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纳米级CdS粒子尺寸量子化的化学效应研究 被引量:15
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作者 陈德文 王素华 《中国科学(B辑)》 CSCD 北大核心 1996年第3期262-268,共7页
研究了无机半导体硫化镉超微团簇粒子界面光反应行为,结果表明,纳米粒子的尺寸量子化效应不仅体现在其光物理特性上,而且也体现在其所引发的表面光催化反应行为中,即随着粒子尺寸的变化,被吸附于粒子界面的化合物的光反应方向和机理或... 研究了无机半导体硫化镉超微团簇粒子界面光反应行为,结果表明,纳米粒子的尺寸量子化效应不仅体现在其光物理特性上,而且也体现在其所引发的表面光催化反应行为中,即随着粒子尺寸的变化,被吸附于粒子界面的化合物的光反应方向和机理或反应强度也随之有所变化.这是由于粒子的氧化还原电位也随着粒子尺寸而改变所致.这种效应对于控制界面反应的机理及提高其选择性有重要意义. 展开更多
关键词 纳米粒子 尺寸量子化效应 硫化镉 半导体
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CdS纳米粒子的微波法制备及其光谱特性研究 被引量:10
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作者 程伟青 刘迪 严拯宇 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2008年第6期1348-1352,共5页
用微波法以硫代乙酰胺为硫源,成功合成了CdS纳米粒子。透射电子显微镜(TEM)对合成的CdS纳米粒子的表征结果为粒径约12 nm,粒径分布较为均匀,分散性较好。研究了微波功率、pH值、反应时间等因素对其吸收光谱,荧光光谱和粒径的影响。结... 用微波法以硫代乙酰胺为硫源,成功合成了CdS纳米粒子。透射电子显微镜(TEM)对合成的CdS纳米粒子的表征结果为粒径约12 nm,粒径分布较为均匀,分散性较好。研究了微波功率、pH值、反应时间等因素对其吸收光谱,荧光光谱和粒径的影响。结果表明,在微波功率为30%、初始反应pH 9.0、微波反应时间为25 min时,可合成质量较高的CdS纳米粒子。比较了以硫代乙酰胺、硫脲和硫化钠为硫源合成的CdS纳米粒子,结果表明,以硫代乙酰胺为硫源合成的CdS纳米粒子荧光带边发射强,缺陷发射弱,荧光性质较好;而以硫脲为硫源合成的CdS纳米粒子荧光边带发射弱;以硫化钠为硫源合成的CdS纳米粒子荧光以缺陷发射为主。铜离子在6.4-512μg·L^-1范围内对该纳米粒子荧光的猝灭呈现良好线性,可用于痕量铜离子的测定。 展开更多
关键词 微波法 CDS纳米粒子 荧光光谱 尺寸量子化效应
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Linear and Nonlinear Optical Absorptions of a Donor Impurity in Spherical Quantum Dots 被引量:1
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作者 XIE Wen-Fang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第7期155-158,共4页
An investigation of the optical properties of a hydrogenic donor in spherical parabolic quantum dots hasbeen performed by using the matrix diagonalization method.The optical absorption coefficient between the ground(L... An investigation of the optical properties of a hydrogenic donor in spherical parabolic quantum dots hasbeen performed by using the matrix diagonalization method.The optical absorption coefficient between the ground(L=0) and the first excited state (L=1) have been examined based on the computed energies and wave functions.The results are presented as a function of the incident photon energy for the different values of the confinement strength.These results show the effects of the quantum size and the impurity on the optical absorption coefficient of a donorimpurity quantum dot. 展开更多
关键词 quantum dot optical absorption
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Binding Energy of an Off-Center D^-in a Spherical Quantum Dot
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作者 LIU Dong-Ming XIE Wen-Fang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第5期919-922,共4页
Using the method of matrix diagonalization, we investigate an off-center D^- in a spherical quantum dot (QD) subjected to a parabolic potential confinement. We discuss the effect of the position of an impurity in th... Using the method of matrix diagonalization, we investigate an off-center D^- in a spherical quantum dot (QD) subjected to a parabolic potential confinement. We discuss the effect of the position of an impurity in the QD on the binding energy of the D system, Eurthermore, we compare a negatively charged donor D^- with a neutral donor DO confined by a spherical QD with a parabolic potentiM. The results have clearly demonstrate the so-called quantum size effect. The binding energy is dependent on the confining potential hw0 and the impurity ion distance D. 展开更多
关键词 quantum dots DONOR
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Noble and valuable: atomically precise gold nanoclusters 被引量:1
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作者 Shuxin Wang Haizhu Yu Manzhou Zhu 《Science China Chemistry》 SCIE EI CAS CSCD 2016年第2期206-208,共3页
Atomically precise gold nanoclusters have recently attracted intensive attention due to their significance in catalysis,chemical sensing,and bio-application.These nanoclusters often possess unique optical,chemical or ... Atomically precise gold nanoclusters have recently attracted intensive attention due to their significance in catalysis,chemical sensing,and bio-application.These nanoclusters often possess unique optical,chemical or physical properties originated from the quantum size effect(i.e.size andshapemorphology). 展开更多
关键词 Chemical sensors GOLD
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