Switchable ionic compounds have wide applications in chemical processes.A switchable ionic compound based on 1,8-diazabicyclo-[5.4.0]-undec-7-ene(DBU),CH_3OH and CO_2 was synthesized and characterized.DBU/CH_3OH/CO_2 ...Switchable ionic compounds have wide applications in chemical processes.A switchable ionic compound based on 1,8-diazabicyclo-[5.4.0]-undec-7-ene(DBU),CH_3OH and CO_2 was synthesized and characterized.DBU/CH_3OH/CO_2 ionic compound was prepared in the presence of excess methanol,and then the excess methanol was removed by reduced pressure distillation in CO_2 atmosphere.The product yield(100%) reached the theoretical maximum for the first time.Its structure was identified by NMR,FT-IR,and XRD.The crystal product shows 8strong peaks in XRD at 2θ values of 16.0547°,16.4308°,16.7651°,18.8714°,19.2140°,21.9471°,22.0780°,and25.5661°.Its decomposition onset temperature(53 ℃) was affirmed by TGA,which is lower than its melting point.And its ionic switch point was measured by conductivity.展开更多
A comprehensive appraisal is performed on the newly bred of 28 hybrid middle-season rice combinations, with Yangliangyou 6 as a control, a total of 29 combinations, in terms of high and stable yield, adaptability and ...A comprehensive appraisal is performed on the newly bred of 28 hybrid middle-season rice combinations, with Yangliangyou 6 as a control, a total of 29 combinations, in terms of high and stable yield, adaptability and disease resistance. Two-line hybrid combinations have a total of 24, accounting for 82.76% of the exhibition, but there were only 5 three-line hybrid combinations have accounting for 17.24% of the exhibition. There are 13 high-quality two-line cross combinations, representing 54.17% of the two-line hybrid combinations. In the 8 hybrid combinations, whose yield per unit area is more than that of the control, 7 are two-line hybrid combinations, and the last one is the three-line hybrid combination. There are 15 two-line hybrid combinations with whole growth period 10 d shorter than Yangliangyou 6.展开更多
The purpose of this study is to explore the urban morphological aspects of cities governed by the juridical regime of emphyteusis, a recurrent situation in the northeastern part of the state of Silo Paulo, Brazil, wit...The purpose of this study is to explore the urban morphological aspects of cities governed by the juridical regime of emphyteusis, a recurrent situation in the northeastern part of the state of Silo Paulo, Brazil, with special attention to the city of Ribeirao Preto. The concession of lands to the Catholic Church was a recurring practice in Brazil during the colonial and imperial periods, when the cities were being established. As these lands were intended for the formation of patrimonial goods to show the devotion of the residents to a Catholic saint, the lands were not allowed to be commercialized. The tenure reveals a relation in which there is an owner--the landlord--who has direct control of the urban land. This owner allows another--the leaseholder--the useful domain of the land, thus giving the latter the right to use the land, the obligation to pay an annual tax and the responsibility to give the owner a percentage of the sales generated from the land. In 1845, farmers donated a tract of land to be used to glorify Silo Sebastiao. This land is now the city of Ribeirao Preto, and it is this conjuncture that defined the structure and the transformation of the original urban form of the current city.展开更多
基金Supported by the Doctoral Fund of Ministry of Education of China(20130181130006)the Key Program of National Natural Science Foundation of China(21336008)the National Natural Science Foundation of China(21476150)
文摘Switchable ionic compounds have wide applications in chemical processes.A switchable ionic compound based on 1,8-diazabicyclo-[5.4.0]-undec-7-ene(DBU),CH_3OH and CO_2 was synthesized and characterized.DBU/CH_3OH/CO_2 ionic compound was prepared in the presence of excess methanol,and then the excess methanol was removed by reduced pressure distillation in CO_2 atmosphere.The product yield(100%) reached the theoretical maximum for the first time.Its structure was identified by NMR,FT-IR,and XRD.The crystal product shows 8strong peaks in XRD at 2θ values of 16.0547°,16.4308°,16.7651°,18.8714°,19.2140°,21.9471°,22.0780°,and25.5661°.Its decomposition onset temperature(53 ℃) was affirmed by TGA,which is lower than its melting point.And its ionic switch point was measured by conductivity.
基金Supported by Wuhan Experimental Station of National Rice Industry Technology System(CARS-01-63)Hubei Key Research and Development Technology Program(2014ABA021)National Agricultural Science Technology Achievement Transformation Fund(2014GB2D100579)~~
文摘A comprehensive appraisal is performed on the newly bred of 28 hybrid middle-season rice combinations, with Yangliangyou 6 as a control, a total of 29 combinations, in terms of high and stable yield, adaptability and disease resistance. Two-line hybrid combinations have a total of 24, accounting for 82.76% of the exhibition, but there were only 5 three-line hybrid combinations have accounting for 17.24% of the exhibition. There are 13 high-quality two-line cross combinations, representing 54.17% of the two-line hybrid combinations. In the 8 hybrid combinations, whose yield per unit area is more than that of the control, 7 are two-line hybrid combinations, and the last one is the three-line hybrid combination. There are 15 two-line hybrid combinations with whole growth period 10 d shorter than Yangliangyou 6.
文摘The purpose of this study is to explore the urban morphological aspects of cities governed by the juridical regime of emphyteusis, a recurrent situation in the northeastern part of the state of Silo Paulo, Brazil, with special attention to the city of Ribeirao Preto. The concession of lands to the Catholic Church was a recurring practice in Brazil during the colonial and imperial periods, when the cities were being established. As these lands were intended for the formation of patrimonial goods to show the devotion of the residents to a Catholic saint, the lands were not allowed to be commercialized. The tenure reveals a relation in which there is an owner--the landlord--who has direct control of the urban land. This owner allows another--the leaseholder--the useful domain of the land, thus giving the latter the right to use the land, the obligation to pay an annual tax and the responsibility to give the owner a percentage of the sales generated from the land. In 1845, farmers donated a tract of land to be used to glorify Silo Sebastiao. This land is now the city of Ribeirao Preto, and it is this conjuncture that defined the structure and the transformation of the original urban form of the current city.