层化海洋中二阶多色波对可渗透结构的绕射问题

可渗透结构具有使波浪作用减弱的效应,而海水的层化及水波的非线性使结构的波绕射产生多层复杂机制。将可渗透结构应用于复杂海况条件中,海水的层化性、波浪的非线性及结构的透空性构成了波绕射的一个十分复杂的数学问题。该问题存在理论研究的必要性,而文章则着重探讨其数学分析的可能性。通过引入二层海的层化海模式及Stokes二阶波的非线性波模式,给出了二阶多色波对透空结构的波绕射的定解问题提法,提出了复合形式的二阶多色波辐射条件式及可渗透结构的二阶物面条件式,应用特征函数解法与积分法推导了多色波对结构绕射的一阶势解与二阶作用的耦合积分解式,并讨论了解式所涉及无穷积分的算法。

二阶多色波对结构的绕射问题

引入二层海的层化海模型及二阶水波的多色波作用机制，对层化海条件下的二阶多色波的绕射作用问题进行了分析．推导了二层海二阶绕射波的远场解式．指出了二层海条件下二阶绕射波作用积分解建立的数学过程。

Multilayer distribution of carbon dioxide system in surface water of the Yellow Sea in spring

Surface water can be divided into three layers from top downward： surface microlayer （SML, thickness≤50 μm）, subsurface layer （SSL, ≈25 cm） and surface layer （SL, l-5m）, among which the SML plays an important role on sea-air interaction because of its unique physical-chemical property. Carbon dioxide system including DIC （dissolved inorganic carbon）, Alk （alkalinity）, pH and pCO： （partial pressure of CO2） in multilayered waters of the Yellow Sea was studied for the first time in March and May 2005. The results show that： DIC and Alk are obviously enriched in SML. The contents ofDIC, Alk and pCO2 become lower in turn from SML, SSL to SL, higher in March and lower in May, whereas for pH it was opposite. The relationship between DIC and Alk is clearly positive, but negative between pH and pCO2. Meanwhile, pCO2 and temperature/salinity is also in positive relation, pCO2 decreases with latitude increase. DIC and Alk show a similar variation trend with the maximum at 02：00-03：00, but pH and pCO2 show an opposite pattern. In addition, the distribution patterns are similar to each other in the three layers. The Yellow Sea is shown to be a sink of atmospheric CO2 in spring by two methods： （1） comparing pCO2 in seawater and atmosphere; （2） turning direction of ＂pH-depth＂ curve. Calculation on the base of pCO2 data in SML in four models shows that carbon flux in spring in the area was about -6.96×10^6 t C.

Stratigraphic Division Based on Minor Elements in the Sediment Core Q43 from the Outer Shelf of the East China Sea:Approached Through Correspondence Analysis and Fuzzy Cluster Analysis

The multivariate statistical techniques, principal component analysis, Q-modefactor analysis, correspondence analysis and fuzzy C-means clustering were applied to analyzing thedatasets of minor element concentrations in sediment samples of a core collected from the outershelf of the East China Sea. According to the analysis results, the sediment core Q43 can be dividedinto three strata with different features in minor elements. The first stratum (unit Ⅰ) ischaracterized by higher concentrations of Ⅴ, Cr, Cd and Sc, which are active and inactive elements.The second stratum (unit Ⅱ) is controlled by ultrastable elements Ⅴ, Ti, Cr, Th, Sc, Pb, etc. Thethird stratum (unit Ⅲ) is dominated by Ni, Co, Ba, Rb and Mn, which are authigenic andvolcanogenic elements. The geochemical features of the core Q43 show environmental changes in thedepositional process from the Late Pleistocene to Holocene.

Carboniferous–Permian marine transgressions in the Jiyang Depression

In recent years, great attention has been paid to oil and gas exploration in the Carboniferous-Permian strata of the Bohaiwan basin, especially the Carboniferous-Permian marine transgression, using data from drilling, outcrops and carbonate acid-insoluble residue experiments together with the tectonic evo- lutionary history of the peripheral orogenic zones of the North China plate and the Tan-Lu fault zones. The .＇;tudy concludes that marine transgressions took place on six occasions during Carboniferous-Perm- ian time in the Jiyang Depression. The marine transgressions were concentrated in the Late Carbonifer- ous： two marine transgressions occurred in the early Late Carboniferous, and the scale of the first was smaller and the time was shorter than those of the second. The other four marine transgressions hap- pened in the late Late Carboniferous, the first and the fourth of which were larger in scale and longer in time than the second and the third. The seawater came from the Jiaobei area, the eastward part of the Qinling-Dabie residual sea basin, and invaded progressively as a planar flow from south to north and from east to west. These findings have great significance for thorough analysis of the sedimentary characteristics and evolution of the Carboniferous-Permian strata in the livang Denression.

Coral Bleaching in Arrecifes de Cozumel National Park after Tropical Storm Rina in October 2011

Extensive bleaching of Montastrea annularis spp. group and several other scleractinian taxa occurred on the reefs within the Arrecifes de Cozumel National Park of Cozumel, Mexico, after the passage of Hurricane/Tropical Storm Rina. We conducted six drift dives at five different dive sites （-13 h of scuba diving） and photographed a variety of reefs scenes at depths of 10-28 m. Bleaching was noted at depths of 10-40 m in a variety of scleractinian species, including M. annularis species group, especially M. faveolata and Siderastrea siderea. Considering that local dive guides had not observed bleaching prior to the storm and the sea surface temperature did not exceed the local bleaching threshold, it is probable that the extensive rainfall associated with Hurricane/Tropical Storm Rina lowered salinity sufficiently via subsurface freshwater springs to cause bleaching in susceptible species. This suggests the need to monitor not only subsurface sea temperature but also subsurface salinity in localities where freshwater springs occur adjacent to or within coral reefs.

Seasonal variations of rotifers from a high altitude urban shallow water body, La Cantera Oriente (Mexico City, Mexico)

La Cantera Oriente is a shallow freshwater volcanic water body located at an altitude of 2 270 m above sea level in the Ecological Reserve of San Angel Pedregal of Mexico City （Mexico）. In order to ensure the conservation of its biological heritage including zooplankton, the present work was undertaken to quantify the seasonal changes in the diversity and density of rotifers and the selected physico- chemical variables during 2013-2014. Qualitative analysis of the zooplankton samples yielded 68 rotifer species which represented 24 genera in 15 families. Brachionus calyciflorus Pallas, 1766, B. quadridentatus Hermann, 1783, Polyarthra vulgaris Carlin, 1943, Lecane closterocerca （Schmarda, 1859） and Keratella cochlearis （Gosse, 1851） were the most common species. Preston plots of species frequency-density revealed that as many as 30% of the rotifer taxa were dominant throughout the year. The species with high population densities were Brachionus quadridentatus, Lecane closterocerca, Keratella cochlearis, and Lepadellapatella; their peak densities were 2 000, 1 000, 180 and 90 ind./L, all occurring in summer. Canonical correspondence analysis showed that Platyias quadricornis was related to the concentration of phosphates available in the environment and the conductivity, while B. quadridentatus was positively correlated with chlorophyll-a. The trophic status of the lake was eutrophic based on Chl-a content but oligotrophic with relation to the Braehionus： Trichocerca ratio.

Decadal variability of chlorophyll α in the South China Sea: a possible mechanism

Four climatologies on a monthly scale (January, April, May and November) of chlorophyll a within the South China Sea (SCS) were calculated using a Coastal Zone Color Scanner (CZCS) (1979-1983) and the Sea-viewing Wide Field-of-view Sensor (SeaWiFS) (1998-2002). We analyzed decadal variability of chlorophyll a by comparing the products of the two observation periods. The relationships of variability in chlorophyll a with sea surface wind speed (SSW), sea surface temperature (SST), wind stress (WS), and mixed layer depth (MLD) were determined. The results indicate that there is obvious chlorophyll a decadal variability in the SCS. The decadal chlorophyll a presents distinct seasonal variability in characteristics, which may be as a result of various different dynamic processes. The negative chlorophyll a concentration anomaly in January was associated with the warming of SST and a shallower MLD. Generally, there were higher chlorophyll a concentrations in spring during the SeaWiFS period compared with the CZCS period. However, the chlorophyll a concentration exhibits some regional differences during this season, leading to an explanation being difficult. The deepened MLD may have contributed to the positive chlorophyll a concentration anomalies from the northwestern Luzon Island to the northeastern region of Vietnam during April and May. The increases of chlorophyll a concentration in northwestern Borneo during May may be because the stronger SSW and higher WS produce a deeper mixed layer and convective mixing, leading to high levels of nutrient concentrations. The higher chlorophyll a off southeastern Vietnam may be associated with the advective transport of the colder water extending from the Karimata Strait to southeastern Vietnam.

Tropical Pacific Decadal Variability in Subsurface Temperature

The nature decadal variability of the equatorial Pacific subsurface temperature is examined in the control simulation with the Geophysical Fluid Dynamics Laboratory coupled model CM2.1.The dominant mode of the subsurface temperature variations in the equator Pacific features a 20-40 year period and is North-South asymmetric about the equator.Decadal variations of the thermocline are most pronounced in the southwest of the Tropical Pacific.Decadal variation of the north-south asymmetric Sea Surface wind in the tropical Pacific,especially in the South Pacific Convergence,is the dominant mechanism of the nature decadal variation of the subsurface temperature in the equatorial Pacific.

Determination of copper complexation in surface microlayer of Daya Bay and Jiaozhou Bay

Copper complexing ligands concentration (C C) and conditional stability constant of the sea surface microlayer (SML) and subsurface layer (SSL) samples, collected from Daya Bay of Guangdong Province and Jiaozhou Bay of Shandong Province, were determined by anodic stripping voltammetry (ASV) technique. C C of Daya Bay in the SML ranged from 6.19×10-7 to 3.52×10-7 mol/L. C C of Jiaozhou Bay in the SML ranged from 5.30×10-7 to 3.03×10-7 mol/L in August 1998 and from 3.46×10-7 to 1.36×10-7 mol/L in May 2000. The C C concentrations were higher in all surface microlayer samples, compared with corresponding subsurface samples. The average enrichment factors of copper complexation in the SML observed above were 1.58, 1.41 and 1.56, respectively. The enrichment of C C concentration in the microlayer demonstrated that organic ligands had certain buffer action on the toxicity of the enriched trace metals in the same layer. Conditional stability constants of the SML in Jiaozhou Bay were lower than those of the SSL; however, it showed just opposite for Daya Bay. BOD (biological oxygen demand) and COD (chemical oxygen demand) indicated the organic matter content, also showed enriched in the SML. C C had an obvious relationship with BOD or COD.

Process of Salinisation of a Lagoon and a Coastal Aquifer in Annaba Area （East Algerian）

The study area is located in a Mediterranean region, so the effects of the climate variations are very important. The authors contribution to this subject is based on the compilation of many results obtained from dissertations and theses that are carried out under their supervision. The main tool used, in addition to other methods, is the water hydrochemistry as it is proved very useful in obtaining good results and helpful in getting objective interpretations regarding the presence and absence of salinity. Several factors are undertaken to show the presence of salts in waters in the plain, the lithology of the geological formations shows that they are composed of alluvium sediments where the permeability is quite high, and this enables hydraulic communication between the fresh water of the aquifer and saline water of the sea. The study of climate shows a decrease of precipitation which favors an important decrease of recharge rate to the aquifer, and hence a decrease of water resource. The strontium which is a good indicator for the origin of salinity shows a variation that indicates a variation in the distribution of the salinity, and therefore diverse origins of salinity all over the studied area. This can infer the presence of marine invasion in the down-stream part of the aquifer, whereas elsewhere salinity is caused by the presence of evaporitic formation, mainly by the argillaceous matrix in the bottom of the lake. in the up-stream part of the aquifer. In the lake, salinity is explained

Variation of Soil Labile Organic Carbon Pools along an Elevational Gradient in the Wuyi Mountains,China

土壤活性有机碳(LOC)是一组活跃的化学物质,由于其较短的周转时间和对环境变化的敏感性在全球碳循环中发挥着重要的作用。但是,对活性有机碳在亚热带森林沿海拔梯度的空间变异还缺乏了解。在本研究中,我们测定了福建武夷山自然保护区不同海拔高度具有代表性的中亚热带常绿阔叶林(500 m)、针叶林(1150 m)、亚高山矮林(1750 m)以及高山草甸(2150 m)土壤不同土层(0-10,10-25和25-40 cm)中微生物可利用碳(MAC)、微生物量碳(MBC)、易氧化碳(ROC)、水溶性碳(WSOC)和轻组碳(LFC),并观测了相应的植物凋落物质量(LM),土壤温度和湿度。结果表明:沿海拔梯度的植被变化和土层深度变化对土壤活性有机碳有显著的影响。微生物可利用碳、微生物量碳、易氧化碳和水溶性碳在不同土层均沿海拔高度的增加而显著增加;而低海拔的常绿阔叶林和针叶林中轻组碳的含量高于亚高山矮林和高山草甸的轻组碳的含量。各土壤活性有机碳库均随土层的加深而减小。除轻组碳外,各碳库间存在着极显著的正相关(p【0.001)。轻组碳分别在低海拔(常绿阔叶林和针叶林)和高海拔(亚高山矮林和高山草甸)与各碳库显著相关。

Biostratigraphy and geography of the Ordovician-Silurian Lungmachi black shales in South China

Based on the new material of seven Ordovician-Silurian boundary sections investigated recently, together with previously published data, we analyze the temporal and spatial distributions of the Lungmachi black shales, a key petroleum source bed widely distributed in South China. The Lungmachi black shales range in age from the Normalograptus persculptus Biozone of the uppermost Ordovician to the Spirograptus guerichi Biozone of the lower Telychian, and ten graptolite biozones can be recognized within this unit. The basal and upper contacts of the Lungmachi black shales are diachronous. The basal contact ranges from the N. persculptus to the C. cyphus biozones, a span of five graptolite biozones over two stages. The upper contact ranges from the D. pectinatus-M. argenteus Biozone to the Spirograptus guerichi Biozone, which spans four graptolite biozones over two stages. The Yichang Uplift resulted in the formation of the Hunan-Hubei Submarine High in the border area of Hubei, Hunan, and Chongqing. This is supported by a break in sedimentation in this area spanning all or part of the Hirnantian, and in many areas extending into the underlying Katian and overlying Rhuddanian. Comparison of the distribution of the Katian to Rhuddanian strata in this area indicates a growth and subsequent reduction in area of the Hunan-Hubei Submarine High particularly in the Hirnantian to early Rhuddanian. This may partly represent the influence of the process of formation and melting of ice sheet in Ordovician South Pole and consequent sea level change.

Analysis of internal tidal characteristics in the layer above 450 m from acoustic Doppler current profiler observations in the Luzon Strait

The characteristics of internal tides in the upper layer of the Luzon Strait are investigated on the basis of direct-observation current data recorded on April 25 and September 26, 2008 by an acoustic Doppler current profiler. Spectral analysis and energy estimation show that the diurnals and semidiurnals carry most of the energy of internal tides. Values of the depth-integrated total energy E for the three frequency bands of diurnal, semidiurnal, and high frequencies are 31, 6.9, and 3.4 kJ. m, respectively. Near-inertial peaks are only present in the baroclinic component. The behavior of typical tidal frequencies （i.e., O1, K1, M2, MK3, and M4） and the near-inertial frequency is basically consistent with linear internal wave theory, which predicts E＋（ω）/E_（ω）=（ω-f）2/（ω＋f）2 at depths above 66 m, while not all prominent tidal components coincide well with the relation of the linear internal wave field at other depths. Examinations of depth structures of the baroclinic tides and temporal variations show that the surface tides and internal tides are both of mixed type, having diurnal inequality and spring-neap fortnight periods. The K1 and O1 tides have comparable cross- and along-shelf components, while the M2 and S2 tides propagate toward the shelf in the northern South China Sea as wave beams. The amplitude and phase of internal tides vary with time, but M2 and S2 tides appear to have structures dominated by the first mode, while the K1 and O1 tides resemble second-mode structures. The minor to major axis ratios are close to expected values of flω in the thermocline.

Chemistry of daytime HOx radicals in marine boundary layer in the sea of Japan:Based on the ratio between the reactivity of HC and NOx

The ratio between the reactivity of HC and NOx, i.e., φ = ∑kOH＋HC, [HCi] / （kOH＋No[NO] ＋ kOH＋NO2 [NO2]）, is used to study the chemistry of HOx radicals （HOE and OH） in the marine boundary layer （MBL）. Data analysis shows that HOx production and OH/HO2 ratio strongly depend on φ. The OH radical concentration presents an ascending tendency in low φ region but a de- clining one in high ∞ region, while HO2 radical increases with increasing φ under low φ conditions but appears to be nearly constant with the variation of ∞ under high φ conditions. The observed OH/HO2 ratio shows a continuous decrease with the increase of φ. Model studies are conducted to illuminate the behavior of HOx radicals in different φ regions, and the results represent general agreement with the observed variations of HOx radicals and can well explain the observed behavior of HOx radicals. This study demonstrates that φ could be used as an efficient parameter to ascertain the behavior of HOx radicals in the clean marine boundary layer.

Sea surface temperature evolution in the western South China Sea since MIS 12 as evidenced by planktonic foraminiferal assemblages and Globigerinoides ruber Mg/Ca ratio

Based on the detailed planktonic foraminifera faunal count and Globigerinoides ruber Mg/Ca ratio analysis of Core MD05-2901,we reconstructed the longest Mg/Ca sea surface temperature(SST) sequence of the upwelling area off Vietnam in the western South China Sea(SCS).Ocean environment,especially the SST variation,over the last 450 ka is discussed in this study.SST variation has typical glacial/interglacial alternations from 23.03°C to 29.93°C with a glacial/interglacial difference of 4.8°C on average.SST during the interglacial periods fluctuates significantly,up to 5.6°C,which is larger than the average glacial/interglacial difference.SST variation during the glacial periods is much smaller.Spectrum analysis shows that SST change dominates on the typical Milankovitch cycles,such as 112,40.7 and 23.6 ka.Evident leading of SST variation against the δ 18 O can be observed during the Terminations 1,4,and 5,which is confirmed by their cross-spectrum analysis on these cycles.MD05-2901 is the first core in the South China Sea that has multi-SST records,such as SST Mg/Ca,k' 37 U-SST and planktonic foraminiferal fauna-based SST.SSTs from different methods can be correlated with each other in glacial/interglacial time scale,whereas SST Mg/Ca records abrupt climate change events more clearly.SST Mg/Ca at MD05-2901 since MIS 5 is 0.6°C lower than that of the southern SCS on average,but equivalent to or even 2°C lower than that of the northern SCS during some interglacial period.The SST character of MD05-2901 reflects less influence of latitude,but an important role of the regional upwelling driven by the eastern Asian summer monsoon,and suggests a stronger upwelling during the interglacial periods in the western SCS.

Impacts of boundary layer parameterization schemes and air-sea coupling on WRF simulation of the East Asian summer monsoon

The planetary boundary layer （PBL） scheme in the regional climate model （RCM） has a significant impact on the interactions and exchanges of moisture, momentum, and energy between land, ocean, and atmosphere; however, its uncertainty will cause large systematic biases of RCM. Based on the four different PBL schemes （YSU, ACM2, Boulac, and MYJ） in Weather Research and Forecasting （WRF） model, the impacts of these schemes on the simulation of circulation and precipitation during the East Asian summer monsoon （EASM） are investigated. The simulated results of the two local turbulent kinetic energy （TKE） schemes, Boulac and MYJ, are more consistent with the observations than those in the two nonlocal closure schemes, YSU and ACM2. The former simulate more reasonable low-level southwesterly flow over East China and west pacific subtropical high （WPSH） than the latter. As to the modeling of summer monsoon precipitation, both the spatial distributions and temporal evolutions from Boulac and MTT are also better than those in YSU and ACM2 schemes. In addition, through the comparison between YSU and Boulac experiments, the differences from the results of EASM simulation are more obvious over the oceanic area. In the experiments with the nonlocal schemes YSU and ACM2, the boundary layer mixing processes are much stronger, which lead to produce more sea surface latent heat flux and enhanced convection, and finally induce the overestimated precipitation and corresponding deviation of monsoon circulation. With the further study, it is found that the absence of air-sea interaction in WRF may amplify the biases caused by PBL scheme over the ocean. Consequently, there is a reduced latent heat flux over the sea surface and even more reasonable EASM simulation, if an ocean model coupled into WRF.

Holocene delta evolution and sequence stratigraphy of the Pearl River Delta in South China

We analyzed the sedimentary characteristics and chronostratigraphy of the Pearl River Delta in South China, and discussed the Holocene stratigraphic characteristics and the filling process since the Holocene, based on 90 boreholes. Our results showed that the maximum transgressive surface of the Pearl River Delta was located in the soft marine silt horizons, whereas it was shown as an erosion surface in areas with tidal scour. From bottom to top, Holocene sedimentary sequences were fluvial facies, floodplain-estuary facies, and estuary-delta facies in the paleo-valley, while the paleo-interfluve sequences were described as littoral facies, estuary facies, and delta facies. Vertical accumulation sequences of Holocene sediments were shown primarily as positive tapering-shaped sequences with no typical foreset, topset, or other sedimentary sequences of the Gilbert Delta. The paleo-Pearl River estuary had different evolution models in the highstand systems tract (HST) compared with other large deltas worldwide, in that it is dominated by a unique and complex geomorphologic boundary, and that it is a multi-sourced delta compounded by the independent and parallel development of fluvial sedimentary bodies with different scales. A huge estuary was formed in the present Pearl River Delta area when the post-glacial transgression reached maximum at about 6 ka BP. The estuary was divided into two parts by obstruction of a series of islands, an upper part composed of the semi-enclosed inner paleo-bay connected to rivers and a lower part consisting of the outer paleo-bay connected to the ocean. Both of these areas were interlinked by only a few narrows, in which the fluvial sediments are accumulated primarily in the inner paleo-bay. During 6-2 ka BP, the sedimentation in various regions of the inner paleo-bay occurred simultaneously with independent development under the remodeling and transformation effect of complex boundaries on river and ocean dynamics. After 2 ka BP, the evolution of the delta is no longer a simple natural process, but rather a common remodeling process accomplished by nature and humans.