This research has focused on the treatment of zinc flue dust by an acid leach process, combining an environmentally suitable impurity removal process to recover cadmium. Optimum conditions were found as follows： H2SO...This research has focused on the treatment of zinc flue dust by an acid leach process, combining an environmentally suitable impurity removal process to recover cadmium. Optimum conditions were found as follows： H2SO4 concentration 90 g/L, liquid/solid ratio 6：1, leaching temperature 60 ℃ and leaching time 1.0 h. Under these conditions, 95.8% cadmium was recovered. FeAsO4 and Fe（OH）3 precipitates with FeCI3 are found to be highly effective to obtain a high degree of separation of heavy metals and the oxyanions of arsenic from the leachate. The overall separation of arsenic and other heavy metals and precipitate settling rates are optimum at n（Fe）/n（As） ratio of 3：l and pH 6. The removal rates ofFe, Pb and Cu from the solution were greater than 98.9%, and As removal rate was 99.6%. A solvent extraction with P204 was used for the separation of zinc and cadmium. Optimum conditions are obtained as follows： 20% P204 （volume fraction） diluted with kerosene at room temperature, pH 3.0, and varying organic/aqueous （O/A） phase ratio 1：1. The extraction rate of zinc is 99.2% under these conditions. Spherical cadmium particles showing nearly uniform size were produced by hydrogen reduction at 310 ℃ and the crystal structure was cubic. In addition, the purity of the recovered cadmium powder is more than 99.99%.展开更多
The properties of dust ion acoustic waves are investigated in an unmagnetized multicomponent plasma system consisting of ion beam, charged positive and negative ions, electrons obeying nonthermal-Tsallis distribution ...The properties of dust ion acoustic waves are investigated in an unmagnetized multicomponent plasma system consisting of ion beam, charged positive and negative ions, electrons obeying nonthermal-Tsallis distribution and stationary negatively charged dust grains by the conventional Sagdeev pseudopotential method, through which the condition for existence of several nonlinear structures is analyzed theoretically. The dispersion relation for electrostatic waves is derived and analyzed and an expression of the energy integral equation is obtaJned. It is reported here that our plasma model supports solitions, double layers and supersoliton solutions for certain range of parameters. Finally, the effects of different physical plasma parameters on these nonlinear structures are studied numerically. The present theory should be helpful in understanding the salient features of the electrostatic waves in space and in laboratory plasmas where two distinct groups of ions and non-Maxwellian distributed electrons are present.展开更多
文摘This research has focused on the treatment of zinc flue dust by an acid leach process, combining an environmentally suitable impurity removal process to recover cadmium. Optimum conditions were found as follows： H2SO4 concentration 90 g/L, liquid/solid ratio 6：1, leaching temperature 60 ℃ and leaching time 1.0 h. Under these conditions, 95.8% cadmium was recovered. FeAsO4 and Fe（OH）3 precipitates with FeCI3 are found to be highly effective to obtain a high degree of separation of heavy metals and the oxyanions of arsenic from the leachate. The overall separation of arsenic and other heavy metals and precipitate settling rates are optimum at n（Fe）/n（As） ratio of 3：l and pH 6. The removal rates ofFe, Pb and Cu from the solution were greater than 98.9%, and As removal rate was 99.6%. A solvent extraction with P204 was used for the separation of zinc and cadmium. Optimum conditions are obtained as follows： 20% P204 （volume fraction） diluted with kerosene at room temperature, pH 3.0, and varying organic/aqueous （O/A） phase ratio 1：1. The extraction rate of zinc is 99.2% under these conditions. Spherical cadmium particles showing nearly uniform size were produced by hydrogen reduction at 310 ℃ and the crystal structure was cubic. In addition, the purity of the recovered cadmium powder is more than 99.99%.
文摘The properties of dust ion acoustic waves are investigated in an unmagnetized multicomponent plasma system consisting of ion beam, charged positive and negative ions, electrons obeying nonthermal-Tsallis distribution and stationary negatively charged dust grains by the conventional Sagdeev pseudopotential method, through which the condition for existence of several nonlinear structures is analyzed theoretically. The dispersion relation for electrostatic waves is derived and analyzed and an expression of the energy integral equation is obtaJned. It is reported here that our plasma model supports solitions, double layers and supersoliton solutions for certain range of parameters. Finally, the effects of different physical plasma parameters on these nonlinear structures are studied numerically. The present theory should be helpful in understanding the salient features of the electrostatic waves in space and in laboratory plasmas where two distinct groups of ions and non-Maxwellian distributed electrons are present.
