In order to protect C/C composites from oxidation, SiC-MoSi2 composite coating was synthesized by chemical vapor infiltration /reaction （CVI/CVR） technology. A porous Mo layer was prefabricated on SiC coated C/C com...In order to protect C/C composites from oxidation, SiC-MoSi2 composite coating was synthesized by chemical vapor infiltration /reaction （CVI/CVR） technology. A porous Mo layer was prefabricated on SiC coated C/C composites, and then MoSi2 and SiC were subsequently prepared in a CVI /CVR process using methyltrichlorosilane （MTS） as precursor. The deposition and reaction mechanism of the MoSi2-SiC composite coating was investigated by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The oxidation behavior of SiC-MoSi2 coated specimens was tested. The results show that the porous Mo layer can be densified with SiC phase decomposed from MTS, and transformed into SiC-MoSi2 by reacting with MTS as well. A dense composite coating was prepared with optimized deposition parameters. The coated specimen exhibits a good oxidation resistance with a little mass loss of 1.25% after oxidation at 1500 °C for 80 h.展开更多
Lewis acidic 1-allyl-3-methylimidazolium chloroaluminate ionic liquids were used as promising elec-trolytes in the low-temperature electrodeposition of aluminium.Systematic studies on deposition process have been perf...Lewis acidic 1-allyl-3-methylimidazolium chloroaluminate ionic liquids were used as promising elec-trolytes in the low-temperature electrodeposition of aluminium.Systematic studies on deposition process have been performed by cyclic voltammetry and chronoamperometry.The surface morphology and X-ray diffraction(XRD) patterns of deposits prepared at different experimental conditions were also investigated.It was shown that the nu-cleation density and growth rate of crystallites had a great effect on the structure of aluminium deposited.The crys-tallographic orientation of deposits was mainly influenced by temperature and current density.Smooth,dense and well adherent aluminium coatings were obtained on copper substrates at 10-25 mA?cm?2 and 313.2-353.2 K.More-over,the current efficiency of deposition and purity of aluminium have been significantly improved,demonstrating that the ionic liquids tested have a prospectful potential in electroplating and electrorefining of aluminium.展开更多
The Andaman and Nicobar Islands are one of the Union Territories of India, located in the eastern part of the Bay of Bengal. In 2010 summer, the increment in sea surface water temperature （up to 34℃） resulted in th...The Andaman and Nicobar Islands are one of the Union Territories of India, located in the eastern part of the Bay of Bengal. In 2010 summer, the increment in sea surface water temperature （up to 34℃） resulted in the bleaching of about 74% to 77% of corals in the South Andaman. During this event, coral species such as Acropora cerealis, A. humilis, Montipora sp., Favia paIlida, Diploastrea sp., Goniopora sp. Fungia concinna, Gardineroseries sp., Porites sp., Favites abdita and Lobophyllia robusta were severely affected. This study is to assess the recovery status of the reef ecosystem by estimating the percentage of Live Coral cover, Bleached coral cover, Dead coral with algae, Rubble, Sandy fiat, Algal assemblage and other associated organisms, The sedimentation rate （mg cm^-2 d^-1） and coral coverage （%） were assessed during this study period. The average sedimentation rate was ranged between 0.27 and 0.89 mg cm^-2 d^1. The observed post bleaching recovery of coral cover was 21.1% at Port Blair Bay and 13.29% at Havelock Island. The mortality rate of coral cover due to this bleaching was estimated as 2.05% at Port Blair Bay and 9.82% at Havelock Island. Once the sea water temperature resumed back to the normal condition, most of the corals were found recovered.展开更多
The most critical disadvantages of the Zn-air flow battery system are corrosion of the zinc, which appears as a high self-discharge current density and a short cycle life due to the non-uniform, dendritic, zinc electr...The most critical disadvantages of the Zn-air flow battery system are corrosion of the zinc, which appears as a high self-discharge current density and a short cycle life due to the non-uniform, dendritic, zinc electrodeposition that can lead to internal short-circuit. In our efforts to find a dendrite-free Zn electrodeposition which can be utilized in the Zn-air flow battery, the surface morphology of the electrolytic Zn deposits on a polished polymer carbon composite anode in alkaline, additive-free solutions was studied. Experiments were carried out with 0.1 M, 0.2 M and 0.5 M zincate concentrations in 8 M KOH. The effects of different working conditions such as： elevated temperatures, different current densities and different flow velocities, on current efficiency and dendrite formation were investigated. Specially designed test flow-cell with a central transparent window was employed. The highest Coulombic efficiencies of 80%-93% were found for 0.5 M ZnO in 8 M KOH, at increased temperatures （50-70 ℃）, current densities of up to 100 mA.cm2 and linear electrolyte flow velocities higher than 6.7 cm.s1.展开更多
Based on satellite data and the estimated inversion strength(EIS) derived by Wood et al.(2006), a feasible and uncomplicated stratocumulus scheme is proposed, referred to as EIS scheme. It improves simulation of cloud...Based on satellite data and the estimated inversion strength(EIS) derived by Wood et al.(2006), a feasible and uncomplicated stratocumulus scheme is proposed, referred to as EIS scheme. It improves simulation of cloud radiative forcing(CRF) in the Grid-point Atmospheric Model of IAP/LASG version 2(GAMIL2.0) model. When compared with the original lower troposphere stability(LTS) scheme, the EIS scheme reproduces more reasonable climatology distributions of clouds and CRF. The parameterization partly corrects CRF underestimation at mid and high latitudes and overestimation in the convective region. Such improvements are achieved by neglecting the effect of free-tropospheric stratification changes that follow a cooler moist adiabat at middle and high latitude, thereby improving simulated cloudiness. The EIS scheme also improves simulation of the CRF interannual variability. The positive net CRF and negative stratiform anomaly in the East Asian and western North Pacific monsoon regions(EAWNPMR) are well simulated. The EIS scheme is more sensitive to sea surface temperature anomalies(SSTA) than the LTS. Therefore, under the effect of a warmer SSTA in the EAWNPMR, the EIS generates a stronger negative stratiform response, which reduces radiative heating in the low and mid troposphere, in turn producing strong subsidence and negative anomalies of both moisture and cloudiness. Consequent decreases in cloud reflection and shading effects ultimately improve simulation of incoming surface shortwave radiative fluxes and CRF. Because of the stronger subsidence, a stronger anomalous anticyclone over the Philippines Sea is simulated by the EIS run, which leads to a better positive precipitation anomaly in eastern China during ENSO winter.展开更多
基金Projects(51221001,51272213,51072166)supported by the National Natural Science Foundation of ChinaProject(GBKY1021)supported by the Fundamental Research Foundation of Northwestern Polytechnical University,ChinaProject(B08040)supported by Program of Introducing Talents of Discipline to Universities,China
文摘In order to protect C/C composites from oxidation, SiC-MoSi2 composite coating was synthesized by chemical vapor infiltration /reaction （CVI/CVR） technology. A porous Mo layer was prefabricated on SiC coated C/C composites, and then MoSi2 and SiC were subsequently prepared in a CVI /CVR process using methyltrichlorosilane （MTS） as precursor. The deposition and reaction mechanism of the MoSi2-SiC composite coating was investigated by X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The oxidation behavior of SiC-MoSi2 coated specimens was tested. The results show that the porous Mo layer can be densified with SiC phase decomposed from MTS, and transformed into SiC-MoSi2 by reacting with MTS as well. A dense composite coating was prepared with optimized deposition parameters. The coated specimen exhibits a good oxidation resistance with a little mass loss of 1.25% after oxidation at 1500 °C for 80 h.
基金Supported by the National Basic Research Program of China (2009CB219901)the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (2012BAF03B01)+1 种基金the National Natural Science Foundation of China (20906096,20873152)the Open-end Fund of State Key Laboratory of Multiphase Complex Systems (MPCS-2011-D-06)
文摘Lewis acidic 1-allyl-3-methylimidazolium chloroaluminate ionic liquids were used as promising elec-trolytes in the low-temperature electrodeposition of aluminium.Systematic studies on deposition process have been performed by cyclic voltammetry and chronoamperometry.The surface morphology and X-ray diffraction(XRD) patterns of deposits prepared at different experimental conditions were also investigated.It was shown that the nu-cleation density and growth rate of crystallites had a great effect on the structure of aluminium deposited.The crys-tallographic orientation of deposits was mainly influenced by temperature and current density.Smooth,dense and well adherent aluminium coatings were obtained on copper substrates at 10-25 mA?cm?2 and 313.2-353.2 K.More-over,the current efficiency of deposition and purity of aluminium have been significantly improved,demonstrating that the ionic liquids tested have a prospectful potential in electroplating and electrorefining of aluminium.
文摘The Andaman and Nicobar Islands are one of the Union Territories of India, located in the eastern part of the Bay of Bengal. In 2010 summer, the increment in sea surface water temperature （up to 34℃） resulted in the bleaching of about 74% to 77% of corals in the South Andaman. During this event, coral species such as Acropora cerealis, A. humilis, Montipora sp., Favia paIlida, Diploastrea sp., Goniopora sp. Fungia concinna, Gardineroseries sp., Porites sp., Favites abdita and Lobophyllia robusta were severely affected. This study is to assess the recovery status of the reef ecosystem by estimating the percentage of Live Coral cover, Bleached coral cover, Dead coral with algae, Rubble, Sandy fiat, Algal assemblage and other associated organisms, The sedimentation rate （mg cm^-2 d^-1） and coral coverage （%） were assessed during this study period. The average sedimentation rate was ranged between 0.27 and 0.89 mg cm^-2 d^1. The observed post bleaching recovery of coral cover was 21.1% at Port Blair Bay and 13.29% at Havelock Island. The mortality rate of coral cover due to this bleaching was estimated as 2.05% at Port Blair Bay and 9.82% at Havelock Island. Once the sea water temperature resumed back to the normal condition, most of the corals were found recovered.
文摘The most critical disadvantages of the Zn-air flow battery system are corrosion of the zinc, which appears as a high self-discharge current density and a short cycle life due to the non-uniform, dendritic, zinc electrodeposition that can lead to internal short-circuit. In our efforts to find a dendrite-free Zn electrodeposition which can be utilized in the Zn-air flow battery, the surface morphology of the electrolytic Zn deposits on a polished polymer carbon composite anode in alkaline, additive-free solutions was studied. Experiments were carried out with 0.1 M, 0.2 M and 0.5 M zincate concentrations in 8 M KOH. The effects of different working conditions such as： elevated temperatures, different current densities and different flow velocities, on current efficiency and dendrite formation were investigated. Specially designed test flow-cell with a central transparent window was employed. The highest Coulombic efficiencies of 80%-93% were found for 0.5 M ZnO in 8 M KOH, at increased temperatures （50-70 ℃）, current densities of up to 100 mA.cm2 and linear electrolyte flow velocities higher than 6.7 cm.s1.
基金supported by the National Natural Science Foundation of China(Grant No.41125017)the National Basic Research Program of China(Grant No.2010CB951904)
文摘Based on satellite data and the estimated inversion strength(EIS) derived by Wood et al.(2006), a feasible and uncomplicated stratocumulus scheme is proposed, referred to as EIS scheme. It improves simulation of cloud radiative forcing(CRF) in the Grid-point Atmospheric Model of IAP/LASG version 2(GAMIL2.0) model. When compared with the original lower troposphere stability(LTS) scheme, the EIS scheme reproduces more reasonable climatology distributions of clouds and CRF. The parameterization partly corrects CRF underestimation at mid and high latitudes and overestimation in the convective region. Such improvements are achieved by neglecting the effect of free-tropospheric stratification changes that follow a cooler moist adiabat at middle and high latitude, thereby improving simulated cloudiness. The EIS scheme also improves simulation of the CRF interannual variability. The positive net CRF and negative stratiform anomaly in the East Asian and western North Pacific monsoon regions(EAWNPMR) are well simulated. The EIS scheme is more sensitive to sea surface temperature anomalies(SSTA) than the LTS. Therefore, under the effect of a warmer SSTA in the EAWNPMR, the EIS generates a stronger negative stratiform response, which reduces radiative heating in the low and mid troposphere, in turn producing strong subsidence and negative anomalies of both moisture and cloudiness. Consequent decreases in cloud reflection and shading effects ultimately improve simulation of incoming surface shortwave radiative fluxes and CRF. Because of the stronger subsidence, a stronger anomalous anticyclone over the Philippines Sea is simulated by the EIS run, which leads to a better positive precipitation anomaly in eastern China during ENSO winter.
