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V型小麦直链淀粉-正癸醇复合物的制备及其表征 被引量:6
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作者 娄雪 杨留枝 +3 位作者 史苗苗 闫溢哲 王菲 刘延奇 《河南农业大学学报》 CAS CSCD 北大核心 2020年第5期871-878,912,共9页
为了探究改性淀粉及其制备条件,以小麦淀粉为原料,经酸解得到小麦直链淀粉,加入溶于无水乙醇的正癸醇制备小麦直链淀粉-正癸醇复合物,考察无水乙醇体积分数、结晶温度、正癸醇体积及淀粉质量浓度对复合物结晶结构的影响,并以小麦直链淀... 为了探究改性淀粉及其制备条件,以小麦淀粉为原料,经酸解得到小麦直链淀粉,加入溶于无水乙醇的正癸醇制备小麦直链淀粉-正癸醇复合物,考察无水乙醇体积分数、结晶温度、正癸醇体积及淀粉质量浓度对复合物结晶结构的影响,并以小麦直链淀粉为对照,对该复合物进行表征测定。通过正交试验确定最优制备条件为乙醇体积分数38%,结晶温度为40℃,正癸醇0.3 mL,淀粉质量浓度50 g·L^-1,经X-射线衍射(diffraction of X-rays,XRD)谱图显示该复合物为V型结晶结构,结晶度最高为57.9%。傅里叶红外光谱(fourier transform infrared spectroscopy,FT-IR)结果表明正癸醇与小麦直链淀粉发生复合。便携式拉曼光谱(Raman)结果表明V型复合物比小麦直链淀粉更加短程有序。差示扫描量热(differential scanning calorimetry,DSC)结果显示V型复合物的结构更加稳定。此外,通过扫描电子显微镜(scanning electron microscope,SEM)观察到V型复合物的形貌为无规则碎片状。 展开更多
关键词 小麦直链淀粉 正癸醇 V型复合物 X-射线衍射 表征测定
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小麦直链淀粉-单甘酯-色氨酸三元复合物的制备及分析 被引量:5
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作者 杨留枝 娄雪 +3 位作者 史苗苗 闫溢哲 王菲 刘延奇 《河南农业大学学报》 CAS CSCD 2021年第3期477-484,共8页
将单甘酯、色氨酸与小麦直链淀粉进行复合,通过冷凝回流法制备小麦直链淀粉-单甘酯-色氨酸三元复合物,应用X-射线衍射仪、傅里叶红外光谱仪、拉曼光谱仪、差示扫描量热仪、扫描电子显微镜等研究复合物的结晶结构、有序性、热特性及微观... 将单甘酯、色氨酸与小麦直链淀粉进行复合,通过冷凝回流法制备小麦直链淀粉-单甘酯-色氨酸三元复合物,应用X-射线衍射仪、傅里叶红外光谱仪、拉曼光谱仪、差示扫描量热仪、扫描电子显微镜等研究复合物的结晶结构、有序性、热特性及微观结构的变化。以三元复合物结晶度为指标,通过单因素试验探究无水乙醇体积分数、色氨酸质量和单甘酯质量对复合物结晶度的影响。结果表明,当无水乙醇体积分数35%,色氨酸质量0.09 g,单甘酯质量0.07 g,同时小麦直链淀粉质量1.0 g,结晶温度40℃下复合物结晶度为61.4%。与小麦直链淀粉相比,小麦直链淀粉-单甘酯-色氨酸三元复合物的结晶度更高,热稳定性更好,微观结构发生显著变化,但其短程有序性稍有降低。 展开更多
关键词 小麦直链淀粉 单甘酯 色氨酸 三元复合物 X-射线衍射
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小麦直链淀粉-单甘酯复合物的制备及表征 被引量:5
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作者 娄雪 杨留枝 +3 位作者 史苗苗 闫溢哲 王菲 刘延奇 《食品科技》 CAS 北大核心 2020年第11期243-249,共7页
采用冷凝回流法制备小麦直链淀粉-单甘酯复合物,研究乙醇体积分数、单甘酯和结晶温度等对复合物结晶结构的影响。通过正交试验确定最优制备条件:小麦直链淀粉1.0 g,乙醇浓度38%,单甘酯0.07 g,结晶温度为40℃。对复合物进行结构表征,结... 采用冷凝回流法制备小麦直链淀粉-单甘酯复合物,研究乙醇体积分数、单甘酯和结晶温度等对复合物结晶结构的影响。通过正交试验确定最优制备条件:小麦直链淀粉1.0 g,乙醇浓度38%,单甘酯0.07 g,结晶温度为40℃。对复合物进行结构表征,结果证明:小麦直链淀粉与单甘酯发生复合,形成V型结晶结构,X-射线衍射仪(XRD)图谱显示其复合物均为V型结晶结构,结晶度最高为62.1%。傅里叶红外光谱(FT-IR)和便携式拉曼光谱仪(Raman)显示配体与小麦直链淀粉发生复合,同时复合物与小麦直链淀粉相比其短程有序性降低。差示扫描量热仪(DSC)显示复合物的结构更加稳定。此外,通过扫描电子显微镜(SEM)显示复合物的形貌发生显著变化,为圆片状。 展开更多
关键词 小麦直链淀粉 小麦直链淀粉-单甘酯 复合物 结构
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Correlation analysis between major nutritional components and resistant starch content in wheat 被引量:3
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作者 张志转 陈多璞 吴殿星 《Agricultural Science & Technology》 CAS 2007年第2期2-7,共6页
With 94 spring wheat cultivars as experimental materials, the correlations between the content of resistant starch (RS) in uncooked flour and cooked flour, and the apparent amylose content (AAC), protein, lipid we... With 94 spring wheat cultivars as experimental materials, the correlations between the content of resistant starch (RS) in uncooked flour and cooked flour, and the apparent amylose content (AAC), protein, lipid were investigated. The results showed that RS contents in both the uncooked flour and cooked flour assumed significantly positive correlation with AAC, and significantly negative cor- relation with protein content; and they were proved to be not significantly correlated with lipid content. RS content in uncooked flour was significantly correlated with that in cooked flour. These results provided references for the genetic improvement of wheat cultivars. 展开更多
关键词 apparent amylose content PROTEIN LIPID resistant starch CORRELATION
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Amylose contents of cereals; influence of household processing on the amylose contents of these foods
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作者 Nizakat Bibi Zahid Mehmood Aurang Zeb 《Journal of Agricultural Science and Technology》 2009年第6期1-5,12,共6页
Amylose is a food starch found in cereals, legumes and root vegetables. Keeping in view the importance of amylose for various food industries as well as its importance on domestic level, the current study was conducte... Amylose is a food starch found in cereals, legumes and root vegetables. Keeping in view the importance of amylose for various food industries as well as its importance on domestic level, the current study was conducted to analyze the amylose content of common cereals e. g rice (sela, coarse and basmati), maize yellow, Kisan and Azam varieties and wheat (Tatara, Fakhr-e-sarhad and Bakhtawar-92) varieties as well as quantifying the influence of cooking/boiling procedures on the amylose contents of cereals. The maximum amylose content were observed for wheat variety Tatara (24.28%) followed by Bakhtawar-92 (22.74%) and Fakhr-e-sarhad (19.77%). Among maize and rice varieties studied, Kisan and course rice were rich in amylose content with values of 27.19 and 30.48% respectively. The chapti of Tatra wheat were scored highest for appearance (7.6), flavor (7.5), texture (7.6) and overall acceptability (7.55). The roti of Kisan and Azam varieties got maximum appearance score of 7.6 as compared to 7.4 for maize yellow variety. Basmati rice was scored highest regarding appearance (8.4), flavor (8.6), texture (8.6) and overall acceptability (8.53. The moisture content ranged from 10.61 (Azam) to 8.01% (wheat variety Fakhr-e-sarhad). Cooking reduced the amylose content of wheat bread from (19.77%-24.28%) to (15.47%-15.94%) with cooking time of 5 min, maize bread from (21.48%-27.19%) to (19.53 %-25.85%) with maximum cooking time of 10 min and boiled rice from (24.90%-30.48%) to (24.18%-30.19%) with cooking time ranging from 12 to 20 min. It can be inferred from these studies that the reduction in amylose content were more in chapti/roti preparation of wheat and maize varieties as compared to boiling of rice varieties and that significant varietals differences exist in amylose content of the uncooked samples. 展开更多
关键词 WHEAT MAIZE rice AMYLOSE COOKING sensory evaluation
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