Platinum and palladium(PtPd)alloy nanoparticles(NPs)are excellent catalysts for direct methanol fuel cells.In this study,we developed PtPd alloy NPs through the co‐reduction of K2PtCl4and Na2PdCl4in a polyol synthesi...Platinum and palladium(PtPd)alloy nanoparticles(NPs)are excellent catalysts for direct methanol fuel cells.In this study,we developed PtPd alloy NPs through the co‐reduction of K2PtCl4and Na2PdCl4in a polyol synthesis environment.During the reaction,the feed molar ratio of the two precursors was carried over to the final products,which have a narrow size distribution with a mean size of approximately4nm.The catalytic activity for methanol oxidation reactions possible depends closely on the composition of as‐prepared PtPd alloy NPs,and the NPs with a Pt atomic percentage of approximately75%result in higher activity and stability with a mass specific activity that is7times greater than that of commercial Pt/C catalysts.The results indicate that through composition control,PtPd alloy NPs can improve the effectiveness of catalytic performance.展开更多
An integrated simulation of powder effects on particle temperature and microstructural evolution in laser directed energy deposition additive manufacturing process was carried out.The spatial distribution of the flyin...An integrated simulation of powder effects on particle temperature and microstructural evolution in laser directed energy deposition additive manufacturing process was carried out.The spatial distribution of the flying powder particles was simulated by the discrete element method to calculate the energy for the flying powder particles under the laser−particle interaction with electromagnetic wave analysis.Combined with the phase field method,the influence of particle size on the microstructural evolution was studied.The microstructural evolution is validated through comparison with experimental observation.Results indicate that the narrow particle size distribution is beneficial to obtaining a more uniform temperature distribution on the deposited layers and forming smaller equiaxed grains near the side surfaces of the sample.Appropriate powder particle size is beneficial to the conversion of the electromagnetic energy into heat.Particles with small size are recommended to form equiaxed grains and to improve product quality.Appropriate powder flow rate improves the laser energy efficiency,and higher powder flow rate leads to more uniform equiaxed grains on both sides of the cross-section.展开更多
The particle size distribution, heavy mineral constituents and rare earth elements (REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay. The resul...The particle size distribution, heavy mineral constituents and rare earth elements (REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay. The results showed that the clay had some properties of areolian deposits, which could be compared with those of the loess in North China; and its chondrite normalized curves of REE were similar to those of the Xiashu loess, implying that they shared the same origin. It was concluded in combination with the results reported by other researchers that the Quaternary red clay of southern Anhui Province originated from aeolian deposits, and this could reveal the cycles of warm and cold climates in the area during the Quaternary period.展开更多
The gradient descent(GD)method is used to fit the measured data(i.e.,the laser grain-size distribution of the sediments)with a sum of four weighted lognormal functions.The method is calibrated by a series of ideal num...The gradient descent(GD)method is used to fit the measured data(i.e.,the laser grain-size distribution of the sediments)with a sum of four weighted lognormal functions.The method is calibrated by a series of ideal numerical experiments.The numerical results indicate that the GD method not only is easy to operate but also could effectively optimize the parameters of the fitting function with the error decreasing steadily.The method is applied to numerical partitioning of laser grain-size components of a series of Garzêloess samples and three bottom sedimentary samples of submarine turbidity currents modeled in an open channel laboratory flume.The overall fitting results are satisfactory.As a new approach of data fitting,the GD method could also be adapted to solve other optimization problems.展开更多
Let G be a connected graph with vertex-set V(G)and edge-set E(G).A subset F of E(G)is an s-restricted edge-cut of G if G-F is disconnected and every component of G-F has at least s vertices.Letλs(G)be the minimum siz...Let G be a connected graph with vertex-set V(G)and edge-set E(G).A subset F of E(G)is an s-restricted edge-cut of G if G-F is disconnected and every component of G-F has at least s vertices.Letλs(G)be the minimum size of all s-restricted edge-cuts of G andξs(G)=min{|[X,V(G)\X]|:|X|=s,G[X]is connected},where[X,V(G)\X]is the set of edges with exactly one end in X.A graph G with an s-restricted edge-cut is called super s-restricted edge-connected,in short super-λs,ifλs(G)=ξs(G)and every minimum s-restricted edge-cut of G isolates one component G[X]with|X|=s.It is proved in this paper that a connected vertex-transitive graph G with degree k>5 and girth g>5 is super-λs for any positive integer s with s 2g or s 10 if k=g=6.展开更多
When the shoot apical meristem of plants is damaged or removed,fecundity and/or plant growth may suffer(under-compensation),remain unaffected(compensation)or increase(overcompensation).The latter signifies a potential...When the shoot apical meristem of plants is damaged or removed,fecundity and/or plant growth may suffer(under-compensation),remain unaffected(compensation)or increase(overcompensation).The latter signifies a potential‘cost’of apical dominance.Using natural populations of 19 herbaceous angiosperm species with a conspicuously vertical,apically dominant growth form,we removed(clipped)the shoot apical meristem for replicate plants early in the growing season to test for a potential cost of apical dominance.Clipped and unclipped(control)plants had their near neighbours removed,and were harvested after flowering production had finished but before seed dispersal.Dry mass was measured separately for aboveground body size(shoots),leaves,seeds and fruits;and number of leaves,fruits and seeds per plant were counted.We predicted that:(i)our study species(because of their strong apically dominant growth form)would respond to shoot apical meristem removal with greater branching intensity,and thus overcompensation in terms of fecundity and/or biomass;and(ii)overcompensation is particularly enabled for species that produce smaller but more leaves,and hence with a larger bud bank of axillary meristems available for deployment in branching and/or fruit production.Widely variable compensatory capacities were recorded,and with no significant between-species relationship with leaf size or leafing intensity—thus indicating no generalized potential cost of apical dominance.Overall,the results point to species-specific treatment effects on meristem allocation patterns,and suggest importance for effects involving local variation in resource availability,and between-species variation in phenology,life history traits and susceptibility to herbivory.展开更多
基金supported by the National Natural Science Foundation of China (21373272)~~
文摘Platinum and palladium(PtPd)alloy nanoparticles(NPs)are excellent catalysts for direct methanol fuel cells.In this study,we developed PtPd alloy NPs through the co‐reduction of K2PtCl4and Na2PdCl4in a polyol synthesis environment.During the reaction,the feed molar ratio of the two precursors was carried over to the final products,which have a narrow size distribution with a mean size of approximately4nm.The catalytic activity for methanol oxidation reactions possible depends closely on the composition of as‐prepared PtPd alloy NPs,and the NPs with a Pt atomic percentage of approximately75%result in higher activity and stability with a mass specific activity that is7times greater than that of commercial Pt/C catalysts.The results indicate that through composition control,PtPd alloy NPs can improve the effectiveness of catalytic performance.
基金The authors are grateful for the financial supports from the National Natural Science Foundation of China(No.11572074)the Liaoning Provincial Natural Science Foundation,China(No.2019-KF-05-07)。
文摘An integrated simulation of powder effects on particle temperature and microstructural evolution in laser directed energy deposition additive manufacturing process was carried out.The spatial distribution of the flying powder particles was simulated by the discrete element method to calculate the energy for the flying powder particles under the laser−particle interaction with electromagnetic wave analysis.Combined with the phase field method,the influence of particle size on the microstructural evolution was studied.The microstructural evolution is validated through comparison with experimental observation.Results indicate that the narrow particle size distribution is beneficial to obtaining a more uniform temperature distribution on the deposited layers and forming smaller equiaxed grains near the side surfaces of the sample.Appropriate powder particle size is beneficial to the conversion of the electromagnetic energy into heat.Particles with small size are recommended to form equiaxed grains and to improve product quality.Appropriate powder flow rate improves the laser energy efficiency,and higher powder flow rate leads to more uniform equiaxed grains on both sides of the cross-section.
文摘The particle size distribution, heavy mineral constituents and rare earth elements (REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay. The results showed that the clay had some properties of areolian deposits, which could be compared with those of the loess in North China; and its chondrite normalized curves of REE were similar to those of the Xiashu loess, implying that they shared the same origin. It was concluded in combination with the results reported by other researchers that the Quaternary red clay of southern Anhui Province originated from aeolian deposits, and this could reveal the cycles of warm and cold climates in the area during the Quaternary period.
基金supported by the National Natural Science Foundation of China(Grant Nos.41072176,41371496)the National Science and Technology Supporting Program of China(Grant No.2013BAK05B04)the Fundamental Research Funds for the Central Universities(Grant No.201261006)
文摘The gradient descent(GD)method is used to fit the measured data(i.e.,the laser grain-size distribution of the sediments)with a sum of four weighted lognormal functions.The method is calibrated by a series of ideal numerical experiments.The numerical results indicate that the GD method not only is easy to operate but also could effectively optimize the parameters of the fitting function with the error decreasing steadily.The method is applied to numerical partitioning of laser grain-size components of a series of Garzêloess samples and three bottom sedimentary samples of submarine turbidity currents modeled in an open channel laboratory flume.The overall fitting results are satisfactory.As a new approach of data fitting,the GD method could also be adapted to solve other optimization problems.
基金supported by National Natural Science Foundation of China(Grant No.61073046)
文摘Let G be a connected graph with vertex-set V(G)and edge-set E(G).A subset F of E(G)is an s-restricted edge-cut of G if G-F is disconnected and every component of G-F has at least s vertices.Letλs(G)be the minimum size of all s-restricted edge-cuts of G andξs(G)=min{|[X,V(G)\X]|:|X|=s,G[X]is connected},where[X,V(G)\X]is the set of edges with exactly one end in X.A graph G with an s-restricted edge-cut is called super s-restricted edge-connected,in short super-λs,ifλs(G)=ξs(G)and every minimum s-restricted edge-cut of G isolates one component G[X]with|X|=s.It is proved in this paper that a connected vertex-transitive graph G with degree k>5 and girth g>5 is super-λs for any positive integer s with s 2g or s 10 if k=g=6.
基金This work was supported by a Natural Sciences and Engineering Research Council of Canada research grant to L.W.A.
文摘When the shoot apical meristem of plants is damaged or removed,fecundity and/or plant growth may suffer(under-compensation),remain unaffected(compensation)or increase(overcompensation).The latter signifies a potential‘cost’of apical dominance.Using natural populations of 19 herbaceous angiosperm species with a conspicuously vertical,apically dominant growth form,we removed(clipped)the shoot apical meristem for replicate plants early in the growing season to test for a potential cost of apical dominance.Clipped and unclipped(control)plants had their near neighbours removed,and were harvested after flowering production had finished but before seed dispersal.Dry mass was measured separately for aboveground body size(shoots),leaves,seeds and fruits;and number of leaves,fruits and seeds per plant were counted.We predicted that:(i)our study species(because of their strong apically dominant growth form)would respond to shoot apical meristem removal with greater branching intensity,and thus overcompensation in terms of fecundity and/or biomass;and(ii)overcompensation is particularly enabled for species that produce smaller but more leaves,and hence with a larger bud bank of axillary meristems available for deployment in branching and/or fruit production.Widely variable compensatory capacities were recorded,and with no significant between-species relationship with leaf size or leafing intensity—thus indicating no generalized potential cost of apical dominance.Overall,the results point to species-specific treatment effects on meristem allocation patterns,and suggest importance for effects involving local variation in resource availability,and between-species variation in phenology,life history traits and susceptibility to herbivory.
