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碳膜夹层锂硫电池的电化学性能 被引量:4
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作者 余劲鹏 张明 +2 位作者 丁飞 唐致远 刘兴江 《电化学》 CAS CSCD 北大核心 2014年第2期105-109,共5页
选取Super-P(SP)、KB或MWCNTs导电碳膜夹层,并置于硫电极与隔膜间组装成扣式锂硫电池.相关评估结果表明,碳膜夹层可显著提高锂硫电池循环性能,硫电极(载硫量为80%,by mass,下同)循环40周后比容量均在800 mAh·g-1以上.上述三种碳膜... 选取Super-P(SP)、KB或MWCNTs导电碳膜夹层,并置于硫电极与隔膜间组装成扣式锂硫电池.相关评估结果表明,碳膜夹层可显著提高锂硫电池循环性能,硫电极(载硫量为80%,by mass,下同)循环40周后比容量均在800 mAh·g-1以上.上述三种碳膜的物理性质有较大差异,导致相应电池具有不同电性能.KB碳膜夹层电池呈现较强的电化学极化效应;SP碳膜夹层电池循环初期可释放出最高的比容量,而循环稳定性较差;MWCNTs碳膜可视为较适宜的导电碳夹层材料. 展开更多
关键词 锂硫电池 导电碳膜 夹层 电化学性能
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A new measurement method of crack propagation rate for brittle rock under THMC coupling condition 被引量:7
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作者 Wei YI Qiu-hua RAO +1 位作者 Zhuo LI Qing-qing SHEN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2019年第8期1728-1736,共9页
A new electrical method of conductive carbon-film(with waterproof and anticorrosion ability)was proposed to continuously measure crack propagation rate of brittle rock under THMC coupling condition.A self-designed cou... A new electrical method of conductive carbon-film(with waterproof and anticorrosion ability)was proposed to continuously measure crack propagation rate of brittle rock under THMC coupling condition.A self-designed coupling testing system was used to conduct THMC coupling fracture tests of the pre-cracked red sandstone specimens(where the temperature is only changed)by this new electrical method of conductive carbon-film.Calculation results obtained by the energy method coincide well with the test results.And the higher the temperature is,the earlier the crack is initiated and the larger the crack propagation rate and accelerated velocity are,which can prove the validity of the new electrical method.This new electrical method has advantages of continuously measuring crack propagation rate over the conventional electrical,optical and acoustic methods,and can provide important basis for safety assessment and cracking-arrest design of deep rock mass engineering. 展开更多
关键词 crack propagation rate electrical method of conductive carbon-film thermo-hydro-mechanical-chemical coupling energy method brittle rock
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