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小金属粒子团簇生长中的van der Waals作用
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作者 钟建伟 高国良 《山东科技大学学报(自然科学版)》 CAS 2003年第z1期94-95,共2页
用jellium模型和无规相近似(RPA)方法分析金属粒子团簇的电磁特性及相关的van der Waals作用.计算了一些金属的van der Waals系数和静态极化率.
关键词 小金属粒子 jellium模型 VAN der Waals作用
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H_2/CO中Fe_3(CO)_(12)/Y催化剂小金属离子特性研究
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作者 郭国清 黄友梅 《天然气化工—C1化学与化工》 CAS CSCD 北大核心 2000年第6期15-18,37,共5页
以Fe3(CO) 12 为母体制备的Fe3(CO) 12 /Y催化剂在较低反应温度 2 80℃表现出高活性和低碳烯烃选择性 ,而以Fe(NO3) 3 为母体制备的Fe(NO3) 3/Y催化剂无催化活性。Fe3(CO) 12 /Y和Fe(NO3) 3/Y催化剂在程序升温反应中CO和H2 浓度变化曲... 以Fe3(CO) 12 为母体制备的Fe3(CO) 12 /Y催化剂在较低反应温度 2 80℃表现出高活性和低碳烯烃选择性 ,而以Fe(NO3) 3 为母体制备的Fe(NO3) 3/Y催化剂无催化活性。Fe3(CO) 12 /Y和Fe(NO3) 3/Y催化剂在程序升温反应中CO和H2 浓度变化曲线呈现截然不同的两种变化趋势 ,前者为小金属粒子异变趋势 ,后者为普通金属粒子顺变趋势。Fe3(CO) 12 /Y催化剂高活性及低碳烯烃选择性与其高分散小金属粒子特性密切相关。 展开更多
关键词 Fe3(CO)12 Fe3(CO)12/Y 低碳烯烃 小金属粒子
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Particle size polydispersity of the rheological properties in magnetorheological fluids
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作者 TANG HongZhe 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2011年第7期1258-1262,共5页
Dispersion of metal particles in fluids can be used to manufacture magnetorheologic fluids(MRF).Properties of these dispersion systems are mainly determined by the arrangements and contacts among particles.In this pap... Dispersion of metal particles in fluids can be used to manufacture magnetorheologic fluids(MRF).Properties of these dispersion systems are mainly determined by the arrangements and contacts among particles.In this paper,particles with smaller sizes than those in the target dispersion system are added using iron particles dispersed in silicon oil as a model to control the arrangements and contacts.The result suggests that these small-sized particles have a significant effect on the viscoelastic properties of the dispersion.The maximum packing density and the fluid viscosity depend mainly on the adhesion of small particles,which is directly related to the fraction of small particles in the model dispersion system.Under a magnetic field,the yield stress of the dispersion system is proportional to the concentration of iron particles,suggesting that the yield stress relies directly on the presence of small particles.These small particles in the fluid determine the difference in stress of the magnetorheological fluid(MRF) with or without a magnetic field. 展开更多
关键词 magnetorheological fluids (MRF) iron particles yield stress BIMODAL
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