Graphene sponge(GS) with microscale size, high mechanical elasticity and electrical conductivity has attracted great interest as a sensing material for piezoresistive pressure sensor. However, GS offering a lower limi...Graphene sponge(GS) with microscale size, high mechanical elasticity and electrical conductivity has attracted great interest as a sensing material for piezoresistive pressure sensor. However, GS offering a lower limit of pressure detection with high gauge factor, which is closely dependent on the mechanical and electrical properties and determined by the fabrication process, is still demanded. Here, γ-ray irradiation reduced GS is reported to possess a gauge factor of 1.03 kPa^–1 with pressure detection limit of 10 Pa and high stress retention of 76% after 800 cycles of compressing/relaxation at strain of 50%. Compared with the carbon nanotube(CNT) reinforced GS, the improved lower limit of pressure detection and gauge factor of the GS prepared by γ-ray irradiation is due to the low compression stress(0.9 kPa at stain of 50%). These excellent physical properties of the GS are ascribed to the mild,residual free, and controllable reduction process offered by γ-ray irradiation.展开更多
基金the National Natural Science Foundation of China(21503064)Anhui Provincial Natural Science Foundation for support(1508085QE103)+3 种基金the Ministry of Science and Technology of China(2015CB351903)the 100 Talents Program of the Chinese Academy of Sciences,USTC Startupthe Fundamental Research Funds for the Central Universities(WK2060140003)iChEM
文摘Graphene sponge(GS) with microscale size, high mechanical elasticity and electrical conductivity has attracted great interest as a sensing material for piezoresistive pressure sensor. However, GS offering a lower limit of pressure detection with high gauge factor, which is closely dependent on the mechanical and electrical properties and determined by the fabrication process, is still demanded. Here, γ-ray irradiation reduced GS is reported to possess a gauge factor of 1.03 kPa^–1 with pressure detection limit of 10 Pa and high stress retention of 76% after 800 cycles of compressing/relaxation at strain of 50%. Compared with the carbon nanotube(CNT) reinforced GS, the improved lower limit of pressure detection and gauge factor of the GS prepared by γ-ray irradiation is due to the low compression stress(0.9 kPa at stain of 50%). These excellent physical properties of the GS are ascribed to the mild,residual free, and controllable reduction process offered by γ-ray irradiation.