面向聚合物微器件超声波精密封接的阵列微导能结构

为提高聚合物超声波精密封接的可控性,预防高温度场下聚合物的熔融流延影响封接界面质量和精度,提出了阵列式微导能结构。以聚甲基丙烯酸甲酯(PMMA)微小管道的封接为实验对象,研究了阵列微导能结构的尺度对超声波封接过程的影响;采用热压成型工艺在被封接表面制作了5组不同高度的微结构。采用基于声波传递效率反馈的超声波精密封接方式,对超声波作用下聚合物界面的润湿行为进行了观察分析,讨论了结构尺度对超声波封接质量的影响。结果表明,随着微结构尺寸的增大,实现完全联接需要的超声波能量呈递增的趋势。该种微导能结构有效控制了聚合物熔融流延,获得了均一的封接面,可实现高质量精密封接。

Effect of KOH treatment on structural and photovoltaic properties of ZnO nanorod arrays

ZnO nanorod arrays （NRs） were synthesized on the fluorine-doped SnO2 transparent conductive glass （FTO） by a simple chemical bath deposition （CBD） method combined with alkali-etched method in potassium hydroxide （KOH） solution. X-ray diffraction （XRD）, scanning electron microscopy （SEM） and current-voltage （I-V） curve were used to characterize the structure, morphologies and optoelectronic properties. The results demonstrated that ZnO NRs had wurtzite structures, the morphologies and photovoltaic properties of ZnO NRs were closely related to the concentration of KOH and etching time, well-aligned and uniformly distributed ZnO NRs were obtained after etching with 0.1 mol/L KOH for 1 h. ZnO NRs treated by KOH had been proved to have superior photovoltaic properties compared with high density ZnO NRs. When using ZnO NRs etched with 0.1 mol/L KOH for 1 h as the anode of solar cell, the conversion efficiency, short circuit current and open circuit voltage, compared with the unetched ZnO NRs, increased by 0.71%, 2.79 mA and 0.03 V, respectively.

Collisional Line Assignments and Hyperfine Structure Interpretation in Cs22^3△1g State

Accurately known energy level structure of the A＇∑u＋b3 IIu complex of states from a recent global de-perturbation of these states has enabled additional assignments of 140 perturbation facilitated infrared-infrared double resonance （PFIIDR） transitions to the 2^3△1g state from collisionally populated intermediate 1 ＋ A Eu levels. Together with the 221 previously observed 2^3△1g←A1∑u＋←X1∑g＋ Eu X Eg double resonance lines [J. Chem. Phys. 128, 204313 （2008）], molecular constants and the Rydberg-Klein-Rees potential energy curve of the 23△1g state have been recalculated （excluding 54 perturbed levels）. The centrifugal distortion constant has been determined and agrees well with the value calculated based on standard empirical formulas. The hyperfine structure of the 23△1g state, which has not resolved in our sub-Doppler excitation spectra of the 23△1g state, has been interpreted with a preliminary simulation.

Experimental study of low-temperature electrical radiant floor heating system

To evaluate the thermal performance of a low-temperature electrical radiant floor heating system,an experimental facility equipped with a constant temperature chamber and different specimen floors is designed and built.The heating cable is installed in the floor slab with a unit-rated power of 30 W/m.Twenty-four different schemes are worked out and tested,which include three kinds of composite floor structures and eight kinds of cable distances.The cable distances are 30,40,50,60,80,100,130,150 mm.The main affective factors of the thermal performance and their influencing regularity are discussed.The experimental results show that the system has good stability and reliability,and the ratio of the radiation heat-transfer rate to the gross heat-transfer rate is greater than 50%.When the floor structure and the cable distance are fixed,the gross heat-transfer rate of the upper floor surface has a maximum value at an optimal cable distance.Under the experimental conditions in this paper,the optimal cable distance is 50 mm.

Microstructures and properties of porous TiAl-based intermetallics prepared by freeze-casting

Preparation of porous Ti Al-based intermetallics with aligned and elongated pores by freeze-casting was investigated. Engineering Ti-43 Al-9V-1Y powder(D50=50 μm), carboxymethyl cellulose, and guar gum were used to prepare the aqueous-based slurries for freeze-casting. Results showed that the porous Ti Al was obtained by using a freezing temperature of -5 ℃ and the pore structure was tailored by varying the particle content of slurry. The total porosity reduced from 81% to 62% and the aligned pore width dropped from approximately 500 to around 270 μm, with increasing the particle content from 10 to 30 vol.%. Furthermore, the compressive strength along the aligned pores increased from 16 to 120 MPa with the reduction of porosity. The effective thermal conductivities of porous Ti Al were lower than 1.81 W/(m·K) and showed anisotropic property with respect to the pore orientation.

Attenuation of wave propagation in a novel periodic structure

A novel periodic mount was presented. A theoretical model was developed to describe the dynamics of wave propagation in the novel periodic mount. The model was derived using Hamilton's energy conservation principle. The characteristics of wave propagation in unit cell were analyzed by transfer matrix formulation. Numerical examples were given to illustrate the effectiveness of the periodic mount. The experiments were carried out to identify the predications of the theoretical model. The obtained results show that the experimental results coincide with the prediction of theoretical model. No pass bands appear in the overall frequency range measured when waves propagate in the longitude direction of the periodic mount. These dramatic results demonstrate its potential as an excellent mount in attenuating and isolating vibration transmission.

Optimum Parameters of MgZnSSe/ZnSe BRAQ WET

A theoretical basis of optimally designed BRAQWET is pr esented. The optimum parameters of MgZnSSe/ZnSe BRAQWET are obtained by the ca lculation of band-structure according to the depletion approximation.

MnQ_2(Q=S,Se,Te)and Te_4 Structures and Their Semiconductor Properties

The solvo―thermal technique is used for the synthesis of [Mn(en)_3]Te_4 (I).The crystal structure has been determined by single crystal X―ray diffraction techniques. Thecrystal belongs to the monoclinic, space group p2_1/c with unit cell:a = 0. 846 1(1), b=1.5653(2),c=1.426 9(2) nm, α = 90°, β=91. 37(1) (3)°, γ=90°, V=1. 889 3(4) nm^3, and Z=4. The resultsshow that the structure contains a linear chain Zintl anion, [Te_4 ]^(2-) and a complex cation,[Mn(en)_3l^(2+). Optical studies have been performed on the powder sample of I, suggesting that thecompound is a semiconductor with a band gap of 0. 73 eV. The semiconductor properties for MnQ_2(Q=S, Se, Te) and [Mn(en)_3]Te_4 have been discussed by molecular orbital theory.

Electronic and Optical Properties of Rock-Salt A1N under High Pressure via First-Principles Analysis

Electronic and optical properties of rock-salt AIN under high pressure are investigated by first-principlesmethod based on the plane-wave basis set.Analysis of band structures suggests that the rock-salt AIN has an indirectgap of 4.53 eV,which is in good agreement with other results.By investigating the effects of pressure on the energygap,the different movement of conduction band at X point below and above 22.5 GPa is predicted.The opticalproperties including dielectric function,absorption,reflectivity,and refractive index are also calculated and analyzed.Itis found that the rock-salt AIN is transparent from the partially ultra-violet to the visible light area and hardly does thetransparence affected by the pressure.Furthermore,the curve of optical spectrum will shift to high energy area (blueshift) with increasing pressure.

Influences of a Side-Coupled Triple Quantum Dot on Kondo Transport Through a Quantum Dot

Kondo transport properties through a Kondo-type quantum dot （QD） with a side-coupled triple-QD structure are systematically investigated by using the non-equilibrium Green＇s function method. We firstly derive the formulae of the current, the linear conductance, the transmission coefficient, and the local density of states. Then we carry out the analytical and numerical studies and some universal conductance properties are obtained. It is shown that the number of the conductance valleys is intrinsically determined by the side-coupled QDs and at most equal to the number of the QDs included in the side-coupled structure in the asymmetric limit. In the process of forming the conductance valleys, the side-coupled QD system plays the dominant role while the couplings between the Kondo-type QD and the side-coupled structure play the subsidiary and indispensable roles. To testify the validity of the universal conductance properties, another different kinds of side-coupled triple-QD structures are considered. It should be emphasized that these universal properties axe applicable in understanding this kind of systems with arbitrary many-QD side structures.

Synthesis of texture-excellent mesoporous alumina using PEG1000 as structure-directing agent

By varying concentration of PEG1000 as a structure-directing agent,mesoporous alumina with excellent textural properties was synthesized.The prepared mesoporous alumina displays high thermal stability,as shown by its textural properties at different calcination temperatures of 600-850 °C.Characterization by SEM and TEM revealed that the added PEG surfactant induced the formation of petal-like alumina.XRD results clarified that all samples were amorphous and their peaks were around the peaks of γ-alumina.N_2 adsorption-desorption analysis showed that the prepared mesoporous alumina,if with PEG1000 in hydrolysis of aluminum isopropoxide,had excellent textural properties with large specific surface area,high pore volume and suitable pore size.The petal-like structure existing in the alumina samples improved their textural parameters,and the role and influential mechanism of PEG1000 were analyzed.

Formation mechanism and modulation of electromagnetically induced transparency-like transmission in side-coupled structures

Based on Fabry model and finite-different time-domain(FDTD) method, the plasmonic structure composed of a metal-insulator-metal(MIM) bus waveguide and a side-coupled resonator was investigated. It is found that the transmission features can be regulated by the cavity width and coupling distance. Electromagnetically induced transparency(EIT)-like transmission can be excited by adding an identical resonator on the pre-existing structure. Combining the foregoing theoretical analysis with coupled mode theory(CMT), the formation process of the EIT-like transmission was detailedly analyzed. EIT-like transmission can also be excited in plasmonic structure with two detuned resonators. By altering the structure parameters, the transparency window can be purposefully modulated. With the merits of compact structure and simplicity in fabrication, the proposed structures may have a broad prospect of applications in highly integrated optical circuits.

First-Principle Studies on Conductive Behaviors of P-Type ZnO Codoped by N and B

Using a first-principle method, the electronic structures and the impurity formation energy of ZnO, ZnO （N）, ZnO （N＋B）, and ZnO （2N＋B） have been calculated, based on which the feasibility to obtain p-type ZnO ＆ discussed. According to the results, when ZnO is single doped by N, the acceptor level is deep, and the formation energy is negative, so the ideal p-type ZnO can not be obtained by this way. On the contrary, when 2N＋B are codoped into ZnO, the acceptor level becomes much lower, and the formation energy is positive, so it is a better way to obtain p-type ZnO.

The Guidance and Meaning directed by the Three Phases of Memory on the Reading of Literature Works Written by the Style of Stream of Consciousness ——taking the Work Hear the Wind Sing by Haruki Murakami as an Example

Recently, the researchers put their attention on the literature works on Virginia Woolf or James Joyce too heavily just because the skill of stream of consciousness is used through the novel completely. Choosing this novel by Japanese writer as an example is an experiment, because the stream of consciousness as a composing method has melted its impression into the modem novel. And in the researcher＇s opinion, regardless the traditional part, the researching focus should be shifted on the works written by nowadays writer. To begin this paper, there are four questions should be solved： First, the definition of stream of consciousness should be known clearly; another question is the structure analysis of structure of Hear the Wind Sing; secondly, compared with the mental space theory and blending theory by Fauconnier, how to judge the function of Three Phases of memory＇s direction on reading should be focused on; thirdly, the reason why readers meet the problem of barrier when they read the stream of consciousness novel, and how the memory helps to solve the problem should be study in this section. Fourth, the extra factors which support the function of memory will enhance the skill of reading the SOC novel and finally foreground the meaning.

Effects of Long-term Right Ventricular Apical Pacing on Left Ventricular Remodeling and Cardiac Function

Objective: To investigate the impacts of long-term right ventricular apical pacing on the ventricular remodeling and cardiac functions of patients with high-grade and third-degree atrioventricular blockage with normal heart structures and cardiac functions. In addition, we provide many evidences for choosing an optimal electrode implantation site.Methods: Study participants included patients who were admitted for pacemaker replacements and revisited for examinations of implanted pacemakers at outpatient. Pacemakers were implanted to treat high-grade and third-degree atrioventricular blockage. At the time of pacemaker implantation, patients had normal cardiac functions and showed no serious heart diseases or cardiac dilatation. The durations from the implantation to follow-up were more than 5 years. The pacing rate was higher than 80%. Patients with a left ventricular ejection fraction (LVEF) < 50% and a left ventricular end-diastolic diameter (LVEDD) > 55 mm were excluded. Ventricular remodeling was defined as follows:increase of LVEDD by 10% and a reduction of LVEF by 25% for five years after implantation. Cardiac functions were evaluated according to New York Heart Association (NYHA) classification.Results:A total of 82 patients with a mean age of (66.97±13.19) years (range, 12 to 91 years old),among which 39 male and 43 female were enrolled in this study. The average duration between two assessments was 8.7 years (104.4 months). Before pacemaker implantation, the average left atrial diameter (LA), LVEDD and LVEF were 37.0 mm, 50.23 mm and 64.87%, respectively. After the implantation, these values were 39.39 mm (P=0.000163), 50.82 mm (P=0.177842) and 60.50% (P=0.000104), respectively. Four patients (4.87%) had ventricular remodeling with deteriorations of cardiac function, three of which had anterior wall myocardial infarction after implantation and one had type II diabetes. Clinical symptoms of heart failure were not found among the patients who did not exhibit ventricular remodeling. Conclusion: Through a long-period follow-up study, we found that long-term right ventricular apical pacing in patients with normal heart structure and cardiac function would not generally cause ventricular remodeling and clinical deteriorations of cardiac function. Right ventricular apical is a safe and effective site for pacing electrode wire implantation.

Constructal entransy dissipation rate minimization for leaf-like fins

Based on constructal theory,the constructs of the leaf-like fins are optimized by taking minimum entransy dissipation rate(for the fixed total thermal current,i.e.,the equivalent thermal resistance) as optimization objective.The optimal constructs of the leaf-like fins with minimum dimensionless equivalent thermal resistance are obtained.The results show that there exists an optimal elemental leaf-like fin number,which leads to an optimal global heat conduction performance of the first order leaf-like fin.The Biot number has little effects on the optimal elemental fin number,optimal ratios of length and width of the elemental and first order leaf-like fins;with the increase of the thermal conductivity ratio of the vein and blade,the optimal elemental fin number and optimal ratio of the length and width of the elemental leaf-like fin increase,and the optimal shape of the first order leaf-like fin becomes tubbier.The optimal construct based on entransy dissipation rate minimization is obviously different from that based on maximum temperature difference minimization.The dimensionless equivalent thermal resistance based on entransy dissipation rate minimization is reduced by 11.54% compared to that based on maximum temperature difference minimization,and the global heat conduction performance of the leaf-like fin is effectively improved.For the same volumes of the elemental and first order leaf-like fins,the minimum dimensionless equivalent thermal resistance of the first order of the leaf-like fin is reduced by 30.10% compared to that of the elemental leaf-like fin,and the global heat conduction performance of the first order leaf-like fin is obviously better than that of the elemental leaf-like fin.Essentially,this is because the temperature gradient field of the first order leaf-like fin based on entransy dissipation rate minimization is more homogenous than that of the elemental leaf-like fin.The dimensionless equivalent thermal resistance defined based on entransy dissipation rate reflects the average heat transfer performance of the leaf-like fin,and can provide some guidelines for the thermal design of the fins from the viewpoint of heat transfer optimization.

The critical role of spin rotation in the giant magnetostriction of La(Fe,Al)_(13)

As an efficient converter between electromagnetic and mechanical energies, magnetostriction is an intriguing property for not only fundamental studies but also technological applications. However, the understanding of its microscopic origin remains challenging, which is critical for the development of magnetostriction materials. Here, the critical role of spin rotation in the giant magnetostriction of La(Fe,Al)_(13) is first revealed by the in-situ magnetic and temperature field of neutron powder diffraction. The giant magnetostriction originates from magnetic-field-driven spin moment rotation of canting structure, in which the sharp increase of ferromagnetic component causes the elongation of icosahedron inside of lattice. Furthermore, it is the first time to reveal the accurate canting antiferromagnetic structure in La(Fe,Al)_(13). The present study provides a new strategy, i.e., the spin rotation, for exploring new magnetostriction functional materials.

Identifying the genes of unconventional high temperature superconductors

We elucidate a recently emergent framework in unifying the two families of high temperature （high To） superconductors, cuprates and iron-based superconductors. The unification suggests that the latter is simply the counterpart of the former to realize robust extended s-wave pairing symmetries in a square lattice. The unification identifies that the key ingredients （gene） of high Tc superconductors is a quasi two dimensional electronic environment in which the d-orbitals of cations that partic- ipate in strong in-plane couplings to the p-orbitals of anions are isolated near Fermi energy. With this gene, the superexchange magnetic interactions mediated by anions could maximize their contributions to superconductivity. Creating the gene requires special arrangements between local electronic structures and crystal lattice structures. The speciality explains why high Tc superconductors are so rare. An explicit prediction is made to realize high Tc superconductivity in Co/Ni-based materials with a quasi two dimensional hexagonal lattice structure formed by trigonal bipyramidal complexes.

Nonlinear investigation of beam-wave interaction in double-groove loaded folded-waveguide traveling-wave tube

A W-band traveling-wave tube (TWT) with double-groove loaded folded waveguide structure (FWSWS) has been designed and numerically modelled. The nonlinear performance of such a TWT is investigated by a particle-in-cell code MAGIC3D. Simulation results indicate this TWT produces a saturated electromagnetic power of 170.2 W at 90 GHz, corresponding to 36.9 dB gain and 69.6 mm interaction distance. A comparison between the novel folded waveguide traveling-wave tube (FWTWT) and the conventional one is also carried out to verify the effect of groove loading on the large-signal performance of TWT. Within the same working conditions, the double groove-loaded FWTWT could obtain higher saturated output power and gain in a shorter interaction length. The maximum of output power and gain of this novel TWT is 58.6% and 10% higher than those of the conventional FWTWT, while the 3-dB bandwidth of TWT is reduced to 4 GHz. With the additional advantage of ease of fabrication based on micro-electro-mechanical systems (MEMS) technologies, the double-groove loaded FWSWS is suitable for a millimeter-wave TWT with high power capacity and gain.

Enhancement of photoresponsive electrical characteristics of multilayer MoS2 transistors using rubrene patches

Multilayer MoS2 is a promising active material for sensing, energy harvesting, and optoelectronic devices owing to its intriguing tunable electronic band structure. However, its optoelectronic applications have been limited due to its indirect band gap nature. In this study, we fabricated a new type of phototransistor using multilayer MoS2 crystal hybridized with p-type organic semiconducting rubrene patches. Owing to the outstanding photophysical properties of rubrene, the device characteristics such as charge mobility and photoresponsivity were considerably enhanced to an extent depending on the thickness of the rubrene patches. The enhanced photoresponsive conductance was analyzed in terms of the charge results of the nanoscale laser confocal time-resolved PL measurements. transfer doping effect, validated by the microscope photoluminescence （PL） and