金属增材与层间强化复合制造研究进展

采用增材制造与层间强化工艺结合的复合制造方式,对增材制造零件的关键位置选择性地进行强化处理,能改善零件表层区域的表面质量、微观结构以及残余应力分布,提升增材制造构件的整体力学性能。本文首先介绍了不同的金属强化工艺,综述了增材制造与层间强化的复合制造技术对金属材料的微观结构、孔隙、残余应力和力学性能的影响,最后,展望了增材与层间强化复合制造技术的发展方向。

基于激光原位预热的连续纤维增材制造层间强化机理研究

连续纤维复合材料增材制造具有成形自由度高、材料利用率高、模具依赖度低等优点,能够实现复合材料的快速低成本一体化制造,满足航空航天等领域复材构件短周期高性能的成形需求。但基于层层堆积成形原理的连续纤维复合材料制件层间性能较差,在长期使役过程中极易出现分层失效,严重限制其广泛应用。本研究提出了基于激光原位预热的连续纤维增材制造成形方法,通过建立基于“生死单元”技术的有限元仿真模型,揭示了激光预热对增材制造成形温度分布及其演变规律,并通过实验验证了其对改善成形制件层间性能的有效性,最终获得了激光预热的层间强化机理。结果表明,激光预热能够快速加热样件表面温度,促进层间树脂的熔合粘接,并进一步促进成形丝材的重熔浸渍,相较于未经预热样件,激光预热后层间剪切强度最大提升115%。

Experimental investigation of vibration pretreatment-microwave curing process for carbon fiber reinforced resin matrix composites

The vibration pretreatment-microwave curing process is an efficient,low energy consumption,and high-quality out-of-autoclave curing process for carbon fiber resin matrix composites.This study aims to investigate the impact of vibration pretreatment temperature on the fiber weight content,microscopic morphology and mechanical properties of the composite laminates by using optical digital microscopy,universal tensile testing machine and thermo-gravimetric analyzer.Additionally,the combined mode of Bragg fiber grating sensor and temperature measurement fiber was employed to explore the effect of vibration pretreatment on the strain process during microwave curing.The study results revealed that the change in vibration pretreatment temperature had a slight impact on the fiber weight content when the vibration acceleration remained constant.The metallographic and interlaminar strength of the specimen formed at a vibration pretreatment temperature of 80℃ demonstrated a porosity of 0.414% and a 10.69% decrease in interlaminar shear strength compared to autoclave curing.Moreover,the introduction of the vibration energy field during the microwave curing process led to a significant reduction in residual strain in both the 0°and 90°fiber directions,when the laminate was cooled to 60℃.

Effect of Mo and ZrO_(2)nanoparticles addition on interfacial properties and shear strength of Sn58Bi/Cu solder joint

The influence of Mo and ZrO_(2)nanoparticles addition on the interfacial properties and shear strength of Sn58Bi solder joint was investigated.The interfacial microstructures of Sn58Bi/Cu,Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints were analysed using a scanning electron microscope(SEM)coupled with energy dispersive X-ray(EDX)and the X-ray diffraction(XRD).Intermetallic compounds(IMCs)of MoSn_(2)are detected in the Sn58Bi+Mo/Cu solder joint,while SnZr,Zr_(5)Sn_(3),ZrCu and ZrSn_(2)are detected in Sn58Bi+ZrO_(2)/Cu solder joint.IMC layers for both composite solders comprise of Cu_(6)Sn_(5) and Cu_(3)Sn.The SEM images of these layers were used to measure the IMC layer’s thickness.The average IMC layer’s thickness is 1.4431μm for Sn58Bi+Mo/Cu and 0.9112μm for Sn58Bi+ZrO_(2)/Cu solder joints.Shear strength of the solder joints was investigated via the single shear lap test method.The average maximum load and shear stress of the Sn58Bi+Mo/Cu and Sn58Bi+ZrO_(2)/Cu solder joints are increased by 33%and 69%,respectively,as compared to those of the Sn58Bi/Cu solder joint.By comparing both composite solder joints,the latter prevails better as adding smaller sized ZrO_(2)nanoparticles improves the interfacial properties granting a stronger solder joint.

Effect of SnO_2 intermediate layer on performance of Ti/SnO_2/MnO_2 electrode during electrolytic-manganese process

SnO2intermediate layers were coated on the titanium(Ti)substrate by thermal decomposition.Scanning electronmicroscope(SEM)and X-ray diffraction(XRD)results show that uniform SnO2intermediate layers with rutile crystal structure weresuccessfully achieved.According to the results of linear sweep voltammetry(LSV),oxygen evolution potential(OEP)of theTi/SnO2/MnO2electrodes decreases with increasing SnO2content,indicating that the electro-catalytic oxidation activity of theelectrode increases.Accelerated service life tests results demonstrate that SnO2intermediate layer can improve the service life of theTi/SnO2/MnO2electrode.As the content of SnO2intermediate layer increases,the cell voltage and the energy consumption decreaseapparently.

Corrosion damage evolution and mechanical properties of carbon fiber reinforced aluminum laminate

Fiber metal laminates(FMLs),a kind of lightweight material with excellent comprehensive performance,have been successfully applied in aerospace.FMLs reinforced with carbon fiber have better mechanical properties than those with glass or aramid fiber.However,carbon fiber binding metal may lead to galvanic corrosion which limits its application.In this paper,electrochemical methods,optical microscope and scanning electron microscope were used to analyze the corrosion evolution of carbon fiber reinforced aluminum laminate(CARALL)in corrosive environment and explore anti-corrosion ways to protect CARALL.The results show that the connection between carbon fiber and aluminum alloy changes electric potential,causing galvanic corrosion.The galvanic corrosion will obviously accelerate CARALL corroded in solution,leading to a 72.1%decrease in interlaminar shear strength,and the crevice corrosion has a greater impact on CARALL resulting in delamination.The reduction of interlaminar shear strength has a similar linear relationship with the corrosion time.In addition,the adhesive layers between carbon fiber and aluminum alloy cannot protect CARALL,while side edge protection can effectively slow down corrosion rate.Therefore,the exposed edges should be coated with anti-corrosion painting.CARALL has the potential to be used for aerospace components.