enhanced fluorescence effect with Cd（Ⅱ） and Hg（Ⅱ） via the interruption of photoinduced electron transfer （PET） process, which has been utilized as the basis of the fabrication of the metal ions-sensitive fluorescent chemosensor. The analytical performance characteristics of the proposed Cd（Ⅱ）- and Hg（Ⅱ）- sensitive chemosensors were investigated. It shows a linear response toward Cd（Ⅱ） and Hg（Ⅱ） in the concentration range of 1.0×10-3 to 1.0×10-7 M with a limit of detection of 1.0×10-7 M and 0.5×10-7M for Cd（Ⅱ） and Hg（Ⅱ）, respectively. The chemosensor shows good selectivity for Cd（Ⅱ） over a large number of other transition metal ions, i.e., Cu（Ⅱ）, Zn（Ⅱ） and mixed metal ions.

A possible new family of unconventional high temperature superconductors

We suggest a new family of Co[Ni-based materials that may host unconventional high temperature superconductivity （high-To）. These materials carry layered square lattices with each layer being formed by vertex-shared transition metal tetrahedra cation-anion complexes. The electronic physics in these materials is determined by the two dimensional layer and is fully attributed to the three near degenerated t2g d-orbitals close to a d7 filling configuration in the d-shell of CoJNi atoms. The electronic structure meets the necessary criteria for unconventional high Tc materials proposed recently by us to unify the two known high-Tc families, cuprates and iron-based superconductors. We predict that they host superconducting states with a d-wave pairing symmetry with Tc potentially higher than those of iron-based superconductors. These materials, if realized, can be a fertile new ground to study strongly correlated electronic Physics and provide decisive evidence for superconducting pairing mechanism.

Two-dimensional semiconductors with possible high room temperature mobility

We have calculated the longitudinal acoustic phonon limited electron mobility of 14 twvo-dimensional semiconductors with composition of MX2, where M （= Mo, W, Sn, Hf, Zr and Pt） is the transition metal, and X is S, Se and Te. We treated the scattering matrix by the deformation potential approximation. We found that out of 14 compounds, MoTe2, HfSe2 and ZrSe2 are promising regarding to their possible high mobility and finite band gap. The phonon limited mobility can be above 2,500 cm^2·V^-1·s^-1 at room temperature.

Ferric perchlorate-mediated radical reactions of [60]fullerene

Transition-metal-salt-mediated radical reactions of fullerenes have attracted extensive attention as a new and important method for fullerene functionalization. The application of relatively cheap and easily available ferric perchlorate (Fe(ClO 4 ) 3 ) to the synthesis of [60]fullerene (C 60 ) has demonstrated remarkable advantages and afforded a series of novel fullerene derivatives. In this review we present our recent progress in this area and summarize the reactions of C 60 with malonate esters, β-keto esters, nitriles, aldehydes/ketones, and arylboronic acids in the presence of Fe(ClO 4 ) 3 to afford the C 60-fused disubstituted lactones, C 60-fused hemiketal, C 60-fused dihydrofuran, C 60-fused oxazoles, C 60-fused 1,3-dioxolanes, and fullerenyl boronic esters. The possible reaction mechanisms for the above-mentioned reactions are also described in detail.