规划法在接触分析中的无意义射线解

利用规划法解接触问题时会遇到无意义射线解的情况。基于参变量变分原理，对这一问题进行了讨论，指出了使这种情况发生的一个原因。除了对常规的互补性条件进行考虑之外，Ｌｅｍｋｅ算法求解时还应考虑一种内互补条件，由此可以避免无意义射线解的情况。

论莫尔斯的室内声场简正波理论解的完备性

物理学家莫尔斯提出的室内受迫振动简正波理论在数学处理上无懈可击,但是,其声压解全部由简正波组成,无法直接观察到直达声的存在,因此,近些年来受到国内一些学者的置疑:该简正波理论解是包括直达声的全部解,还是不包括直达声的部分解?在傅里叶分析和狄拉克函数的基础上,经过严格的数学推导,证明莫尔斯简正波理论关于室内声源的基本假设是正确的,其物理涵义是:室内任意一个声源分布及由室内壁面反射引起的一系列镜像声源组合后可表示为分立简正函数的迭加,回答了国内一些学者对莫尔斯的室内声源基本假设的置疑。此外,在空间域上由简正波解推导出了射线解,证明室内受迫振动简正波理论与镜像原理完全等价。据此,认为简正波理论解是室内稳态声场的完备解。

Effects of PVP K30 on Aqueous Solubility and Dissolution Propertiesof Daidzein

AimTo study effects of PVP K30 on the aque ou s solubility and dissolution properties of daidzein. Methods To measure the aqueous solubility and dissolution rates of daidzein in three diffe rent states (within solid dispersions, physical mixtures and as a pure drug) and investigate drug-polymer interactions in the solid state using X-ray powder d iffraction and fourier-transform infrared spectroscopy. Results The negative values of the Gibbs free energy and enthalpy of transfer explaine d the spontaneous transfer of daidzein from phosphate buffer solution (PBS) to a solution of PVP in PBS. X-ray powder diffraction patterns showed that the drug was in the amorphous state (ratio of the drug ∶ PVP<1∶5) when dispers ed i n PVP K30. The infrared spectra indicated there exist interactions between the O H of daidzein and the C=O of PVP K30. Conclusionthe dispersion of daidzein in PVP K30 considerably enhances the solubility and dissolution rat e.

Enhanced Enzymatic Hydrolysis of Miscanthus sinensis Following Synergic Pretreatment with ^(60)Co γ-ray Irradiation and Alkaline Hydrogen Peroxide

[Objective] This study aimed to investigate the effects of different pretreat- ments on enzymatic saccharification of Miscanthus sinensis and improve reducing sugar yield in the enzymolysis process. [Method] M. sinensis was pretreated with 60Co y-ray irradiation and alkaline hydrogen peroxide, to analyze their effects on re- ducing sugar yield of enzymatic hydrolysis. [Result] After pretreatment with 400 kGy 60Co y-ray irradiation, reducing sugar yield in the enzymolysis process of M sinensis was 76.24 mg/g; after synergic pretreatment with 400 kGy 60Co y-ray irradiation and alkaline hydrogen peroxide, reducing sugar yield in the enzymolysis process of M. sinensis was 505.08 mg/g, which was improved by 5.6 times compared to that in pretreatment with 400 kGy 60Co y-ray irradiation. Based on process optimization, the optimal hydrolysis conditions were obtained： pretreatment temperature 30 ℃, NaOH concentration 1.2%, hydrogen peroxide concentration 2%, pretreatment time 6 h. [Conclusion] Synergic pretreatment with 60Co y-ray irradiation and alkaline hydrogen peroxide could significantly improve reducing sugar yield in the enzymolysis process of M. sinensis, which provided a new theoretical basis for preparing fuel ethanol with M. sinensis.

一种基于序贯估计的直达声区水面舰船被动测距方法

该文利用基于射线的盲解卷积方法,从直达声区的水面舰船噪声中提取出船和锚系于海底的垂直接收阵之间的时域信道响应,并利用直达波在不同阵元相对于参考阵元的到达时间差,通过序贯方法,利用射线模型和声速剖面信息,对水面舰船距接收阵的距离进行了估计.通过处理海深约为580 m的2016年美国圣巴巴拉海峡的实验数据,对1.6~3.5 km直达声区范围内Anna Maersk商船与垂直阵之间的距离进行了估计,验证了测距方法的有效性,并将结果与系统测量值和几何方法的估计值进行了比较.由于该方法不需要对海底参数进行估计,所以在海底参数未知时要优于传统匹配场方法;在声速剖面存在跃层且海底为多层分布的复杂信道条件下,该方法仍能对距离进行有效估计,且与测量值的相对误差在6%以内,小于几何方法的估计误差,测距结果精度较高.

Preparation of calcium phosphate coatings on Mg-1.0Ca alloy

The calcium phosphate coatings were prepared by virtue of electrochemical deposition in order to improve the corrosion resistance of Mg-1.0Ca alloys in simulated body fluids.The chemical compositions,structures and morphologies of the coatings were investigated by energy dispersive spectroscopy(EDS),X-ray diffractometry(XRD)and scanning electron microscopy(SEM), respectively.The potentiodynamic electrochemical technique was employed to investigate the bio-degradation behavior of Mg-1.0Ca alloys with Ca-P coatings in Hank's solutions.The experimental results show that the deposited coatings predominately consist of flake-shape brushite(DCPD,CaHPO4·2H2O)crystallites.The corrosion resistance of the substrates with coatings is improved in Hank's solutions significantly.

Alteration of diaspore by thermal treatment

Diaspore （α-AlOOH） was heated at various temperatures from 300 to 1 000 ℃ for 2 h. The alteration of diaspore by thermal treatment was investigated by differential thermal analysis, thermogravimetric analysis and X-ray diffraction. The mechanism of thermal decomposition of diaspore was discussed according to the Coats-Redfern （equation.） It is found that after thermal treatment at 500 ℃, diaspore is transformed entirely to corundum （（α-Al2O3）.） Combined with the mass loss ratio obtained from the thermogravimetric analysis data, the activation energies for the thermal treatment of diaspore are calculated as Ea=10.4 kJ/mol below 400 ℃ and Eb=47.5 kJ/mol above 400 ℃, respectively, which is directly related to the structural alteration of diaspore during the thermal treatment. The results indicate that the thermal decomposition of diaspore is conducted primarily by means of an interfacial reaction.

Effects of Elevated Solar UV-B Radiation from Ozone Depletion on Terrestrial Ecosystems

In the last three decades much researchhas been carried out to investigate the biologicaleffects of a thinning stratospheric ozone layeraccompanied by an enhanced level of solarultraviolet-B radiation at the Earth’s surface.Enhanced UV-B radiation affects ecosystems in manyways directly and indirectly. The responses can bebiochemical, physiological, morphological oranatomical, and the direction of the response can varybetween different species, communities andecosystems. In this paper we firstly introduce generalconcepts, and methods for measuring the ecologicaleffects of UV-B radiation. Secondly, we provide anoverview interpretation of the effects of enhancedUV-B on terrestrial ecosystems from recent studies.These studies include effects of UV-B on growth andreproduction, composition of communities,competitive balance, decomposition of litter, andinteractions with other factors etc. Finally, werecommend future research directions to identify theeffects of elevated UV-B radiation on ecosystems inChina.

Preparation of microsized single-crystalline Co_3O_4 by high-temperature hydrolysis

Microsized single-crystalline Co3O4 has been synthesized by high-temperature hydrolysis of CoCD2H20 at 600℃. The samples were characterized by powder X-ray diffraction （XRD）, scanning electron microscopy （SEM） and transmission electron microscopy （TEM）. The results reveal that the as-prepared powders are microsized single-crystalline CO3O4 with cubic spinel structure. An increase in the high-temperature hydrolysis time results in the evolution of particle shapes from cube to quasi-sphere, and then to octahedron. The effect of NaCl additive on the surface morphologies of Co3O4 particles was experimentally investigated. The results indicate that the NaCl additive acts as an inert disperse phase in the high-temperature hydrolysis, and prevents the aggregation of Co3O4 particles effectively.

Extractability of Cu in Alkaline Biosolids-Amended Soilsas Influenced by γ-Irradiation

An incubation experiment was conducted to investigate themicrobial biomass associated Cu in four contrasting soils to which analkaline stabilised sewage sludge cake was applied. The organisms ofsludge- amended and control soils were killed using γ-irradiationtechnique, and the aqueous and acid-extractable Cu concentrationswere determined. Addition of the sludge product increasedsignificantly the concentration of both the aqueous and diluteHOAc-extractable Cu in all the irradiated soils compared to thenon-sterilised sludge/soil mixtures, but the increase was morepronounced in the dilute acid-extractable Cu, indicating that the Curendered extractable in water and dilute acetic acid by γ-irradiation existed in the both soil liquid and solid phases. Theadditional increase in extractable Cu following the biocidaltreatment is likely to be due to release of Cu from the same fractionof soil microbial biomass.

Influence of alkylpyridinium ionic liquids on copper electrodeposition from acidic sulfate electrolyte

The effect of two alkylpyridinium ionic liquids （py-iLs） including N-butylpyridinium hydrogen sulfate （BpyHSO4） and N-hexylpyridinium hydrogen sulfate （HpyHSO4） on the kinetics of copper electrodeposition from acidic sulfate solution was investigated by cyclic voltammetry and potentiodynamic polarization measurements. Results from cyclic voltammetry indicate that these py-iLs have a pronounced inhibiting effect on CuE＋ electroreduction and there exists a typical nucleation and growth process. Kinetic parameters such as Tafel slope, transfer coefficient and exchange current density obtained from Tafel plots, lead to the conclusion that py-iLs inhibit the charge transfer by slightly changing the copper electrodeposition mechanism through their adsorption on the cathodic surface. In addition, scanning electron microscope （SEM） and X-ray diffraction analyses reveal that the presence of these additives leads to more leveled and fine-grained cathodic deposits without changing the crystal structure of the electrodeposited copper but strongly affects the crystallographic orientation by significantly inhibiting the growth of （111）, （200） and （311） planes.

Facile Synthesis of Coronene Dimers Having Unique Optical Properties

The authors synthesized very pure dimer phase of coroneae by simple heat-treatment and subsequent sublimation purification. It was confirmed by laser desorption/ionization mass spectroscopy measurements that pure dimer phase of coronenes can be obtained by controlling the fusing and sublimation temperatures. The crystal structure of the dimer phase was analyzed by synchrotron XRD （X-ray diffraction） experiments. It was also found that very bright red light is emitted by irradiating ultra violet light （λ = 350 nm） to the dimer phase. The external and internal quantum yields were determined to be 5.56% and 6.95%, respectively.

General Solutions of Reflection Equations for Bariev Model

The integrable general open-boundary conditions for the one-dimensional Bariev chain are considered. All kinds of solutions to the reflection equation （RE） and its dual are obtained.

Conservation Laws and Analytic Soliton Solutions for Coupled Integrable Dispersionless Equations with Symbolic Computation

Under investigation in this paper are two coupled integrable dispersionless (CID) equations modelingthe dynamics of the current-fed string within an external magnetic field.Through a set of the dependent variabletransformations, the bilinear forms for the CID equations are derived.Based on the Hirota method and symboliccomputation, the analytic N-soliton solutions are presented.Infinitely many conservation laws for the CID equationsare given through the known spectral problem.Propagation characteristics and interaction behaviors of the solitons areanalyzed graphically.

Preparation and characterization of lithium hexafluorophosphate for lithium-ion battery electrolyte

A promising preparation method for lithium hexafluorophosphate(LiPF6)was introduced.Phosphorus pentafluoride(PF5) was first prepared using CaF2 and P2O5 at 280℃for 3 h.LiPF6 was synthesized in acetonitrile solvent by LiF and PF5 at room temperature(20-30℃)for 4 h.The synthesized LiPF6 was characterized by infrared spectrometry and X-ray diffraction(XRD). Atomic absorption and ion chromatography results show that the purity of synthesized LiPF6 reaches 99.98%.Thermal stability of self-synthesized LiPF6 was analyzed by differential thermal analysis and thermogravimetry.The results indicate that the self-synthesized LiPF6 has higher purity,lower impurity contents and better thermal stability than the commercial LiPF6.

One step synthesis and characterization of copper doped sulfated titania and its enhanced photocatalytic activity in visible light by degradation of methyl orange

This paper reports on the synthesis of copper doped sulfated titania nano-crystalline powders with varying （2.0%-10.0%, by mass） by single step sol gel method. The synthesized photo catalyst has been characterized by employing various techniques like X-ray Diffraction （XRD）, Ultraviolet-Visible Diffuse Reflection Spectroscopy （UV-Vis DRS）, X-ray Photoelectron Spectroscopy （XPS）, Scanning Electron Microscopy （SEM）, Energy Dispersive Spectrometry （EDS）, Fourier Transform Infrared Spectroscopic Studies （FT-IR）, and Transmission Electron Microscopy （TEM）. From the XRD and TEM results, all the samples were reported in anatase phase with reduction in particle size in the range of 7 to 12 nm. SEM indicated the change in morphology of the particles. The presence of copper in titania lattice was evidenced by XPS. From UV-Vis DRS and FT-IR studies indicated that prominent absorption shift is observed towards visible region （red shift）, the entry ofCu2 ＋ into Ti02 lattice as a substitution- al dopant and S042- ions were covalently bonded with Ti4＋ on the surface of the copper doped titania respectively. The photocatalytic activity studies were investigated by considering methyl orange （MO） as dye pollutant in the presence of the visible light. The effect of various parameters like effect of dosage of the catalyst, dopant concentration, pH of the solution, and concentration of the dye was studied in detail.

Characterization of stereostructure by X-ray and technology of extracting in combination hydrolysis in situ of acankoreanogenin from leaves of Acanthopanax gracilistylus W.W.Smith

To study the stereostructure by X-ray and the technology of extracting acankoreanogenin from the leaves of Acanthopanax graeilistylus W. W. Smith （AGS）, the crystal structure was measured with a Bruker APEX-Ⅱ area-detector diffractometer instrument and the technology of extracting in combination hydrolysis in situ （ECHS） was compared with these of traditional methods. The crystal belongs to the monoclinic system, space group P2b with unit cell parameters： a=（8.3652±0.0006） nm, b=（24.721±0.002） nm, and c=（14.5587±0.0011） nm, α=90°, β=97.850 （4） °, γ=90 °, V=2982.51 nm3, Dc= 1.179 mg/m3, and the molecular number （Z） of elementary structures was 2. The comparisons show that the extraction rate of acankoreanogenin with ECHS methods is much higher than that of traditional methods. Then, central composite design-response surface methodology （CCD-RSM） was adopted for optimizing the extraction rate of ECHS methods. The optimized values of extraction parameters are as follows： for the for extraction process of acid hydrolysis are that extraction time 110.8 min, solvent-herb ratio 11.5 and acid content 5.25%; the best extraction process of basic hydrolysis are that extract time 120 min, solvent-herb ratio 8.7 and the alkali content 8.79%. Finally, the extracts were purified with decolorizing carbon after alkali solution and acid-isolation and purity of acankoreanogenin was 98.7%.

A Note on the Solution of Water Wave Scattering Problem Involving Small Deformation on a Porous Channel-Bed

The solution of water wave scattering problem involving small deformation on a porous bed in a channel, where the upper surface is bounded above by an infinitely extent rigid horizontal surface, is studied here within the framework of linearized water wave theory. In such a situation, there exists only one mode of waves propagating on the porous surface. A simplified perturbation analysis, involving a small parameter ε （≤1） , which measures the smallness of the deformation, is employed to reduce the governing Boundary Value Problem （BVP） to a simpler BVP for the first-order correction of the potential function. The first-order potential function and, hence, the first-order reflection and transmission coefficients are obtained by the method based on Fourier transform technique as well as Green＇s integral theorem with the introduction of appropriate Green＇s function. Two special examples of bottom deformation： the exponentially damped deformation and the sinusoidal ripple bed, are considered to validate the results. For the particular example of a patch of sinusoidal ripples, the resonant interaction between the bed and the upper surface of the fluid is attained in the neighborhood of a singularity, when the ripples wavenumbers of the bottom deformation become approximately twice the components of the incident field wavenumber along the positive x -direction. Also, the main advantage of the present study is that the results for the values of reflection and transmission coefficients are found to satisfy the energy-balance relation almost accurately.

Radiation-Chemical Degradation of Oxalic Acid in Water Solutions

Co60 gamma ray radiolysis of aqueous oxalic acid solution （1 × 10-2 M） was investigated within the dose range up to 80 kGy. The value of pH increases from 2.0 to 4.0 and approximately 90% of oxalic acid and its derivatives are degraded at the dose of 80 kGy. Dissolved O2 affects to the degradation of oxalic acid at the initial stage due to total consumption of O2 at the dose of 2 kGy. Formation of CO2 occurs at a higher rate at the initial stage until the dissolved 02 is fully consumed. The kinetic model of oxalic acid degradation in aqueous solution under the gamma irradiation was tested. The suggested mechanism complies with the experimental data both of our own and of that reported earlier.

Approximate Analytic Solution of Solitary Wave for a Class of Nonlinear Disturbed Long-Wave System

In this paper, the approximate expressions of the solitary wave solutions for a class of nonlinear disturbed long-wave system are constructed using the homotopie mapping method.