Gallium-titanium-zinc oxide(GTZO) transparent conducting oxide(TCO) thin films were deposited on glass substrates by radio frequency magnetron sputtering. The dependences of the microstructure and optoelectronic prope...Gallium-titanium-zinc oxide(GTZO) transparent conducting oxide(TCO) thin films were deposited on glass substrates by radio frequency magnetron sputtering. The dependences of the microstructure and optoelectronic properties of GTZO thin films on Ar gas pressure were observed. The X-ray diffraction(XRD) and scanning electron microscopy(SEM) results show that all the deposited films are polycrystalline with a hexagonal structure and have a preferred orientation along the c-axis perpendicular to the substrate. With the increment of Ar gas pressure, the microstructure and optoelectronic properties of GTZO thin films will be changed. When Ar gas pressure is 0.4 Pa, the deposited films possess the best crystal quality and optoelectronic properties.展开更多
To study the ferroelectric photovoltaic effect based on polycrystalline films, preparation of high-quality polycrystalline films with low leakage and high remnant polarization is essential. Polycrystalline BiFeO3 (BF...To study the ferroelectric photovoltaic effect based on polycrystalline films, preparation of high-quality polycrystalline films with low leakage and high remnant polarization is essential. Polycrystalline BiFeO3 (BFO) thin films with extremely large remnant polarization (2Pr = 180 ~aC/cm2) were successfully deposited on glass substrates coated with indium tin oxide using a modified radio frequency magnetron sputtering method. Symmetric and asymmetric cells were constructed to investigate the ferroelectric photovoltaic effect in order to understand the relationship between polarization and photovoltaic response. All examined cells showed polarization-induced photovoltaic effect. Our findings also showed that the ferroelectric photovoltaic effect is highly dependent on the material used for the top electrode and the thickness of the polycrystalline film.展开更多
Compared to traditional optical domes, domes of sapphire coated with films can effectively reduce emissivity and increase transmittance. The purpose of this work is to investigate the thermal radiation effect on sapph...Compared to traditional optical domes, domes of sapphire coated with films can effectively reduce emissivity and increase transmittance. The purpose of this work is to investigate the thermal radiation effect on sapphire optical dome coated with yttrium oxide by a radio frequency mag- netron sputtering method. The emissivity of sapphire coated with Y203 films is studied by both numerical and experi- mental methods. The results indicate that the emissivity of sapphire substrate is reduced effectively with increasing the thickness of the Y203 film. In addition, a finite element model is developed to simulate the radiation intensity of the optical dome. The thermal responses indicate that the max- imum temperature is reduced apparently compared with the uncoated sapphire as Y203 film thicknesses increase. The average irradiance distribution at different film thicknesses with time shows that the self-thermal radiation disturbance of sapphire optical dome delays 0.93 s when the thickness of Y203 film is 200μm, which can guarantee the dome works properly and effectively even in a harsh environment.展开更多
基金supported by the National Natural Science Foundation of China(No.11504436)the Natural Science Foundation of Hubei Province(No.2015CFB364)the Fundamental Research Funds for the Central Universities(Nos.CZW14019 and CZW15045)
文摘Gallium-titanium-zinc oxide(GTZO) transparent conducting oxide(TCO) thin films were deposited on glass substrates by radio frequency magnetron sputtering. The dependences of the microstructure and optoelectronic properties of GTZO thin films on Ar gas pressure were observed. The X-ray diffraction(XRD) and scanning electron microscopy(SEM) results show that all the deposited films are polycrystalline with a hexagonal structure and have a preferred orientation along the c-axis perpendicular to the substrate. With the increment of Ar gas pressure, the microstructure and optoelectronic properties of GTZO thin films will be changed. When Ar gas pressure is 0.4 Pa, the deposited films possess the best crystal quality and optoelectronic properties.
基金supported by the National High Technology Research and Development Program(Grant No.2011AA050511)Jiangsu"333"Project,the Priority Academic Program Development of Jiangsu Higher Education Institutions and Research and Innovation Project for College Graduates of Jiangsu Province(Grant No.CXLX13_722)
文摘To study the ferroelectric photovoltaic effect based on polycrystalline films, preparation of high-quality polycrystalline films with low leakage and high remnant polarization is essential. Polycrystalline BiFeO3 (BFO) thin films with extremely large remnant polarization (2Pr = 180 ~aC/cm2) were successfully deposited on glass substrates coated with indium tin oxide using a modified radio frequency magnetron sputtering method. Symmetric and asymmetric cells were constructed to investigate the ferroelectric photovoltaic effect in order to understand the relationship between polarization and photovoltaic response. All examined cells showed polarization-induced photovoltaic effect. Our findings also showed that the ferroelectric photovoltaic effect is highly dependent on the material used for the top electrode and the thickness of the polycrystalline film.
文摘Compared to traditional optical domes, domes of sapphire coated with films can effectively reduce emissivity and increase transmittance. The purpose of this work is to investigate the thermal radiation effect on sapphire optical dome coated with yttrium oxide by a radio frequency mag- netron sputtering method. The emissivity of sapphire coated with Y203 films is studied by both numerical and experi- mental methods. The results indicate that the emissivity of sapphire substrate is reduced effectively with increasing the thickness of the Y203 film. In addition, a finite element model is developed to simulate the radiation intensity of the optical dome. The thermal responses indicate that the max- imum temperature is reduced apparently compared with the uncoated sapphire as Y203 film thicknesses increase. The average irradiance distribution at different film thicknesses with time shows that the self-thermal radiation disturbance of sapphire optical dome delays 0.93 s when the thickness of Y203 film is 200μm, which can guarantee the dome works properly and effectively even in a harsh environment.